Metamagnetism

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Metamagnetism is a sudden (often, dramatic) increase in the magnetization of a material with a small change in an externally applied magnetic field. The metamagnetic behavior may have quite different physical causes for different types of metamagnets. Some examples of physical mechanisms leading to metamagnetic behavior are:

  1. Itinerant metamagnetism - Exchange splitting of the Fermi surface in a paramagnetic system of itinerant electrons causes an energetically favorable transition to bulk magnetization near the transition to a ferromagnet or other magnetically ordered state. [1] [2] [3]
  2. Antiferromagnetic transition - Field-induced spin flips in antiferromagnets cascade at a critical energy determined by the applied magnetic field. [4]

Depending on the material and experimental conditions, metamagnetism may be associated with a first-order phase transition, a continuous phase transition at a critical point (classical or quantum), or crossovers beyond a critical point that do not involve a phase transition at all. These wildly different physical explanations sometimes lead to confusion as to what the term "metamagnetic" is referring in specific cases.

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<span class="mw-page-title-main">Helimagnetism</span>

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<span class="mw-page-title-main">Pulsed electron paramagnetic resonance</span>

Pulsed electron paramagnetic resonance (EPR) is an electron paramagnetic resonance technique that involves the alignment of the net magnetization vector of the electron spins in a constant magnetic field. This alignment is perturbed by applying a short oscillating field, usually a microwave pulse. One can then measure the emitted microwave signal which is created by the sample magnetization. Fourier transformation of the microwave signal yields an EPR spectrum in the frequency domain. With a vast variety of pulse sequences it is possible to gain extensive knowledge on structural and dynamical properties of paramagnetic compounds. Pulsed EPR techniques such as electron spin echo envelope modulation (ESEEM) or pulsed electron nuclear double resonance (ENDOR) can reveal the interactions of the electron spin with its surrounding nuclear spins.

<span class="mw-page-title-main">Arrott plot</span>

In condensed matter physics, an Arrott plot is a plot of the square of the magnetization of a substance, against the ratio of the applied magnetic field to magnetization at one fixed temperature(s). Arrott plots are an easy way of determining the presence of ferromagnetic order in a material. They are named after American physicist Anthony Arrott who introduced them as a technique for studying magnetism in 1957.

References

  1. Wohlfarth, E. P.; Rhodes, P. (1962). "Collective Electron Metamagnetism". Phil. Mag. 7 (83): 1817–1824. Bibcode:1962PMag....7.1817W. doi:10.1080/14786436208213848.
  2. Levitin, R. Z.; Markosyan, A. S. (1988). "Зонный метамагнетизм". Usp. Fiz. Nauk (in Russian). 155 (8): 623–657. doi: 10.3367/UFNr.0155.198808c.0623 .
  3. Levitin, R. Z.; Markosyan, A. S. (1988). "Itinerant Magnetism". Physics-Uspekhi . 31 (8): 730–749. Bibcode:1988SvPhU..31..730L. doi:10.1070/PU1988v031n08ABEH004922.
  4. Stryjewski, E.; Giordano, N. (1977). "Metamagnetism". Advances in Physics . 26 (5): 487–650. Bibcode:1977AdPhy..26..487S. doi:10.1080/00018737700101433.