Andradite

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Andradite [Adr]
Andradite-Mali.jpg
Single crystal (4.2 cm) – Diakon, Nioro du Sahel Circle, Kayes Region, Mali
General
Category Garnet group
Formula
(repeating unit)
Ca3Fe2(SiO4)3
IMA symbol Adr [1]
Strunz classification 9.AD.25
Crystal system Cubic
Crystal class Hexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space group Ia3d
Unit cell a = 12.056 Å; Z = 8
Identification
ColorYellow, greenish yellow to emerald-green, dark green; brown, brownish red, brownish yellow; grayish black, black; may be sectored
Crystal habit Commonly well-crystallized dodecahedra, trapezohedra, or combinations, also granular to massive
Cleavage none
Fracture conchoidal to uneven
Tenacity Brittle
Mohs scale hardness6.5 to 7
Luster Adamantine to resinous, dull
Streak White
Diaphaneity Transparent to translucent
Specific gravity 3.859 calculated; 3.8–3.9 measured
Optical propertiesIsotropic, typically weakly anisotropic
Refractive index n = 1.887
Absorption spectra demantoid – 440 nm band or complete absorption at 440 nm and below, may also have lines at 618, 634, 685, 690 nm [2]
References [2] [3] [4] [5]
Major varieties
Demantoid transparent light to dark green to yellow-green
Melaniteopaque black
Topazolitetransparent to translucent yellow, may show chatoyancy

Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.

Contents

Andradite includes three varieties:

It was first described in 1868 for an occurrence in Drammen, Buskerud, Norway. [3] [4] [7] Andradite was named after the Brazilian statesman, naturalist, professor and poet José Bonifácio de Andrada e Silva (1763–1838). [3] [7]

Occurrence

It occurs in skarns developed in contact metamorphosed impure limestones or calcic igneous rocks; in chlorite schists and serpentinites and in alkalic igneous rocks (typically titaniferous). Associated minerals include vesuvianite, chlorite, epidote, spinel, calcite, dolomite and magnetite. [3] It is found in Iran, Italy, the Ural Mountains of Russia, Arizona and California and in Dnipropetrovsk Oblast in Ukraine.

Like the other garnets, andradite crystallizes in the cubic space group Ia3d, with unit-cell parameter of 12.051 Å at 100 K. [8]

The spin structure of andradite contains two mutually canted equivalent antiferromagnetic sublattices [9] below the Néel temperature (TN=11 K [10] ).

See also

Related Research Articles

<span class="mw-page-title-main">Beryl</span> Gemstone: beryllium aluminium silicate

Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring, hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.

<span class="mw-page-title-main">Titanite</span> Nesosilicate mineral

Titanite, or sphene (from Ancient Greek σφηνώ (sphēnṓ) 'wedge'), is a calcium titanium nesosilicate mineral, CaTiSiO5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly replaced by thorium.

<span class="mw-page-title-main">Tourmaline</span> Cyclosilicate mineral group

Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.

<span class="mw-page-title-main">Garnet</span> Mineral, semi-precious stone

Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.

<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Peridot</span> Green gem-quality mineral

Peridot, sometimes called chrysolite, is a yellowish-green transparent variety of olivine. Peridot is one of the few gemstones that occur in only one color.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Actinolite</span> Mineral

Actinolite is an amphibole silicate mineral with the chemical formula Ca2(Mg4.5–2.5Fe2+0.5–2.5)Si8O22(OH)2.

<span class="mw-page-title-main">Diopside</span> Pyroxene mineral

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

<span class="mw-page-title-main">Cordierite</span> Mg, Fe, Al cyclosilicate mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings.

<span class="mw-page-title-main">Almandine</span> Species of mineral belonging to the garnet group

Almandine, also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia Minor. Almandine is an iron alumina garnet, of deep red color, inclining to purple. It is frequently cut with a convex face, or en cabochon, and is then known as carbuncle. Viewed through the spectroscope in a strong light, it generally shows three characteristic absorption bands.

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Hornfels</span>

Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are caused by fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.

<span class="mw-page-title-main">Chlorite group</span> Type of mineral

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

<span class="mw-page-title-main">Demantoid</span> Green gemstone variety of the mineral andradite

Demantoid is the green gemstone variety of the mineral andradite, a member of the garnet group of minerals. Andradite is a calcium- and iron-rich garnet. The chemical formula is Ca3Fe2(SiO4)3 with chromium substitution as the cause of the demantoid green color. Ferric iron is the cause of the yellow in the stone.

<span class="mw-page-title-main">Pyrope</span> Mineral of the garnet group

The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek words for fire and eye. Despite being less common than most garnets, it is a widely used gemstone with numerous alternative names, some of which are misnomers. Chrome pyrope, and Bohemian garnet are two alternative names, the usage of the latter being discouraged by the Gemological Institute of America. Misnomers include Colorado ruby, Arizona ruby, California ruby, Rocky Mountain ruby, Elie Ruby, Bohemian carbuncle, and Cape ruby.

<span class="mw-page-title-main">Spessartine</span> Nesosilicate, manganese aluminium garnet species

Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3. This mineral is sometimes mistakenly referred to as spessartite.

<span class="mw-page-title-main">Grossular</span> Garnet, nesosilicate mineral

Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.

<span class="mw-page-title-main">Hauyne</span> Tectosilicate mineral with sometimes a blue colour due to a cyclic trisulfide anion

Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

<span class="mw-page-title-main">Hydrogrossular</span> Calcium aluminium garnet

Hydrogrossular is a calcium aluminium garnet series (formula: Ca3Al2(SiO4)3−x(OH)4x, with hydroxide (OH) partially replacing silica (SiO4)). The endmembers of the hydrogarnet family (grossular, hibschite, and katoite) depend on the degree of substitution (x):

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Gemological Institute of America, GIA Gem Reference Guide 1995, ISBN   0-87311-019-6
  3. 1 2 3 4 Handbook of Mineralogy
  4. 1 2 Andradite, Mindat.org
  5. Webmineral data
  6. Melanite, Mindat.org
  7. 1 2 3 4 Grande, Lance; Augustyn, Allison (2009). Gems and Gemstones: Timeless Natural Beauty of the Mineral World. University of Chicago Press. pp. 188–91. ISBN   978-0-226-30511-0.
  8. Thomas Armbruster and Charles A. Geiger (1993): "Andradite crystal chemistry, dynamic X-site disorder and structural strain in silicate garnets." European Journal of Mineralogy v. 5, no. 1, p. 59-71.
  9. Danylo Zherebetskyy (2010). Quantum mechanical first principles calculations of the electronic and magnetic structure of Fe-bearing rock-forming silicates , PhD Thesis, Universal Publishers/Dissertation.com, Boca Raton, Florida, USA, p. 136. ISBN   1-59942-316-2.
  10. Enver Murad (1984): "Magnetic ordering in andradite." American Mineralogist 69, no. 7-8; pp. 722–24.

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