Corrosion fatigue

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Corrosion fatigue is fatigue in a corrosive environment. It is the mechanical degradation of a material under the joint action of corrosion and cyclic loading. Nearly all engineering structures experience some form of alternating stress, and are exposed to harmful environments during their service life. The environment plays a significant role in the fatigue of high-strength structural materials like steel, aluminum alloys and titanium alloys. Materials with high specific strength are being developed to meet the requirements of advancing technology. However, their usefulness depends to a large extent on the degree to which they resist corrosion fatigue.

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The effects of corrosive environments on the fatigue behavior of metals were studied as early as 1930. [1]

The phenomenon should not be confused with stress corrosion cracking, where corrosion (such as pitting) leads to the development of brittle cracks, growth and failure. The only requirement for corrosion fatigue is that the sample be under tensile stress.

Effect of corrosion on S-N diagram

Effect of corrosion on S-N diagram Effect of corrosion on fatigue diagram.JPG
Effect of corrosion on S-N diagram

The effect of corrosion on a smooth-specimen S-N diagram is shown schematically on the right. Curve A shows the fatigue behavior of a material tested in air. A fatigue threshold (or limit) is seen in curve A, corresponding to the horizontal part of the curve. Curves B and C represent the fatigue behavior of the same material in two corrosive environments. In curve B, the fatigue failure at high stress levels is retarded, and the fatigue limit is eliminated. In curve C, the whole curve is shifted to the left; this indicates a general lowering in fatigue strength, accelerated initiation at higher stresses and elimination of the fatigue limit.

To meet the needs of advancing technology, higher-strength materials are developed through heat treatment or alloying. Such high-strength materials generally exhibit higher fatigue limits, and can be used at higher service stress levels even under fatigue loading. However, the presence of a corrosive environment during fatigue loading eliminates this stress advantage, since the fatigue limit becomes almost insensitive to the strength level for a particular group of alloys. [2] This effect is schematically shown for several steels in the diagram on the left, which illustrates the debilitating effect of a corrosive environment on the functionality of high-strength materials under fatigue.

Effect of corrosion on fatigue limits of steels Effect of corrosion on fatigue limit.jpg
Effect of corrosion on fatigue limits of steels

Corrosion fatigue in aqueous media is an electrochemical behavior. Fractures are initiated either by pitting or persistent slip bands. [3] Corrosion fatigue may be reduced by alloy additions, inhibition and cathodic protection, all of which reduce pitting. [4] Since corrosion-fatigue cracks initiate at a metal's surface, surface treatments like plating, cladding, nitriding and shot peening were found to improve the materials' resistance to this phenomenon. [5]

Crack-propagation studies in corrosion fatigue

Schematic of typical fatigue-crack-growth behavior Sub critical fatigue crack growth.jpg
Schematic of typical fatigue-crack-growth behavior

In normal fatigue-testing of smooth specimens, about 90 percent is spent in crack nucleation and only the remaining 10 percent in crack propagation. However, in corrosion fatigue crack nucleation is facilitated by corrosion; typically, about 10 percent of life is sufficient for this stage. The rest (90 percent) of life is spent in crack propagation. Thus, it is more useful to evaluate crack-propagation behavior during corrosion fatigue.

Fracture mechanics uses pre-cracked specimens, effectively measuring crack-propagation behavior. For this reason, emphasis is given to crack-propagation velocity measurements (using fracture mechanics) to study corrosion fatigue. Since fatigue crack grows in a stable fashion below the critical stress-intensity factor for fracture (fracture toughness), the process is called sub-critical crack growth.

The diagram on the right shows typical fatigue-crack-growth behavior. In this log-log plot, the crack-propagation velocity is plotted against the applied stress-intensity range. Generally there is a threshold stress-intensity range, below which crack-propagation velocity is insignificant. Three stages may be visualized in this plot. Near the threshold, crack-propagation velocity increases with increasing stress-intensity range. In the second region, the curve is nearly linear and follows Paris' law(6); [6] in the third region crack-propagation velocity increases rapidly, with the stress-intensity range leading to fracture at the fracture-toughness value.

Crack propagation under corrosion fatigue may be classified as a) true corrosion fatigue, b) stress corrosion fatigue or c) a combination of true, stress and corrosion fatigue.

True corrosion fatigue

Crack-growth behavior under true corrosion fatigue True corrosion fatigue.jpg
Crack-growth behavior under true corrosion fatigue

In true corrosion fatigue, the fatigue-crack-growth rate is enhanced by corrosion; this effect is seen in all three regions of the fatigue-crack growth-rate diagram. The diagram on the left is a schematic of crack-growth rate under true corrosion fatigue; the curve shifts to a lower stress-intensity-factor range in the corrosive environment. The threshold is lower (and the crack-growth velocities higher) at all stress-intensity factors. Specimen fracture occurs when the stress-intensity-factor range is equal to the applicable threshold-stress-intensity factor for stress-corrosion cracking.

When attempting to analyze the effects of corrosion fatigue on crack growth in a particular environment, both corrosion type and fatigue load levels affect crack growth in varying degrees. Common types of corrosion include filiform, pitting, exfoliation, intergranular; each will affect crack growth in a particular material in a distinct way. For instance, pitting will often be the most damaging type of corrosion, degrading a material's performance (by increasing the crack-growth rate) more than any other kind of corrosion; even pits of the order of a material's grain size may substantially degrade a material. The degree to which corrosion affects crack-growth rates also depends on fatigue-load levels; for instance, corrosion can cause a greater increase in crack-growth rates at a low loads than it does at a high load. [7]

Stress-corrosion fatigue

Crack-growth behavior under stress-corrosion fatigue Stress corrosion fatigue.jpg
Crack-growth behavior under stress-corrosion fatigue

In materials where the maximum applied-stress-intensity factor exceeds the stress-corrosion cracking-threshold value, stress corrosion adds to crack-growth velocity. This is shown in the schematic on the right. In a corrosive environment, the crack grows due to cyclic loading at a lower stress-intensity range; above the threshold stress intensity for stress corrosion cracking, additional crack growth (the red line) occurs due to SCC. The lower stress-intensity regions are not affected, and the threshold stress-intensity range for fatigue-crack propagation is unchanged in the corrosive environment. In the most-general case, corrosion-fatigue crack growth may exhibit both of the above effects; crack-growth behavior is represented in the schematic on the left.

Combined true-corrosion and stress-corrosion fatigue Combined True & Stress corrosion fatigue.jpg
Combined true-corrosion and stress-corrosion fatigue

See also

Related Research Articles

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Embrittlement

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Paris law

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Polymer fracture is the study of the fracture surface of an already failed material to determine the method of crack formation and extension in polymers both fiber reinforced and otherwise. Failure in polymer components can occur at relatively low stress levels, far below the tensile strength because of four major reasons: long term stress or creep rupture, cyclic stresses or fatigue, the presence of structural flaws and stress-cracking agents. Formations of submicroscopic cracks in polymers under load have been studied by x ray scattering techniques and the main regularities of crack formation under different loading conditions have been analyzed. The low strength of polymers compared to theoretically predicted values are mainly due to the many microscopic imperfections found in the material. These defects namely dislocations, crystalline boundaries, amorphous interlayers and block structure can all lead to the non-uniform distribution of mechanical stress.

Crack closure is a phenomenon in fatigue loading, where the opposing faces of a crack remain in contact even with an external load acting on the material. As the load is increased, a critical value will be reached at which time the crack becomes open. Crack closure occurs from the presence of material propping open the crack faces and can arise from many sources including plastic deformation or phase transformation during crack propagation, corrosion of crack surfaces, presence of fluids in the crack, or roughness at cracked surfaces.

Fracture of biological materials may occur in biological tissues making up the musculoskeletal system, commonly called orthopedic tissues: bone, cartilage, ligaments, and tendons. Bone and cartilage, as load-bearing biological materials, are of interest to both a medical and academic setting for their propensity to fracture. For example, a large health concern is in preventing bone fractures in an aging population, especially since fracture risk increases ten fold with aging. Cartilage damage and fracture can contribute to osteoarthritis, a joint disease that results in joint stiffness and reduced range of motion.

Striation (fatigue)

Striations are marks produced on the fracture surface that show the incremental growth of a fatigue crack. A striation marks the position of the crack tip at the time it was made. The term striation generally refers to ductile striations which are rounded bands on the fracture surface separated by depressions or fissures and can have the same appearance on both sides of the mating surfaces of the fatigue crack. Although some research has suggested that many loading cycles are required to form a single striation, it is now generally thought that each striation is the result of a single loading cycle.

Crack growth equation

A crack growth equation is used for calculating the size of a fatigue crack growing from cyclic loads. The growth of fatigue cracks can result in catastrophic failure, particularly in the case of aircraft. A crack growth equation can be used to ensure safety, both in the design phase and during operation, by predicting the size of cracks. In critical structure, loads can be recorded and used to predict the size of cracks to ensure maintenance or retirement occurs prior to any of the cracks failing.

Fastran is a computer program for calculating the rate of fatigue crack growth by combining crack growth equations and a simulation of the plasticity at the crack tip.

References

  1. P. T. Gilbert, Metallurgical Reviews 1 (1956), 379
  2. H. Kitegava in Corrosion Fatigue, Chemistry, Mechanics and Microstructure, O. Devereux et al. eds. NACE, Houston (1972), p. 521
  3. C. Laird and D. J. Duquette in Corrosion Fatigue, Chemistry, Mechanics and Microstructure, p. 88
  4. J. Congleton and I. H. Craig in Corrosion Processes, R. N. Parkins (ed.). Applied Science Publishers, London (1982), p. 209
  5. H. H. Lee and H. H. Uhlig, Metall. Trans. 3 (1972), 2949
  6. P. C. Paris and F. Erdogan, J. Basic Engineering, ASME Trans. 85 (1963) 528
  7. Craig L. Brooks, Scott A. Prost-Domasky, Kyle T. Honeycutt and Thomas B. Mills, "Predictive modeling of structure service life" in ASM Handbook Volume 13A, Corrosion: Fundamental, Testing and Protection, October 2003, 946-958.