Exotic atom

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An exotic atom is an otherwise normal atom in which one or more sub-atomic particles have been replaced by other particles of the same charge. For example, electrons may be replaced by other negatively charged particles such as muons (muonic atoms) or pions (pionic atoms). [1] [2] Because these substitute particles are usually unstable, exotic atoms typically have very short lifetimes and no exotic atom observed so far can persist under normal conditions.

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Muonic atoms

Muonic helium, made out of 2 protons, 2 neutrons, 1 muon and 1 electron. Hydrogen-4.1.svg
Muonic helium, made out of 2 protons, 2 neutrons, 1 muon and 1 electron.

In a muonic atom (previously called a mu-mesic atom, now known to be a misnomer as muons are not mesons), [3] an electron is replaced by a muon, which, like the electron, is a lepton. Since leptons are only sensitive to weak, electromagnetic and gravitational forces, muonic atoms are governed to very high precision by the electromagnetic interaction.

Since a muon is more massive than an electron, the Bohr orbits are closer to the nucleus in a muonic atom than in an ordinary atom, and corrections due to quantum electrodynamics are more important. Study of muonic atoms' energy levels as well as transition rates from excited states to the ground state therefore provide experimental tests of quantum electrodynamics.

Muon-catalyzed fusion is a technical application of muonic atoms.

Other muonic atoms can be formed when negative muons interact with ordinary matter. [4] The muon in muonic atoms can either decay or get captured by a proton. Muon capture is much important in heavier muonic atoms, thus shorten the muon's lifetime from 2.2 μs to only 0.08 μs. [4]

Muonic hydrogen

Muonic hydrogen is like normal hydrogen with the electron replaced by a negative muon—that is a proton orbited by a muon. It is important in addressing the proton radius puzzle.

Muonic helium (Hydrogen-4.1)

The symbol 4.1H (Hydrogen-4.1) has been used to describe the exotic atom muonic helium (4He-μ), which is like helium-4 in having two protons and two neutrons. [5] However one of its electrons is replaced by a muon, which also has charge –1. Because the muon's orbital radius is less than 1/200th the electron's orbital radius (due to the mass ratio), the muon can be considered as a part of the nucleus. The atom then has a nucleus with two protons, two neutrons and one muon, with total nuclear charge +1 (from two protons and one muon) and only one electron outside, so that it is effectively an isotope of hydrogen instead of an isotope of helium. A muon's weight is approximately 0.1 Da so the isotopic mass is 4.1. Since there is only one electron outside the nucleus, the hydrogen-4.1 atom can react with other atoms. Its chemical behavior behaves more like a hydrogen atom than an inert helium atom. [5] [6] [7]

Hadronic atoms

A hadronic atom is an atom in which one or more of the orbital electrons are replaced by a negatively charged hadron. [8] Possible hadrons include mesons such as the pion or kaon, yielding a pionic atom [9] or a kaonic atom (see Kaonic hydrogen), collectively called mesonic atoms; antiprotons, yielding an antiprotonic atom; and the
Σ
particle, yielding a
Σ
or sigmaonic atom. [10] [11] [12]

Unlike leptons, hadrons can interact via the strong force, so the orbitals of hadronic atoms are influenced by nuclear forces between the nucleus and the hadron. Since the strong force is a short-range interaction, these effects are strongest if the atomic orbital involved is close to the nucleus, when the energy levels involved may broaden or disappear because of the absorption of the hadron by the nucleus. [2] [11] Hadronic atoms, such as pionic hydrogen and kaonic hydrogen, thus provide experimental probes of the theory of strong interactions, quantum chromodynamics. [13]

Onium

An onium (plural: onia) is the bound state of a particle and its antiparticle. The classic onium is positronium, which consists of an electron and a positron bound together as a metastable state, with a relatively long lifetime of 142 ns in the triplet state. [14] Positronium has been studied since the 1950s to understand bound states in quantum field theory. A recent development called non-relativistic quantum electrodynamics (NRQED) used this system as a proving ground.

Pionium, a bound state of two oppositely charged pions, is useful for exploring the strong interaction. This should also be true of protonium, which is a proton–antiproton bound state. Understanding bound states of pionium and protonium is important in order to clarify notions related to exotic hadrons such as mesonic molecules and pentaquark states. Kaonium, which is a bound state of two oppositely charged kaons, has not been observed experimentally yet.

The true analogs of positronium in the theory of strong interactions, however, are not exotic atoms but certain mesons, the quarkonium states, which are made of a heavy quark such as the charm or bottom quark and its antiquark. (Top quarks are so heavy that they decay through the weak force before they can form bound states.) Exploration of these states through non-relativistic quantum chromodynamics (NRQCD) and lattice QCD are increasingly important tests of quantum chromodynamics.

Muonium, despite its name, is not an onium state containing a muon and an antimuon, because IUPAC assigned that name to the system of an antimuon bound with an electron. However, the production of a muon–antimuon bound state, which is an onium (called true muonium), has been theorized. [15] The same applies to the ditauonium (or "true tauonium") exotic QED atom. [16]

Hypernuclear atoms

Atoms may be composed of electrons orbiting a hypernucleus that includes strange particles called hyperons. Such hypernuclear atoms are generally studied for their nuclear behaviour, falling into the realm of nuclear physics rather than atomic physics.

Quasiparticle atoms

In condensed matter systems, specifically in some semiconductors, there are states called excitons, which are bound states of an electron and an electron hole.

Exotic molecules

An exotic molecule contains one or more exotic atoms.

"Exotic molecule" can also refer to a molecule having some other uncommon property such as a pyramidal hexamethylbenzene#Dication and a Rydberg atom.

See also

Related Research Articles

<span class="mw-page-title-main">Fermion</span> Type of subatomic particle

In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Fermions have a half-odd-integer spin and obey the Pauli exclusion principle. These particles include all quarks and leptons and all composite particles made of an odd number of these, such as all baryons and many atoms and nuclei. Fermions differ from bosons, which obey Bose–Einstein statistics.

<span class="mw-page-title-main">Hadron</span> Composite subatomic particle

In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules, which are held together by the electric force. Most of the mass of ordinary matter comes from two hadrons: the proton and the neutron, while most of the mass of the protons and neutrons is in turn due to the binding energy of their constituent quarks, due to the strong force.

<span class="mw-page-title-main">Muon</span> Subatomic particle

A muon is an elementary particle similar to the electron, with an electric charge of −1 e and a spin of 1/2, but with a much greater mass. It is classified as a lepton. As with other leptons, the muon is not thought to be composed of any simpler particles.

<span class="mw-page-title-main">Muonium</span> Exotic atom made up of an antimuon and an electron

Muonium is an exotic atom made up of an antimuon and an electron, which was discovered in 1960 by Vernon W. Hughes and is given the chemical symbol Mu. During the muon's 2.2 µs lifetime, muonium can undergo chemical reactions. Because, like a proton, the antimuon's mass is vastly larger than that of the electron, muonium is more similar to atomic hydrogen than positronium. Its Bohr radius and ionization energy are within 0.5% of hydrogen, deuterium, and tritium, and thus it can usefully be considered as an exotic light isotope of hydrogen.

<span class="mw-page-title-main">Particle physics</span> Study of subatomic particles and forces

Particle physics or high-energy physics is the study of fundamental particles and forces that constitute matter and radiation. The field also studies combinations of elementary particles up to the scale of protons and neutrons, while the study of combination of protons and neutrons is called nuclear physics.

<span class="mw-page-title-main">Proton</span> Subatomic particle with positive charge

A proton is a stable subatomic particle, symbol
p
, H+, or 1H+ with a positive electric charge of +1 e (elementary charge). Its mass is slightly less than the mass of a neutron and 1,836 times the mass of an electron (the proton-to-electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei).

<span class="mw-page-title-main">Positronium</span> Bound state of an electron and positron

Positronium (Ps) is a system consisting of an electron and its anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two particles annihilate each other to predominantly produce two or three gamma-rays, depending on the relative spin states. The energy levels of the two particles are similar to that of the hydrogen atom. However, because of the reduced mass, the frequencies of the spectral lines are less than half of those for the corresponding hydrogen lines.

A timeline of atomic and subatomic physics.

The Bohr radius is a physical constant, approximately equal to the most probable distance between the nucleus and the electron in a hydrogen atom in its ground state. It is named after Niels Bohr, due to its role in the Bohr model of an atom. Its value is 5.29177210544(82)×10−11 m.

Muon-catalyzed fusion is a process allowing nuclear fusion to take place at temperatures significantly lower than the temperatures required for thermonuclear fusion, even at room temperature or lower. It is one of the few known ways of catalyzing nuclear fusion reactions.

<span class="mw-page-title-main">Tau (particle)</span> Elementary subatomic particle with negative electric charge

The tau, also called the tau lepton, tau particle, tauon or tau electron, is an elementary particle similar to the electron, with negative electric charge and a spin of 1/2. Like the electron, the muon, and the three neutrinos, the tau is a lepton, and like all elementary particles with half-integer spin, the tau has a corresponding antiparticle of opposite charge but equal mass and spin. In the tau's case, this is the "antitau". Tau particles are denoted by the symbol
τ
and the antitaus by 
τ+
.

<span class="mw-page-title-main">Antiprotonic helium</span> Exotic matter with an antiproton in place of an electron

Antiprotonic helium is a three-body atom composed of an antiproton and an electron orbiting around a helium nucleus. It is thus made partly of matter, and partly of antimatter. The atom is electrically neutral, since both electrons and antiprotons each have a charge of −1, whereas helium nuclei have a charge of +2. It has the longest lifetime of any experimentally producible matter-antimatter bound state.

<span class="mw-page-title-main">Deep inelastic scattering</span> Type of collision between subatomic particles

In particle physics, deep inelastic scattering is the name given to a process used to probe the insides of hadrons, using electrons, muons and neutrinos. It was first attempted in the 1960s and 1970s and provided the first convincing evidence of the reality of quarks, which up until that point had been considered by many to be a purely mathematical phenomenon. It is an extension of Rutherford scattering to much higher energies of the scattering particle and thus to much finer resolution of the components of the nuclei.

In quantum electrodynamics, the anomalous magnetic moment of a particle is a contribution of effects of quantum mechanics, expressed by Feynman diagrams with loops, to the magnetic moment of that particle. The magnetic moment, also called magnetic dipole moment, is a measure of the strength of a magnetic source.

<span class="mw-page-title-main">Nuclear binding energy</span> Minimum energy required to separate particles within a nucleus

Nuclear binding energy in experimental physics is the minimum energy that is required to disassemble the nucleus of an atom into its constituent protons and neutrons, known collectively as nucleons. The binding energy for stable nuclei is always a positive number, as the nucleus must gain energy for the nucleons to move apart from each other. Nucleons are attracted to each other by the strong nuclear force. In theoretical nuclear physics, the nuclear binding energy is considered a negative number. In this context it represents the energy of the nucleus relative to the energy of the constituent nucleons when they are infinitely far apart. Both the experimental and theoretical views are equivalent, with slightly different emphasis on what the binding energy means.

Quantum electrodynamics (QED), a relativistic quantum field theory of electrodynamics, is among the most stringently tested theories in physics. The most precise and specific tests of QED consist of measurements of the electromagnetic fine-structure constant, α, in various physical systems. Checking the consistency of such measurements tests the theory.

<span class="mw-page-title-main">Onium</span> Quantum state of a particle and its antiparticle

An onium is a bound state of a particle and its antiparticle. These states are usually named by adding the suffix -onium to the name of one of the constituent particles, with one exception for "muonium"; a muon–antimuon bound pair is called "true muonium" to avoid confusion with old nomenclature.

<span class="mw-page-title-main">Atomic nucleus</span> Core of an atom; composed of nucleons (protons and neutrons)

The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron in 1932, models for a nucleus composed of protons and neutrons were quickly developed by Dmitri Ivanenko and Werner Heisenberg. An atom is composed of a positively charged nucleus, with a cloud of negatively charged electrons surrounding it, bound together by electrostatic force. Almost all of the mass of an atom is located in the nucleus, with a very small contribution from the electron cloud. Protons and neutrons are bound together to form a nucleus by the nuclear force.

<span class="mw-page-title-main">True muonium</span> Predicted exotic atom

For atoms where muons have replaced one or more electrons, see Muonic atom. For the onium of an electron and an antimuon, see muonium.

References

  1. §1.8, Constituents of Matter: Atoms, Molecules, Nuclei and Particles, Ludwig Bergmann, Clemens Schaefer, and Wilhelm Raith, Berlin: Walter de Gruyter, 1997, ISBN   3-11-013990-1.
  2. 1 2 Exotic atoms Archived 2007-12-22 at the Wayback Machine , AccessScience, McGraw-Hill. accessdate=September 26, 2007.
  3. Dr. Richard Feynman's Douglas Robb Memorial Lectures
  4. 1 2 Devons, S.; Duerdoth, I. (1969). "Muonic Atoms". In Baranger, M.; Vogt, E. (eds.). Advances in Nuclear Physics. Springer. pp. 295–423. doi:10.1007/978-1-4684-8343-7_5. ISBN   978-1-4684-8345-1.
  5. 1 2 Fleming, D. G.; Arseneau, D. J.; Sukhorukov, O.; Brewer, J. H.; Mielke, S. L.; Schatz, G. C.; Garrett, B. C.; Peterson, K. A.; Truhlar, D. G. (28 Jan 2011). "Kinetic Isotope Effects for the Reactions of Muonic Helium and Muonium with H2". Science. 331 (6016): 448–450. Bibcode:2011Sci...331..448F. doi:10.1126/science.1199421. PMID   21273484. S2CID   206530683.
  6. Moncada, F.; Cruz, D.; Reyes, A (2012). "Muonic alchemy: Transmuting elements with the inclusion of negative muons". Chemical Physics Letters. 539: 209–221. Bibcode:2012CPL...539..209M. doi:10.1016/j.cplett.2012.04.062.
  7. Moncada, F.; Cruz, D.; Reyes, A. (10 May 2013). "Electronic properties of atoms and molecules containing one and two negative muons". Chemical Physics Letters. 570: 16–21. Bibcode:2013CPL...570...16M. doi:10.1016/j.cplett.2013.03.004.
  8. Deloff, A. (2003). Fundamentals in Hadronic Atom Theory. River Edge, New Jersey: World Scientific. p. 3. ISBN   981-238-371-9.
  9. Hori, M.; Aghai-Khozani, H.; Sótér, A.; Dax, A.; Barna, D. (6 May 2020). "Laser spectroscopy of pionic helium atoms". Nature. 581 (7806): 37–41. Bibcode:2020Natur.581...37H. doi:10.1038/s41586-020-2240-x. PMID   32376962. S2CID   218527999.
  10. p. 8, §16.4, §16.5, Deloff.
  11. 1 2 The strange world of the exotic atom, Roger Barrett, Daphne Jackson and Habatwa Mweene, New Scientist, August 4, 1990. accessdate=September 26, 2007.
  12. p. 180, Quantum Mechanics, B. K. Agarwal and Hari Prakash, New Delhi: Prentice-Hall of India Private Ltd., 1997. ISBN   81-203-1007-1.
  13. Exotic atoms cast light on fundamental questions, CERN Courier, November 1, 2006. accessdate=September 26, 2007.
  14. Adkins, G. S.; Fell, R. N.; Sapirstein, J. (29 May 2000). "Order α2 Corrections to the Decay Rate of Orthopositronium". Physical Review Letters. 84 (22): 5086–5089. arXiv: hep-ph/0003028 . Bibcode:2000PhRvL..84.5086A. doi:10.1103/PhysRevLett.84.5086. PMID   10990873. S2CID   1165868.
  15. DOE/SLAC National Accelerator Laboratory (June 4, 2009). "Theorists Reveal Path To True Muonium – Never-seen Atom". ScienceDaily. Retrieved June 7, 2009.
  16. d'Enterria, David; Perez-Ramos, Redamy; Shao, Hua-Sheng (2022). "Ditauonium spectroscopy". European Physical Journal C . 82 (10): 923. arXiv: 2204.07269 . Bibcode:2022EPJC...82..923D. doi:10.1140/epjc/s10052-022-10831-x. S2CID   248218441.