Chromium(III) sulfide

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Chromium(III) sulfide
Cr2S3 structure.jpg
Identifiers
ECHA InfoCard 100.031.477 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 234-638-8
PubChem CID
Properties
Cr2S3
Molar mass 200.19 g/mol
AppearanceBrown to black powder
Odor odorless
Density 3.77 g/cm3
Melting point 1350 °C
insoluble
+2390.0·10−6 cm3/mol
Hazards
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 [1]
REL (Recommended)
TWA 0.5 mg/m3 [1]
IDLH (Immediate danger)
250 mg/m3 [1]
Safety data sheet (SDS)
Related compounds
Other anions
Chromium(III) oxide
Chromium(III) telluride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chromium(III) sulfide is the inorganic compound with the formula Cr 2 S 3. It is a brown-black solid. Chromium sulfides are usually nonstoichiometric compounds, with formulas ranging from CrS to Cr0.67S (corresponding to Cr2S3).

Contents

Preparation

Chromium(III) sulfide can be prepared through the reaction of a stoichiometric mixture of the elements at 1000 °C [2]

It is a solid that is insoluble in water. According to X-ray crystallography, its structure is a combination of that of nickel arsenide (1:1 stoichiometry) and Cd(OH)2 (1:2 stoichiometry). Some metal-metal bonding is indicated by the short Cr-Cr distance of 2.78 Å. [3]

See also

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. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

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Chromium(II) selenide is an inorganic compound with the chemical formula CrSe. It crystalizes in a hexagonal structure with space group P63/mmc. It is one of many related Chromium-Selenium phases, including Cr7Se8, Cr3Se4, Cr0.68Se, Cr2Se3, and Cr5Se8. The compound has been described as an antiferromagnet, but its inverse magnetic susceptibility does not match the behavior expected for an antiferromagnet according to the Curie–Weiss law. One suggestion was that the Néel temperature is at 320 K, as the temperature where the compound has maximum specific heat. When synthesized as single atomic layer, CrSe is ferromagnetic, with a Curie Temperature of around 280 K.

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Chromium(III) bromide is an inorganic compound with the chemical formula CrBr3. It is a dark colored solid that appears green in transmitted light but red with reflected light. It is used as a precursor to catalysts for the oligomerization of ethylene.

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Chromium(III) phosphate describes inorganic compounds with the chemical formula CrPO4.(H2O)n, where n = 0, 4, or 6. All are deeply colored solids. Anhydrous CrPO4 is green. The hexahydrate CrPO4•6H2O is violet.

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Beryllium sulfide (BeS) is an ionic compound from the sulfide group with the formula BeS. It is a white solid with a sphalerite structure that is decomposed by water and acids.

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Chromium(II) sulfide is an inorganic compound of chromium and sulfur with the chemical formula CrS. The compound forms black hexagonal crystals, insoluble in water.

References

  1. 1 2 3 NIOSH Pocket Guide to Chemical Hazards. "#0141". National Institute for Occupational Safety and Health (NIOSH).
  2. Georg Brauer: Handbuch der präparativen anorganischen Chemie. 3., umgearb. Auflage. Band III. Enke, Stuttgart 1981, ISBN   3-432-87823-0, S. 1493
  3. Jellinek, F. "The structures of the Chromium Sulphides" Acta Crystallographica 1957, volume 10, p620-p628 doi : 10.1107/S0365110X57002200