Pyrope

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Pyrope
Pyrope-260132.jpg
General
Category Nesosilicate
Formula
(repeating unit)
Mg3Al2(SiO4)3
IMA symbol Prp [1]
Strunz classification 9.AD.25
Crystal system Cubic
Crystal class Hexoctahedral (m3m)
H–M symbol: (4/m 3 2/m)
Space group Ia3d
Identification
ColorBlood red to black red, red, orange red, pink, some varieties are very dark, almost black, while others can take tones of purple to purple red, Some chromium-rich pyropes are thermochromic, becoming green when heated. [2]
Crystal habit Euhedra typically display rhombic dodecahedral form, but trapezohedra are not uncommon, and hexoctahedra are seen in some rare samples. Massive and granular forms also occur.
Cleavage None
Fracture Conchoidal
Mohs scale hardness7.0–7.5
Luster greasy to vitreous [3]
Streak White
Specific gravity 3.78+0.09
−0.16
[3]
Polish lustervitreous [3]
Optical propertiesSingle refractive, often anomalous double refractive [3]
Refractive index 1.74 normal, but ranges from 1.714 to over 1.742 [3]
Birefringence Isotropic, appears black in cross-polarized light
Pleochroism none
Ultraviolet fluorescence inert
Absorption spectra broad band at 564 nm with cutoff at 440 to 445 nm. Fine gem quality pyropes may show chromium lines in the red end of the spectrum
Solubility Insoluble in water, weakly soluble in HF
Mineral association Olivine, pyroxene, hornblende, biotite, diamond
References [4]

The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek words for fire and eye. Despite being less common than most garnets, it is a widely used gemstone with numerous alternative names, some of which are misnomers. Chrome pyrope, and Bohemian garnet are two alternative names, the usage of the latter being discouraged by the Gemological Institute of America. [3] Misnomers include Colorado ruby, Arizona ruby, California ruby, Rocky Mountain ruby, Elie Ruby, Bohemian carbuncle, and Cape ruby.

The composition of pure pyrope is Mg3Al2(SiO4)3, although typically other elements are present in at least minor proportions—these other elements include Ca, Cr, Fe and Mn. Pyrope forms a solid solution series with almandine and spessartine, which are collectively known as the pyralspite garnets (pyrope, almandine, spessartine). Iron and manganese substitute for the magnesium in the pyrope structure. The resultant, mixed composition garnets are defined according to their pyrope-almandine ratio. The semi-precious stone rhodolite is a garnet of ~70% pyrope composition.

The origin of most pyrope is in ultramafic rocks, typically peridotite from the Earth's mantle: these mantle-derived peridotites can be attributed both to igneous and metamorphic processes. Pyrope also occurs in ultrahigh-pressure (UHP) metamorphic rocks, as in the Dora-Maira massif in the western Alps. In that massif, nearly pure pyrope occurs in crystals to almost 12 cm (5 in) in diameter; some of that pyrope has inclusions of coesite, and some has inclusions of enstatite and sapphirine.

Pyrope is common in peridotite xenoliths from kimberlite pipes, some of which are diamond-bearing. Pyrope found in association with diamond commonly has a Cr2O3 content of 3–8%, which imparts a distinctive violet to deep purple coloration (often with a greenish tinge) and because of this is often used as a kimberlite indicator mineral in areas where erosive activity makes pinpointing the origin of the pipe difficult. These varieties are known as chrome-pyrope, or G9/G10 garnets.

Mineral identification

Pyrope aggregate. Garnet Group-Pyrope Iron aluminum silicate Barton Mines, Gore Mountain, Warren County, New York 2861.jpg
Pyrope aggregate.

In hand specimens, pyrope is very tricky to distinguish from almandine; however, it is likely to display fewer flaws and inclusions. Other distinguishing criteria are listed in the adjacent table. Care should be taken when using these properties as many of those listed have been determined from synthetically grown, pure-composition pyrope. Others, such as pyrope's high specific gravity, may be of little use when studying a small crystal embedded in a matrix of other silicate minerals. In these cases, mineral association with other mafic and ultramafic minerals may be the best indication that the garnet you are studying is pyrope.

In petrographic thin section, the most distinguishing features of pyrope are those shared with the other common garnets: high relief and isotropy. Garnets tend to be less strongly coloured than other silicate minerals in thin section, although pyrope may show a pale pinkish purple hue in plane-polarized light. The lack of cleavage, commonly euhedral crystal morphology, and mineral associations should also be used in identification of pyrope under the microscope.

Related Research Articles

<span class="mw-page-title-main">Garnet</span> Mineral, semi-precious stone

Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.

<span class="mw-page-title-main">Kimberlite</span> Igneous rock which sometimes contains diamonds

Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an 83.5-carat (16.70 g) diamond called the Star of South Africa in 1869 spawned a diamond rush and the digging of the open-pit mine called the Big Hole. Previously, the term kimberlite has been applied to olivine lamproites as Kimberlite II, however this has been in error.

<span class="mw-page-title-main">Dunite</span> Ultramafic and ultrabasic rock from Earths mantle which is made of the mineral olivine

Dunite, also known as olivinite, is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with minor amounts of other minerals such as pyroxene, chromite, magnetite, and pyrope. Dunite is the olivine-rich endmember of the peridotite group of mantle-derived rocks.

<span class="mw-page-title-main">Xenolith</span>

A xenolith is a rock fragment that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term xenolith is almost exclusively used to describe inclusions in igneous rock entrained during magma ascent, emplacement and eruption. Xenoliths may be engulfed along the margins of a magma chamber, torn loose from the walls of an erupting lava conduit or explosive diatreme or picked up along the base of a flowing body of lava on the Earth's surface. A xenocryst is an individual foreign crystal included within an igneous body. Examples of xenocrysts are quartz crystals in a silica-deficient lava and diamonds within kimberlite diatremes. Xenoliths can be non-uniform within individual locations, even in areas which are spatially limited, e.g. rhyolite-dominated lava of Niijima volcano (Japan) contains two types of gabbroic xenoliths which are of different origin - they were formed in different temperature and pressure conditions.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Phlogopite</span> Member of the mica family of phyllosilicates

Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.

<span class="mw-page-title-main">Diopside</span> Pyroxene mineral

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

<span class="mw-page-title-main">Eclogite</span> A dense metamorphic rock formed under high pressure

Eclogite is a metamorphic rock containing garnet (almandine-pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisite, dolomite, corundum and, rarely, diamond. The chemistry of primary and accessory minerals is used to classify three types of eclogite. The broad range of eclogitic compositions has led a longstanding debate on the origin of eclogite xenoliths as subducted, altered oceanic crust.

<span class="mw-page-title-main">Almandine</span> Species of mineral belonging to the garnet group

Almandine, also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia Minor. Almandine is an iron alumina garnet, of deep red color, inclining to purple. It is frequently cut with a convex face, or en cabochon, and is then known as carbuncle. Viewed through the spectroscope in a strong light, it generally shows three characteristic absorption bands.

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Pyroxenite</span> Igneous rock

Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the websterites which contain both types of pyroxenes. Closely allied to this group are the hornblendites, consisting essentially of hornblende and other amphiboles.

Knorringite is a mineral species belonging to the garnet group, and forms a series with the species pyrope. It was discovered in 1968 in the Kao kimberlite pipe in the Butha-Buthe District of Lesotho and is named after Oleg Von Knorring, a professor of mineralogy at the University of Leeds in England.

<span class="mw-page-title-main">Spessartine</span> Nesosilicate, manganese aluminium garnet species

Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3. This mineral is sometimes mistakenly referred to as spessartite.

<span class="mw-page-title-main">Andradite</span> Nesosilicate mineral species of garnet

Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.

<span class="mw-page-title-main">Lherzolite</span>

Lherzolite is a type of ultramafic igneous rock. It is a coarse-grained rock consisting of 40 to 90% olivine along with significant orthopyroxene and lesser amounts of calcic chromium-rich clinopyroxene. Minor minerals include chromium and aluminium spinels and garnets. Plagioclase can occur in lherzolites and other peridotites that crystallize at relatively shallow depths. At greater depth plagioclase is unstable and is replaced by spinel. At approximately 90 km depth, pyrope garnet becomes the stable aluminous phase. Garnet lherzolite is a major constituent of the Earth's upper mantle. Lherzolite is known from the lower ultramafic part of ophiolite complexes, from alpine-type peridotite massifs, from fracture zones adjacent to mid-oceanic ridges, and as xenoliths in kimberlite pipes and alkali basalts. Partial melting of spinel lherzolite is one of the primary sources of basaltic magma.

<span class="mw-page-title-main">Rhodolite</span> Rose-colored gemstone of the garnet group

Rhodolite is a varietal name for rose-pink to red mineral pyrope, a species in the garnet group. It was first described from Cowee Valley, Macon County, North Carolina. The name is derived from the Greek "rhodon" for "rose-like", in common with other pink mineral types. This coloration, and the commonly inclusion-free nature of garnet from this locality, has led to rhodolite being used as a gemstone. Rhodolite like other varietal names is not officially recognized as a mineralogical term, but rather used as an accepted trade name.

<span class="mw-page-title-main">Harzburgite</span> Ultramafic mantle rock


Harzburgite, an ultramafic, igneous rock, is a variety of peridotite consisting mostly of the two minerals olivine and low-calcium (Ca) pyroxene (enstatite); it is named for occurrences in the Harz Mountains of Germany. It commonly contains a few percent chromium-rich spinel as an accessory mineral. Garnet-bearing harzburgite is much less common, found most commonly as xenoliths in kimberlite.

<span class="mw-page-title-main">Navajo volcanic field</span> Volcanic field in southwestern United States

The Navajo volcanic field is a monogenetic volcanic field located in the Four Corners region of the United States, in the central part of the Colorado Plateau. The volcanic field consists of over 80 volcanoes and associated intrusions of unusual potassium-rich compositions, with an age range of 26.2 to 24.7 million years (Ma).

<span class="mw-page-title-main">Diamond inclusions</span>

Diamond inclusions are the non-diamond materials that get encapsulated inside diamond during its formation process in the mantle. The trapped materials can be other minerals or fluids like water. Since diamonds have high strength and low reactivity with either the inclusion or the volcanic host rocks which carry the diamond to the Earth's surface, the diamond serves as a container that preserves the included material intact under the changing conditions from the mantle to the surface. Although diamonds can only place a lower bound on the pressure of their formation, many inclusions provide additional constraints on the pressure, temperature and even age of formation.

References

  1. Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Thermochromic Cr-rich Pyrope Garnets
  3. 1 2 3 4 5 6 (Gia), Gemological. Gem Reference Guide. City: Gemological Institute of America (GIA), 1988. ISBN   0-87311-019-6
  4. Mineralienatlas