Disulfuric acid

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Disulfuric acid
Dischwefelsaure - Disulfuric acid.svg
Pyrosulfuric acid molecule ball.png
Names
IUPAC name
Disulfuric acid [1]
Other names
Pyrosulfuric acid, Oleum
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.069 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 231-976-8
MeSH Pyrosulfuric+acid
PubChem CID
UNII
  • InChI=1S/H2O7S2/c1-8(2,3)7-9(4,5)6/h(H,1,2,3)(H,4,5,6) Yes check.svgY
    Key: VFNGKCDDZUSWLR-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/H2O7S2/c1-8(2,3)7-9(4,5)6/h(H,1,2,3)(H,4,5,6)
    Key: VFNGKCDDZUSWLR-UHFFFAOYAZ
  • OS(=O)(=O)OS(O)(=O)=O
  • OS(=O)(=O)OS(=O)(=O)O
  • O=S(=O)(O)OS(=O)(=O)O
Properties
H2O7S2
Molar mass 178.13 g·mol−1
Appearancecolorless
Melting point 36 °C (97 °F; 309 K)
Acidity (pKa)2.5 (20 °C; in conc. H2SO4) [2]
Conjugate base Disulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Disulfuric acid (alternative spelling disulphuric acid) or pyrosulfuric acid (alternative spelling pyrosulphuric acid), also named oleum, is a sulfur oxoacid. [3] It is a major constituent of fuming sulfuric acid, oleum, and this is how most chemists encounter it. As confirmed by X-ray crystallography, the molecule consists of a pair of SO2(OH) groups joined by an oxide. [4]

Contents

Reactions

It is also a minor constituent of liquid anhydrous sulfuric acid due to the equilibria:

The acid is prepared by reacting excess sulfur trioxide (SO3) with sulfuric acid:

Disulfuric acid can be seen as the sulfuric acid analog of an acid anhydride. The mutual electron-withdrawing effects of each sulfuric acid unit on its neighbour causes a marked increase in acidity. Disulfuric acid is strong enough to protonate "normal" sulfuric acid in the (anhydrous) sulfuric acid solvent system. There are salts of disulfuric acid, commonly called pyrosulfates, e.g. potassium pyrosulfate.

There are other related acids with the general formula H2O·(SO3)x though none can be isolated.

See also

Related Research Articles

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<span class="mw-page-title-main">Oxide</span> Chemical compound where oxygen atoms are combined with atoms of other elements

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<span class="mw-page-title-main">Sulfuric acid</span> Chemical compound (H₂SO₄)

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<span class="mw-page-title-main">Oleum</span> Corrosive liquid of excess sulfur trioxide in solution.

Oleum, or fuming sulfuric acid, is a term referring to solutions of various compositions of sulfur trioxide in sulfuric acid, or sometimes more specifically to disulfuric acid.

Sulfur trioxide (alternative spelling sulphur trioxide, also known as nisso sulfan) is the chemical compound with the formula SO3. It has been described as "unquestionably the most [economically] important sulfur oxide". It is prepared on an industrial scale as a precursor to sulfuric acid.

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with the aid of a catalyst into diatomic nitrogen, and water. A reductant, typically anhydrous ammonia, aqueous ammonia, or a urea solution, is added to a stream of flue or exhaust gas and is reacted onto a catalyst. As the reaction drives toward completion, nitrogen, and carbon dioxide, in the case of urea use, are produced.

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<span class="mw-page-title-main">Fluorosulfuric acid</span> Chemical compound

Fluorosulfuric acid (IUPAC name: sulfurofluoridic acid) is the inorganic compound with the chemical formula HSO3F. It is one of the strongest acids commercially available. It is a tetrahedral molecule and is closely related to sulfuric acid, H2SO4, substituting a fluorine atom for one of the hydroxyl groups. It is a colourless liquid, although commercial samples are often yellow.

<span class="mw-page-title-main">Potassium bisulfate</span> Chemical compound

Potassium bisulfate (potassium bisulphate) is an inorganic compound with the chemical formula KHSO4 and is the potassium acid salt of sulfuric acid. It is a white, water-soluble solid.

An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one other element, with at least one hydrogen atom bonded to oxygen that can dissociate to produce the H+ cation and the anion of the acid.

<span class="mw-page-title-main">Triflic acid</span> Chemical compound

Triflic acid, the short name for trifluoromethanesulfonic acid, TFMS, TFSA, HOTf or TfOH, is a sulfonic acid with the chemical formula CF3SO3H. It is one of the strongest known acids. Triflic acid is mainly used in research as a catalyst for esterification. It is a hygroscopic, colorless, slightly viscous liquid and is soluble in polar solvents.

<span class="mw-page-title-main">Chlorosulfuric acid</span> Chemical compound

Chlorosulfuric acid (IUPAC name: sulfurochloridic acid) is the inorganic compound with the formula HSO3Cl. It is also known as chlorosulfonic acid, being the sulfonic acid of chlorine. It is a distillable, colorless liquid which is hygroscopic and a powerful lachrymator. Commercial samples usually are pale brown or straw colored.

<span class="mw-page-title-main">Manganese heptoxide</span> Chemical compound

Manganese(VII) oxide (manganese heptoxide) is an inorganic compound with the formula Mn2O7. Manganese heptoxide is a volatile liquid with an oily consistency. It is a highly reactive and powerful oxidizer that reacts explosively with nearly any organic compound. It was first described in 1860. It is the acid anhydride of permanganic acid.

Hyponitrous acid is a chemical compound with formula H
2
N
2
O
2
or HON=NOH. It is an isomer of nitramide, H2N−NO2; and a formal dimer of azanone, HNO.

Thiosulfuric acid is the inorganic compound with the formula H2S2O3. It has attracted academic interest as a simple, easily accessed compound that is labile. It has few practical uses.

References

  1. International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005). Cambridge (UK): RSCIUPAC. ISBN   0-85404-438-8. p. 130. Electronic version.
  2. Perrin, D. D., ed. (1982) [1969]. Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution. IUPAC Chemical Data (2nd ed.). Oxford: Pergamon (published 1984). Entry 62. ISBN   0-08-029214-3. LCCN   82-16524.
  3. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8.
  4. Hönle, Wolfgang (1991). "Crystal structure of H2S2O7 at 298 K". Zeitschrift für Kristallographie - Crystalline Materials. 196 (1–4). doi:10.1524/zkri.1991.196.14.279. S2CID   101311329.