Aenigmatite | |
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General | |
Category | Inosilicates |
Formula (repeating unit) | Na2Fe2+5TiSi6O20 |
IMA symbol | Aen [1] |
Strunz classification | 9.DH.40 |
Crystal system | Triclinic |
Crystal class | Pinacoidal (1) (same H-M symbol) |
Space group | P1 |
Unit cell | a = 10.415(1), b = 10.840(1) c = 8.931(1) [Å]; Z = 2 α = 105.107(4)° β = 96.610(5)° γ = 125.398(4)° |
Identification | |
Color | Velvet-black |
Crystal habit | Poorly developed prismatic crystals, occurring as irregular clusters; pseudomonoclinic |
Twinning | Complex by rotation perpendicular to (011) or about [010] of the pseudomonoclinic cell; polysynthetic |
Cleavage | Good on {010} and {100} |
Fracture | Uneven |
Tenacity | Brittle |
Mohs scale hardness | 5.5 |
Luster | Vitreous to greasy |
Streak | Reddish brown |
Diaphaneity | Translucent to opaque |
Specific gravity | 3.81 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.780 – 1.800 nβ = 1.800 – 1.820 nγ = 1.870 – 1.900 |
Birefringence | δ = 0.090 – 0.100 |
Pleochroism | X = yellow brown; Y = red-brown; Z = dark brown to black |
2V angle | Measured: 27° to 55° |
Dispersion | r < v; very strong |
References | [2] [3] [4] |
Aenigmatite, also known as cossyrite after Cossyra, the ancient name of Pantelleria, is a sodium, iron, titanium inosilicate mineral. The chemical formula is Na2Fe2+5TiSi6O20 and its structure consists of single tetrahedral chains with a repeat unit of four and complex side branches. It forms brown to black triclinic lamellar crystals. It has Mohs hardness of 5.5 to 6 and specific gravity of 3.74 to 3.85. Aenigmatite forms a solid-solution series with wilkinsonite, Na2Fe2+4Fe3+2Si6O20.
Aenigmatite is primarily found in peralkaline volcanic rocks, pegmatites, and granites as well as silica-poor intrusive rocks. It was first described by August Breithaupt in 1865 for an occurrence in the Ilimaussaq intrusive complex of southwest Greenland. Its name comes from αίνιγμα, the Greek word for "riddle".
It was also reported from the Kaidun meteorite, possibly a Mars meteorite, which landed in March 1980 in South Yemen. Other notable studied occurrences include:
The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and between 64 and 90 percent of NaAlSi3O8.
Kogarkoite is a sodium sulfate fluoride mineral with formula Na3(SO4)F. It has a pale blue color, a specific gravity of about 2.67 and a hardness of 3.5. The crystal is monoclinic and is a type of naturally occurring antiperovskite. Kogarkoite is named after the Russian petrologist Lia Nikolaevna Kogarko (born 1936) who discovered the mineral.
Phonolite is an uncommon shallow intrusive or extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. It has an unusually high (12% or more) Na2O + K2O content, defining its position in the TAS classification of igneous rocks. Its coarse grained (phaneritic) intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name phonolite comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name clinkstone is given as a synonym.
Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).
Cotunnite is the natural mineral form of lead(II) chloride (PbCl2). Unlike the pure compound, which is white, cotunnite can be white, yellow, or green. The density of mineral samples spans range 5.3–5.8 g/cm3. The hardness on the Mohs scale is 1.5–2. The crystal structure is orthorhombic dipyramidal and the point group is 2/m 2/m 2/m. Each Pb has a coordination number of 9. Cotunnite occurs near volcanoes: Vesuvius, Italy; Tarapacá, Chile; and Tolbachik, Russia.
Carbonatite is a type of intrusive or extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification.
Eudialyte, whose name derives from the Greek phrase Εὖ διάλυτος, eu dialytos, meaning "well decomposable", is a somewhat rare, nine-member-ring cyclosilicate mineral, which forms in alkaline igneous rocks, such as nepheline syenites. Its name alludes to its ready solubility in acid.
Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine–augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite series, the sodium is variably replaced by calcium with iron(II) and magnesium replacing the iron(III) to balance the charge. Aluminum also substitutes for the iron(III). Acmite is a fibrous green-colored variety.
Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic.
Pigeonite is a mineral in the clinopyroxene subgroup of the pyroxene group. It has a general formula of (Ca,Mg,Fe)(Mg,Fe)Si2O6. The calcium cation fraction can vary from 5% to 25%, with iron and magnesium making up the rest of the cations.
Kornerupine (also called Prismatine) is a rare boro-silicate mineral with the chemical formula (Mg,Fe2+)4(Al,Fe3+)6(SiO4,BO4)5(O,OH)2. It crystallizes in the orthorhombic – dipyramidal crystal system as brown, green, yellow to colorless slender tourmaline like prisms or in massive fibrous forms. It has a Mohs hardness of 7 and a specific gravity of 3.3 to 3.34. Its indices of refraction are nα=1.660 – 1.671, nβ=1.673 – 1.683 and nγ=1.674 – 1.684.
The Sierra Nevada Batholith is a large batholith which forms the core of the Sierra Nevada mountain range in California, exposed at the surface as granite.
The Coast Range Arc was a large volcanic arc system, extending from northern Washington through British Columbia and the Alaska Panhandle to southwestern Yukon. The Coast Range Arc lies along the western margin of the North American Plate in the Pacific Northwest of western North America. Although taking its name from the Coast Mountains, this term is a geologic grouping rather than a geographic one, and the Coast Range Arc extended south into the High Cascades of the Cascade Range, past the Fraser River which is the northward limit of the Cascade Range proper.
Pantellerite is a type of volcanic rock, specifically a peralkaline rhyolite. It has a higher iron and lower aluminium composition than comendite. It is named after Pantelleria, a volcanic island in the Strait of Sicily and the type location for this rock. On Pantelleria the rock is usually found as a vitrophyre containing phenocrysts of anorthoclase or sanidine. Quartz is found only in the most strongly peralkaline rocks. Mafic minerals may include aegirine, fayalite, aenigmatite, ilmenite, and sodic amphibole.
The Cathedral Peak Granodiorite (CPG) was named after its type locality, Cathedral Peak in Yosemite National Park, California. The granodiorite forms part of the Tuolumne Intrusive Suite, one of the four major intrusive suites within the Sierra Nevada. It has been assigned radiometric ages between 88 and 87 million years and therefore reached its cooling stage in the Coniacian.
Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.
Stillwellite-(Ce) is a rare-earth boro-silicate mineral with chemical formula (Ce,La,Ca)BSiO5.
The geology of North Macedonia includes the study of rocks dating to the Precambrian and a wide array of volcanic, sedimentary and metamorphic rocks formed in the last 539 million years.