Strongly correlated material

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The perovskite structure of BSCCO, a high-temperature superconductor and a strongly correlated material. Bi2212 Unit Cell.png
The perovskite structure of BSCCO, a high-temperature superconductor and a strongly correlated material.

Strongly correlated materials are a wide class of compounds that include insulators and electronic materials, and show unusual (often technologically useful) electronic and magnetic properties, such as metal-insulator transitions, heavy fermion behavior, half-metallicity, and spin-charge separation. The essential feature that defines these materials is that the behavior of their electrons or spinons cannot be described effectively in terms of non-interacting entities. [1] Theoretical models of the electronic (fermionic) structure of strongly correlated materials must include electronic (fermionic) correlation to be accurate. As of recently, the label quantum materials is also used to refer to strongly correlated materials, among others.

Contents

Transition metal oxides

Many transition metal oxides belong to this class [2] which may be subdivided according to their behavior, e.g. high-Tc, spintronic materials, multiferroics, Mott insulators, spin Peierls materials, heavy fermion materials, quasi-low-dimensional materials, etc. The single most intensively studied effect is probably high-temperature superconductivity in doped cuprates, e.g. La2−xSrxCuO4. Other ordering or magnetic phenomena and temperature-induced phase transitions in many transition-metal oxides are also gathered under the term "strongly correlated materials."

Electronic structures

Typically, strongly correlated materials have incompletely filled d- or f-electron shells with narrow energy bands. One can no longer consider any electron in the material as being in a "sea" of the averaged motion of the others (also known as mean field theory). Each single electron has a complex influence on its neighbors.

The term strong correlation refers to behavior of electrons in solids that is not well-described (often not even in a qualitatively correct manner) by simple one-electron theories such as the local-density approximation (LDA) of density-functional theory or Hartree–Fock theory. For instance, the seemingly simple material NiO has a partially filled 3d band (the Ni atom has 8 of 10 possible 3d-electrons) and therefore would be expected to be a good conductor. However, strong Coulomb repulsion (a correlation effect) between d electrons makes NiO instead a wide-band gap insulator. Thus, strongly correlated materials have electronic structures that are neither simply free-electron-like nor completely ionic, but a mixture of both.

Theories

Extensions to the LDA (LDA+U, GGA, SIC, GW, etc.) as well as simplified models Hamiltonians (e.g. Hubbard-like models) have been proposed and developed in order to describe phenomena that are due to strong electron correlation. Among them, dynamical mean field theory (DMFT) successfully captures the main features of correlated materials. Schemes that use both LDA and DMFT explain many experimental results in the field of correlated electrons.

Structural studies

Experimentally, optical spectroscopy, high-energy electron spectroscopies, resonant photoemission, and more recently resonant inelastic (hard and soft) X-ray scattering (RIXS) and neutron spectroscopy have been used to study the electronic and magnetic structure of strongly correlated materials. Spectral signatures seen by these techniques that are not explained by one-electron density of states are often related to strong correlation effects. The experimentally obtained spectra can be compared to predictions of certain models or may be used to establish constraints to the parameter sets. One has for instance established a classification scheme of transition metal oxides within the so-called Zaanen–Sawatzky–Allen diagram. [3]

Applications

The manipulation and use of correlated phenomena has applications like superconducting magnets and in magnetic storage (CMR)[ citation needed ] technologies. Other phenomena like the metal-insulator transition in VO2 have been explored as a means to make smart windows to reduce the heating/cooling requirements of a room. [4] Furthermore, metal-insulator transitions in Mott insulating materials like LaTiO3 can be tuned through adjustments in band filling to potentially be used to make transistors that would use conventional field effect transistor configurations to take advantage of the material's sharp change in conductivity. [5] Transistors using metal-insulator transitions in Mott insulators are often referred to as Mott transistors, and have been successfully fabricated using VO2 before, but they have required the larger electric fields induced by ionic liquids as a gate material to operate. [6]

See also

Related Research Articles

<span class="mw-page-title-main">Condensed matter physics</span> Branch of physics dealing with a property of matter

Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with "condensed" phases of matter: systems of many constituents with strong interactions between them. More exotic condensed phases include the superconducting phase exhibited by certain materials at low temperature, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other theories to develop mathematical models.

A semiconductor is a material, which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. Its conducting properties may be altered in useful ways by introducing impurities ("doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits.

<span class="mw-page-title-main">Kondo effect</span> Physical phenomenon due to impurities

In physics, the Kondo effect describes the scattering of conduction electrons in a metal due to magnetic impurities, resulting in a characteristic change i.e. a minimum in electrical resistivity with temperature. The cause of the effect was first explained by Jun Kondo, who applied third-order perturbation theory to the problem to account for scattering of s-orbital conduction electrons off d-orbital electrons localized at impurities. Kondo's calculation predicted that the scattering rate and the resulting part of the resistivity should increase logarithmically as the temperature approaches 0 K. Experiments in the 1960s by Myriam Sarachik at Bell Laboratories provided the first data that confirmed the Kondo effect. Extended to a lattice of magnetic impurities, the Kondo effect likely explains the formation of heavy fermions and Kondo insulators in intermetallic compounds, especially those involving rare earth elements such as cerium, praseodymium, and ytterbium, and actinide elements such as uranium. The Kondo effect has also been observed in quantum dot systems.

<span class="mw-page-title-main">Nevill Francis Mott</span> English physicist, Nobel prize winner

Sir Nevill Francis Mott was a British physicist who won the Nobel Prize for Physics in 1977 for his work on the electronic structure of magnetic and disordered systems, especially amorphous semiconductors. The award was shared with Philip W. Anderson and J. H. Van Vleck. The three had conducted loosely related research. Mott and Anderson clarified the reasons why magnetic or amorphous materials can sometimes be metallic and sometimes insulating.

<span class="mw-page-title-main">Hubbard model</span>

The Hubbard model is an approximate model used to describe the transition between conducting and insulating systems. It is particularly useful in solid-state physics. The model is named for John Hubbard.

Electronic correlation is the interaction between electrons in the electronic structure of a quantum system. The correlation energy is a measure of how much the movement of one electron is influenced by the presence of all other electrons.

<span class="mw-page-title-main">Mott insulator</span> Materials classically predicted to be conductors, that are actually insulators

Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators. These insulators fail to be correctly described by band theories of solids due to their strong electron–electron interactions, which are not considered in conventional band theory. A Mott transition is a transition from a metal to an insulator, driven by the strong interactions between electrons. One of the simplest models that can capture Mott transition is the Hubbard model.

<span class="mw-page-title-main">Nickel(II) oxide</span> Chemical compound

Nickel(II) oxide is the chemical compound with the formula NiO. It is the principal oxide of nickel. It is classified as a basic metal oxide. Several million kilograms are produced annually of varying quality, mainly as an intermediate in the production of nickel alloys. The mineralogical form of NiO, bunsenite, is very rare. Other nickel(III) oxides have been claimed, for example: Ni
2
O
3
and NiO
2
, but they have yet to be proven by X-ray crystallography.

The Max Planck Institute for Solid State Research was founded in 1969 and is one of the 82 Max Planck Institutes of the Max Planck Society. It is located on a campus in Stuttgart, together with the Max Planck Institute for Intelligent Systems.

Metal–insulator transitions are transitions of a material from a metal to an insulator. These transitions can be achieved by tuning various ambient parameters such as temperature, pressure or, in case of a semiconductor, doping.

In solid-state physics, heavy fermion materials are a specific type of intermetallic compound, containing elements with 4f or 5f electrons in unfilled electron bands. Electrons are one type of fermion, and when they are found in such materials, they are sometimes referred to as heavy electrons. Heavy fermion materials have a low-temperature specific heat whose linear term is up to 1000 times larger than the value expected from the free electron model. The properties of the heavy fermion compounds often derive from the partly filled f-orbitals of rare-earth or actinide ions, which behave like localized magnetic moments. The name "heavy fermion" comes from the fact that the fermion behaves as if it has an effective mass greater than its rest mass. In the case of electrons, below a characteristic temperature (typically 10 K), the conduction electrons in these metallic compounds behave as if they had an effective mass up to 1000 times the free particle mass. This large effective mass is also reflected in a large contribution to the resistivity from electron-electron scattering via the Kadowaki–Woods ratio. Heavy fermion behavior has been found in a broad variety of states including metallic, superconducting, insulating and magnetic states. Characteristic examples are CeCu6, CeAl3, CeCu2Si2, YbAl3, UBe13 and UPt3.

<span class="mw-page-title-main">Jan Zaanen</span> Dutch physicist

Jan Zaanen is professor of theoretical physics at Leiden University, the Netherlands. He is best known for his contributions to the understanding of the quantum physics of the electrons in strongly correlated material, and in particular high temperature superconductivity. Zaanen's areas of interest are in the search for novel forms of collective quantum phenomena realized in systems build from mundane constituents like electrons, spins, and atoms.

A Mott transition is a metal-nonmetal transition in condensed matter. Due to electric field screening the potential energy becomes much more sharply (exponentially) peaked around the equilibrium position of the atom and electrons become localized and can no longer conduct a current.

Spinons are one of three quasiparticles, along with holons and orbitons, that electrons in solids are able to split into during the process of spin–charge separation, when extremely tightly confined at temperatures close to absolute zero. The electron can always be theoretically considered as a bound state of the three, with the spinon carrying the spin of the electron, the orbiton carrying the orbital location and the holon carrying the charge, but in certain conditions they can behave as independent quasiparticles.

<span class="mw-page-title-main">Kondo insulator</span>

In solid-state physics, Kondo insulators (also referred as Kondo semiconductors and heavy fermion semiconductors) are understood as materials with strongly correlated electrons, that open up a narrow band gap (in the order of 10 meV) at low temperatures with the chemical potential lying in the gap, whereas in heavy fermion materials the chemical potential is located in the conduction band. The band gap opens up at low temperatures due to hybridization of localized electrons (mostly f-electrons) with conduction electrons, a correlation effect known as the Kondo effect. As a consequence, a transition from metallic behavior to insulating behavior is seen in resistivity measurements. The band gap could be either direct or indirect. Most studied Kondo insulators are FeSi, Ce3Bi4Pt3, SmB6, YbB12, and CeNiSn, although there are over a dozen known Kondo insulators.

Dynamical mean-field theory (DMFT) is a method to determine the electronic structure of strongly correlated materials. In such materials, the approximation of independent electrons, which is used in density functional theory and usual band structure calculations, breaks down. Dynamical mean-field theory, a non-perturbative treatment of local interactions between electrons, bridges the gap between the nearly free electron gas limit and the atomic limit of condensed-matter physics.

In condensed matter physics, a quantum spin liquid is a phase of matter that can be formed by interacting quantum spins in certain magnetic materials. Quantum spin liquids (QSL) are generally characterized by their long-range quantum entanglement, fractionalized excitations, and absence of ordinary magnetic order.

Dieter Vollhardt is a German physicist and Professor of Theoretical Physics at the University of Augsburg.

<span class="mw-page-title-main">George Sawatzky</span>

George Albert Sawatzky is a Canadian physicist, known for his research in solid state physics and strongly correlated electron systems. He has co-developed the Cini-Sawatzky theory of the Auger effect and the ZSA (Zaanen-Sawatzky-Allen) classification of bandgaps in solids.

Quantum materials is an umbrella term in condensed matter physics that encompasses all materials whose essential properties cannot be described in terms of semiclassical particles and low-level quantum mechanics. These are materials that present strong electronic correlations or some type of electronic order, such as superconducting or magnetic orders, or materials whose electronic properties are linked to non-generic quantum effects – topological insulators, Dirac electron systems such as graphene, as well as systems whose collective properties are governed by genuinely quantum behavior, such as ultra-cold atoms, cold excitons, polaritons, and so forth. On the microscopic level, four fundamental degrees of freedom – that of charge, spin, orbit and lattice – become intertwined, resulting in complex electronic states; the concept of emergence is a common thread in the study of quantum materials.

References

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  2. Millis, A. J. "Lecture notes on "Strongly Correlated" Transition Metal Oxides" (PDF). Columbia University. Retrieved June 20, 2012.
  3. J. Zaanen; G. A. Sawatzky; J. W. Allen (1985). "Band Gaps and Electronic Structure of Transition-Metal Compounds" (PDF). Physical Review Letters. 55 (4): 418–421. Bibcode:1985PhRvL..55..418Z. doi:10.1103/PhysRevLett.55.418. hdl: 1887/5216 . PMID   10032345.
  4. J. M. Tomczak; S. Biermann (2009). "Optical properties of correlated materials – Or why intelligent windows may look dirty". Physica Status Solidi B. 246 (9): 1996–2005. arXiv: 0907.1575 . Bibcode:2009PSSBR.246.1996T. doi:10.1002/pssb.200945231. S2CID   6942417.
  5. Scheiderer, Philipp; Schmitt, Matthias; Gabel, Judith; Zapf, Michael; Stübinger, Martin; Schütz, Philipp; Dudy, Lenart; Schlueter, Christoph; Lee, Tien-Lin; Sing, Michael; Claessen, Ralph (2018). "Tailoring Materials for Mottronics: Excess Oxygen Doping of a Prototypical Mott Insulator". Advanced Materials. 30 (25): 1706708. arXiv: 1807.05724 . Bibcode:2018AdM....3006708S. doi:10.1002/adma.201706708. PMID   29732633. S2CID   19134593.
  6. Nakano, M.; Shibuya, K.; Okuyama, D.; Hatano, T.; Ono, S.; Kawasaki, M.; Iwasa, Y.; Tokura, Y. (July 2012). "Collective bulk carrier delocalization driven by electrostatic surface charge accumulation". Nature. 487 (7408): 459–462. Bibcode:2012Natur.487..459N. doi:10.1038/nature11296. PMID   22837001. S2CID   4401622.

Further reading