Lustre (mineralogy)

Last updated

Lustre (British English) or luster (American English; see spelling differences) is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the Latin lux, meaning "light", and generally implies radiance, gloss, or brilliance.

British English is the standard dialect of the English language as spoken and written in the United Kingdom. Variations exist in formal, written English in the United Kingdom. For example, the adjective wee is almost exclusively used in parts of Scotland and Ireland, and occasionally Yorkshire, whereas little is predominant elsewhere. Nevertheless, there is a meaningful degree of uniformity in written English within the United Kingdom, and this could be described by the term British English. The forms of spoken English, however, vary considerably more than in most other areas of the world where English is spoken, so a uniform concept of British English is more difficult to apply to the spoken language. According to Tom McArthur in the Oxford Guide to World English, British English shares "all the ambiguities and tensions in the word 'British' and as a result can be used and interpreted in two ways, more broadly or more narrowly, within a range of blurring and ambiguity".

American English Set of dialects of the English language spoken in the United States

American English, sometimes called United States English or U.S. English, is the set of varieties of the English language native to the United States. American English is considered one of the most influential dialects of English globally, including on other varieties of English.

Crystal solid material whose constituent atoms, molecules, or ions are arranged in an ordered pattern extending in all three spatial dimensions

A crystal or crystalline solid is a solid material whose constituents are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification.

Contents

A range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term vitreous (derived from the Latin for glass, vitrum) refers to a glassy lustre. A list of these terms is given below.

Glass Amorphous solid that exhibits a glass transition

Glass is a non-crystalline, amorphous solid that is most often transparent and has widespread practical, technological, and decorative uses in, for example, window panes, tableware, optics and optoelectronics. The most familiar, and historically the oldest, types of manufactured glass are "silicate glasses" based on the chemical compound silica (silicon dioxide, or quartz), the primary constituent of sand. The term glass, in popular usage, is often used to refer only to this type of material, which is familiar from use as window glass and in glass bottles. Of the many silica-based glasses that exist, ordinary glazing and container glass is formed from a specific type called soda-lime glass, composed of approximately 75% silicon dioxide (SiO2), sodium oxide (Na2O) from sodium carbonate (Na2CO3), calcium oxide (CaO), also called lime, and several minor additives.

Lustre varies over a wide continuum, and so there are no rigid boundaries between the different types of lustre. (For this reason, different sources can often describe the same mineral differently. This ambiguity is further complicated by lustre's ability to vary widely within a particular mineral species.) The terms are frequently combined to describe intermediate types of lustre (for example, a "vitreous greasy" lustre).

Some minerals exhibit unusual optical phenomena, such as asterism (the display of a star-shaped luminous area) or chatoyancy (the display of luminous bands, which appear to move as the specimen is rotated). A list of such phenomena is given below.

Chatoyancy Optical reflectance effect seen in certain gemstones

In gemology, chatoyancy, or chatoyance or cat's eye effect, is an optical reflectance effect seen in certain gemstones. Coined from the French "œil de chat", meaning "cat's eye", chatoyancy arises either from the fibrous structure of a material, as in tiger's eye quartz, or from fibrous inclusions or cavities within the stone, as in cat's eye chrysoberyl. The precipitates that cause chatoyance in chrysoberyl are the mineral rutile, composed mostly of titanium dioxide. Examined samples have yielded no evidence of tubes or fibres. The rutile precipitates all align perpendicularly with respect to cat's eye effect. It is reasoned that the lattice parameter of the rutile matches only one of the three orthorhombic crystal axes of the chrysoberyl, resulting in preferred alignment along that direction.

Common terms

Adamantine lustre

Cut diamonds. Brillanten.jpg
Cut diamonds.

Adamantine minerals possess a superlative lustre, which is most notably seen in diamond. [1] Such minerals are transparent or translucent, and have a high refractive index (of 1.9 or more). [2] Minerals with a true adamantine lustre are uncommon, with examples being cerussite and cubic zirconia. [2]

Diamond Allotrope of carbon often used as a gemstone and an abrasive

Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. At room temperature and pressure, another solid form of carbon known as graphite is the chemically stable form, but diamond almost never converts to it. Diamond has the highest hardness and thermal conductivity of any natural material, properties that are utilized in major industrial applications such as cutting and polishing tools. They are also the reason that diamond anvil cells can subject materials to pressures found deep in the Earth.

Refractive index dimensionless number that describes how fast light propagates through the material

In optics, the refractive index or index of refraction of a material is a dimensionless number that describes how fast light travels through the material. It is defined as

Cerussite carbonate mineral

Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and an important ore of lead. The name is from the Latin cerussa, white lead. Cerussa nativa was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name cruise to the mineral, whilst the present form, cerussite, is due to W. Haidinger (1845). Miners' names in early use were lead-spar and white-lead-ore.

Minerals with a lesser (but still relatively high) degree of lustre are referred to as subadamantine, with some examples being garnet and corundum. [1]

Garnet mineral, semi-precious stone

Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.

Corundum Oxide mineral

Corundum is a crystalline form of aluminium oxide typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is also a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange.

Dull lustre

Kaolinite KaolinUSGOV.jpg
Kaolinite

Dull (or earthy) minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, approximating a Lambertian reflector. An example is kaolinite. [3] A distinction is sometimes drawn between dull minerals and earthy minerals, [4] with the latter being coarser, and having even less lustre.

Lambertian reflectance is the property that defines an ideal "matte" or diffusely reflecting surface. The apparent brightness of a Lambertian surface to an observer is the same regardless of the observer's angle of view. More technically, the surface's luminance is isotropic, and the luminous intensity obeys Lambert's cosine law. Lambertian reflectance is named after Johann Heinrich Lambert, who introduced the concept of perfect diffusion in his 1760 book Photometria.

Kaolinite phyllosilicate mineral

Kaolinite is a clay mineral, part of the group of industrial minerals with the chemical composition Al2Si2O5(OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica (SiO
4
) linked through oxygen atoms to one octahedral sheet of alumina (AlO
6
) octahedra. Rocks that are rich in kaolinite are known as kaolin or china clay.

Greasy lustre

Moss opal Moos-Opal1.jpg
Moss opal

Greasy minerals resemble fat or grease. A greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite, jadeite. [2] Many minerals with a greasy lustre also feel greasy to the touch. [5]

Metallic lustre

Pyrite Pyrite 3.jpg
Pyrite

Metallic (or splendent) minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, [6] pyrite [7] and magnetite. [8]

Pearly lustre

Muscovite Mineral Mica GDFL006.JPG
Muscovite

Pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls. [9] Such minerals possess perfect cleavage, with examples including muscovite and stilbite. [2]

Resinous lustre

Amber Amber hg.jpg
Amber

Resinous minerals have the appearance of resin, chewing gum or (smooth-surfaced) plastic. A principal example is amber, which is a form of fossilized resin. [10]

Silky lustre

Satin spar variety of gypsum Selenite Gips Marienglas.jpg
Satin spar variety of gypsum

Silky minerals have a parallel arrangement of extremely fine fibres, [2] giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum. A fibrous lustre is similar, but has a coarser texture.

Submetallic lustre

Sphalerite Sphalerite4.jpg
Sphalerite

Submetallic minerals have similar lustre to metal, but are duller and less reflective. A submetallic lustre often occurs in near-opaque minerals with very high refractive indices, [2] such as sphalerite, cinnabar, anthracite, and cuprite.

Vitreous lustre

Quartz Quartz Bresil.jpg
Quartz

Vitreous minerals have the lustre of glass. (The term is derived from the Latin for glass, vitrum.) This type of lustre is one of the most commonly seen, [9] and occurs in transparent or translucent minerals with relatively low refractive indices. [2] Common examples include calcite, quartz, topaz, beryl, tourmaline and fluorite, among others.

Waxy lustre

Jade Jadestein.jpg
Jade

Waxy minerals have a lustre resembling wax. Examples include jade [11] and chalcedony. [12]

Optical phenomena

Asterism

Sapphire cabochon Star-Saphire.jpg
Sapphire cabochon

Asterism is the display of a star-shaped luminous area. It is seen in some sapphires and rubies, where it is caused by impurities of rutile. [12] [13] It can also occur in garnet, diopside and spinel.

Aventurescence

Aventurine Aventurine.jpg
Aventurine

Aventurescence (or aventurization) is a reflectance effect like that of glitter. It arises from minute, preferentially oriented mineral platelets within the material. These platelets are so numerous that they also influence the material's body colour. In aventurine quartz, chrome-bearing fuchsite makes for a green stone and various iron oxides make for a red stone. [12]

Chatoyancy

Tiger's eye Tigers-Eye.jpg
Tiger's eye

Chatoyant minerals display luminous bands, which appear to move as the specimen is rotated. Such minerals are composed of parallel fibers (or contain fibrous voids or inclusions), which reflect light into a direction perpendicular to their orientation, thus forming narrow bands of light. The most famous examples are tiger's eye and cymophane, but the effect may also occur in other minerals such as aquamarine, moonstone and tourmaline.

Colour change

Alexandrite Alexandrite 26.75cts.jpg
Alexandrite

Colour change is most commonly found in alexandrite, a variety of chrysoberyl gemstones. Other gems also occur in colour-change varieties, including (but not limited to) sapphire, garnet, spinel. Alexandrite displays a colour change dependent upon light, along with strong pleochroism. The gem results from small-scale replacement of aluminium by chromium oxide, which is responsible for alexandrite's characteristic green to red colour change. Alexandrite from the Ural Mountains in Russia is green by daylight and red by incandescent light. Other varieties of alexandrite may be yellowish or pink in daylight and a columbine or raspberry red by incandescent light. The optimum or "ideal" colour change would be fine emerald green to fine purplish red, but this is rare.

Iridescence

Iridescence is the 'play' or 'fire' of rainbow-coloured light caused by very thin regular structures or layers beneath the surface of a gemstone. Similar to a thin film of oil on water, these layers interfere with the rays of reflected light, reinforcing some colours and cancelling others. Iridescence is seen at its best in precious opal. [14]

Schiller

Labradorite Labradoryt, Madagaskar.JPG
Labradorite

Schiller, from German for "colour play", [15] is the metallic iridescence originating from below the surface of a stone that occurs when light is reflected between layers of minerals. It is seen in moonstone and labradorite and is very similar to adularescence and aventurescence. [16]

Related Research Articles

Gemstone Piece of mineral crystal used to make jewelry

A gemstone is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks and occasionally organic materials that are not minerals are also used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some soft minerals are used in jewelry because of their luster or other physical properties that have aesthetic value. Rarity is another characteristic that lends value to a gemstone.

Spinel An oxide mineral

Spinel is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl2O4 in the cubic crystal system. Its name comes from Latin "spina" (arrow).

Sapphire Sapphire is one of two Corundum gemstones (and the other one is Ruby)

Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminum oxide (α-Al2O3) with trace amounts of elements such as iron, titanium, chromium, copper, or magnesium. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. The only color corundum stone that the term sapphire is not used for is red, which is called a ruby. Pink colored corundum may be either classified as ruby or sapphire depending on locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires – 9 on the Mohs scale (the third hardest mineral, after diamond at 10 and moissanite at 9.5) – sapphires are also used in some non-ornamental applications, such as infrared optical components, high-durability windows, wristwatch crystals and movement bearings, and very thin electronic wafers, which are used as the insulating substrates of special-purpose solid-state electronics such as integrated circuits and GaN-based blue LEDs.

Chrysoberyl Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

Gemology Science dealing with natural and artificial gemstone materials

Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is considered a geoscience and a branch of mineralogy. Some jewelers are academically trained gemologists and are qualified to identify and evaluate gems.

Pleochroism optical phenomenon in which a substance appears to be different colors when observed at different angles, especially with polarized light

Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with polarized light.

Labradorite mineral: intermediate member of a solid solution series (50 to 70 % anorthite and albite)

Labradorite ((Ca, Na)(Al, Si)4O8), a feldspar mineral, is an intermediate to calcic member of the plagioclase series. It has an anorthite percentage (%An) of between 50 and 70. The specific gravity ranges from 2.68 to 2.72. The streak is white, like most silicates. The refractive index ranges from 1.559 to 1.573 and twinning is common. As with all plagioclase members, the crystal system is triclinic, and three directions of cleavage are present, two of which are nearly at right angles and are more obvious, being of good to perfect quality. (The third direction is poor.) It occurs as clear, white to gray, blocky to lath shaped grains in common mafic igneous rocks such as basalt and gabbro, as well as in anorthosites.

Sphalerite sulfide mineral

Sphalerite ( S) is a mineral that is the chief ore of zinc. It consists largely of zinc sulfide in crystalline form but almost always contains variable iron. When iron content is high it is an opaque black variety, marmatite. It is usually found in association with galena, pyrite, and other sulfides along with calcite, dolomite, and fluorite. Miners have also been known to refer to sphalerite as zinc blende, black-jack and ruby jack.

Nepheline A silica-undersaturated aluminosilicate mineral

Nepheline, also called nephelite (from Greek: νεφέλη, "cloud"), is a feldspathoid: a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites.

Cordierite cyclosilicate, mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings.

Almandine garnet, nesosilicate mineral

Almandine, also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia Minor. Almandine is an iron alumina garnet, of deep red color, inclining to purple. It is frequently cut with a convex face, or en cabochon, and is then known as carbuncle. Viewed through the spectroscope in a strong light, it generally shows three characteristic absorption bands.

Sapphirine a rare mineral of the sapphirine supergroup, single chain inosilicate mineral with polytopes 1A, 2M, 3A, 4M, 5A; a silicate of magnesium and aluminium, (Mg,Al)₈(Al,Si)₆O₂₀ (with Fe as a major impurity); named after its sapphire-like colour

Sapphirine is a rare mineral, a silicate of magnesium and aluminium with the chemical formula (Mg,Al)8(Al,Si)6O20 (with iron as a major impurity). Named for its sapphire-like colour, sapphirine is primarily of interest to researchers and collectors: well-formed crystals are treasured and occasionally cut into gemstones. Sapphirine has also been synthesized for experimental purposes via a hydrothermal process.

Demantoid green andradite variety

Demantoid is the green gemstone variety of the mineral andradite, a member of the garnet group of minerals. Andradite is a calcium- and iron-rich garnet. The chemical formula is Ca3Fe2(SiO4)3 with chromium substitution as the cause of the demantoid green color. Ferric iron is the cause of the yellow in the stone.

Spessartine garnet, nesosilicate mineral

Spessartine, sometimes mistakenly referred to as spessartite, is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3. The mineral spessartine should not be confused with a type of igneous rock (a lamprophyre) called spessartite.

Grossular garnet, nesosilicate mineral

Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.

Andradite garnet, nesosilicate mineral

Andradite is a species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.

Opalescence

Opalescence refers to the optical phenomena displayed by the mineraloid gemstone opal. However, there are three notable types of opal, each with different optical effects, so the intended meaning varies depending on context. The optical effects seen in various types of opal are a result of refraction or reflection (common) due to the layering, spacing, and size of the myriad microscopic silicon dioxide spheres and included water in its physical structure. When the size and spacing of the silica spheres are relatively small, refracted blue-green colors are prevalent; when relatively larger, refracted yellow-orange-red colors are seen; and when larger yet, reflection yields a milky-hazy sheen.

Adularescence Magnificent views seen below the surface of certain gemstones when light passes thru lines

Adularescence is an optical phenomenon, similar to labradorescence and aventurescence, that is produced in gemstones such as moonstones.

References

  1. 1 2 GIA Gem Reference Guide. Gemological Institute of America. 1995. ISBN   0-87311-019-6.
  2. 1 2 3 4 5 6 7 Duda, Rudolf & Rejl, Lubos (1990). Minerals of the World. Arch Cape Press. ISBN   0-517-68030-0.
  3. "Webmineral: Kaolinite Mineral Data" . Retrieved 2008-06-21.
  4. Hankin, Rosie (1998). Rocks, Crystals & Minerals. Quintet Publishing. ISBN   1-86155-480-X.
  5. "Emporia State University: GO 340 Gemstones & Gemology: Visual Properties" . Retrieved 2008-06-19.
  6. "Webmineral: Galena Mineral Data" . Retrieved 2008-07-05.
  7. "Webmineral: Pyrite Mineral Data" . Retrieved 2008-07-05.
  8. "Webmineral: Magnetite Mineral Data" . Retrieved 2008-07-05.
  9. 1 2 "Optical properties of Rocks and Minerals" . Retrieved 2008-06-01.
  10. "Webmineral: Amber Mineral Data" . Retrieved 2008-06-21.
  11. "Emporia State University: GO 340 Gemstones & Gemology: Jade" . Retrieved 2008-07-14.
  12. 1 2 3 Bonewitz, Ronald Louis (2005). Rock and Gem. Dorling Kindersley. pp. 152–153. ISBN   0-7513-4400-1.
  13. Emsley, John (2001). Nature's Building Blocks: An A-Z Guide to the Elements. Oxford University Press. pp. 451–53. ISBN   0-19-850341-5.
  14. G., Read, Peter (2008). Gemmology (3rd ed.). London: N.A.G. ISBN   9780719803611. OCLC   226280870.
  15. "Schiller". wiktionary.
  16. Shipley, Robert M. (2007). Dictionary of gems and gemology. Read Books. p. 93. ISBN   0-87311-007-2.