Vauquelinite

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Vauquelinite
Vauquelinite-120513.jpg
General
Category Phosphate mineral
Formula
(repeating unit)
CuPb2(CrO4)(PO4)(OH)
IMA symbol Vql [1]
Strunz classification 7.FC.05
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/n
Unit cell a = 13.754(5)  Å, b = 5.806(6) Å
c = 9.563(3) Å; β = 94.55°; Z = 4
Identification
ColorOlive-green, apple-green, brown to nearly black
Crystal habit Irregular wedge shaped crystals, mammillary, reniform masses
Twinning Present on {102}
Cleavage Indistinct
Fracture Irregular
Tenacity Brittle
Mohs scale hardness2.5 – 3
Luster Adamantine, resinous
Streak Greenish or brownish
Diaphaneity Translucent
Specific gravity 6.16
Optical propertiesBiaxial (−)
Refractive index nα = 2.110 nβ = 2.220 nγ = 2.220
Birefringence δ = 0.110
Pleochroism X = Light green, Y = Light brown, Z = Light brown
2V angle Near zero
References [2] [3] [4]

Vauquelinite is a complex mineral with the formula Cu Pb 2(Cr O 4)(PO4)(OH) making it a combined chromate and phosphate of copper and lead. It forms a series with the arsenate mineral fornacite. [2]

It was first described in 1818 in the Beryozovskoye deposit, Urals, Russia, and named for Louis Vauquelin (1763–1829), a French chemist. [2] It occurs in oxidized hydrothermal ore deposits and is associated with crocoite, pyromorphite, mimetite, cerussite, beudantite and duftite at the type locality in Russia. [4]

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<span class="mw-page-title-main">Crocoite</span> Lead chromate mineral

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<span class="mw-page-title-main">Fornacite</span>

Fornacite is a rare lead, copper chromate arsenate hydroxide mineral with the formula: Pb2Cu(CrO4)(AsO4)(OH). It forms a series with the phosphate mineral vauquelinite. It forms variably green to yellow, translucent to transparent crystals in the monoclinic – prismatic crystal system. It has a Mohs hardness of 2.3 and a specific gravity of 6.27.

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Vladimirite is a rare calcium arsenate mineral with a formula of Ca5(HAsO4)2(AsO4)2·5H2O. It is named after the Vladimirovskoye deposit in Russia, where it was discovered in the 1950s.

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<span class="mw-page-title-main">Hemihedrite</span>

Hemihedrite is a rare lead zinc chromate silicate mineral with formula Pb10Zn(CrO4)6(SiO4)2(F,OH)2. It forms a series with the copper analogue iranite.

Bilibinskite is an Au – Cu – Pb telluride. It is a rare mineral that was named after Soviet geologist Yuri Bilibin (1901–1952), who researched the geology of gold deposits during the time of the USSR.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Mindat – Vauquelinite
  3. Webmineral – Vauquelinite
  4. 1 2 Handbook of Mineralogy – Vauquelinite