Nepheline syenite of the Intrusive Complex of Tanguá, State of Rio de Janeiro, Brazil (Motoki et al., 2011a)
Nepheline syenites are silica-undersaturated and some are peralkaline (terms discussed in igneous rock). Nepheline is a feldspathoid, a solid-solution mineral, that does not coexist with quartz; rather, nepheline would react with quartz to produce alkali feldspar.
They are distinguished from syenites not only by the presence of nepheline but also by the occurrence of many other minerals rich in alkalis and in rare earths and other incompatible elements. In nepheline syenites, alkali feldspar dominates, commonly represented by orthoclase and the exsolved lamellar albite, form perthite. In some rocks the potash feldspar, in others the soda feldspar predominates. Fresh clear microcline is very characteristic of some types of nepheline syenite.
Sodalite, colorless and transparent in thin section, but frequently pale blue in the hand specimens, is the principal feldspathoid mineral in addition to nepheline. Reddish-brown to black aenigmatite occurs also in these rocks. Extremely iron-rich olivine is rare, but is present in some nepheline syenite. Other minerals common in minor amounts include sodium-rich pyroxene, biotite, titanite, iron oxides, apatite, fluorite, melanitegarnet, and zircon. Cancrinite occurs in several nepheline-syenites. A great number of interesting and rare minerals have been recorded from nepheline syenites and the pegmatite veins which intersect them.
Macroscopic aspects
Kakortokite (eudialytic nepheline syenite) Kangerdluarssaq Fjord, far-southern Greenland. Slab is 9.5 cm tall.
Macroscopic aspects of nepheline syenite are similar to those of granite. The presence of nepheline and absence of quartz are the fundamental difference. Biotite is generally of low content and the main mafic minerals are clinopyroxene (±) and amphibole (±). The macroscopic colour is grey, being little darker than granite. There is high-grade metamorphic rock originated from nepheline syenite that is characterized by gneiss texture of very rare occurrence. It is called nepheline syenite gneiss or litchfieldite. An example is found at Canaã village, State of Rio de Janeiro, Brazil.
Texture
The rock is holocrystalline, generally equigranular, equidirectional, and gross with grain size of 2mm to 5mm. In certain rare cases, the rock contains alkaline feldspar phenocrysts of 2cm to 5cm in length and 5mm to 2cm in thickness. The phenocrysts demonstrate orientation and eventually show cumulative texture.
Mineral composition
The main minerals are alkali feldspar, nepheline, clinopyroxene (±), amphibole (±), and biotite (±). Nepheline is the main feldspathoid. Quartz and orthopyroxene are absent. According to the IUGS classification nomenclature (International Union of Geological Sciences, Streckeisen, 1978), nepheline syenite has 10% < F/(F + A + P) < 60% and P/(A + P) < 10% (where F – feldspathoids, A – alkali feldspar, and P – plagioclase volume fractions). Phonolite is the fine-grained equivalent. In case nepheline is less than 10%, the rock is called alkaline syenite with nepheline or pulaskite. The similar rock without quartz and nepheline is denominated alkaline syenite or syenite. Because of the presence of feldspathoids, nepheline syenite is classified to be a typical alkaline rock.
The alkaline feldspar is not potassic, but generally sodic-potassic, which is characterized by interlocking anorthoclase, called perthite. In the alkali feldspar almost pure albite domains are observed. Nepheline generally shows partial alteration into natrolite and cancrinite. The clinopyroxene is sodic whose composition varies from hedenbergite to aegirine-augite. This mineral eventually presents resorption shape. The reaction rim constituted by amphibole and/or biotite is commonly observed. The amphibole is of high alkali, such as alkaline hornblende and riebeckite. The alkaline clinopyroxene and amphibole are characteristics of typical alkaline rocks. Biotite is annite, with high Fe/Mg ratio.
The accessory minerals are magnetite, ilmenite, apatite, and titanite. Eventually, sodalite is found along hydrothermal fractures. Different from granite, zircon is rare and, if present, it is as xenocrysts. On the other hand, nepheline syenite gneiss contains abundant and large zircon crystals.
Genesis
Silica-undersaturated igneous rocks typically are formed by low degrees of partial melting in the Earth's mantle. Carbon dioxide may dominate over water in source regions. Magmas of such rocks are formed in a variety of environments, including continental rifts, ocean islands, and supra-subduction positions in subduction zones. Nepheline syenite and phonolite may be derived by crystal fractionation from more mafic silica-undersaturated mantle-derived melts, or as partial melts of such rocks. Igneous rocks with nepheline in their normative mineralogy commonly are associated with other unusual igneous rocks such as carbonatite.
Distribution
Pseudoleucite nepheline syenite of the Intrusive Complex of Morro de São João, State of Rio de Janeiro, Brazil (Motoki et al., 2011b)
Phonolite lavas formed in the East African rift in particularly large quantity, and the volume there may exceed the volume of all other phonolite occurrences combined, as discussed by Barker (1983).
Rocks of this class also occur in Brazil (Serra de Tingua) containing sodalite and often much augite, in the western Sahara and Cape Verde Islands; also at Zwarte Koppies in the Transvaal, Madagascar, São Paulo in Brazil, Paisano Pass in West Texas, United States, and Montreal, Quebec, Canada. The rock of Salem, Massachusetts, United States, is a mica-foyaite rich in albite and aegirine: it accompanies granite and essexite. Litchfieldite is another well-marked type of nepheline-syenite, in which albite is the dominant feldspar. It is named after Litchfield, Maine, United States, where it occurs in scattered blocks. Biotite, cancrinite and sodalite are characteristic of this rock. A similar nepheline-syenite is known from Hastings County, Ontario, and contains hardly any orthoclase, but only albite feldspar. Nepheline is very abundant and there is also cancrinite, sodalite, scapolite, calcite, biotite and hornblende. The lujaurites are distinguished from the rocks above described by their dark color, which is due to the abundance of minerals such as augite, aegirine, arfvedsonite and other kinds of amphibole. Typical examples are known near Lujaur on the White Sea, where they occur with umptekites and other very peculiar rocks. Other localities for this group are at Julianehaab in Greenland with sodalite-syenite; at their margins they contain pseudomorphs after leucite. The lujaurites frequently have a parallel-banding or gneissose structure. Sodalite-syenites in which sodalite very largely or completely takes the place of nepheline occur in Greenland, where they contain also microcline-perthite, aegirine, arfvedsonite and eudialyte.
Cancrinitesyenite, with a large percentage of cancrinite, has been described from Dalekarlia, Sweden and from Finland. Urtite from Lujaur Urt on the White Sea consists very largely of nepheline, with aegirine and apatite, but no feldspar. Jacupirangite (from Jacupiranga in Brazil) is a blackish rock composed of titaniferous augite, magnetite, ilmenite, perofskite and nepheline, with secondary biotite.
Nomenclature
There is a wide variety of silica-undersaturated and peralkaline igneous rocks, including many informal place-name varieties named after the locations in which they were first discovered. In many cases these are plain nepheline syenites containing one or more rare minerals or mineraloids, which do not warrant a new formal classification. These include;
Foyaite: foyaites are named after Foya in the Serra de Monchique, in southern Portugal. These are K-feldspar-nepheline syenites containing <10% ferromagnesian minerals, usually pyroxene, hornblende and biotite.
Laurdalite: The laurdalites, from Laurdal in Norway, are grey or pinkish, and in many ways closely resemble the larvikites of southern Norway, with which they occur. They contain anorthoclase feldspars, biotite or greenish augite, much apatite and in some cases, olivine.
Thin section image of the nepheline syenite of the Intrusive Complex of Tanguá, State of Rio de Janeiro, Brazil (Motoki et al., 2011a)
The chemical peculiarities of the nepheline-syenites are well marked. They are exceedingly rich in alkalis and in alumina (hence the abundance of felspathoids and alkali feldspars), with silica varying from 50 to 56%, while lime, magnesia and iron are never present in great quantity, though somewhat more variable than the other components. A worldwide average of the major elements in nepheline syenite tabulated by Barker (1983) is listed below, expressed as weight percent oxides.
Nepheline syenite is characterized by high ratio of (Na2O+K2O)/SiO2 and (Na2O+K2O)/Al2O3, which are represented respectively by the existence of nepheline and alkaline mafic minerals. Therefore, it is classified geochemically as alkaline rock. This rock has low Fe and Mg contents, in total about 3wt%, and in this sense it is classified to be felsic rock. However, the SiO2 content is not so high, being 53% to 62wt%, which is equivalent to andesite and diorite. In this sense, it corresponds to intermediate rock. Light rare-earth elements are highly concentrated, indicating that the magma is highly differentiated.
Because nepheline syenite lacks quartz and is rich in feldspar and nepheline, it is used in the manufacturing of glass and ceramics.
Applications
Industrial use of nepheline syenite includes refractories, glass making, ceramics and, in pigments and fillers. In these applications the nepheline syenite is ground and dark minerals are carefully separated leaving a mixture of primarily feldspar and nepheline. This mixture is higher in alkali and aluminium and typically lower in iron and silica than feldspars from pegmatites making it a good raw material. In 1994 production of nepheline syenite in Canada and Norway, the largest producing countries, was 600,000 tonnes and 330,000 tonnes respectively.[5]
Requirements for nepheline syenite as a raw material for glass manufacturer include:[6]
Al2O3 >23%; >14% Na2O + K2O; Fe2O3 <0.1%,
Absence of refractory minerals.
Coarsely ground, typically -40# to +200# mesh.
The typical mineralogical and chemical analysis of a ceramic grade nepheline syenite are:[7]
↑ Sutherland, D.S. (editor) (1982) Igneous Rocks of the British Isles, page 211
↑ Eby, G. N., 2012, The Beemerville alkaline complex, northern New Jersey, in Harper, J. A., ed., Journey along the Taconic unconformity, northeastern Pennsylvania, New Jersey, and southeastern New York: Guidebook, 77th Annual Field Conference of Pennsylvania Geologists, Shawnee on Delaware, PA, p. 85–91.
↑ 'Industrial Minerals - A Global Geology' P.W. Harben, M. Kuzvart, Milos. Industrial Minerals, Pg. 268
↑ ’Industrial Minerals And Their Uses - A Handbook And Formular’ P. A. Ciullo. William Andrew, 1996. Pg. 43
Gabbro is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term gabbro may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite.
Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations. It is considered a granitoid. Some syenites contain larger proportions of mafic components and smaller amounts of felsic material than most granites; those are classed as being of intermediate composition.
Trachyte is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and alkali metals. It is the volcanic equivalent of syenite.
Phonolite is an uncommon shallow intrusive or extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic. Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. It has an unusually high Na2O + K2O content, defining its position in the TAS classification of igneous rocks. Its coarse grained (phaneritic) intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name phonolite comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name clinkstone is given as a synonym.
Basanite is an igneous, volcanic (extrusive) rock with aphanitic to porphyritic texture. It is composed mostly of feldspathoids, pyroxenes, olivine, and plagioclase and forms from magma low in silica and enriched in alkali metal oxides that solidifies rapidly close to the Earth's surface.
The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing primary quartz. A notable exception where feldspathoids and quartz-bearing rocks are found together is the Red Hill Syenite.
Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.
Nephelinite is a fine-grained or aphanitic igneous rock made up almost entirely of nepheline and clinopyroxene. If olivine is present, the rock may be classified as an olivine nephelinite. Nephelinite is dark in color and may resemble basalt in hand specimen. However, basalt consists mostly of clinopyroxene (augite) and calcic plagioclase.
Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.
Essexite, also called nepheline monzogabbro, is a dark gray or black holocrystalline plutonic igneous rock. Its name is derived from the type locality in Essex County, Massachusetts, in the United States.
Theralite is, in petrology, the name given to calcic foidal gabbro, a plutonic hylocrystalline rock consisting of augite, olivine, calcic plagioclase (labradorite), and nepheline, along with accessories including biotite, magnetite, ilmenite and analcime.
Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.
Borolanite is an historical petrological name for a pyroxene-melanite bearing nepheline syenite variety which contains nepheline-alkali feldspar pseudomorphs interpreted to be after leucite which occur as conspicuous white spots in the dark rock matrix. The rock occurs in the Borralan Igneous Complex or Loch Borralan Complex which is an alkalic igneous complex near Loch Borralan in northwest Scotland.
Litchfieldite is a rare igneous rock. It is a coarse-grained, foliated variety of nepheline syenite, sometimes called nepheline syenite gneiss or gneissic nepeheline syenite. Litchfieldite is composed of two varieties of feldspar, with nepheline, sodalite, cancrinite and calcite. The mafic minerals, when present, are magnetite and an iron-rich variety of biotite (lepidomelane).
Normative mineralogy is a calculation of the composition of a rock sample that estimates the idealised mineralogy of a rock based on a quantitative chemical analysis according to the principles of geochemistry.
Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhibit a considerable variety of types and are of great interest petrographically. For the presence of this mineral it is necessary that the silica percentage of the rock should be low, since leucite is incompatible with free quartz and reacts with it to form potassium feldspar. Because it weathers rapidly, leucite is most common in lavas of recent and Tertiary age, which have a fair amount of potassium, or at any rate have potassium equal to or greater than sodium; if sodium is abundant nepheline occurs rather than leucite.
Case hardening is a weathering phenomenon of rock surface induration. It is observed commonly in: felsic alkaline rocks, such as nepheline syenite, phonolite and trachyte; pyroclastic rocks, as pyroclastic flow deposit, fine air-fall deposits and vent-filling pyroclastic deposits; sedimentary rocks, as sandstone and mudstone.
Shonkinite is an intrusive igneous rock found in few places in the world. It is unique in having low silica, feldspathoid minerals, and large blocky crystals of black augite. It makes up much of the hard dark grey rock comprising certain mountains and buttes in Montana that are remnants of laccoliths and stocks, such as the Highwood mountains.
The Red Hill Syenite is a layered igneous rock complex in central New Hampshire, about 20 mi (32 km) east of Plymouth. The Red Hill Syenite is part of the White Mountain magma series, which underlays the White Mountains of New Hampshire. Red Hill is roughly oval-shaped, covers just under 7.7 square miles (20 km2), and has a summit elevation of 2,028 feet (618 m).
References
Sørensen, H. 1974. The alkaline rocks. 1st Edition. John Wiley & Sons Ltd. 634 p. ISBN0-471-81383-4.
Streckeisen, A. L. 1978. IUGS Subcommission on the Systematics of Igneous Rocks. Classification and Nomenclature of Volcanic Rocks, Lamprophyres, Carbonatites and Melilite Rocks. Recommendations and Suggestions. Neues Jahrbuch für Mineralogie, Abhandlungen, 141, 1–14.
Motoki, A., Sichel, S. E., Vargas, T., Aires, J. R., Iwanuch, W., Mello, S. L. M., Motoki, K. F., Silva, S., Balmant, A., Gonçalves, J. 2010. Geochemical evolution of the felsic alkaline rocks of Tanguá, Rio Bonito, and Itaúna intrusive bodies, State of Rio de Janeiro, Brazil. Geociências, Rio Claro, 29–3, 291–310.
Motoki, A., Araújo, A. L., Sichel, S. E., Motoki, K. F., Silva, S. Nepheline syenite magma differentiation process by continental crustal assimilation for the Cabo Frio Island intrusive complex, State of Rio de Janeiro, Brazil. Geociências, Rio Claro, 2011, in press.
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