Serpentinite

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Serpentinite from the Maurienne valley, Savoie, French Alps Serpentinite sur gneiss.jpg
Serpentinite from the Maurienne valley, Savoie, French Alps
Sample of serpentinite from the Golden Gate National Recreation Area, California, United States Serpentinite.JPG
Sample of serpentinite from the Golden Gate National Recreation Area, California, United States
Chromitic serpentinite (7.9 cm (3.1 in) across), Styria Province, Austria. Protolith was a Proterozoic-Early Paleozoic upper mantle dunite peridotite that has been multiply metamorphosed during the Devonian, Permian, and Mesozoic. Chromitic serpentinite Styria Province, Austria.jpg
Chromitic serpentinite (7.9 cm (3.1 in) across), Styria Province, Austria. Protolith was a Proterozoic-Early Paleozoic upper mantle dunite peridotite that has been multiply metamorphosed during the Devonian, Permian, and Mesozoic.
Tightly folded serpentinite from the Tux Alps, Austria. Closeup view about 30 cm x 20 cm (12 in x 8 in). Folded serpentinite.jpg
Tightly folded serpentinite from the Tux Alps, Austria. Closeup view about 30 cm × 20 cm (12 in × 8 in).

Serpentinite is a metamorphic rock composed predominantly of serpentine group minerals formed by serpentinization of mafic or ultramafic rocks. The ancient origin of the name is uncertain, it may be from the similarity of its texture or color to snake skin. [1] Greek pharmacologist Dioscorides (AD 50) recommended eating this rock to prevent snakebite. [2]

Contents

Serpentinite has been called serpentine or serpentine rock, particularly in older geological texts and in wider cultural settings. [3] [4] [5] [6] [7]

Most of the chemical reactions necessary to synthesize acetyl-CoA, essential to basic biochemical pathways of life, take place during serpentinization. Serpentinite thermal vents are therefore considered a candidate for the origin of life on Earth.

Formation and mineralogy

Serpentinite is formed by near to complete serpentinization of mafic or ultramafic rocks. [8] Serpentinite is formed from mafic rock that is hydrated by carbon dioxide-deficient sea water that is pressed into the rock at great depths below the ocean floor. [9] This occurs at mid-ocean ridges and in the forearc mantle of subduction zones. [10] [11]

The final mineral composition of serpentinite is usually dominated by antigorite, lizardite, chrysotile (minerals of the serpentine subgroup), and magnetite ( Fe3O4 ), with brucite ( Mg(OH)2 ) less commonly present. Lizardite, chrysotile, and antigorite all have approximately the formula Mg3(Si2O5)(OH)4 or (Mg2+, Fe2+)3Si2O5(OH)4, but differ in minor components and in form. [10] Accessory minerals, present in small quantities, include awaruite, other native metal minerals, and sulfide minerals. [12]

Ophiolite of the Gros Morne National Park, Newfoundland. Ophiolites characteristically have a serpentinite component. Gros Morne moho.jpg
Ophiolite of the Gros Morne National Park, Newfoundland. Ophiolites characteristically have a serpentinite component.

Hydrogen production

The serpentinization reaction involving the transformation of fayalite (Fe-end member of olivine) by water into magnetite and quartz also produces molecular hydrogen H2 according to the following reaction:

This reaction closely resembles the Schikorr reaction also producing hydrogen gas by oxidation of Fe2+ ions into Fe3+ ions by the protons   H+ of water. Two   H+ are then reduced into H2.

In the Schikorr reaction, the two   H+ reduced into H2 are these from two OH− anions, then transformed into two oxide anions (O2−) directly incorporated into the magnetite crystal lattice while the water in excess is liberated as a reaction by-product.

Hydrogen produced by the serpentinization reaction is important because it can fuel microbial activity in the deep subsurface environment.[ citation needed ]

Hydrothermal vents and mud volcanoes

A white carbonate spire in the Lost City hydrothermal field Expl2224 - Flickr - NOAA Photo Library.jpg
A white carbonate spire in the Lost City hydrothermal field

Deep sea hydrothermal vents located on serpentinite close to the axis of mid-ocean ridges generally resemble black smokers located on basalt, but emit complex hydrocarbon molecules. The Rainbow field of the Mid-Atlantic Ridge is an example of such hydrothermal vents. Serpentinization alone cannot provide the heat supply for these vents, which must be driven mostly by magmatism. However, the Lost City Hydrothermal Field, located off the axis of the Mid-Atlantic Ridge, may be driven solely by heat of serpentinization. Its vents are unlike black smokers, emitting relatively cool fluids (40 to 75 °C (104 to 167 °F)) that are highly alkaline, high in magnesium, and low in hydrogen sulfide. The vents build up very large chimneys, up to 60 meters (200 ft) in height, composed of carbonate minerals and brucite. Lush microbial communities are associated with the vents. Though the vents themselves are not composed of serpentinite, they are hosted in serpentinite estimated to have formed at a temperature of about 200 °C (392 °F). [13] Sepiolite deposits on mid-ocean ridges may have formed through serpentinite-driven hydrothermal activity. [14] However, geologists continue to debate whether serpentinization alone can account for the heat flux from the Lost City field. [13]

The forearc of the Marianas subduction zone hosts large serpentinite mud volcanoes, which erupt serpentinite mud that rises through faults from the underlying serpentinized forearc mantle. Study of these mud volcanoes gives insights into subduction processes, and the high pH fluids emitted at the volcanoes support a microbial community. [15] [11] Experimental drilling into the gabbro layer of oceanic crust near mid-ocean ridges has demonstrated the presence of a sparse population of hydrocarbon-degrading bacteria. These may feed on hydrocarbons produced by serpentinization of the underlying ultramafic rock. [16] [17]

Potential 'cradle of life'

Serpentinite thermal vents are a candidate for the environment in which life on Earth originated. [15] Most of the chemical reactions necessary to synthesize acetyl-CoA, essential to basic biochemical pathways of life, take place during serpentinization. [18] The sulfide-metal clusters that activate many enzymes resemble sulfide minerals formed during serpentinization. [19]

Ecology

Serpentinite ecosystem in the south of New Caledonia Landscape, south of New Caledonia.jpg
Serpentinite ecosystem in the south of New Caledonia

Soil cover over serpentinite bedrock tends to be thin or absent. Soil with serpentine is poor in calcium and other major plant nutrients, but rich in elements toxic to plants such as chromium and nickel. [20] Some species of plants, such as Clarkia franciscana and certain species of manzanita, are adapted to living on serpentinite outcrops. However, because serpentinite outcrops are few and isolated, their plant communities are ecological islands and these distinctive species are often highly endangered. [21] On the other hand, plant communities adapted to living on the serpentine outcrops of New Caledonia resist displacement by introduced species that are poorly adapted to this environment. [22]

Serpentine soils are widely distributed on Earth, in part mirroring the distribution of ophiolites and other serpentine bearing rocks. [23] There are outcroppings of serpentine soils in the Balkan Peninsula, Turkey, the island of Cyprus, the Alps, Cuba, and New Caledonia. In North America, serpentine soils also are present in small but widely distributed areas on the eastern slope of the Appalachian Mountains in the eastern United States, and in the Pacific Ranges of Oregon and California.[ citation needed ]

Occurrences

Notable occurrences of serpentinite are found at Thetford Mines, Quebec; Lake Valhalla, New Jersey; Gila County, Arizona; Lizard complex, Lizard Point, Cornwall; and in localities in Greece, Italy, and other parts of Europe. [24] Notable ophiolites containing serpentinite include the Semail Ophiolite of Oman, the Troodos Ophiolite of Cyprus, the Newfoundland ophiolites, and the Main Ophiolite Belt of New Guinea. [25]

Uses

Drinking cups, examples of serpentinite-turning from Zoblitz in the Erzgebirgskreis Zwei trinkbecher, zoeblitz.jpg
Drinking cups, examples of serpentinite-turning from Zöblitz in the Erzgebirgskreis
College Hall at University of Pennsylvania College Hall U Penn.JPG
College Hall at University of Pennsylvania

Decorative stone in architecture and art

Serpentine group minerals have a Mohs hardness of 2.5 to 3.5, so serpentinite is easily carved. [26] Grades of serpentinite higher in calcite, along with the verd antique (breccia form of serpentinite), have historically been used as decorative stones for their marble-like qualities. College Hall at the University of Pennsylvania, for example, is constructed out of serpentine. Popular sources in Europe before contact with the Americas were the mountainous Piedmont region of Italy and Larissa, Greece. [27] Serpentinites are used in many ways in the arts and crafts. For example, the rock has been turned in Zöblitz in Saxony for several hundred years. [28]

By the Inuit

The Inuit and other indigenous people of the Arctic areas and less so of southern areas used the carved bowl shaped serpentinite qulliq or kudlik lamp with wick, to burn oil or fat to heat, make light and cook with. The Inuit made tools and more recently carvings of animals for commerce. [29]

As an ovenstone

A variety of chlorite talc schist associated with Alpine serpentinite is found in Val d'Anniviers, Switzerland and was used for making "ovenstones" (German : Ofenstein), a carved stone base beneath a cast iron stove. [30]

Neutron shield in nuclear reactors

Serpentinite has a significant amount of bound water, hence it contains abundant hydrogen atoms able to slow down neutrons by elastic collision (neutron thermalization process). Because of this, serpentinite can be used as dry filler inside steel jackets in some designs of nuclear reactors. For example, in RBMK series, as at Chernobyl, it was used for top radiation shielding to protect operators from escaping neutrons. [31] Serpentine can also be added as aggregate to special concrete used in nuclear reactor shielding to increase the concrete density (2.6 g/cm3 (0.094 lb/cu in)) and its neutron capture cross section. [32] [33]

CO2 sequestration

Because it readily absorbs carbon dioxide, serpentinite may be of use for sequestering atmospheric carbon dioxide. [34] To speed up the reaction, serpentinite may be reacted with carbon dioxide at elevated temperature in carbonation reactors. Carbon dioxide may also be reacted with alkaline mine waste from serpentine deposits, or carbon dioxide may be injected directly into underground serpentinite formations. [35] Serpentinite may also be used as a source of magnesium in conjunction with electrolytic cells for CO2 scrubbing. [36]

Cultural references

It is the state rock of California, USA and the California Legislature specified that serpentine was "the official State Rock and lithologic emblem." [4] In 2010, a bill was introduced which would have removed serpentine's special status as state rock due to it potentially containing chrysotile asbestos. [37] The bill met with resistance from some California geologists, who noted that the chrysotile present is not hazardous unless it is mobilized in the air as dust. [38] [ needs update ]

See also

Related Research Articles

<span class="mw-page-title-main">Dunite</span> Ultramafic and ultrabasic rock from Earths mantle which is made of the mineral olivine

Dunite, also known as olivinite, is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with minor amounts of other minerals such as pyroxene, chromite, magnetite, and pyrope. Dunite is the olivine-rich endmember of the peridotite group of mantle-derived rocks.

<span class="mw-page-title-main">Chemosynthesis</span> Biological process building organic matter using inorganic compounds as the energy source

In biochemistry, chemosynthesis is the biological conversion of one or more carbon-containing molecules and nutrients into organic matter using the oxidation of inorganic compounds or ferrous ions as a source of energy, rather than sunlight, as in photosynthesis. Chemoautotrophs, organisms that obtain carbon from carbon dioxide through chemosynthesis, are phylogenetically diverse. Groups that include conspicuous or biogeochemically important taxa include the sulfur-oxidizing Gammaproteobacteria, the Campylobacterota, the Aquificota, the methanogenic archaea, and the neutrophilic iron-oxidizing bacteria.

<span class="mw-page-title-main">Hydrothermal vent</span> Fissure in a planets surface from which heated water emits

Hydrothermal vents are fissures on the seabed from which geothermally heated water discharges. They are commonly found near volcanically active places, areas where tectonic plates are moving apart at mid-ocean ridges, ocean basins, and hotspots. The dispersal of hydrothermal fluids throughout the global ocean at active vent sites creates hydrothermal plumes. Hydrothermal deposits are rocks and mineral ore deposits formed by the action of hydrothermal vents.

<span class="mw-page-title-main">Serpentine subgroup</span> Group of phyllosilicate minerals

Serpentine subgroup are greenish, brownish, or spotted minerals commonly found in serpentinite. They are used as a source of magnesium and asbestos, and as decorative stone. The name comes from the greenish color and smooth or scaly appearance from the Latin serpentinus, meaning "snake-like".

The iron–sulfur world hypothesis is a set of proposals for the origin of life and the early evolution of life advanced in a series of articles between 1988 and 1992 by Günter Wächtershäuser, a Munich patent lawyer with a degree in chemistry, who had been encouraged and supported by philosopher Karl R. Popper to publish his ideas. The hypothesis proposes that early life may have formed on the surface of iron sulfide minerals, hence the name. It was developed by retrodiction from extant biochemistry in conjunction with chemical experiments.

The abiogenic petroleum origin hypothesis proposes that most of earth's petroleum and natural gas deposits were formed inorganically, commonly known as abiotic oil. Scientific evidence overwhelmingly supports a biogenic origin for most of the world's petroleum deposits. Mainstream theories about the formation of hydrocarbons on earth point to an origin from the decomposition of long-dead organisms, though the existence of hydrocarbons on extraterrestrial bodies like Saturn's moon Titan indicates that hydrocarbons are sometimes naturally produced by inorganic means. A historical overview of theories of the abiogenic origins of hydrocarbons has been published.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Ultramafic rock</span> Type of igneous and meta-igneous rock

Ultramafic rocks are igneous and meta-igneous rocks with a very low silica content, generally >18% MgO, high FeO, low potassium, and are usually composed of greater than 90% mafic minerals. The Earth's mantle is composed of ultramafic rocks. Ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as carbonatites and ultrapotassic igneous rocks.

<span class="mw-page-title-main">Serpentinization</span> Formation of serpentinite by hydration and metamorphic transformation of olivine

Serpentinization is a hydration and metamorphic transformation of ferromagnesian minerals, such as olivine and pyroxene, in mafic and ultramafic rock to produce serpentinite. Minerals formed by serpentinization include the serpentine group minerals, brucite, talc, Ni-Fe alloys, and magnetite. The mineral alteration is particularly important at the sea floor at tectonic plate boundaries.

<span class="mw-page-title-main">Lost City Hydrothermal Field</span> Hydrothermal field in the mid-Atlantic Ocean

The Lost City Hydrothermal Field, often referred to simply as Lost City, is an area of marine alkaline hydrothermal vents located on the Atlantis Massif at the intersection between the Mid-Atlantic Ridge and the Atlantis Transform Fault, in the Atlantic Ocean. It is a long-lived site of active and inactive ultramafic-hosted serpentinization, abiotically producing many simple molecules such as methane and hydrogen which are fundamental to microbial life. As such it has generated scientific interest as a prime location for investigating the origin of life on Earth and other planets similar to it.

<span class="mw-page-title-main">Serpentine soil</span> Soil type

Serpentine soil is an uncommon soil type produced by weathered ultramafic rock such as peridotite and its metamorphic derivatives such as serpentinite. More precisely, serpentine soil contains minerals of the serpentine subgroup, especially antigorite, lizardite, and chrysotile or white asbestos, all of which are commonly found in ultramafic rocks. The term "serpentine" is commonly used to refer to both the soil type and the mineral group which forms its parent materials.

<span class="mw-page-title-main">Hydrogen cycle</span> Hydrogen exchange between the living and non-living world

The hydrogen cycle consists of hydrogen exchanges between biotic (living) and abiotic (non-living) sources and sinks of hydrogen-containing compounds.

Talc carbonates are a suite of rock and mineral compositions found in metamorphosed ultramafic rocks.

Hydrogen-oxidizing bacteria are a group of facultative autotrophs that can use hydrogen as an electron donor. They can be divided into aerobes and anaerobes. The former use hydrogen as an electron donor and oxygen as an acceptor while the latter use sulphate or nitrogen dioxide as electron acceptors. Species of both types have been isolated from a variety of environments, including fresh waters, sediments, soils, activated sludge, hot springs, hydrothermal vents and percolating water.

<span class="mw-page-title-main">Listwanite</span>

Listwanite (also sometimes spelled listvenite, listvanite, or listwaenite) is a rock type that forms when the groundmass of ultramafic rocks, most commonly mantle peridotites, is partially altered to carbonate minerals and cut by ubiquitous carbonate veins containing one or more of magnesite, calcite, dolomite, ankerite, and/or siderite. Original pyroxene and olivine in the peridotite are commonly altered to Mg- or Ca-carbonate and hydrous Mg-silicates, such as serpentine and talc. Complete carbonation of peridotite means that every single atom of magnesium and calcium as well as some of the iron atoms have combined with CO2 to form secondary carbonate minerals such a magnesite, calcite, and siderite, while the remaining silica atoms, formerly found in pyroxene and olivine (prior to alteration), are found in quartz, serpentine, and talc. Thus, in terms of bulk mineralogy, listwanites consist primarily of quartz (often of a rusty red colour), carbonate, serpentine, talc, ± mariposite/fuchsite (i.e., Cr-muscovite) ± gold.

<span class="mw-page-title-main">Rainbow Vent Field</span> System of hydrothermal vents on the Mid-Atlantic Ridge

The Rainbow hydrothermal vent field is a system of ultramafic-hosted hydrothermal vents located at 36°14'N on the Mid-Atlantic Ridge (MAR). It was discovered in 1994 from temperature readings of ten high-temperature black smokers at a depth of approximately 2.3 kilometres (1.4 mi), where fluids can exceed 365 °C (689 °F). The site is shallower and larger in area than many other vent fields along the Azores section of the MAR with an area of 1.5 square kilometres. Located 370 km (229.91 mi) southeast of Faial Island, it is a popular geochemical sampling and modeling site due to close proximity to the Azores and definitive representation of serpentinization from hydrothermal circulation and synthesis.

<span class="mw-page-title-main">Hydrothermal vent microbial communities</span> Undersea unicellular organisms

The hydrothermal vent microbial community includes all unicellular organisms that live and reproduce in a chemically distinct area around hydrothermal vents. These include organisms in the microbial mat, free floating cells, or bacteria in an endosymbiotic relationship with animals. Chemolithoautotrophic bacteria derive nutrients and energy from the geological activity at Hydrothermal vents to fix carbon into organic forms. Viruses are also a part of the hydrothermal vent microbial community and their influence on the microbial ecology in these ecosystems is a burgeoning field of research.

<span class="mw-page-title-main">Dun Mountain-Maitai Terrane</span> Geological feature in New Zealand

The Dun Mountain-Maitai Terrane comprises the Dun Mountain Ophiolite Belt, Maitai Group and Patuki Mélange. The Dun Mountain Ophiolite is an ophiolite of Permian age located in New Zealand's South Island. Prehistorically this ophiolite was quarried by Māori for both metasomatized argillite and pounamu (jade) which was used in the production of tools and jewellery.

Antigorite Magnesium-Fe phyllosilicate mineral of the serpentine group

Antigorite is a lamellated, monoclinic mineral in the phyllosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentinites. Antigorite, and its serpentine polymorphs, play an important role in subduction zone dynamics due to their relative weakness and high weight percent of water (up to 13 weight % H2O). It is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland and is commonly used as a gemstone in jewelry and carvings.

Formatotrophs are organisms that can assimilate formate or formic acid to use as a carbon source or for reducing power. Some authors classify formatotrophs as one of the five trophic groups of methanogens, which also include hydrogenotrophs, acetotrophs, methylotrophs, and alcoholotrophs. Formatotrophs have garnered attention for applications in biotechnology as part of a "formate bioeconomy" in which synthesized formate could be used as a nutrient for microoganisms. Formate can be electrochemically synthesized from CO2 and renewable energy, and formatotrophs may be genetically modified to enhance production of biochemical products to be used as biofuels. Technical limitations in culturing formatotrophs have limited the discovery of natural formatotrophs and impeded research on their formate-metabolizing enzymes, which are of interest for applications in carbon sequestration and astrobiology.

References

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  36. ↑ Li, Wenzhi; Li, Wen; Li, Baoqing; Bai, Zongqing (February 2009). "Electrolysis and heat pretreatment methods to promote CO2 sequestration by mineral carbonation". Chemical Engineering Research and Design. 87 (2): 210–215. Bibcode:2009CERD...87..210L. doi:10.1016/j.cherd.2008.08.001.
  37. ↑ Fimrite, Peter (16 July 2010). "Geologists protest bill to remove state rock". San Francisco Chronicle. Retrieved 17 April 2018.
  38. ↑ Frazell, Julie; Elkins, Rachel; O'Geen, Anthony; Reynolds, Robert; Meyers, James. "Facts about Serpentine Rock and Soil Containing Asbestos in California" (PDF). ANR Catalog. University of California Division of Agriculture and Natural Resources. Retrieved 17 April 2018.
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