Andradite [Adr] | |
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General | |
Category | Garnet group |
Formula (repeating unit) | Ca3Fe2(SiO4)3 |
IMA symbol | Adr [1] |
Strunz classification | 9.AD.25 |
Crystal system | Cubic |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Ia3d |
Unit cell | a = 12.056 Å; Z = 8 |
Identification | |
Color | Yellow, greenish yellow to emerald-green, dark green; brown, brownish red, brownish yellow; grayish black, black; may be sectored |
Crystal habit | Commonly well-crystallized dodecahedra, trapezohedra, or combinations, also granular to massive |
Cleavage | none |
Fracture | conchoidal to uneven |
Tenacity | Brittle |
Mohs scale hardness | 6.5 to 7 |
Luster | Adamantine to resinous, dull |
Streak | White |
Diaphaneity | Transparent to translucent |
Specific gravity | 3.859 calculated; 3.8–3.9 measured |
Optical properties | Isotropic, typically weakly anisotropic |
Refractive index | n = 1.887 |
Absorption spectra | demantoid – 440 nm band or complete absorption at 440 nm and below, may also have lines at 618, 634, 685, 690 nm [2] |
References | [2] [3] [4] [5] |
Major varieties | |
Demantoid | transparent light to dark green to yellow-green |
Melanite | opaque black |
Topazolite | transparent to translucent yellow, may show chatoyancy |
Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.
Andradite includes three varieties:
It was first described in 1868 for an occurrence in Drammen, Buskerud, Norway. [3] [4] [7] Andradite was named after the Brazilian statesman, naturalist, professor and poet José Bonifácio de Andrada e Silva (1763–1838). [3] [7]
It occurs in skarns developed in contact metamorphosed impure limestones or calcic igneous rocks; in chlorite schists and serpentinites and in alkalic igneous rocks (typically titaniferous). Associated minerals include vesuvianite, chlorite, epidote, spinel, calcite, dolomite and magnetite. [3] It is found in Iran, Italy, the Ural Mountains of Russia, Arizona and California and in Dnipropetrovsk Oblast in Ukraine.
Like the other garnets, andradite crystallizes in the cubic space group Ia3d, with unit-cell parameter of 12.051 Å at 100 K. [9]
The spin structure of andradite contains two mutually canted equivalent antiferromagnetic sublattices [10] below the Néel temperature (TN=11 K [11] ).
Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.
Titanite, or sphene (from Ancient Greek σφηνώ (sphēnṓ) 'wedge'), is a calcium titanium nesosilicate mineral, CaTiSiO5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly replaced by thorium.
Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula Al2SiO4(F, OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.
Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.
Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.
Peridot, sometimes called chrysolite, is a yellow-green transparent variety of olivine. Peridot is one of the few gemstones that occur in only one color.
Zircon is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green.
Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4 tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
Actinolite is an amphibole silicate mineral with the chemical formula Ca2(Mg4.5–2.5Fe2+0.5–2.5)Si8O22(OH)2.
Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2O
6. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.
Almandine, also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia Minor. Almandine is an iron alumina garnet, of deep red color, inclining to purple. It is frequently cut with a convex face, or en cabochon, and is then known as carbuncle. Viewed through the spectroscope in a strong light, it generally shows three characteristic absorption bands.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Demantoid is the green gemstone variety of the mineral andradite, a member of the garnet group of minerals. Andradite is a calcium- and iron-rich garnet. The chemical formula is Ca3Fe2(SiO4)3 with chromium substitution as the cause of the demantoid green color. Ferric iron is the cause of the yellow in the stone.
The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek words for fire and eye. Despite being less common than most garnets, it is a widely used gemstone with numerous alternative names, some of which are misnomers. Chrome pyrope, and Bohemian garnet are two alternative names, the usage of the latter being discouraged by the Gemological Institute of America. Misnomers include Colorado ruby, Arizona ruby, California ruby, Rocky Mountain ruby, Elie Ruby, Bohemian carbuncle, and Cape ruby.
Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3. This mineral is sometimes mistakenly referred to as spessartite.
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.
Hauyne or haüyne, also called hauynite or haüynite, old name Azure spar, is a rare tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.
Hydrogrossular is a calcium aluminium garnet series (formula: Ca3Al2(SiO4)3−x(OH)4x, with hydroxide (OH) partially replacing silica (SiO4)). The endmembers of the hydrogarnet family (grossular, hibschite, and katoite) depend on the degree of substitution (x):
Colophonite, less commonly kalophonit (from Ancient Greek: κολοφωνία, kolophonia, rosin or rosin colors) — an obsolete historical name for a brownish calcium-iron mineral of the garnet family, a variety of grossular (later, andradite), discovered as an associated metamorphic mineral in the iron ore mines of the southern Norwegian islands, primarily Tromø (near Arendal). It is a nesosilicate, with formula Ca3Fe3+2(SiO4)3. Other names for colophonite: resin garnet (French: Grenat résinite), calderite, rosin garnet.
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