Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ion, respectively, in the crystal. The formula of the admixture of the three most common endmembers is written as Ca10(PO4)6(OH,F,Cl)2, and the crystal unit cell formulae of the individual minerals are written as Ca10(PO4)6(OH)2, Ca10(PO4)6F2 and Ca10(PO4)6Cl2.
Delvauxite, also known as borickite, is a yellow to brown to dark brown amorphous mineral, sometimes forming a botryoidal mass. Its chemical formula is CaFe
4(PO
4,SO
4)
2(OH)
8•(4-6)H
2O. and it may sometimes form stalactites.
Triplite is a rare phosphate mineral with formula: (Mn, Fe)2PO4(F, OH). It occurs in phosphate-rich granitic pegmatites typically as irregular brown opaque masses. Triplite was first described in 1813 for an occurrence in Chanteloube, Limousin, France. The name is from the Greek triplos for triple, in reference to the three cleavage directions. In color and appearance, it is very similar to rhodocrosite, another manganese bearing mineral. Chemically, it is also quite similar to triploidite the difference being that triplite is fluorine dominant while triploidite is hydroxide dominant.
Mellite, also called honeystone, is an unusual mineral being also an organic chemical. It is chemically identified as an aluminium salt of mellitic acid, and specifically as aluminium benzene hexacarboxylate hexadecahydrate, with the chemical formula Al2C6(COO)6·16H2O.
Calderite is a mineral in the garnet group with the chemical formula (Mn2+, Ca)3(Fe3+, Al)2(SiO4)3.
Brianite is a phosphate mineral with the chemical formula Na2CaMg(PO4)2. It was first identified in an iron meteorite. This mineral is named after Brian Harold Mason (1917–2009), a pioneer in meteoritics.
Berlinite (aluminium phosphate, chemical formula AlPO4 or Al(PO4)) is a rare high-temperature hydrothermal or metasomatic phosphate mineral. It has the same crystal structure as quartz with a low temperature polytype isostructural with α–quartz and a high temperature polytype isostructural with β–quartz. Berlinite can vary from colorless to greyish or pale pink and has translucent crystals.
Alluaudite is a relatively common alkaline manganese iron phosphate mineral with the chemical formula (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3. It occurs as metasomatic replacement in granitic pegmatites and within phosphatic nodules in shales.
Tobermorite is a calcium silicate hydrate mineral with chemical formula: Ca5Si6O16(OH)2·4H2O or Ca5Si6(O,OH)18·5H2O.
Cyrilovite (NaFe33+(PO4)2(OH)4·2(H2O)) is a hydrous sodium iron phosphate mineral. It is isomorphous and isostructural with wardite, the sodium aluminium counterpart.
Fluellite is a mineral with the chemical formula Al2(PO4)F2(OH)•7H2O. The name is from its chemical composition, being a fluate of alumine (French).
Edenite is a double chain silicate mineral of the amphibole group with the general chemical composition NaCa2Mg5(Si7Al)O22(OH)2. Edenite is named for the locality of Edenville, Orange County, New York, where it was first described.
Imogolite is an aluminium silicate clay mineral with the chemical formula Al2SiO3(OH)4. It occurs in soils formed from volcanic ash and was first described in 1962 for an occurrence in Uemura, Kumamoto prefecture, Kyushu Region, Japan. Its name originates from the Japanese word imogo, which refers to the brownish yellow soil derived from volcanic ash. It occurs together with allophane, quartz, cristobalite, gibbsite, vermiculite and limonite.
Wairakite is a zeolite mineral with an analcime structure but containing a calcium ion. The chemical composition is Ca8(Al16Si32O96)•16H2O. It is named for the location of its discovery in Wairakei, North Island, New Zealand, by Alfred Steiner in 1955. The first finds were in hydrothermally altered rhyolitic tuffs, ignimbrites and volcaniclastic rocks. The mineral has since been found in metamorphic rocks and in geothermal areas. It was most likely first successfully synthesized in a laboratory in 1970.
Collinsite is a mineral with chemical formula Ca
2(Mg,Fe2+
)(PO
4)
2•2H
2O. It was discovered in British Columbia, Canada, and formally described in 1927. It was named in honor of William Henry Collins (1878–1937), director of the Geological Survey of Canada. There are three varieties of the mineral: magnesian collinsite, zincian collinsite, and strontian collinsite. The crystal structure consists of polyhedral chains linked by weak hydrogen bonds.
Merrillite is a calcium phosphate mineral with the chemical formula Ca9NaMg(PO4)7. It is an anhydrous, sodium-rich member of the merrillite group of minerals.
Kovdorskite, Mg2PO4(OH)·3H2O, is a rare, hydrated, magnesium phosphate mineral. It was first described by Kapustin et al., and is found only in the Kovdor Massif near Kovdor, Kola Peninsula, Russia. It is associated with collinsite, magnesite, dolomite, hydrotalcite, apatite, magnetite, and forsterite.
Skorpionite (IMA2005-010) is a zinc phosphate mineral with chemical formula Ca3Zn2(PO4)2CO3(OH)2·H2O, originally found in the Skorpion Mine and named after it (Rosh Pinah, Lüderitz district, ǁKaras Region, Namibia).
Fluorcarmoite-(BaNa) is a rare phosphate mineral, belonging to arrojadite group, with the formula Ba[]Na2Na2[]CaMg13Al(PO4)11(PO3OH)F2. It is a barium-rich member of the group, as is arrojadite-(BaNa), arrojadite-(BaFe), fluorarrojadite-(BaFe) and an unapproved species ferri-arrojadite-(BaNa). The "-(BaNa)" suffix informs about the dominance of the particular elements (here barium and sodium) at the corresponding structural sites.
Afmite (IMA symbol: Afm) is phosphate mineral with the chemical formula Al3(OH)4(PO4)(PO3OH)·H2O. It is named for the French mineralogy group Association Française de Microminéralogie, or AFM for short.
