Corundum

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Corundum
Several corundum crystals.jpg
General
Category Oxide mineral – Hematite group
Formula
(repeating unit)
Al2O3
IMA symbol Crn [1]
Strunz classification 4.CB.05
Dana classification 4.3.1.1
Crystal system Trigonal
Crystal class Hexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space group R3c (No. 167)
Unit cell a = 4.75 Å, c = 12.982 Å; Z = 6
Identification
ColorColorless, gray, golden-brown, brown; purple, pink to red, orange, yellow, green, blue, violet; may be color zoned, asteriated mainly grey and brown
Crystal habit Steep bipyramidal, tabular, prismatic, rhombohedral crystals, massive or granular
Twinning Polysynthetic twinning common
Cleavage None – parting in 3 directions
Fracture Conchoidal to uneven
Tenacity Brittle
Mohs scale hardness9 (defining mineral) [2]
Luster Adamantine to vitreous
Streak Colorless
Diaphaneity Transparent, translucent to opaque
Specific gravity 3.95–4.10
Optical propertiesUniaxial ()
Refractive index nω = 1.767–1.772
nε = 1.759–1.763
Pleochroism None
Melting point 2,044 °C (3,711 °F)
Fusibility Infusible
Solubility Insoluble
Alters toMay alter to mica on surfaces causing a decrease in hardness
Other characteristicsMay fluoresce or phosphoresce under UV light
References [3] [4] [5] [6]
Major varieties
Sapphire Any color except red
Ruby Red
Emery Black granular corundum intimately mixed with magnetite, hematite, or hercynite

Corundum is a crystalline form of aluminium oxide (Al2O3) typically containing traces of iron, titanium, vanadium, and chromium. [3] [4] It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. [7] Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. [7] A rare type of sapphire, padparadscha sapphire, is pink-orange.

Contents

The name "corundum" is derived from the Tamil-Dravidian word kurundam (ruby-sapphire) (appearing in Sanskrit as kuruvinda). [8] [9]

Because of corundum's hardness (pure corundum is defined to have 9.0 on the Mohs scale), it can scratch almost all other minerals. It is commonly used as an abrasive on sandpaper and on large tools used in machining metals, plastics, and wood. Emery, a variety of corundum with no value as a gemstone, is commonly used as an abrasive. It is a black granular form of corundum, in which the mineral is intimately mixed with magnetite, hematite, or hercynite. [6]

In addition to its hardness, corundum has a density of 4.02 g/cm3 (251 lb/cu ft), which is unusually high for a transparent mineral composed of the low-atomic mass elements aluminium and oxygen. [10]

Geology and occurrence

Corundum from Brazil, size about 2 cm x 3 cm (0.8 in x 1 in) Corindon azulEZ.jpg
Corundum from Brazil, size about 2 cm × 3 cm (0.8 in × 1 in)

Corundum occurs as a mineral in mica schist, gneiss, and some marbles in metamorphic terranes. It also occurs in low-silica igneous syenite and nepheline syenite intrusives. Other occurrences are as masses adjacent to ultramafic intrusives, associated with lamprophyre dikes and as large crystals in pegmatites. [6] It commonly occurs as a detrital mineral in stream and beach sands because of its hardness and resistance to weathering. [6] The largest documented single crystal of corundum measured about 65 cm × 40 cm × 40 cm (26 in × 16 in × 16 in), and weighed 152 kg (335 lb). [11] The record has since been surpassed by certain synthetic boules. [12]

Corundum for abrasives is mined in Zimbabwe, Pakistan, Afghanistan, Russia, Sri Lanka, and India. Historically it was mined from deposits associated with dunites in North Carolina, US, and from a nepheline syenite in Craigmont, Ontario. [6] Emery-grade corundum is found on the Greek island of Naxos and near Peekskill, New York, US. Abrasive corundum is synthetically manufactured from bauxite. [6]

Four corundum axes dating to 2500 BC from the Liangzhu culture and Sanxingcun culture (the latter of which is located in Jintan District) have been discovered in China. [13] [14]

Synthetic corundum

The Verneuil process allows the production of flawless single-crystal sapphire and ruby gems of much larger size than normally found in nature. It is also possible to grow gem-quality synthetic corundum by flux-growth and hydrothermal synthesis. Because of the simplicity of the methods involved in corundum synthesis, large quantities of these crystals have become available on the market at a fraction of the cost of natural stones. [17]

Apart from ornamental uses, synthetic corundum is also used to produce mechanical parts (tubes, rods, bearings, and other machined parts), scratch-resistant optics, scratch-resistant watch crystals, instrument windows for satellites and spacecraft (because of its transparency in the ultraviolet to infrared range), and laser components. For example, the KAGRA gravitational wave detector's main mirrors are 23 kg (50 lb) sapphires, [18] and Advanced LIGO considered 40 kg (88 lb) sapphire mirrors. [19] Corundum has also found use in the development of ceramic armour thanks to its high hardiness. [20]

Structure and physical properties

Crystal structure of corundum Corundum.png
Crystal structure of corundum
Molar volume vs. pressure at room temperature Corundum-pV.svg
Molar volume vs. pressure at room temperature

Corundum crystallizes with trigonal symmetry in the space group R3c and has the lattice parameters a = 4.75 Å and c = 12.982 Å at standard conditions. The unit cell contains six formula units. [4] [21]

The toughness of corundum is sensitive to surface roughness [22] [23] and crystallographic orientation. [24] It may be 6–7 MPa·m1/2 for synthetic crystals, [24] and around 4 MPa·m1/2 for natural. [25]

In the lattice of corundum, the oxygen atoms form a slightly distorted hexagonal close packing, in which two-thirds of the octahedral sites between the oxygen ions are occupied by aluminium ions. [26] The absence of aluminium ions from one of the three sites breaks the symmetry of the hexagonal close packing, reducing the space group symmetry to R3c and the crystal class to trigonal. [27] The structure of corundum is sometimes described as a pseudohexagonal structure. [28]

Generalization

Because of its prevalence, corundum has also become the name of a major structure type (corundum type) found in various binary and ternary compounds. [29]

See also

Related Research Articles

<span class="mw-page-title-main">Gemstone</span> Piece of mineral crystal used to make jewelry

A gemstone is a piece of mineral crystal which, when cut or polished, is used to make jewelry or other adornments. Certain rocks and occasionally organic materials that are not minerals may also be used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some softer minerals such as brazilianite may be used in jewelry because of their color or luster or other physical properties that have aesthetic value. However, generally speaking, soft minerals are not typically used as gemstones by virtue of their brittleness and lack of durability.

<span class="mw-page-title-main">Kyanite</span> Aluminosilicate mineral

Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.

<span class="mw-page-title-main">Muscovite</span> Hydrated phyllosilicate mineral

Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 meters × 3 meters (16.5 feet × 10 feet) have been found in Nellore, India.

<span class="mw-page-title-main">Spinel</span> Mineral or gemstone

Spinel is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl
2
O
4
in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals.

<span class="mw-page-title-main">Sapphire</span> Gem variety of corundum

Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide (α-Al2O3) with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name sapphire is derived from the Latin word sapphirus, itself from the Greek word sappheiros (σάπφειρος), which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires – 9 on the Mohs scale (the third hardest mineral, after diamond at 10 and moissanite at 9.5) – sapphires are also used in some non-ornamental applications, such as infrared optical components, high-durability windows, wristwatch crystals and movement bearings, and very thin electronic wafers, which are used as the insulating substrates of special-purpose solid-state electronics such as integrated circuits and GaN-based blue LEDs. Sapphire is the birthstone for September and the gem of the 45th anniversary. A sapphire jubilee occurs after 65 years.

<span class="mw-page-title-main">Garnet</span> Mineral, semi-precious stone

Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.

<span class="mw-page-title-main">Feldspar</span> Group of rock-forming minerals

Feldspar is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.

<span class="mw-page-title-main">Ruby</span> Variety of corundum, mineral, gemstone

A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum. Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphires. Ruby is one of the traditional cardinal gems, alongside amethyst, sapphire, emerald, and diamond. The word ruby comes from ruber, Latin for red. The color of a ruby is due to the element chromium.

<span class="mw-page-title-main">Chrysoberyl</span> Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

<span class="mw-page-title-main">Gemology</span> Science dealing with natural and artificial gemstone materials

Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is a geoscience and a branch of mineralogy. Some jewelers are academically trained gemologists and are qualified to identify and evaluate gems.

<span class="mw-page-title-main">Aluminium oxide</span> Chemical compound with formula Al2O3

Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al2O3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and applications. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire. Al2O3 is significant in its use to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point.

An abrasive is a material, often a mineral, that is used to shape or finish a workpiece through rubbing which leads to part of the workpiece being worn away by friction. While finishing a material often means polishing it to gain a smooth, reflective surface, the process can also involve roughening as in satin, matte or beaded finishes. In short, the ceramics which are used to cut, grind and polish other softer materials are known as abrasives.

<span class="mw-page-title-main">Nepheline</span> Silica-undersaturated aluminosilicate mineral

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<span class="mw-page-title-main">Jewel bearing</span> Jewel-lined bearing used in precision instruments, particularly mechanical watches

A jewel bearing is a plain bearing in which a metal spindle turns in a jewel-lined pivot hole. The hole is typically shaped like a torus and is slightly larger than the shaft diameter. The jewels are typically made from the mineral corundum, usually either synthetic sapphire or synthetic ruby. Jewel bearings are used in precision instruments where low friction, long life, and dimensional accuracy are important. Their main use is in mechanical watches.

<span class="mw-page-title-main">Diamond simulant</span> Diamond-like object which is not a diamond

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The Verneuil method, also called flame fusion, was the first commercially successful method of manufacturing synthetic gemstones, developed in the late 1883 by the French chemist Auguste Verneuil. It is primarily used to produce the ruby, sapphire and padparadscha varieties of corundum, as well as the diamond simulants rutile, strontium titanate and spinel. The principle of the process involves melting a finely powdered substance using an oxyhydrogen flame, and crystallising the melted droplets into a boule. The process is considered to be the founding step of modern industrial crystal growth technology, and remains in wide use to this day.

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References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Mohs' scale of hardness". Collector's corner. Mineralogical Society of America. Retrieved 10 January 2014.
  3. 1 2 Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1997). "Corundum". Handbook of Mineralogy (PDF). Vol. III Halides, Hydroxides, Oxides. Chantilly, VA, US: Mineralogical Society of America. ISBN   0962209724. Archived (PDF) from the original on 2006-09-05.
  4. 1 2 3 "Corundum". Mindat.org.
  5. "Corundum". Webmineral.com. Archived from the original on 25 November 2006.
  6. 1 2 3 4 5 6 Hurlbut, Cornelius S.; Klein, Cornelis (1985). Manual of Mineralogy (20th ed.). Wiley. pp.  300–302. ISBN   0-471-80580-7.
  7. 1 2 Giuliani, Gaston; Ohnenstetter, Daniel; Fallick, Anthony E.; Groat, Lee; Fagan; Andrew J. (2014). "The Geology and Genesis of Gem Corundum Deposits". Gem Corundum. Research Gate: Mineralogical Association of Canada. pp. 37–38. ISBN   978-0-921294-54-2.
  8. Harper, Douglas. "corundum". Online Etymology Dictionary .
  9. Jeršek, Miha; Jovanovski, Gligor; Boev, Blažo; Makreski, Petre (2021). "Intriguing minerals: corundum in the world of rubies and sapphires with special attention to Macedonian rubies". ChemTexts. 7 (3): 19. doi:10.1007/s40828-021-00143-0. ISSN   2199-3793. S2CID   233435945.
  10. "The Mineral Corundum". galleries.com.
  11. Rickwood, P. C. (1981). "The largest crystals" (PDF). American Mineralogist. 66: 885–907. Archived (PDF) from the original on 2009-06-20.
  12. "Rubicon Technology grows 200 kg "super boule"". LED Inside. 21 April 2009.
  13. "Chinese made first use of diamond". BBC News. BBC. May 2005.
  14. Alexandra, Goho (16 February 2005). "In the Buff: Stone Age tools may have derived luster from diamond". Science News.
  15. Duroc-Danner, J. M. (2011). "Untreated yellowish orange sapphire exhibiting its natural colour" (PDF). Journal of Gemmology. 32 (5): 175–178. doi:10.15506/jog.2011.32.5.174. Archived from the original (PDF) on 16 May 2013.
  16. Bahadur (1943). "A Handbook of Precious Stones" . Retrieved 19 August 2007.
  17. Walsh, Andrew (February 2010). "The commodification of fetishes: Telling the difference between natural and synthetic sapphires". American Ethnologist. 37 (1): 98–114. doi:10.1111/j.1548-1425.2010.01244.x.
  18. Hirose, Eiichi; et al. (2014). "Sapphire mirror for the KAGRA gravitational wave detector" (PDF). Physical Review D. 89 (6): 062003. Bibcode:2014PhRvD..89f2003H. doi:10.1103/PhysRevD.89.062003. Archived (PDF) from the original on 2018-07-24.
  19. Billingsley, GariLynn (2004). "Advanced Ligo Core Optics Components – Downselect". LIGO Laboratory. Retrieved 6 February 2020.
  20. Defense World.Net, Russia’s Armored Steel-Comparable Ceramic Plate Clears Tests, 5th September 2020, Retrieved 29th December 2020
  21. Newnham, R. E.; de Haan, Y. M. (August 1962). "Refinement of the α Al2O3, Ti2O3, V2O3 and Cr2O3 structures*". Zeitschrift für Kristallographie. 117 (2–3): 235–237. Bibcode:1962ZK....117..235N. doi:10.1524/zkri.1962.117.2-3.235.
  22. Farzin-Nia, Farrokh; Sterrett, Terry; Sirney, Ron (1990). "Effect of machining on fracture toughness of corundum". Journal of Materials Science. 25 (5): 2527–2531. Bibcode:1990JMatS..25.2527F. doi:10.1007/bf00638054. S2CID   137548763.
  23. Becker, Paul F. (1976). "Fracture-Strength Anisotropy of Sapphire". Journal of the American Ceramic Society. 59 (1–2): 59–61. doi:10.1111/j.1151-2916.1976.tb09390.x.
  24. 1 2 Wiederhorn, S. M. (1969). "Fracture of Sapphire". Journal of the American Ceramic Society. 52 (9): 485–491. doi:10.1111/j.1151-2916.1969.tb09199.x.
  25. "Corundum, Aluminum Oxide, Alumina, 99.9%, Al2O3". www.matweb.com.
  26. Nesse, William D. (2000). Introduction to mineralogy. New York: Oxford University Press. pp. 363–364. ISBN   9780195106916.
  27. Borchardt-Ott, Walter; Kaiser, E. T. (1995). Crystallography (2nd ed.). Berlin: Springer. p. 230. ISBN   3540594787.
  28. Gea, Laurence A.; Boatner, L. A.; Rankin, Janet; Budai, J. D. (1995). "The Formation Al 2 O 3 /V 2 O 3 Multilayer Structures by High-Dose Ion Implantation". MRS Proceedings. 382: 107. doi:10.1557/PROC-382-107.
  29. Muller, Olaf; Roy, Rustum (1974). The major ternary structural families. New York: Springer-Verlag. ISBN   0-387-06430-3. OCLC   1056558.