Selenidostannate

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Selenidostannates are chemical compounds which contain anionic units of selenium connected to tin. They can be considered as stannates where selenium substitutes for oxygen. Similar compounds include the selenogermanates and thiostannates. They are in the category of chalcogenidotetrelates or more broadly chalcogenometallates.

Contents

Formation

Some selenidostannates can be made by treating tin diselenide (SnSe2) with an alkali selenide dissolved in water. [1] Other possible solvents include  choline chloride with 1,8-diaminooctane, [2]

Properties

Most selenidostannates are semiconductors. Their resistance drops on exposure to light. Also selenidostannates are often coloured, most often orange, red or yellow.

Many are unstable in humid air, as the water reacts with the selenidostannate to form hydrogen selenide (H2Se).

Use

Selenidostannates are primarily of research interest. They are under investigation as photoelectric materials.

List

namechemmwcrystal systemspace groupunit cell Åvolumedensitycommentreferences
tris(μ2-1,2-Diaminoethane)-1,2-diaminoethane-di-lithium triselenido-tin(iv)Li4Sn2Se6 · 8enmonoclinicC2/ca=22.660 b=9.449 c=20.336 β=101.24° [3]
diammonium[NH4]2Sn4Se9orthorhombicPnmaa =13.2274 b=12.4270 c=12.6102supertetrahedra Sn4Se10 arranged in layers [4]
bis(dimethylammonium) heptakis(μ-selenido)-tri-tin dimethylamine solvate[NH2(CH3)2]2Sn3Se7·0.5NH(CH3)2monoclinicC2/ca=23.5939 b=13.6409 c=15.0372, β=102.177°chains of Sn3Se8 [4]
tetrakis(ethylammonium) tetradecakis(μ-selenido)-hexa-tin[NH3C2H5]2Sn3Se7orthorhombicCmcaa=13.5561 b=24.0194 c=27.0184 [4]
bis(Ethylenediammonium) ethylenediamine bis((μ2-selenido)-diseleno-tin(iv))[enH2]2[Sn2Se6] · entriclinicP1a =8.636 b =11.044 c =6.613, α =104.48° β =110.76° γ =79.43°twin edge-bridged SnSe4 tetrahedra [5]
tetrakis(2-Aminoethylammonium) bis(μ2-selenido)-tetraselenido-di-tin(iv) 1,2-diaminoethane[enH]4[SnIV2Se6] · entriclinicP1a=11.212 b=11.631 c=13.097, α=79.40° β=76.82° γ=64.82° [6]
catena(Ethylenediammonium hemiethylenediamine (μ3-selenido)-hexakis(μ2-selenido)-tri-tin(iv))[enH2][Sn3Se7]·0.5enorthorhombicFdd2a=23.597 b=27.563 c=13.877 [4] [5]
catena-(tetrakis(μ2-Seleno)-ethylenediamine-di-tin(iv))[2 SnSe2·en]orthorhombicPca21a 1=3.724 b =11.866 c =13.647 [5]
[(C2H5)3NH]2Sn3Se7P2121212.12 eV [4]
[(C2H5)3NH]2Sn3Se7·0.25H2OmonoclinicP21/n2.1 eV [4]
(Et4N)2Sn3Se7monoclinicP21/ma=10.140 b=13.858 c=12.071, β=100.649° [7]
[NEt4]4[Sn4Se10]cubicP43na = 22.17010897 [8]
bis(tetrapropylammonium) nonaselenidotetrastannate(IV)([C3H7]4N)2[Sn4Se9]monoclinicP21/na = 15.328, b = 19.058, c = 15.398, β = 97.947°, Z = 44454.7orange [9]
(C7N4OH16)2Sn3Se7·H2orthorhombicPbca [4]
(NH3(CH2)8NH3)Sn3Se7triclinicP1 [4]
Octane-1,8-diammonium (μ3-selena)-hexakis(μ2-selena)-tri-tin(NH3(CH2)8NH3)Sn3Se7triclinicP1a=8.4419 b=11.6441 c=13.1857 α=66.636° β=77.989° γ=83.919° [10]
Decane-1,10-diammonium (μ3-selena)-hexakis(μ2-selena)-tri-tin(NH3(CH2)10NH3)Sn3Se7monoclinicC2/ca=23.726 b=13.910 c=15.954 β=111.915° [10]
(NH3(CH2)10NH3)Sn3Se7monoclinicC2/c [4]
tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ3-selenido)-octadecakis(μ2-selenido)-nona-tinmonoclinicP21/ca =18.652 b=20.353 c=20.196 β=105.244° [11]
tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) dodecakis(μ2-selenido)-diselenido-hexa-tin[Mmpmim]4Sn6Se14monoclinicP21/ca=14.270 b=15.549 c=14.377 β=92.749° [11]
bis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) (μ3-selenido)-hexakis(μ2-selenido)-tri-tin[Mmpmim]2Sn3Se7trigonalP3221a=13.9470 b=13.9470 c=27.8553 [11]
octakis(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) tetrakis(μ3-selenido)-docosakis(μ2-selenido)-diselenido-dodeca-tin[Mmpmim]8Sn12Se26monoclinicP21/ca=24.538 b=13.961 c=19.434 β=94.539° [11]
tetra(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) bis(μ3-selenido)-dodecakis(μ2-selenido)-hexa-tin[Mmbmim]4Sn6Se14trigonalP3221a=13.9381 c=27.774 [11]
[prmmim]2[Sn3Se7]P3221 [4]
Bmmim=1-butyl-2,3-dimethylimidazolium[bmmim]2[Sn3Se7]P3221band gap 2.2 eV [4]
Bzmim = 1-benzyl-3-methylimidazolium

bis(1-benzyl-3-methylimidazolium) heptakis(μ-selenido)-tri-tin

[Bzmim]2[Sn3Se7]orthorhombicPbcaa=14.297 b=13.8808 c=16.8855 β=99.817° [12]
Emim = 1-ethyl-3-methylimidazolium

pentakis(1-ethyl-3-methylimidazolium) bis(heptakis(μ-selenido)-tri-tin) chloride unknown solvate

[Emim]5[Sn3Se7]2ClhexagonalP63/mmca=13.8331 c=18.4649 [12]
[DBNH]2[Sn3Se7]·PEGmonoclinicC2/cband gap 2.13 eV [4]
[DBNH]3[NH4][Sn6Se14]trigonalR3band gap 2.02 eV [4]
(H+-DBN)2[Sn3Se7]Cmc21band gap 2.02 eV [4]
(CH3)3N(CH2)2OH]2[Sn3Se7]orthorhombicPbcaband gap 2.35 eV [4]
catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate](CH3)3N(CH2)2OH]2[Sn3Se7]∙H2OmonoclinicP21/na=9.8365 b=13.5796 c=20.7384 β=92.727° Z=42893.02.606orange; [4] [13]
catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin](CH3)3N(CH2)2CH3]2[Sn3Se7]orthorhombicPbcaa =17.534 b =13.7273 c =24.1221 Z=85806.22.547orange [14]
bis(N,N,N-trimethylbutanaminium) poly[heptaselenidotristannate(IV)](Bu(CH3)3N)2[Sn3Se7]monoclinicC2/ca = 23.950, b = 13.760, c = 20.011, β = 114.565°, Z = 85998orange [4] [15]
AEPP = N-aminoethylpiperazine[AEPPH2]2[Sn5Se12]triclinicP1a = 10.6351, b = 10.6850, c = 10.7771, α = 61.344°, β = 62.442°, γ = 67.468 [16]
phen=1,10-Phenanthroline(CH3NH3)4(Sn2Se6)·6phentriclinicP1a 10.594 b 12.225 c 14.945 α 83.589° β 83.133° γ 86.604° [17]
Im=imidazolium

catena-(pentakis(3-n-butyl-1-methylimidazolium) dodecakis(μ-selenido)-nona-tin tetrafluoroborate)

(C4C1C1Im)5[Sn9Se20][BF4]monoclinicP21/na=13.878 b=20.365 c=31.026 β =91.326° Z=487662.652orange [18]
DMMP=2,6-dimethylmorpholine(DMMPH)4[Sn2Se6]monoclinicP21/na=6.158 b=22.381 c=14.642 β=93.57° Z=22014.11.926yellow [18]
catena-(bis(1-ethyl-3-methylimidazolium) bis(2,6-dimethylmorpholin-4-ium) tetradecakis(μ-selenido)-hexa-tin)(C2C1Im)2(DMMPH)2[Sn6Se14]monoclinicP21/na=20.616 b=13.857 c=19.629 β=107.40° Z=453512.821orange [18]
catena-[tetrakis(3-n-Butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(μ3-selenido)-undecakis(μ2-selenido)-selenido-hexa-tin(iv)][BMMIm]4[Sn6Se14]monoclinicP21/ca 24.2744 b 13.8901 c 19.1763 β 94.083° Z=46449.32.503orange [19]
catena-(hexadecakis(1-butyl-2,3-dimethylimidazolium) octakis(μ3-selenido)-octatetracontakis(μ2-selenido)-tetracosa-tin)[BMMIm]16[Sn24Se56]trigonalP32a=27.8622 c=28.0566 Z=318862.42.568red [19]
catena-(tris(3-Butyl-1,2-dimethylimidazolium) 2,6-dimethylmorpholin-4-ium (μ3-selenido)-dodecakis(μ2-selenido)-selenido-hexa-tin)[BMMIm]3[DMMPH][Sn6Se14]triclinicP1a 11.1358 b 12.6745 c 23.362, α 89.690° β 88.473° γ 72.098° Z=23136.62.534orange or yellow (low temp) [19]
1-butyl-3-methyl-inidazolinium[BMIm]4[Sn9Se20]monoclinicCca=19.901 b=26.494 c=14.447 β=105.34 Z=473612.892red [20]
catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate][HOCH2CH2N(CH3)3]2Sn3Se7·H2OmonoclinicP21/na 9.8365 b 13.5796 c 20.7384 β 92.727°orange (high temp) or yellow [21]
catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin][CH3CH2CH2N(CH3)3]2Sn3Se7orthorhombicPbcaa 17.403 b 13.7025 c 23.91132.852yellow [21]
tetrakis(piperidinium) bis(μ-selenido)-tetraselenido-di-tin{[Sn2Se6]·4(C5NH12)}monoclinicP21/na 10.3277 b 10.2808 c 15.7823 β 96.725°2.0110red [22]
catena-[bis(3,6,7,8-tetrahydro-2H-pyrrolo[1,2-a]pyrimidin-5-ium) tetrakis(μ-selenido)-hexa-tin]{[Sn3Se7]·2(HDBN)} DBN = 1,5-diazabicyclo[4.3.0]non-5-eneorthorhombicCmc21a 13.4435 b 24.4817 c 14.4494red [22]
[dabcoH]2[(CH3)2NH2]2[Sn2Se6]monoclinicC2/ma=20.172 b=11.674 c=6.476 β=103.15 Z=21485.22.303yellow [23]
(N2H4)3(N2H5)4Sn2Se6triclinicP1a = 6.6475, b = 9.5474, c = 9.883, α = 94.110°, β = 99.429°, γ = 104.141°, Z = 1 [24]
bis(1-Aminoethylammonium) bis(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane-potassium) bis(μ2-seleno)-tetraseleno-di-tin(iv)(enH)2(2,2,2-crypt-K)2Sn2Se6monoclinicP21/na=8.442 b=25.877 c=14.821 β=104.19°
(MeSn)4Se6triclinicP1a = 9.147, b =10.495 c =10.508, α = 85.60, β = 89.83 γ =65.71° Z=2916adamantane structure [25]
Na4SnS4tetragonalI41acd [26]
Na4SnS4tetragonalP421ca=7.84679 c=6.95798, Z=2428.42yellow [26]
Na4SnSe4·14H2O [26]
Na4SnSe4·16H2OmonoclinicP21/ma = 8.673, b = 16.563, c = 8.647, β = 92.10°, Z = 2tetrahedra; Sn-Se bond length 2.504−2.527 Å [27] [1]
Na4Sn2S6·5H2O [28]
Na4Sn2Se6·13H2OtriclinicP1a = 7.106, b = 10.330, c = 19.009, α = 78.60, β = 85.66, γ = 72.85° Z = 2 (at −130°C)orange-red; tetrahedral edge-shared pairs [27] [29]
Na4Ge2Se6 · 16 H2OmonoclinicP21/ca = 9.894, b = 11.781, c = 12.225, β = 92.90°, Z = 2 [30]
Na4Sn3Se8trigonal bipyramid + tetrahedron [27]
Na6Sn4Se11 · 22 H2OmonoclinicC2/ca 15.325 b 11.634 c 26.739 β 95.81°yellow-orange [31]
Na6Sn2Se7·16H2Ored [29]
catena-(tris(1-Amino-2-ammonioethane) octakis(μ3-selenido)-hexakis(μ2-selenido)-sodium-hexa-tin sesquikis(dimethylamine) sesquihydrate)(enH)3Na[Sn3Se7]2·1.5Me2NH·1.5H2OR32a=13.8647 c=18.962Na+ ion conductor [32]
bis((μ4-Selenido)-(μ3-selenido)-bis(μ2-ethylene-1,2-diamine))-tetra-sodium-tin[Na4(en)4][SnSe4]orthorhombicP41212a=13.090 b=13.090 c=14.548 [33]
Li2MgNaSe4orthorhombicPmn21a = 8.40 b = 7.18 c = 6.73 Z=2405.93.867yellow; moisture absorbing [34]
SnPSe3monoclinicPna=6.8161 b=7.7264 c=9.6437 β=91.073° [35]
K4SnSe4orthorhombicPnmaa=14.714 b=10.323 c=8.248 Z=4yellow [36]
2D-K2Sn2Se5orthorhombicPbcaa=13.0246 b=12.186 c=14.135 Z=8 [37]
K4Sn2Se6tetrahedral edge-shared pairs [27]
K4Sn3Se8orthorhombicCccaa 8.214 b 27.795 c 8.2136 [38]
K0.5[Sn3Se7]hexagonalP6522a=13.8325 c 43.295 Z=127174.12.579red [18]
K6Sn4Se11 . 8H2OmonoclinicC2/ca =28.004 b =9 c =15.192, β 113.8° [7]
K6[SnIII2Se6] [6]
K4Sn4Se10·4.5H2OtrigonalR3a=15.32 c=21.019 [39]
tetrakis(Tetramethylammonium) (hexakis(μ2-seleno)-di-tin(iv)-potassium)K(N(CH3)4)3Sn2Se6triclinicP1a 9.587 b 10.005 c 15.996 α 95.15° β 92.81° γ 106.96° [40]
(μ2-Ethylene-1,2-diamine-N,N')-bis(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium (μ2-ethylene-1,2-diamine-N,N')-(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium hexakis(μ2-selenido)-(tetraselenoxy)-tetra-tin(iv)[18-crown-6-K]4[Sn4Se10]·5enmonoclinicP21/na=22.003 b=18.966 c=24.392 β=97.548° [41]
dipotassium(+) bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)potassium(+)] hexaselenodistannate(4-) tetrakis(ethylenediamine) solvate (18-crown-6)K2[K(C12H24O6)]2[Sn2Se6].4C2H8N2monoclinicP21/na=15.634 b=8.479 c=23.404 β=108.60° [42]
bis((4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium) tris(tetraselenido)-tin(iv)[K-(2,2,2-crypt)]2Sn(Se4)3triclinicP1a=10.7088 b=12.9986 c=21.7865 α=86.299° β=81.598° γ=87.258° [43]
Ca(en)4Ca(en)3[Sn2Se6]triclinicP1a = 10.2708, b = 12.2739, c = 16.3103, α = 93.576°, β = 90.609°, γ = 109.269°, Z = 11936.09 [44]
[VII(dien)2]2[Sn2Se6]monoclinicP21/na 9.7686 b 15.094 c 12.517 β 91.007°band gap 2.11 eV [45]
catena-(tetraethylenepentaminedi-ium octakis(μ-selenido)-bis(tetraethylenepentamine)-tetraselenolato-tetra-tin(iv)-di-vanadium(iii))[H2tepa]0.5[VIII(tepa)(μ-Sn2Se6)]orthorhombicAbm2a=7.808 b=41.97 c=16.982 Z=855652.496 [46]
tepa = tetraethylenepentamine

bis(Hydroxy-tetraethylenepentamine-chromium) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) monohydrate

[Cr(tepa)(OH)]2Sn2Se6·H2OorthorhombicPbcna=16.767 b=14.552 c=14.8592.08 eV [47]
peha = pentaethylenehexamide

bis(Pentaethylenehexamine-chromium) dichloride 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate)

[Cr(peha)]2(Sn2Se6)Cl2monoclinicP21/na=9.636 b=14.361 c=15.357 β=106.50°2.19 eV [47]
en = ethylenediamine, pip = piperazine

pentakis(tris(ethylenediamine)-chromium(iii)) bis(tetrakis(selenyl)-tin(iv)) heptakis(chloride) piperazine solvate

[Cr(en)3]2.5[SnSe4]·Cl3.5·(pip)0.5·1.5H2OtrigonalR3ca=15.4035 c =61.487band gap 2.23 eV;SnSe4 tetrahedron [2]
catena-[(μ3-Selenido)-(μ2-selenido)-bis(1,2-diaminoethane)-selenido-manganese-tin]SnSe3Mn(en)2monoclinicP21/na =9.4565 b =11.2896 c =12.7937 β =103.765° Z=42.657red [48]
catena-[(μ3-Selenido)-bis(μ2-selenido)-(1,2-diaminoethane)-manganese-tin]SnSe3Mn(en)orthorhombicPbcaa=13.9290 b=7.5261 c=19.2572 Z=82018.73.097red [48]
catena-[bis(μ3-Selenido)-bis(μ2-selenido)-bis(1,2-diaminoethane)-di-manganese-tin]MnSnSe4Mn(en)2orthorhombicPnmaa=13.1101 b=14.8267 c=7.9466 Z=41544.662.858yellow [48]
pentaehtylenehexaamine[Mn(peha)][Sn3Se7]monoclinicP21/n [4]
[Mn(dien)2]Sn3Se7·0.5H2OmonoclinicP21/nband gap 1.89 eV [4]
[Mn(en)2.5(en-Me)0.5][Sn3Se7]monoclinicP21/c [4]
catena-[tris(ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin][Mn(en)3][Sn3Se7]monoclinicP21/na=12.2277 b=13.1904 c=15.9272 β=100.174°red [4] [49]
catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin monohydrate][Mn(dien)2][Sn3Se7]∙H2OmonoclinicP21/na=12.3987 b=13.3150 c=16.6672 β=96.378°red; band gap 2.04 eV [4] [49]
[Mn(dien)2]Sn3Se7·0.5H2OmonoclinicP21/na 12.322 b 13.300 c 16.706 β 96.331° [50]
bis(bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) bis(μ-selenido)-tetrakis(selenido)-di-tin[Mn(dien)2]2Sn2Se6monoclinicP21/na 12.677 b 9.585 c 15.595 β 102.49(3)° [50]
[Mn(dien)2]MnSnSe4orthorhombicC2221a=9.002 b=17.761 c=12.967band gap 2.25 eV [51]
catena-[tris(ethane-1,2-diamine)-manganese(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin][Mn(en)3]Sn3Se6(Se2)monoclinicP21/na 11.974 b 14.046 c 15.893, β 99.78° [52]
catena-((bis(diethylenetriamine)-manganese(ii)) bis(μ-selenido)-manganese)[Mn(en)3][Sn(Se4)3]triclinicP1a 10.222 b 12.175 c 12.394, α 89.37° β 74.97° γ 75.66° [52]
en = ethylenediamine, hda = N-(2-hydroxyethyl)ethylenediamine)

bis(bis(ethylenediamine)-(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii)) bis(μ-selenido)-tetrakis(selenido)-di-tin

[Mn(en)2(hda)]2[Sn2Se6]monoclinicP21/na 9.1189 b 12.3968 c 17.515 β 97.010° [53]
catena-[bis(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin][Mn(hda)2][SnMnSe4]monoclinicC2/ca 9.4497 b 17.6025 c 13.1121 β 103.617° [53]
dien = diethylenetriamine

catena-[bis(diethylenetriamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin]

[Mn(dien)2][SnMnSe4]orthorhombicC2221a 9.0169 b 17.740 c 12.9543 [53]
heptakis(μ2-selenido)-(tetraethylenepentamine)-manganese(ii)-tri-tin(iv)Mn(tepa)·Sn3Se7orthorhombicP212121a=12.533 b=13.709 c=13.989 [54]
tetrakis(μ2-selenido)-bis(seleno)-bis(tetraethylenepentamine)-di-manganese(ii)-di-tin(iv)[Mn(tepa)]2(μ2-Sn2Se6)tetragonalI41/aa=26.483 b=26.483 c=10.1423 [54]
hexakis(μ2-selenido)-tetrakis(1,10-phenanthroline)-di-manganese-di-tin dihydrate{[Mn(phen)2]2(μ2-Sn2Se6)}·H2OmonoclinicP21/na 11.061 b 10.061 c 25.21 β 90.081° [17]
catena-((μ3-selenido)-bis(μ2-selenido)-(1,10-phenanthroline)-manganese-tin)[Mn(phen)]2(μ4-Sn2Se6)triclinicP1a 9.721 b 10.257 c 10.346, α 118.24° β 112.53° γ 95.75° [17]
hexakis(μ-2-aminoethan-1-olato)-octakis(μ-selenido)-hepta-manganese-di-tinMn7(ea)6(SnSe4)2orthorhombicPccna=14.886 b=19.354 c=12.4314 Z=43581.52.993orange [55]
catena-(pentakis(μ2-selenido)-bis(1,10-phenanthroline)-manganese-di-tin)[Mn(phen)2](Sn2Se5)monoclinicC2/ca 16.639 b 12.961 c 14.088β 117.91° [17]
catena-[tris(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(tris(ethane-1,2-diamine)-manganese) icosakis(μ-selenido)-selenido-nona-tin chloride](Bmmim)3[Mn(en)3]2[Sn9Se21]ClmonoclinicP21/ca=19.4488 b=19.5108 c=26.6148 β=109.587°red [49]
catena-[hexakis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) bis((N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) tetratriacontakis(selenido)-selenido-pentadeca-tin](Bmmim)6[Mn(dien)2]2Sn15Se35monoclinicP21/na=13.4256 b=29.904 c=19.5845 β=106.643°red [49]
catena-[hemikis(tris(ethane-1,2-diamine)-manganese) hemikis((N-methylethane-1,2-diamine)-bis(ethane-1,2-diamine)-mangnaese) heptakis(μ-selenido)-tri-tin][Mn(en)2.5(en-Me)0.5][Sn3Se7]monoclinicP21/ca=12.1058 b=13.2204 c=18.2504 β=120.839° Z=42507.93.049orange [56]
catena-(bis(4-Aminobutan-1-aminium) tetrakis(μ2-selenido)-manganese-tin)(1,4-dabH)2MnSnSe4orthorhombicFdd2a =23.287 b=25.410 c=6.6053 [57]
tetrakis(2,2'-bipyridine)-hexakis(μ-selenido)-di-tin-di-manganese{Mn(2,2′-bipy)2}2(µ2-Sn2Se6)monoclinicP 21/na=8.756 b=20.960 c=12.484 β=95.66° [58]
hexakis(μ2-Selenido)-bis(1,4,8,11-tetraazacyclotetradecane)-di-manganese(ii)-di-tin{Mn(cyclam)}2(μ-Sn2Se6.15)monoclinicP21/na=9.949 b=16.783 c=11.649 β=105.208° [59]
hexakis(μ2-Selenido)-bis(2,2';6',2''-terpyridine)-di-manganese(ii)-di-tin{Mn(terpy)}2(μ-Sn2Se6)triclinicP1a=9.430 b=10.872 c=11.090 α=117.86° β=102.83° γ=103.22° [59]
tris(μ2-Selenido)-(2,2';6',2''-terpyridine)-manganese(ii)-tin{Mn(terpy)}2(μ-Sn2Se6)triclinicP1a=9.923 b=10.027 c=10.959 α=107.29° β=97.57° γ=115.10° [59]
(NMe4)2[MnSn4Se10]tetragonalI4a=9.865 c =15.317red [60]
Li4MnSn2Se7monoclinicCca=18.126 b=7.221 c=10.470 β=93.43° Z=41403.24.132orange [61]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene[DBNH]2[MnSnSe4]tetragonalP42/ncma=13.0305 c =6.6220 [62]
[Fe(tatda)]Sn3Se7monoclinicP21/n1.93 eV [4]
catena-((bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-iron)[Fe(dien)2]FeSnSe4orthorhombicC2221a =8.974 b =17.755 c =12.967band gap 2.21 eV [51]
bis(bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-tetraselenido-di-tin[Fe(dien)2]2Sn2Se6monoclinicP21/na=12.563 b=9.655 c=15.566 β=102.76°band gap 2.60 eV [51]
bis(bis(diethylenetriamine)-iron(ii)) ethane-1,2-diammonium bis(2-ammonioethyl)amine bis(bis(μ-selenido)-tetraselenido-di-tin)[H2en][H2dien][Fe(dien)2]2(Sn2Se6)2triclinicP1a=8.727 b=12.794 c=14.918, α=66.09° β=84.06° γ=75.33°band gap 2.58 eV [51]
catena-[tris(ethane-1,2-diamine)-iron(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin][Fe(en)3]Sn3Se6(Se2)monoclinicP21/ca =11.950 b =14.083 c =17.995 β =120.25° [52]
tris(ethane-1,2-diamine)-iron(ii) tris[tetraselanato]-tin[Fe(en)3][Sn(Se4)3]triclinicP1a 10.223 b 12.106 c 12.263, α 89.40° β 89.40° γ 75.45° [52]
tatda = 3,6,9,12-tetraazatetradecane-1,14-diamine

catena-[(3,6,9,12-tetraazatetradecane-1,14-diamine)-iron heptakis(μ-selenido)-tri-tin]

[Fe(tatda)]Sn3Se7monoclinicP21/na 12.1067 b 13.3225 c 17.0827 β 96.978° [50]
hexakis(μ2-selenido)-tetrakis(1,10-phenanthroline)-di-iron-di-tin[Fe(phen)2]2(μ2-Sn2Se6)monoclinicC2/ca 26.192 b 11.248 c 17.843 β 98.816° [17]
catena-(bis(tris(1,10-phenanthroline)-iron) bis(μ3-selenido)-dodecakis(μ2-selenido)-hexa-tin hydrate)[Fe(phen)3](Sn3Se7)·1.25H2OtrigonalR3ca=13.9483 c 75.476band gap 1.97 eV [17]
bipy = bipyridine

catena-[nonakis(μ-selenido)-tetra-tin tris(2,2'-bipyridine)-iron dihydrate]

[Fe(bipy)3]Sn4Se9·2H2OtrigonalR3ca=26.902 c 30.673 [63]
[Fe(bipy)3]2[Sn3Se7]2·bipy·2H2OmonoclinicP21/ca 27.055 b 13.391 c 24.756, β 103.88° [63]
heptakis(μ-selenido)-(tetra-ethylenepentamine)-iron-tri-tinSn3Se7Fe(tepa)orthorhombicP212121a 12.4958 b 13.7745 c 14.02333.112black [22]
bis[tris(ethane-1,2-diamine)-iron] 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate)[Fe(en)3]2Sn2Se6orthorhombicPbcaa =15.5062(9)Å b=11.8662 c=19.09662.146red [22]
{CpFe(CO)2}3{CpFe(CO)}Sn3Se4triclinicP1a 12.2066 b 12.584 c 13.0007, α 90.632° β 90.068° γ 120.836° [64]
(NMe4)2[FeSn4Se10]tetragonalI4a=9.878 c=15.345 [60]
[Co(en)3]2Sn2Se6orthorhombicPbcaa=15.640 b=11.564 c=18.742 [46]
[Co(dien)2]2Sn2Se6monoclinicP21/na=10.2224 b=14.5788 c=12.3921 β=91.237°1846.4yellow; black with water, ultrasound turns yellow [65] [46] [66]
[Co(en)(trien)]2Sn2Se6monoclinicP21/na 7.929 b 15.855 c 14.262 β 93.436° [67]
bis(tris(2,2'-bipyridine)-cobalt(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate[Co(2,2′-bipy)3]2[Sn3Se7]2·(2,2′-bipy)·H2OmonoclinicP21/ca=27.032 b=13.392 c=24.763 β=103.85° [58]
catena-[tris(ethylenediamine)-nickel hemikis(heptakis(μ-selenato)-selenato-tri-tin) hemikis(hexakis(μ-selenato)-selenato-tri-tin)][Ni(en)3][Sn3Se6.5(Se2)0.5]orthorhombicPca21a =14.88 b =1.8872Å c =13.8591.95 eV;chains of [Sn3Se7]n2n– and [Sn3Se6(Se)2]n2n– [2]
tris(ethylenediamine)-nickel(ii) tetrakis(μ-selanyl)-selanyl-di-tin[Ni(en)3][Sn2Se5]monoclinicP21/na=8.7998 b=10.0736 c=22.655 β=90.763° [68]
[Ni(en)3]2[Sn2Se6]orthorhombica=15.288 b=11.937 c=19.2393511.0 [46]
catena-[tris(ethylenediamine)-nickel heptakis(μ-selenato)-tri-tin][Ni(en)3][Sn3Se7]monoclinicP21/na=12.32 b=13.19 c=15.73 β=101.07°band gap 2.01 eV [2]
catena-[tris(1,2-diaminoethane)-nickel(ii) pentakis(μ-selenido)-bis(selenido)-tri-tin(iv)][Ni(en)3]Sn3Se7.5orthorhombicPca21a 14.869 b 11.888 c 13.860 [52]
tris(ethane-1,2-diamine)-nickel tris[tetraselanato]-tin[Ni(en)3][Sn(Se4)3]triclinicP1a 10.104 b 12.048 c 12.107, α 89.52° β 75.44° γ 75.78° [52]
phen = 1,10-phenanthroline

tris(1,10-phenanthroline)-nickel(ii) heptakis(μ-selenato)-tri-tin(iv) sesquihydrate

[Ni(phen)3]Sn3Se7·1.5H2OtrigonalR3a=13.971 c=38.281 [69]
[(Ni0.4Zn0.6)(en)6]Sn2Se6 [65]
catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) hemikis((μ2-triethylenetetramine)-bis(triethylenetetramine)-di-nickel) tris(μ3-selenido)-heptadecakis(μ2-selenido)-selenido-nona-tin)2D-(Bmmim)8[Ni2(teta)2(μ-teta)]Sn18Se42monoclinicP21/na =18.9764 b= 25.1081 c =20.5731 β =100.870° [70]
teta = triethylenetetramine

(ethylenediamine)-(triethylenetetramine)-nickel(ii) (triethylenetetramine)-(N-(2-hydroxyethyl)ethylenediamine)-nickel(ii) hexakis(μ-selenido)-tetrakis(selenido)-tetra-tin

[Ni(teta)(en)][Ni(teta)(hda)][Sn4Se10]monoclinicP21/na 12.3191 b 17.7104 c 22.643 β 95.278° [70]
tepa=tetraethylenepentamine

catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) bis(chloro-(tetraethylenepentamine)-nickel) pentakis(μ3-selenido)-tricosakis(μ2-selenido)-(tetraethylenepentamine)-nickel-dodeca-tin)

2D-(Bmmim)4[Ni(tepa)Cl]2[Ni(tepa)Sn12Se28]monoclinicPna=21.2230 b=13.4993 c=23.8715 β =112.461° [70]
Bmmim=1-butyl-2,3-dimethylimidazolium2D-(Bmmim)3[Ni(en)3]2[Sn9Se21]ClmonoclinicP21/ca 19.488 b 19.626 c 26.793 β 109.930° [53]
catena-(bis(1-n-Butyl-2,3-dimethylimidazolium) bis(tris(propane-1,2-diamine)-nickel) bis(bis(μ3-selenido)-heptakis(μ2-selenido)-tetra-tin))3D-(Bmmim)2[Ni(1,2-pda)3]Sn8Se18trigonalR3ca=27.7913 c 47.4281 [70]
catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-nickel sesquikis(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) hemikis(2-amino-N-(2-aminoethyl)ethylammonium) octadecakis(μ-selenido)-octa-tin]2D-(Bmmim)2[Ni(teta)(en)][Sn3Se7]2monoclinicP21/ca=31.088 b=10.5393 c=19.9712 β=99.966° [71]
catena-[(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-(ethane-1,2-diamine)-nickel bis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) tridecakis(μ-selenido)-selenido-hexa-tin]3D-(Bmmim)1.5(dienH)0.5Ni(dien)2[Sn4Se9]2monoclinicP21/ca=24.3753 b=13.3778 c=17.7885 β=93.949° [71]
[Ni(tren)(en)]SnSe3∙H2O638.64monoclinicP21/na=12.8150 b=10.0094

c=15.6626 β=???? Z=4

1885.8band gap [72]
bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin dihydrate[Ni(tren)(en)]2[Sn2S6]·2H2OmonoclinicP21/na 12.7041 b 9.8000 c 15.3989 β 108.843°3.23 eV [73]
bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin hexahydrate[Ni(tren)(en)]2[Sn2S6]·6H2OmonoclinicP21/ca 12.5580 b 9.7089 c 16.0359 β 91.827°3.16 eV [73]
bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin trihydrate[Ni(tren)(1,2-dach)]2[Sn2S6]·3H2OtriclinicP1a 9.8121 b 10.0080 c 12.422, α 86.38° β 79.65° γ 65.71°3.43 eV [73]
bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate[Ni(tren)(1,2-dach)]2[Sn2S6]·4H2OmonoclinicP21/ca 10.7119 b 19.0797 c 11.1005 β 104.803°3.29 eV [73]
bis((tris(2-aminoethyl)amine)-(propane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate[Ni(tren)(1,2-dap)]2[Sn2S6]·4H2OmonoclinicC2/ca 14.3925 b 15.1550 c 18.9307 β 99.108°3.32 eV [73]
bis((tris(2-aminoethyl)amine)-(2-(aminomethyl)pyridine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin decahydrate[Ni(tren)(2amp)]2[Sn2S6]·10H2OmonoclinicP21/na 12.1933 b 13.4025 c 14.8920 β 103.090°3.28 eV [73]
L1 = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane[Ni(L1)][Ni(L1)Sn2S6]n·2H2OmonoclinicP21/ca 11.6481 b 14.4268 c 10.8450 β 95.449°brown [74]
L2 = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane[Ni(L2)]2[Sn2S6]·4H2OtriclinicP1a 9.1562 b 10.3705 c 12.2897 α 66.761° β 85.350° γ 81.308° [74]
(μ2-triethylenetetramine)-bis(triethylenetetramine)-di-nickel(ii) tetrachloride dihydrate[Ni2(trien)2(μ-trien)]Cl4·2H2OorthorhombicPbcaa 13.737 b 13.089 c 18.193 [67]
bis(tris(2,2'-bipyridine)-nickel(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate[Ni(2,2′-bipy)3]2[Sn3Se7]2·(2,2′-bipy)·H2OmonoclinicP 21/ca=26.999 b=13.383 c=24.714 β=103.89° [58]
Cu2SnSe4F3mthermoelectric [75]
(1,4-dabH2)Cu2SnSe4orthorhombicP42/na=14.956 b=14.956 c=12.017 [57]
Na6Cu8Sn3Se13cubicFm3ca =18.4754 [76]
[Cu2SnSe5][Mn(Hen)2(en)]monoclinicP21/ca 9.640 b 21.04 c 10.611 β 100.72°1.49 eV [77]
[(Mn1.67Zn0.33)(en)6]Sn2Se6 [65]
K2Cu2Sn2Se6monoclinicC2/cZ=8black; band gap 1.04 eV [78]
Copper zinc tin selenideCu2ZnSnSe4black; photovoltaic 11.6% efficient [29]
catena-[tris(ethane-1,2-diamine)-zinc(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin][Zn(en)3]Sn3Se6(Se2)monoclinicP21/na 11.949 b 14.060 c 15.794 β 100.39° [52]
tris(ethane-1,2-diamine)-zinc(ii) tris[tetraselanato]-tin[Zn(en)3][Sn(Se4)3]triclinicP1a 10.156 b 12.096 c 12.109, α 89.64° β 75.49° γ 75.87° [52]
Zn2(en)2(μ4-SnSe4)tetragonalI41/aa =7.8032 c =31.528 [53]
tetrakis(μ-selenido)-bis(selenido)-bis(N,N-bis(2-aminoethyl)ethane-1,2-diamine)-di-tin(iv)-di-zinc(ii){Zn(tren)}2(μ-Sn2Se6)monoclinicC2/ca 12.414 b 9.846 c 23.970° β 102.395°2861.5band gap 2.38 eV [79]
tetrakis(μ-selenido)-bis(selenido)-bis(bis(2-(2-aminoethyl)aminoethyl)amine)-di-tin(iv)-di-zinc(ii){Zn(tepa)}2(μ-Sn2Se6)tetragonalI41/aa=26.6205 c =10.05337124.3band gap 2.31 eV [79]
catena-[bis(dimethylammonium) octakis(μ-selenido)-tri-tin(iv)-zinc(ii)][(Me)2NH2]2ZnSn3Se8monoclinicC2a=10.961 b=11.056 c=9.683 β=105.17° [80]
(Me4N)2Zn[Sn4Se10] [81]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene[DBNH]2[ZnSnSe4]tetragonalP42/ncma=13.033 c 6.548band gap 2.42 eV [62]
K2ZnSn3Se8monoclinicP21a 7.639 b 12.400 c 18.384 β 98.13°band gap 2.10 eV [82]
Cu2ZnSnSe4 [75]
[NH4]2Ga4Se8Sn4monoclinicP21/ca 7.582 b 12.501 c 18.377 β 96.43° [83]
catena-(1-ethylpyridinium hexakis(μ-selenido)-gallium-di-tin hydrate)H3CCH2NC5H5GaSn2Se6 ∙ 0.25H2OtetragonalI41/aa=26.401 c =10.464orange [84]
x~0.25Na2−xGa2−xSn1+xSe6monoclinicC2a=13.308 b=7.594 c=13.842 β=118.730°1226.7 [85]
K3Ga6Sn6Se12cubicPa3a=13.5555 Z=122490.84.347colourless [86]
KGaSnSe4cubicPa3a=13.5555 Z=122490.84.347orange [86]
[(TEPA)Mn]2+4[Sn4Ga4Zn2Se20]8−tetragonalP4b2a=17.4951 c 13.5849 [87]
(Et4N)2[Sn6Se10Br6]monoclinicP21/na = 14.0826 b = 14.1904 c = 24.277 β = 92.809° Z = 44845.6 [88]
Rb2Sn2Se5monoclinicC2/ca=11.555 b=8.478 c=12.030 β=108.60 Z=411174.78black; oxygen sensitive [89]
Rb4Sn4Se10·1.5H2OR3a 15.539 c 21.373 [39]
Rb2Cu2Sn2Se6monoclinicC2/cZ=8black; band gap 1.04 eV [78]
RbGaSnSe4cubicPa3a=13.72002582.634.550orange [86]
Rb2Sn4Se9-H2OorthorhombicPnmaa=13.298 b=12.418 c=12.563 [90]
Rb2MnSn3Se8monoclinicP21a 7.7864 b 12.6343 c 18.4878 β 95.810° [91]
Rb2MnSnSe4monoclinicP21/na=8.6015 b=10.956 c=10.675 β=90° [92]
Rb4Cu8Sn3S12cubicFm3ca=18.0851 [93]
(H3O)RbCu6Sn2S8tetragonalI4/ma=14.8834 c=7.6466 [93]
SrZnSnSe4orthorhombicFdd2a 21.6984 b 21.873 c 13.1140 [94]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-yttrium][Y2(tepa)2(μ-OH)2Sn2Se6]orthorhombicPbcaa=12.4190 b=13.6062 c=20.6569 Z=82.467orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-yttrium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate[Y2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2OtetragonalI41/aa=28.24 c=10.9402.025yellow [95]
Ru(bpy)3[Sn4Se9]1755.02trigonalR3ca=27.240 c=31.01 Z=18199272.632dark red [96]
β-Ag8SnSe6Pmn21 [4]
[NH4]3AgSn3Se8tetragonalP4/nbma=8.2155 c=13.413thermochromic: gold-darkred-gold [4] [80]
[NH4]4Ag12Sn7Se22monoclinicC2/ca=52.634 b=6.8175 c=13.5176 β=99.955 Z=44959.15.270black; band gap 1.21 eV [4] [97]
[(Me)2NH2]0.75[Ag1.25SnSe3]tetragonalP421ma=13.998 c=8.685 Z=81701.94.403dark red; band gap 1.85 eV [4] [98]
[CH3NH3]2[H3O]Ag5Sn4Se12·C2H5OHtetragonalP421ma=13.6350 c 9.1491 Z=8band gap 1.80 eV [4] [80]
catena-[bis(methylammonium) dimethylammonium dodecakis(μ-selenido)-penta-silver-tetra-tin][NH3CH3]0.5[NH2(CH3)2]0.25Ag1.25SnSe3tetragonalP421mb =13.7193 c 9.09644.019 [99]
[bmmim]7[AgSn12Se28]triclinicP1band gap 2.2 eV [4]
heptakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ3-selenido)-hexacosakis(μ2-selenido)-dodeca-tin-silver[Mmpmim]7Ag5Sn4Se12∙3H2OtriclinicP1a 10.8983 b 13.5554 c 23.091 α 88.904° β 86.700° γ 68.230° [11]
catena-[N1-(2-azaniumylethyl)ethane-1,2-bis(aminium) dodeca-selenium-tetra-tin-penta-silver trihydrate][H3dien][Ag5Sn4Se12]∙3H2OP421a =14.2623 b =14.2623 c =9.3022 [100]
K2Ag2SnSe4P2/cband gap 1.8 eV [4]
K2Ag2Sn2Se6P4/mmc [4]
K3AgSn3Se8P4/nbmband gap 1.8 eV [4]
[Mn(NH3)6][Ag4Mn4Sn3Se13]orthorhombicF43ca 19.1263Å b 19.1263Å c 19.1263 [101]
catena-(2-aminoethylammonium bis(μ4-sulfido)-bis(μ3-sulfido)-tin-di-copper-silver)[enH][Cu2AgSnS4]orthorhombicPnmaa=19.726 b=7.8544 c=6.5083 Z=41008.353.577red [102]
[Zn(NH3)6][Ag4Zn4Sn3Se13]orthorhombicF43ca=18.9679 b=18.9679 c=18.9679 [101]
(1,4-dabH2)Cu1.72Ag0.28SnSe4tetragonalP42/na=14.990 c=12.059band gap 2.43 eV [103]
Rb3AgSn3Se8P4/nbmband gap 1.8 eV [4]
Li6.4Cd4.8Sn4Se16orthorhombicPna21a=14.400 b=8.399 c=6.787band gap 1.95 eV [104]
tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ3-diselenido)-undecakis(μ2-selenido)-tri-cadmium-tetra-tin[DBNH]4[Cd3Sn4Se11(Se2)2]monoclinicC2/ca=22.236 b=12.623 c=21.756 β=109.91° [105]
Cd(tren)SnSe3triclinicP1a=7.752 b=8.128 c=12.467, α=97.299° β=103.639° γ=107.325° Z=2712.12.865 [106]
K2CdSnSe4625.16tetragonalI42ma=8.084 c=6.920452.24photocatalyst [107]
Cu2CdSnSe4 [75]
catena-(1-ethylpyridinium hexakis(μ-selenido)-indium-di-tin hydrate)CH3CH2NC5H5InSn2Se6 ∙ 0.25H2OtetragonalI41/aa=26.946 c =10.283orange [84]
[NH4]2[In2Sn2Se8]tetragonalI4/mcma=b 8.3731 c 6.719
catena-[tris(1,10-phenanthroline)-cobalt octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrate]Co(phen)3In2Sn2Se8 ∙ C6H11NH2 ∙ 4H2OmonoclinicP21/na=15.610 b=24.238 c=15.828 β=107.04° Z=457262.169orange [108]
tris(1,10-phenanthroline)-nickel octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrateNi(phen)3In2Sn2Se8 ∙ C6H11NH2monoclinicP21/na=15.574 b=24.083 c=15.804 β=107.11° Z=456652.192orange [108]
RbInSnSe4cubicPa3a=13.9728 Z=122728.044.637red; air sensitive [109]
RbInSnSe4monoclinicP21/ca= 7.8104 b= 12.6533 c= 18.7062

β= 96.297

1837.524.589orange [109]
Cs2Sn2Se5 . H2OorthorhombicAma2a =12.05 b =12.405 c =9.426 [7]
Cs2Sn2Se5 
Cs2Sn2Se6triclinicP1a =7.129 b =7.285 c =7.965, α =95.8° β =115.38° γ =108.46° [90]
Cs2Sn3Se7monoclinicC2/ca = 23.214, b = 13.679, c =14,657, β= 111.92°, Z = 8,4317red; SnSe5 trigonal bipyramids connected in sheets [4] [27]
Cs4Sn2Se6yellow; tetrahedral edge-shared pairs [27]
Cs4Sn4Se10·3.2H2OtriclinicP1a=7.235 b=9.468 c=11.235 α=68.77° β=83.25° γ=84.53° [39]
Cs2Sn4Se9-H2OorthorhombicPnmaa =13.514 b =12.54 c =12.679 [90]
(4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium tris(μ3-selenido)-tris(μ2-selenido)-bis(1,2-ethylenediamine-N)-(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-di-cesium-potassium-di-tin(iv)[K-(2,2,2-crypt)]2Cs2Sn2Se6·2entriclinicP1a=10.0019 b=13.8929 c=24.478 α=100.204° β=95.701° γ=90.147° [43]
Cs[Cr(en)2SnSe4]739.67monoclinicP21/na=7.6800 b=13.1483 c=15.7069 β=91.176° Z=41585.73.098black [110]
Cs2MnSnSe4orthorhombicFddda=6.4075 b=14.416 c=24.820 [92]
Cs2MgSn3Se8orthorhombicP212121a 7.9055 b 12.7661 c 18.474 [111]
Cs2MnSn3Se8orthorhombicP212121a 7.8798 b 12.7040 c 18.4556 [91]
Mn4Cs10Se17Sn4 ∙ 15.5H2OtriclinicP1a 13.717 b 15.502 c 18.481 α 77.02° β 74.35° γ 69.71° Z=235123.418red [56]
Zn4Cs10Se17Sn4 ∙ 17H2OtriclinicP1a 13.537 b 15.256 c 18.41, α 76.98° β 73.78° γ 69.57° Z=233863.577yellow [56]
Cs2ZnSn3Se8orthorhombicP212121a 7.8146 b 12.6534 c 18.3747 [111]
CsGaSnSe4orthorhombicPmcna 7.6785Å b 12.655Å c 18.278 [85]
Cd4Cs10Se17Sn4 ∙ 17H2OtriclinicP1a 17.8678 b 17.7949 c 23.5518 α 98.682° β 105.75° γ 90.307° Z=471163.617yellow [56]
Cs2CdSn3Se8orthorhombicP212121a 7.9335 b 12.7336 c 18.5387 [111]
CsInSnSe4cubicPa3a=14.1932 Z=122959.24.755red; air sensitive [109]
Ba2SnSe4709.21monoclinicP21/ca 8.582 b 9.255 c 12.460 β 114.28° Z=4902.25.221orange [112]
α-Ba2SnSe5orthorhombicP212121dark brown [113]
β-Ba2SnSe5monoclinicP21/ca = 9.3949 b = 8.8656 c = 12.5745 β = 113.299° Z = 4961.9high temperature; red [113]
m-Ba2SnSe5monoclinicP121/c1a = 21.17189 b = 9.0915 c = 24.7141 β = 125.621° [114]
Ba6Sn6Se13orthorhombicP212121a 9.2998 b 12.384 c 26.896 Z=43097.85.495black; 1.52 eV [115]
Li2Ba7Sn4Se16cubicI43da=15.1628 Z=43486.15.170 ?red [116]
Na2Ba7Sn4Se16cubicI43da=14.807 Z=432464.082red [116]
BaZnSnSe4orthorhombicFdd2a 22.2402 b 22.7047 c 13.19726664.05.081red; band gap 1.95 eV [117]
BaGa2SnSe6trigonalR3a = 10.145 c = 9.249 Z = 3824.45.253red

NLO 5.2 × AgGaS2 at 2.09 μm birefringence 0.1649 at 1.064 μm

 [118]
Ba4Ga4SnSe12band gap 2.14 [119]
BaAg2SnSe4orthorhombicI222a=7.10 b=7.47 c=8.30band gap 0.2 eV [4] [120]
BaCdSnSe4684.27orthorhombicFdd2a 22.38 b 22.71 c 13.588 Z=3269075.265orange [112]
catena-(hexakis(μ2-selenido)-(N-(2-(amino)ethyl)-N'-(2-((2-(amino)ethyl)amino)ethyl)ethane-1,2-diaminato)-di-tin-lanthanum hemihydrate)(H3O)[La(tepa)(μ-1κ2:2κ2-Sn2Se6)]monoclinicC2/ca=13.845 b=9.805 c=22.010 β=105.949° [121]
tetrakis(μ-selenido)-bis(3,6,9,12-tetraazatetradecane-1,14-diamine)-nitrato-chloro-di-lanthanum(iii)-tin{La(peha)(Cl)}{La(peha)(NO3)}(μ-1κ2:2κ2-SnSe4)]triclinicP1a 8.411 b 14.760 c 16.244 α 92.57° β 91.95° γ 102.18° Z=21967.32.15light yellow [122]
2,2'-(ethane-1,2-diyldiimino)diethanaminium tetrakis(μ-selenido)-tetrakis(triethylenetetramine )-diselenido-di-tin-di-lanthanum(iii) bis(μ-selenido)-tetraselenido-di-tin monohydrate[H2trien][{La(trien)2}2(μ-1κ:2κ-Sn2Se6)][Sn2Se6]·H2OmonoclinicP21/ca=14.903 b=16.763 c=16.552 β=101.231° Z=240562.01orange [122]
[{La(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞triclinicP1a 10.253 b 13.061 c 15.847 α 80.62° β 73.59° γ 88.60° Z=12007.92.514red [123]
[La2(en)8(μ-Se2)]Sn2SemonoclinicP21/na 10.079 b 14.843 c 14.918 β 90.599° Z=22231.72.422yellow [123]
La3AgSnSe7P63 [4]
catena-(hexakis(μ2-Selenido)-(tetraethylenepentamine)-cerium-di-tin monohydrate)(H3O)[Ce(tepa)(μ-1κ2:2κ2-Sn2Se6)]monoclinicC2/ca=13.852 b=9.802 c=22.035 β=105.98° [124]
tetrakis(μ2-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-cerium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ2-selenido)-tetraselenido-di-tin[Htrien]2[{Ce(trien)(tren)}2(μ-1κ:2κ-Sn2Se6)]triclinicP1a 9.832 b 10.584 c 18.091, α 90.097° β 92.448° γ 94.500° [124]
[{Ce(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞triclinicP1a 10.2333 b 13.0790 c 15.7663, α 80.422° β 73.738° γ 88.376° Z=11997.12.532orange [125]
[{Ce(en)4}2(μ-Se2)]Sn2Se6monoclinicP21/na 10.094 b 16.616 c 13.397 β 101.878° Z=22198.92.462light yellow [125]
BaCeSn2Se6orthorhombicPmc21a=4.1908 b=20.749 c=12.406 [126]
tetrakis(μ2-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-neodymium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ2-selenido)-tetraselenido-di-tin[Htrien]2[{Pr(trien)(tren)}2(μ-1κ:2κ-Sn2Se6)]triclinicP1a 9.842 b 10.578 c 18.080, α 90.065° β 92.532° γ 94.511° [124]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-praseodymium][Pr2(tepa)2(μ-OH)2Sn2Se6]orthorhombicPbcaa=12.450 b=13.617 c=21.005 Z=82.622orange [95]
[{Pr(en)3}2(μ-OH)2]Sn2Se6monoclinicP21/na 10.197 b 11.7622 c 15.497 β 98.967° Z=21835.92.510yellow [125]
catena-(bis(μ2-hydroxo)-tetrakis(μ2-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-neodymium-di-tin)[{Nd(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)]orthorhombicPbcaa=12.485 b=13.601 c=20.917 [121]
[{Nd(en)3}2(μ-OH)2]Sn2Se6monoclinicP21/na 10.176 b 11.772 c 15.470 β 99.128° Z=21829.82.531yellow [125]
[{Nd(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞triclinicP1a 10.184 b 12.979 c 15.751, α 80.448° β 73.991° γ 88.552° Z=11973.12.576red [125]
ethane-1,2-diaminium tris(N-(2-(amino)ethyl)ethane-1,2-diamine)-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate)[Hen][Sm(dien)3]Sn2Se6triclinicP1a=10.044 b=12.803 c=15.811 α=66.32° β=72.86° γ=68.35° [127]
bis(bis(N,N-bis(2-(amino)ethyl)ethane-1,2-diamine)-chloro-samarium) hemikis(N,N-bis(2-aminoethyl)ethane-1,2-diamine) bis(μ-selenido)-tetrakis(selenido)-di-tin[Sm(trien)(tren)(Cl)]2Sn2Se6·0.5entriclinicP1a=10.348 b=10.575 c=14.043 α=77.26° β=87.78° γ=61.410° [127]
bis(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-bis(ethane-1,2-diamine)-bis(μ-hydroxy)di-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate)[{Sm(en)(trien)}2(μ-OH)2]Sn2Se6triclinicP1a=10.044 b=12.803 c=15.811, α=66.32° β=72.86° γ=68.35° [127]
catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-samarium-tin hemihydrate][{Sm(tepa)(μ-OH)}2 (μ-1κ:2κ-Sn2Se6)]n·nH2OmonoclinicC2/ca=22.944 b=11.946 c=18.907 β=125.53° Z=442172.27yellow [122]
[Hdien][Sm(dien)2(μ-SnSe4)]monoclinicP2/ca 10.185 b 9.471 c 13.808 β 102.256° [128]
Eu8(Sn4Se14)(Se3)2orthorhombicP21212a = 11.990 b = 16.425 c = 8.543 [129]
catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-europium-tin hemihydrate][{Eu(tepa)(μ-OH)}2 (μ-1κ:2κ-Sn2Se6)]n·nH2OmonoclinicC2/ca=22.904 b=11.981 c=18.894 β=125.52° Z=442202.28yellow [122]
[Hdien][Eu(dien)2(μ-SnSe4)]monoclinicP2/ca 10.185 b 9.453 c 13.791 β 102.165° [128]
[Eu2(dien)4(μ-OH)2]Sn2Se6monoclinicP21/na 12.027 b 11.802 c 13.827 β 99.179° [128]
[{Eu(en)3}2(μ-OH)2]Sn2Se6monoclinicP21/na = 10.136 b = 11.771 c = 15.423 β = 99.322° Z = 21815.8 [130]
catena-(bis(μ2-hydroxo)-tetrakis(μ2-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-gadolinium-di-tin monohydrate)[{Gd(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)]·H2OmonoclinicC2/ca=22.82 b=11.975 c=18.918 β=125.975° [121]
[{Gd(en)3}2(μ-OH)2]Sn2Se6monoclinicP21/na 9.993 b 11.842 c 15.313° β 99.979° Z=21784.62.643yellow [125]
[Hdien][Gd(dien)2(μ-SnSe4)]monoclinicP21/ca 10.300 b 9.426 c 13.875 β 101.678° Z=21319.32.271red [125]
[Gd(dap)4]2[Sn2Se6]Cl2monoclinicP21/ca=10.2385 b=14.1276 c=18.068 β =102.745° [131]
[{Tb(en)3}2(μ-OH)2]Sn2Se61423.62monoclinicP21/na=10.120 b=11.781 c=15.403 β=99.534° Z=21811.12.611 [132]
bis(tetrakis(propane-1,2-diamine)-terbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate[Tb(dap)4]2[Sn2Se6]Cl2·H2OmonoclinicP21/ca=10.240 b=14.116 c=18.030 β=102.808° [131]
catena-[bis(μ2-selenido)-(μ2-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-dysprosium-tin][Dy2(tepa)2(μ-OH)2Sn2Se6]orthorhombicPbcaa=12.4132 b=13.5901 c=20.6722 Z=82.759orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-dysprosium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate[Dy2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2OtetragonalI41/aa=28.2390 c=11.03802.229yellow [95]
[Dy2(en)6(μ2-OH)2][Sn2Se6] [133]
bis(tetrakis(propane-1,2-diamine)-dysprosium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate[Dy(dap)4]2[Sn2Se6]Cl2·H2OmonoclinicP21/ca=10.214 b=14.118 c=18.000 β=102.798° [131]
bis(tetrakis(Propane-1,2-diamine)-holmium chloride) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate)[Ho(dap)4]2[Sn2Se6]Cl2monoclinicP21/ca=10.1839 b=14.1303 c=18.0100 β=102.571° Z=42529.5yellow [134]
bis(μ2-Hydroxo)-tetrakis(diethylenetriamine)-di-holmium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate){[Ho(dien)2]2(μ2-OH)2}[Sn2Se6]monoclinicP21/na=12.0096 b=11.7181 c=13.7717 β=99.138° Z=21913.52.586yellow [134]
bis(bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-bis(μ-hydroxo)-di-holmium) tricyclo[3.3.1.13,7]tetrastannaselenane-1,3,5,7-tetrakis(selenolate) tetrahydrate[Ho2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2OtetragonalI41/aa=28.076 c 10.9488629.62.281yellow; supertetrahedron [134]
catena-[bis(μ2-selenido)-(μ2-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-erbium-tin][Er2(tepa)2(μ-OH)2Sn2Se6]orthorhombicPbcaa=12.418 b=13.605 c=20.636 Z=82.778orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-erbium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate[Er2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2OtetragonalI41/aa=28.1622 c=11.00892.261yellow [95]
[Er2(en)6(μ2-OH)2][Sn2S6]monoclinicP21/na 9.951 b 11.860 c 15.278 β 100.239° [133]
bis(tetrakis(propane-1,2-diamine)-erbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate[Er(dap)4]2[Sn2Se6]Cl2·H2OmonoclinicP21/ca=10.204 b=14.176 c=18.041 β=102.530° [131]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-thulium[Tm2(tepa)2(μ-OH)2Sn2Se6]orthorhombicPbcaa=12.399 b=13.518 c=20.504 Z=82.820orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-thulium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate[Tm2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2OtetragonalI41/aa=28.2080 c=11.01422.258yellow [95]
[Hen]4[Tm(en)4]2[Ag6Sn6S20]·3enmonoclinicC2/ma 14.517 b 24.380 c 13.422 β 94.46° [135]
catena-((μ2-Hydroxo)-bis(μ2-selenido)-selenide-(tetraethylenepentamine)-tin-ytterbium hemihydrate)[{Yb(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)]·H2OmonoclinicC2/ca=21.255 b=12.835 c=17.633 β=125.41° [124]
bis(μ2-Hydroxo)-tetrakis(diethylenetriamine)-di-ytterbium bis(μ2-selenido)-tetraselenido-di-tin[{Yb(dien)2}2(μ-OH)2]Sn2Se6monoclinicP21/na=12.026 b=11.666 c=13.819 β=98.971° Z=4 [124]
DBU=1,8-diazabicyclo[5.4.0]undec-7-ene

catena-(bis(2,3,4,6,7,8,9,10-Octahydropyrimido(1,2-a)azepin-1-ium) bis(μ3-selenido)-pentakis(μ2-selenido)-di-mercury)

[DBUH]2[Hg2Sn2Se6(Se2)]triclinicP1a 10.390 b 12.244 c 13.977 α 86.58° β 79.51° γ 70.14° Z=21644.33.025yellow [136]
catena-(bis(2,3,4,6,7,8,9,10-Octahydro-1H-pyrimido(1,2-a)azepin-5-ium) (μ3-diselenido)-(μ3-selenido)-pentakis(μ2-selenido)-di-mercury-di-tin)[DBUH]2[Hg2Sn2Se5(Se2)]monoclinicP21/ca=14.7289 b=18.6045 c=13.5200 β=111.5713445.333.040red [136]
(tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ3-diselenido)-undecakis(μ2-selenido)-tri-mercury-tetra-tin[DBNH]4[Hg3Sn4Se11(Se2)2]monoclinicC2/ca 22.137 b 12.663 c 21.780° β 109.48° [105]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene[DBNH]2[HgSnSe4]tetragonalP42/ncma=12.8605 c 6.85560band gap 2.46 eV [62]
Li4HgSn2Se7monoclinicCca 18.286b 7.197 c 10.809 β 93.44°red [137]
Li2HgSnSe4orthorhombicPna21a=14.458 b=8.378 c=6.8215 Z=4826.35.217red; SHG 6.0 × AgGaS2 [138]
Na2HgSn2Se6tetragonalI4/mcma=7.8571 c=20.214 [139]
Na2Hg3Sn2Se81516.81tetragonalP4c2a=9.3749 c=9.790 Z=2860.55.854red [138]
K2HgSnSe4tetragonalI4/mcma=8.0531Å c=6.9501 [140]
phen = 1,10-phenanthroline; eta = ethanolamine[Fe(phen)3]Hg2Sn2Se7·1.5eta·0.25H2OtriclinicP1a 13.0238 b 13.6275 c 14.4626 α 81.104° β 88.117° γ 82.840° [141]
teta = triethylenetetramine[Ni2(teta)2(μ-teta)]HgSn3Se9orthorhombicPmc21a 22.731 b 13.2151 c 14.6495 [141]
SrHgSnSe4orthorhombicFdd2a 21.9027 b 21.9059 c 13.5010SHG 5 × AgGaS2 [142]
Cs2HgSn3Se8orthorhombicP212121a 7.9196 b 12.6657 c 18.5375 [111]
BaHgSnSe4orthorhombicFdd2a 22.441 b 22.760 c 13.579SHG 5 × AgGaS2 [142]
Tl4Sn2Se6tetrahedral edge-shared pairs [27]
TlGaSnSe4monoclinicP21/ca=7.501 b= 12.175 c= 18.203

β= 97.164 Z=8

1649.45.646red [86]
TlGaSnSe4cubicPa3a=13.4755 Z=122447.05.770red [86]

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Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.

Oxalate sulfates are mixed anion compounds containing oxalate and sulfate. They are mostly transparent, and any colour comes from the cations.

Tellurogermanates or telluridogermanates are compounds with anions with tellurium bound to germanium. They are analogous with germanates, thiogermanates and selenidogermanates.

A selenophosphate is a chemical compound containing phosphate anions substituted with selenium. Over 7000 compounds are known with a bond between selenium and phosphorus. Compared to phosphorus-sulfur compounds selenophosphates are less thermally stable, and more easily destroyed by water. However they are more stable than tellurophosphates which have an even weaker phosphorus-tellurium bond. Selenophosphates have an oxidation number for phosphorus of +5. But in many there are bonds between phosphorus atoms, reducing the oxidation state to +4, Some may be termed selenophosphites.

An oxalate chloride or oxalato chloride is a mixed anion compound contains both oxalate and chloride anions.

Thallides are compounds containing anions composed of thallium. There are several thallium atoms in a cluster, and it does not occur as a single Tl− in thallides. They are a subclass of trielides, which also includes gallides and indides. A more general classification is polar intermetallics, as clusters contain delocalized multicentre bonds. Thallides were discovered by Eduard Zintl in 1932.

References

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