Ingot

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Aluminium ingot after ejection from mold Lingot aluminium.jpg
Aluminium ingot after ejection from mold
Pouring molten gold into a mold at the La Luz Gold Mine in Siuna, Nicaragua, about 1959. Pouring gold.jpg
Pouring molten gold into a mold at the La Luz Gold Mine in Siuna, Nicaragua, about 1959.

An ingot is a piece of relatively pure material, usually metal, that is cast into a shape suitable for further processing. [1] In steelmaking, it is the first step among semi-finished casting products. Ingots usually require a second procedure of shaping, such as cold/hot working, cutting, or milling to produce a useful final product. Non-metallic and semiconductor materials prepared in bulk form may also be referred to as ingots, particularly when cast by mold based methods. [2] Precious metal ingots can be used as currency (with or without being processed into other shapes), or as a currency reserve, as with gold bars.

Contents

Types

Ingots are generally made of metal, either pure or alloy, heated past its melting point and cast into a bar or block using a mold chill method.

A special case are polycrystalline or single crystal ingots made by pulling from a molten melt.

Single crystal

Single crystal ingots (called boules) of materials are grown (crystal growth) using methods such as the Czochralski process or Bridgeman technique.

The boules may be either semiconductor (e.g. electronic chip wafers, photovoltaic cells) or non-conducting inorganic compounds for industrial and jewelry use (e.g., synthetic ruby, sapphire).

Single crystal ingots of metal are produced in similar fashion to that used to produce high purity semiconductor ingots, [3] i.e. by vacuum induction refining. Single crystal ingots of engineering metals are of interest due to their very high strength due to lack of grain boundaries. The method of production is via single crystal dendrite and not via simple casting. Possible uses include turbine blades.

Copper alloys

In the United States, the brass and bronze ingot making industry started in the early 19th century. The US brass industry grew to be the number one producer by the 1850s. [4] During colonial times the brass and bronze industries were almost non-existent because the British demanded all copper ore be sent to Britain for processing. [5] Copper based alloy ingots weighed approximately 20 pounds (9.1 kg). [6] [7]

Manufacture

Crystalline structure of mold cast ingot. Cast ingot macrostructure.svg
Crystalline structure of mold cast ingot.

Ingots are manufactured by the cooling of a molten liquid (known as the melt) in a mold. The manufacture of ingots has several aims.

Firstly, the mold is designed to completely solidify and form an appropriate grain structure required for later processing, as the structure formed by the cooling of the melt controls the physical properties of the material.

Secondly, the shape and size of the mold is designed to allow for ease of ingot handling and downstream processing. Finally, the mold is designed to minimize melt wastage and aid ejection of the ingot, as losing either melt or ingot increases manufacturing costs of finished products.

A variety of designs exist for the mold, which may be selected to suit the physical properties of the liquid melt and the solidification process. Molds may exist in the top, horizontal or bottom-up pouring and may be fluted or flat walled. The fluted design increases heat transfer owing to a larger contact area. Molds may be either solid "massive" design, sand cast (e.g. for pig iron), or water-cooled shells, depending upon heat transfer requirements. Ingot molds are tapered to prevent the formation of cracks due to uneven cooling. A crack or void formation occurs as the liquid to solid transition has an associated volume change for a constant mass of material. The formation of these ingot defects may render the cast ingot useless and may need to be re-melted, recycled, or discarded.

Pouring ingots at a steel mill Fotothek df n-34 0000253 Metallurge fur Huttentechnik.jpg
Pouring ingots at a steel mill
Re-melted tin affected with tin pest is poured into ingot molds at Rock Island Arsenal Joint Manufacturing and Technology Center, Rock Island, Illinois. Re-melted tin affected with tin pest is poured into ingot molds at Rock Island Arsenal Joint Manufacturing and Technology Center, DVIDS3878892.jpg
Re-melted tin affected with tin pest is poured into ingot molds at Rock Island Arsenal Joint Manufacturing and Technology Center, Rock Island, Illinois.

The physical structure of a crystalline material is largely determined by the method of cooling and precipitation of the molten metal. During the pouring process, metal in contact with the ingot walls rapidly cools and forms either a columnar structure or possibly a "chill zone" of equiaxed dendrites, depending upon the liquid being cooled and the cooling rate of the mold. [8]

For a top-poured ingot, as the liquid cools within the mold, differential volume effects cause the top of the liquid to recede leaving a curved surface at the mold top which may eventually be required to be machined from the ingot. The mold cooling effect creates an advancing solidification front, which has several associated zones, closer to the wall there is a solid zone that draws heat from the solidifying melt, for alloys there may exist a "mushy" zone, which is the result of solid-liquid equilibrium regions in the alloy's phase diagram, and a liquid region. The rate of front advancement controls the time that dendrites or nuclei have to form in the solidification region. The width of the mushy zone in an alloy may be controlled by tuning the heat transfer properties of the mold or adjusting the liquid melt alloy compositions.

Continuous casting methods for ingot processing also exist, whereby a stationary front of solidification is formed by the continual take-off of cooled solid material, and the addition of a molten liquid to the casting process. [9]

Approximately 70 percent of aluminium ingots in the U.S. are cast using the direct chill casting process, which reduces cracking. A total of 5 percent of ingots must be scrapped because of stress induced cracks and butt deformation. [10]

Historical ingots

Plano-convex ingots are widely distributed archaeological artifacts which are studied to provide information on the history of metallurgy.

See also

Related Research Articles

<span class="mw-page-title-main">Metal casting</span> Pouring liquid metal into a mold

In metalworking and jewelry making, casting is a process in which a liquid metal is delivered into a mold that contains a negative impression of the intended shape. The metal is poured into the mold through a hollow channel called a sprue. The metal and mold are then cooled, and the metal part is extracted. Casting is most often used for making complex shapes that would be difficult or uneconomical to make by other methods.

<span class="mw-page-title-main">Zone melting</span> Purification process by moving a molten zone along a metal bar

Zone melting is a group of similar methods of purifying crystals, in which a narrow region of a crystal is melted, and this molten zone is moved along the crystal. The molten region melts impure solid at its forward edge and leaves a wake of purer material solidified behind it as it moves through the ingot. The impurities concentrate in the melt, and are moved to one end of the ingot. Zone refining was invented by John Desmond Bernal and further developed by William G. Pfann in Bell Labs as a method to prepare high-purity materials, mainly semiconductors, for manufacturing transistors. Its first commercial use was in germanium, refined to one atom of impurity per ten billion, but the process can be extended to virtually any solute–solvent system having an appreciable concentration difference between solid and liquid phases at equilibrium. This process is also known as the float zone process, particularly in semiconductor materials processing.

Aluminium–silicon alloys or Silumin is a general name for a group of lightweight, high-strength aluminium alloys based on an aluminum–silicon system (AlSi) that consist predominantly of aluminum - with silicon as the quantitatively most important alloying element. Pure AlSi alloys cannot be hardened, the commonly used alloys AlSiCu and AlSiMg can be hardened. The hardening mechanism corresponds to that of AlCu and AlMgSi.

<span class="mw-page-title-main">Riser (casting)</span>

A riser, also known as a feeder, is a reservoir built into a metal casting mold to prevent cavities due to shrinkage. Most metals are less dense as a liquid than as a solid so castings shrink upon cooling, which can leave a void at the last point to solidify. Risers prevent this by providing molten metal to the casting as it solidifies, so that the cavity forms in the riser and not the casting. Risers are not effective on materials that have a large freezing range, because directional solidification is not possible. They are also not needed for casting processes that utilized pressure to fill the mold cavity.

<span class="mw-page-title-main">Dendrite (metal)</span>

A dendrite in metallurgy is a characteristic tree-like structure of crystals growing as molten metal solidifies, the shape produced by faster growth along energetically favourable crystallographic directions. This dendritic growth has large consequences in regard to material properties.

Spin casting, also known as centrifugal rubber mold casting (CRMC), is a method of utilizing inertia to produce castings from a rubber mold. Typically, a disc-shaped mold is spun along its central axis at a set speed. The casting material, usually molten metal or liquid thermoset plastic, is then poured in through an opening at the top-center of the mold. The filled mold then continues to spin as the metal solidifies.

<span class="mw-page-title-main">Foundry</span> Factory that produces metal castings

A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals processed are aluminum and cast iron. However, other metals, such as bronze, brass, steel, magnesium, and zinc, are also used to produce castings in foundries. In this process, parts of desired shapes and sizes can be formed.

<span class="mw-page-title-main">Continuous casting</span>

Continuous casting, also called strand casting, is the process whereby molten metal is solidified into a "semifinished" billet, bloom, or slab for subsequent rolling in the finishing mills. Prior to the introduction of continuous casting in the 1950s, steel was poured into stationary molds to form ingots. Since then, "continuous casting" has evolved to achieve improved yield, quality, productivity and cost efficiency. It allows lower-cost production of metal sections with better quality, due to the inherently lower costs of continuous, standardised production of a product, as well as providing increased control over the process through automation. This process is used most frequently to cast steel. Aluminium and copper are also continuously cast.

<span class="mw-page-title-main">Investment casting</span> Industrial process based on lost-wax casting

Investment casting is an industrial process based on lost-wax casting, one of the oldest known metal-forming techniques. The term "lost-wax casting" can also refer to modern investment casting processes.

Spray forming, also known as spray casting, spray deposition and in-situ compaction, is a method of casting near net shape metal components with homogeneous microstructures via the deposition of semi-solid sprayed droplets onto a shaped substrate. In spray forming an alloy is melted, normally in an induction furnace, then the molten metal is slowly poured through a conical tundish into a small-bore ceramic nozzle. The molten metal exits the furnace as a thin free-falling stream and is broken up into droplets by an annular array of gas jets, and these droplets then proceed downwards, accelerated by the gas jets to impact onto a substrate. The process is arranged such that the droplets strike the substrate whilst in the semi-solid condition, this provides sufficient liquid fraction to 'stick' the solid fraction together. Deposition continues, gradually building up a spray formed billet of metal on the substrate.

<span class="mw-page-title-main">Pattern (casting)</span>

In casting, a pattern is a replica of the object to be cast, used to form the sand mould cavity into which molten metal is poured during the casting process. Once the pattern has been used to form the sand mould cavity, the pattern is then removed, Molten metal is then poured into the sand mould cavity to produce the casting. The pattern is non consumable and can be reused to produce further sand moulds almost indefinitely.

<span class="mw-page-title-main">Directional solidification</span> Types of solidification within castings

Directional solidification(DS) and progressive solidification are types of solidification within castings. Directional solidification is solidification that occurs from farthest end of the casting and works its way towards the sprue. Progressive solidification, also known as parallel solidification, is solidification that starts at the walls of the casting and progresses perpendicularly from that surface.

Permanent mold casting is a metal casting process that employs reusable molds, usually made from metal. The most common process uses gravity to fill the mold, however gas pressure or a vacuum are also used. A variation on the typical gravity casting process, called slush casting, produces hollow castings. Common casting metals are aluminium, magnesium, and copper alloys. Other materials include tin, zinc, and lead alloys and iron and steel are also cast in graphite molds.

Bismuth bronze or bismuth brass is a copper alloy which typically contains 1-3% bismuth by weight, although some alloys contain over 6% Bi. This bronze alloy is very corrosion-resistant, a property which makes it suitable for use in environments such as the ocean. Bismuth bronzes and brasses are more malleable, thermally conductive, and polish better than regular brasses. The most common industrial application of these metals are as bearings, however the material has been in use since the late nineteenth century as kitchenware and mirrors. Bismuth bronze was also found in ceremonial Inca knives at Machu Picchu. Recently, pressure for the substitution of hazardous metals has increased and with it bismuth bronze is being marketed as a green alternative to leaded bronze bearings and bushings.

<span class="mw-page-title-main">Casting</span> Manufacturing process in which a liquid is poured into a mold to solidify

Casting is a manufacturing process in which a liquid material is usually poured into a mold, which contains a hollow cavity of the desired shape, and then allowed to solidify. The solidified part is also known as a casting, which is ejected or broken out of the mold to complete the process. Casting materials are usually metals or various time setting materials that cure after mixing two or more components together; examples are epoxy, concrete, plaster and clay. Casting is most often used for making complex shapes that would be otherwise difficult or uneconomical to make by other methods. Heavy equipment like machine tool beds, ships' propellers, etc. can be cast easily in the required size, rather than fabricating by joining several small pieces. Casting is a 7,000-year-old process. The oldest surviving casting is a copper frog from 3200 BC.

A casting defect is an undesired irregularity in a metal casting process. Some defects can be tolerated while others can be repaired, otherwise they must be eliminated. They are broken down into five main categories: gas porosity, shrinkage defects, mould material defects, pouring metal defects, and metallurgical defects.

<span class="mw-page-title-main">Centrifugal casting (industrial)</span> Casting technique that is typically used to cast thin-walled cylinders

Centrifugal casting or rotocasting is a casting technique that is typically used to cast thin-walled cylinders. It is typically used to cast materials such as metals, glass, and concrete. A high quality is attainable by control of metallurgy and crystal structure. Unlike most other casting techniques, centrifugal casting is chiefly used to manufacture rotationally symmetric stock materials in standard sizes for further machining, rather than shaped parts tailored to a particular end-use.

An inclusion is a solid particle in liquid aluminium alloy. It is usually non-metallic and can be of different nature depending on its source.

Splat quenching is a metallurgical, metal morphing technique used for forming metals with a particular crystal structure by means of extremely rapid quenching, or cooling.

Direct Chill casting is a method for the fabrication of cylindrical or rectangular solid ingots from non-ferrous metals, especially Aluminum, Copper, Magnesium and their alloys. The original ingots are usually further processed by other methods. More than half of global aluminum production uses the Direct Chill casting process.

References

  1. Chalmers, p. 254.
  2. Wu, B.; Scott, S.; Stoddard, N.; Clark, R.; Sholapurwalla, A. "Simulation of Silicon Casting Process for Photovoltaic (PV) Application" (PDF).
  3. Indium ingots Archived 2009-01-06 at the Wayback Machine , lesscommonmetals.com.
  4. Innovations: The History of Brass Making in the Naugatuck Valley Archived 2009-06-05 at the Wayback Machine . Copper.org (2010-08-25). Retrieved on 2012-02-24.
  5. Innovations: Overview of Recycled Copper Archived 2017-04-30 at the Wayback Machine . Copper.org (2010-08-25). Retrieved on 2012-02-24.
  6. Platers' guide: with which is combined Brass world. Brass world publishing co., inc. 1905. pp. 82–. Retrieved 24 February 2012.
  7. Arthur Amos Noyes; Massachusetts Institute of Technology (1900). Review of American chemical research. pp. 44–. Retrieved 24 February 2012.
  8. Taylor, Howard F; Flemings, Merton. C; Wulff, John (1959). Foundry Engineering. John Wiley and Sons, New York; Chapman and Hall, London. LCCN   59011811.
  9. Müller, H. R. (Ed.) (2006). Continuous casting. John Wiley and Sons.
  10. "Direct Chill Casting Model" (PDF). December 2000. Archived from the original (PDF) on 2011-07-24. Retrieved 2010-03-25.

Further reading