Amazonite

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Amazonite
Amazonita1.jpeg
Amazonite from Brazil
General
Category Tectosilicate
Formula
(repeating unit)
KAlSi3O8
Crystal system Triclinic
Identification
ColorGreen, blue-green
Crystal habit Prismatic
Cleavage Perfect
Fracture Uneven, splintery
Tenacity Brittle
Mohs scale hardness6.0–6.5
Luster Vitreous
Streak White
Diaphaneity Translucent, opaque
Specific gravity 2.56–2.58
Refractive index 1.522–1.530
Birefringence −0.008
Pleochroism Absent
Dispersion None
Ultraviolet fluorescence Weak; olive-green
Other characteristics Radioactive.svg Radioactive 14.05% (K)
References [1] [2] [3] :214–215

Amazonite, also known as amazonstone, [4] is a green tectosilicate mineral, a variety of the potassium feldspar called microcline. [4] [5] [6] Its chemical formula is KAlSi3O8, [1] [7] which is polymorphic to orthoclase.

Contents

Its name is taken from that of the Amazon River, from which green stones were formerly obtained, though it is unknown whether those stones were amazonite. [4] Although it has been used for jewellery for well over three thousand years, as attested by archaeological finds in Middle and New Kingdom Egypt [8] and Mesopotamia, no ancient or medieval authority mentions it. It was first described as a distinct mineral only in the 18th century. [9]

Green and greenish-blue varieties of potassium feldspars that are predominantly triclinic are designated as amazonite. [10] It has been described as a "beautiful crystallized variety of a bright verdigris-green" [11] and as possessing a "lively green colour". [4] It is occasionally cut and used as a gemstone. [12]

Occurrence

Amazonite is a mineral of limited occurrence. In Bronze Age Egypt, it was mined in the southern Eastern Desert at Gebel Migif. In early modern times, it was obtained almost exclusively from the area of Miass in the Ilmensky Mountains, 50 miles (80 km) southwest of Chelyabinsk, Russia, where it occurs in granitic rocks. [4]

Amazonite is now known to occur in various places around the world. Those places are, among others, as follows:

Australia:

China:

Libya:

Mongolia:

Ethiopia:

South Africa:

Sweden:

United States:

Color

For many years, the source of amazonite's color was a mystery. [20] Some people assumed the color was due to copper because copper compounds often have blue and green colors. [20] A 1985 study suggests that the blue-green color results from quantities of lead and water in the feldspar. [20] Subsequent 1998 theoretical studies by A. Julg expand on the potential role of aliovalent lead in the color of microcline. [21]

Other studies suggest the colors are associated with the increasing content of lead, rubidium, and thallium ranging in amounts between 0.00X and 0.0X in the feldspars, with even extremely high contents of PbO, lead monoxide, (1% or more) known from the literature. [10] A 2010 study also implicated the role of divalent iron in the green coloration. [7] These studies and associated hypotheses indicate the complex nature of the color in amazonite; in other words, the color may be the aggregate effect of several mutually inclusive and necessary factors. [9]

Health

A 2021 study by the German Institut für Edelsteinprüfung (EPI) found that the amount of lead that leaked from an 11 g (0.39 oz) sample of amazonite into an acidic solution simulating saliva exceeded European Union standard DIN EN 71-3:2013's recommended amount by five times. This experiment was to simulate a child swallowing amazonite, and could also apply to new alternative medicine practices such as inserting the mineral into oils or drinking water for days. [22]

Related Research Articles

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Amblygonite is a fluorophosphate mineral, (Li,Na)AlPO4(F,OH), composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France.

<span class="mw-page-title-main">Beryl</span> Gemstone: beryllium aluminium silicate

Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.

<span class="mw-page-title-main">Quartz</span> Mineral made of silicon and oxygen

Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of SiO2. Quartz is, therefore, classified structurally as a framework silicate mineral and compositionally as an oxide mineral. Quartz is the second most abundant mineral in Earth's continental crust, behind feldspar.

<span class="mw-page-title-main">Topaz</span> Silicate mineral

Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula Al2SiO4(F, OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.

<span class="mw-page-title-main">Tourmaline</span> Cyclosilicate mineral group

Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.

<span class="mw-page-title-main">Pegmatite</span> Igneous rock with very large interlocked crystals

A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.

<span class="mw-page-title-main">Orthoclase</span> Tectosilicate mineral found in igneous rock

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.

<span class="mw-page-title-main">Microcline</span> Igneous rock-forming tectosilicate mineral

Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase; it is more stable at lower temperatures than orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.

<span class="mw-page-title-main">Chrysoberyl</span> Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

<span class="mw-page-title-main">Albite</span> Mineral, Na-feldspar, Na-silicate, tectosilicate

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3
O
8
. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.

<span class="mw-page-title-main">Brazilianite</span> Yellow-green phosphate mineral

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<span class="mw-page-title-main">Spessartine</span> Nesosilicate, manganese aluminium garnet species

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<span class="mw-page-title-main">Elbaite</span> Cyclosilicate, mineral

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<span class="mw-page-title-main">Litchfieldite</span>

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Barringer Hill is a drowned geological and mineralogical site in central Texas. It lies on the former west side of the Colorado River, beneath Lake Buchanan, about 22 miles (35 km) northeast of the town of Llano. It consists of a pegmatite, lies near the eastern edge of the Central Mineral Region in the Texas Hill Country and is named for John Baringer, who discovered here much gadolinite about 1887.

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References

  1. 1 2 Walter, Schumann (1997). Gemstones of the world (Rev. & expanded ed.). New York: Sterling Pub. Co. p.  164. ISBN   0806994614 via Internet Archive.
  2. "Radioactive Gems : ClassicGems.net". ClassicGems.net. Archived from the original on 2021-02-11. Retrieved 2021-08-13.
  3. 1 2 3 4 5 6 7 8 9 10 11 Schlegel, Dorothy McKenney (1957). "Gem Stones of the United States". Geological Survey Bulletin (1042-G). United States Government Publishing Office via Google Books.
  4. 1 2 3 4 5 6 Wikisource-logo.svg One or more of the preceding sentences incorporates text from a publication now in the public domain :  Chisholm, Hugh, ed. (1911). "Amazon-stone". Encyclopædia Britannica . Vol. 1 (11th ed.). Cambridge University Press. p. 791.
  5. "Amazonite gemstone information". gemdat.org. Archived from the original on 2021-03-01. Retrieved 2018-08-24.
  6. "Amazonite".
  7. 1 2 "Amazonite: Amazonite mineral information and data". mindat.org. Archived from the original on 14 May 2021. Retrieved 13 April 2017.
  8. Harrell and Osman 2007
  9. 1 2 Mikhail Ostrooumov, Amazonite: Mineralogy, Crystal Chemistry, and Typomorphism (Elsevier, 2016), p. 1–12.
  10. 1 2 3 Pivec, E.; Ševčik, J.; Ulrych, J. (December 1981). "Amazonite from the alkali granite of the Avdar Massif, Mongolia". TMPM Tschermaks Petr. Mitt. 28 (4): 277–283. Bibcode:1981TMPM...28..277P. doi:10.1007/BF01081855.
  11. Chisholm, Hugh, ed. (1911). "Microcline"  . Encyclopædia Britannica . Vol. 18 (11th ed.). Cambridge University Press. p. 380.
  12. "Common Minerals of Virginia". Virginia Department of Mines, Minerals and Energy. Commonwealth of Virginia. Archived from the original on 24 July 2021. Retrieved 5 July 2019.
  13. "Barnes L. C., et al, (1980), Some Semiprecious and Ornamental Stones of South Australia, Government Printer, Adelaide, South Australia".
  14. Yang, Jianye; Zhao, Lei; Zhang, Weiguo (April 2014). "The Geochemical Effect of Lanthanides: Its Types and Application for Magmatic Rocks—A New Method to Semi-Quantitatively Determine Strength of Magmatic Fluid Complexation and Fractional Crystallization" (PDF). Journal of Earth Science. 25 (2). China University of Geosciences (Wuhan): 252–262. doi:10.1007/s12583-014-0420-z. ISSN   1674-487X. S2CID   54836739. Archived (PDF) from the original on 2022-10-09.
  15. Sihai, Liu; Changzhi, Wu; Lianxing, Gu; Zunzhong, Zhang; Junhua, Tang; Guangrong, Li; Ruxiong, Lei; Chuansheng, Wang (2008). "中天山白石头泉岩体年代学、岩石成因及构造意义" [Geochronology, petrogenesis and tectonic significances of the Baishitouquan pluton in Middle Tianshan, Northwest China]. Acta Petrologica Sinica (in Chinese). 24 (11). Beijing: China Science Publishing & Media Ltd.: 2720. ISSN   1000-0569.
  16. Suayah, Ismail B.; Miller, Jonathan S.; Miller, Brent V.; et al. (April 2006). "Tectonic significance of Late Neoproterozoic granites from the Tibesti massif in southern Libya inferred from Sr and Nd isotopes and U–Pb zircon data". Journal of African Earth Sciences. 44 (4–5): 564. Bibcode:2006JAfES..44..561S. doi:10.1016/j.jafrearsci.2005.11.020. ISSN   1464-343X. S2CID   26947582.
  17. 1 2 3 4 "Amazonite from South Africa". www.mindat.org. Retrieved 2020-05-25.
  18. Lundegårdh, Per H. (1971). Nyttosten i Sverige (in Swedish). Stockholm: Almqvist & Wiksell. p. 21.
  19. 1 2 Penick, D. Allen Jr.; Sweet, Palmer C. (May 1992). "Mineral collecting sites in Virginia" (PDF). Virginia Minerals. 38 (2). Charlottesville, Virginia: Virginia Department of Mines, Minerals, and Energy: 10–12. Archived from the original (PDF) on 24 April 2012.
  20. 1 2 3 Hoffmeister and Rossman (1985). "A spectroscopic study of irradiation coloring of amazonite; structurally hydrous, Pb-bearing feldspar" (PDF). American Mineralogist. 70: 794–804. Archived (PDF) from the original on 2022-10-09 via Mineralogical Society of America.
  21. Julg, A. (February 1998). "A theoretical study of the absorption spectra of Pb+ and Pb3+ in site K+ of microcline: application to the color of amazonite". Physics and Chemistry of Minerals. 25 (3). Springer-Verlag: 229–233. Bibcode:1998PCM....25..229J. doi:10.1007/s002690050108. ISSN   1432-2021. S2CID   95011489.
  22. "Lead in Amazonite – Caution". Institut für Edelsteinprüfung. April 22, 2021. Archived from the original on March 7, 2021. Retrieved August 13, 2021.

Further reading

Commons-logo.svg Media related to Amazonite at Wikimedia Commons