Lechatelierite

Last updated
Lechatelierite
Lechatelierite created by high voltage power line arcing on rocky soil- 2014-02-12 23-02.jpg
Lechatelierite created by a high voltage power line arcing on rocky soil
General
CategoryOxides
Formula
(repeating unit)
SiO2
IMA symbol Lch [1]
Strunz classification 4/D.01-10
Dana classification 75.0.0.0
Crystal system Amorphous
Identification
Formula mass 60.08 gm
ColourColourless, white
Crystal habit Porcelainous
Cleavage None
Fracture Conchoidal
Mohs scale hardness6.5
Luster Vitreous
Streak White
Diaphaneity Translucent
Density 2.5–2.65

Lechatelierite is silica glass, amorphous SiO2, non-crystalline mineraloid. It is named for Henry Louis Le Chatelier.

Contents

Structure

Lechatelierite is a mineraloid as it does not have a crystal structure. Although not a true mineral, it is often classified in the quartz mineral group.

Formation

One common way in which lechatelierite forms naturally is by very high temperature melting of quartz sand during a lightning strike. The result is an irregular, branching, often foamy hollow tube of silica glass called a fulgurite. [2] Not all fulgurites are lechatelierite; the original sand must be nearly pure silica.

Lechatelierite also forms as the result of high pressure shock metamorphism during meteorite impact cratering and is a common component of a type of glassy ejecta called tektites. Most tektites are blobs of impure glassy material, but tektites from the Sahara Desert in Libya and Egypt, known as Libyan desert glass , are composed of almost pure silica that is almost pure lechatelierite. [3] High pressure experiments have shown that shock pressures of 85 GPa are needed to produce lechatelierite in quartz grains embedded in granite. [4]

Lechatelierite was formed during the impact of a meteorite into a layer of Coconino Sandstone at Meteor Crater in Arizona. During the rapid pressure reduction following the impact, steam expanded the newly formed lechatelierite. The shattered and expanded glass has a density less than that of water. [5]

Lechatelierite may also form artificially, a unique example being the trinitite produced by melting of quartz sand at the first nuclear bomb explosion at Trinity Flats, White Sands, New Mexico. [6]

Related Research Articles

<span class="mw-page-title-main">Impact crater</span> Circular depression in a solid astronomical body formed by the impact of a smaller object

An impact crater is a circular depression in the surface of a solid astronomical body formed by the hypervelocity impact of a smaller object. In contrast to volcanic craters, which result from explosion or internal collapse, impact craters typically have raised rims and floors that are lower in elevation than the surrounding terrain. Impact craters range in size from microscopic craters seen on lunar rocks returned by the Apollo Program to simple bowl-shaped depressions and vast, complex, multi-ringed impact basins. Meteor Crater is a well-known example of a small impact crater on Earth.


A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific minerals, for example, obsidian is an amorphous glass and not a true crystal; lignite (Jet) is derived from the decay of wood under extreme pressure underground; and opal is a mineraloid substance because of its non-crystalline nature. Pearl is a mineraloid substance because the calcite crystals and the aragonite crystals are bonded by an organic material, and naturally occurs without definite proportions of the components.

<span class="mw-page-title-main">Tektite</span> Gravel-sized glass beads formed from meteorite impacts

Tektites are gravel-sized bodies composed of black, green, brown or grey natural glass formed from terrestrial debris ejected during meteorite impacts. The term was coined by Austrian geologist Franz Eduard Suess (1867–1941), son of Eduard Suess. They generally range in size from millimetres to centimetres. Millimetre-scale tektites are known as microtektites.

<span class="mw-page-title-main">Fulgurite</span> Rock type formed by lightning strike

Fulgurites, commonly called "fossilized lightning", are natural tubes, clumps, or masses of sintered, vitrified, or fused soil, sand, rock, organic debris and other sediments that sometimes form when lightning discharges into ground. When composed of silica, fulgurites are classified as a variety of the mineraloid lechatelierite.

<span class="mw-page-title-main">Shocked quartz</span> Form of the mineral quartz, found in nuclear test sites and meteor impact zones

Shocked quartz is a form of quartz that has a microscopic structure that is different from normal quartz. Under intense pressure, the crystalline structure of quartz is deformed along planes inside the crystal. These planes, which show up as lines under a microscope, are called planar deformation features (PDFs), or shock lamellae.

<span class="mw-page-title-main">Coesite</span> Silica mineral, rare polymorph of quartz

Coesite is a form (polymorph) of silicon dioxide (SiO2) that is formed when very high pressure (2–3 gigapascals), and moderately high temperature (700 °C, 1,300 °F), are applied to quartz. Coesite was first synthesized by Loring Coes, Jr., a chemist at the Norton Company, in 1953.

<span class="mw-page-title-main">Impactite</span> Rock created or modified by impact of a meteorite

Impactite is rock created or modified by one or more impacts of a meteorite. Impactites are considered metamorphic rock, because their source materials were modified by the heat and pressure of the impact. On Earth, impactites consist primarily of modified terrestrial material, sometimes with pieces of the original meteorite.

<span class="mw-page-title-main">Albite</span> Mineral, Na-feldspar, Na-silicate, tectosilicate

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3
O
8
. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.

<span class="mw-page-title-main">Stishovite</span> Tetragonal form of silicon dioxide

Stishovite is an extremely hard, dense tetragonal form (polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle.

<span class="mw-page-title-main">Moon rock</span> Rocks on or from the Moon

Moon rock or lunar rock is rock originating from Earth's Moon. This includes lunar material collected during the course of human exploration of the Moon, and rock that has been ejected naturally from the Moon's surface and landed on Earth as meteorites.

<span class="mw-page-title-main">Libyan desert glass</span> Desert glass found in Libya and Egypt

Libyan desert glass or Great Sand Sea glass is an impactite, made mostly of lechatelierite, found in areas in the eastern Sahara, in the deserts of eastern Libya and western Egypt. Fragments of desert glass can be found over areas of tens of square kilometers.

<span class="mw-page-title-main">Clastic rock</span> Sedimentary rocks made of mineral or rock fragments

Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus, chunks, and smaller grains of rock broken off other rocks by physical weathering. Geologists use the term clastic to refer to sedimentary rocks and particles in sediment transport, whether in suspension or as bed load, and in sediment deposits.

<span class="mw-page-title-main">Coconino Sandstone</span> Geologic formation

Coconino Sandstone is a geologic formation named after its exposure in Coconino County, Arizona. This formation spreads across the Colorado Plateau province of the United States, including northern Arizona, northwest Colorado, Nevada, and Utah.

<span class="mw-page-title-main">Maskelynite</span> Glassy material found in some meteorites and meteorite impact craters

Maskelynite is a glassy material found in some meteorites and meteorite impact craters. Typical samples are similar in composition to plagioclase feldspar, and revert to that mineral when melted and recrystallized. It was named after British geologist M.H.N. Story-Maskelyne.

Edward Ching-Te Chao was one of the founders of the field of impact metamorphism, the study of the effects of meteorite impacts on the Earth's crust.

Shock metamorphism or impact metamorphism describes the effects of shock-wave related deformation and heating during impact events.

Vitrified sand is sand that has been heated to a high enough temperature to undergo vitrification, which is the melting of the silicon dioxide or quartz that compose common sand. Vitrified sand is a type of natural glass, contrasted with manufactured glass in which soda ash or potash are added to lower the melting point. Pure quartz melts at 1,650 °C (3,002 °F). There are several natural processes that produce more or less melted sand and one man-made form:

<span class="mw-page-title-main">Seifertite</span> Dense silica mineral

Seifertite is a silicate mineral with the formula SiO2 and is one of the densest polymorphs of silica. It has only been found in Martian and lunar meteorites, where it is presumably formed from either tridymite or cristobalite – other polymorphs of quartz – as a result of heating during the atmospheric re-entry and impact to the Earth, at an estimated minimal pressure of 35 GPa. It can also be produced in the laboratory by compressing cristobalite in a diamond anvil cell to pressures above 40 GPa. The mineral is named after Friedrich Seifert (born 1941), the founder of the Bayerisches Geoinstitut at University of Bayreuth, Germany, and is officially recognized by the International Mineralogical Association.

Reidite is a rare polymorph of ZrSiO4 created when zircon experiences high pressure and temperature. Reidite is denser than zircon and has the same crystal structure as scheelite. All natural occurrences of reidite are associated with meteorite impact events.

Hypatia is a small stone found in Egypt in 1996. It has been claimed to be both a meteorite and kimberlite debris. It has also been claimed to be the first known specimen of a comet nucleus on Earth, although defying physically-accepted models for hypervelocity processing of organic material. As of November 2023, Hypatia has not been officially classified as a meteorite in the Meteoritical Bulletin, which is tasked with recording all scientifically proven meteorites.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Lechatelierite on Mindat.org
  3. Libyan Desert Glass on Mindat
  4. C. Schrand and A. Deutsch, 1998, Formation of Lechatelierite and Impact Melt Glasses in Experimentally Shocked Rocks, Lunar and Planetary Science XXIX 1671.pdf retrieved Sept. 13, 2014
  5. "Puffed up and pulverised". American Museum of Natural History . Retrieved 14 September 2014.
  6. "Lechatelierite Mineral Data" on Mineralogy Database.