Syenite

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Syenite
Igneous rock
Syenite.jpg
Composition
ClassificationFelsic
Plagioclase and K-Feldspars, depleted in quartz
TextureAphanitic
Equivalents Trachyte extrusively
Syenite from Corsica Syenite Tretorre.jpg
Syenite from Corsica
QAPF diagram that shows the quartz (Q), alkali feldspar (A), and plagioclase (P) composition of syenite QAPFsyenite.gif
QAPF diagram that shows the quartz (Q), alkali feldspar (A), and plagioclase (P) composition of syenite
Leucocratic variety of nepheline syenite from Sweden (sarnaite) Nepheline-syenite-2005.jpg
Leucocratic variety of nepheline syenite from Sweden (särnaite)

Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). It is considered a granitoid. Some syenites contain larger proportions of mafic components and smaller amounts of felsic material than most granites; those are classed as being of intermediate composition.

Contents

The extrusive equivalent of syenite is trachyte. [1]

Composition

The feldspar component of syenite is predominantly alkaline in character (usually orthoclase). Plagioclase feldspars may be present in small proportions, between 10% and 35% of the feldspar content. Such feldspars often are interleaved as perthitic components of the rock.

When ferromagnesian minerals are present in syenite at all, they usually occur in the form of amphibole (typically hornblende) and clinopyroxene. Biotite is rare, because in a syenite magma the formation of feldspar consumes nearly all the aluminium. However less Al-rich phyllosilicates may be included, such as annite.

Other common accessory minerals are apatite, titanite, zircon and other opaques.

Most syenites are either peralkaline with high proportions of alkali elements relative to aluminum, or peraluminous with a higher concentration of aluminum relative to alkali (predominantly K and Na) and earth-alkali (predominantly Ca) elements.

Formation

Partial melting

Syenites are products of alkaline igneous activity, generally formed in thick continental crustal areas, or in Cordilleran subduction zones. The formation of syenites can be theorized to be from the melt of granitic or igneous protolith to a fairly low degree of partial melting. This is required because potassium is an incompatible element and tends to enter a melt first, whereas higher degrees of partial melting will liberate more calcium and sodium, which produce plagioclase, and hence a granite, adamellite or tonalite.

At very low degrees of partial melting a silica undersaturated melt is produced, forming a nepheline syenite, where orthoclase is replaced by a feldspathoid such as leucite, nepheline or analcime.

Conversely in certain conditions, large volumes of anorthite crystals may precipitate from thoroughly molten magma in a cumulate process as it cools. This leaves a drastically reduced concentration of silica in the remainder of the melt. The segregation of the silica from the melt leaves it in a state that may favour syenite formation.[ citation needed ]

Fractional crystallization

Some syenites are also theorized to be the product of the fractional crystallization of basaltic magmas. [2]

Occurrence

Boulders of syenite near Concord, North Carolina, c. 1910. Bulletin 426 Plate XVI B Bowlder Outcrop of Syenite.jpg
Boulders of syenite near Concord, North Carolina, c. 1910.

Syenite is not a common rock. Regions where it occurs in significant quantities include the following.

Etymology

The term syenite was originally applied to hornblende granite like that of Syene (now Aswan) in Egypt, from which the name is derived.

Episyenite

Episyenite (or epi-syenite) is a term used in petrology to describe veins, pods, or lenses of rock originally rich in silicon dioxide (SiO2) from which quartz has been severely depleted. [9] This is often accompanied by strong enrichment in potassium and rare earth elements, leaving the altered rock a distinctive brick red color, [10] or by albitization (enrichment in sodium), leaving the altered rock a conspicuous white color. [11]

Episyenites are heterogenous in their properties, but all have experienced nearly complete disappearance of quartz at sub-solidus temperatures; that is, at temperatures below the melting point of the host rock. The formation of episyenites (episyenitization) typically takes place through leaching of quartz by mildly saline hydrothermal fluids, typically near a cooling intrusion. Because episyenitization usually takes place in granitoid rock and usually involves alkaline metasomatism (addition of alkali metal oxides to the rock) the result is a rock that has the mineral composition of an igneous syenite. [11]

In addition to rare earth elements, [10] episyenites may be important sources of uranium [12] and other valuable metals. [11]

Notable occurrences of episyenite are found in the Central Iberian Massif of Spain, [9] in Cambrian to Ordovician beds of New Mexico and Colorado, [10] Scandinavia, Brazil, and Ukraine. [11]

See also

Related Research Articles

In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz. It is contrasted with mafic rocks, which are relatively richer in magnesium and iron. Felsic refers to silicate minerals, magma, and rocks which are enriched in the lighter elements such as silicon, oxygen, aluminium, sodium, and potassium. Felsic magma or lava is higher in viscosity than mafic magma/lava.

<span class="mw-page-title-main">Granite</span> Type of igneous rock

Granite is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies underground. It is common in the continental crust of Earth, where it is found in igneous intrusions. These range in size from dikes only a few centimeters across to batholiths exposed over hundreds of square kilometers.

<span class="mw-page-title-main">Pegmatite</span> Igneous rock with very large interlocked crystals

A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.

<span class="mw-page-title-main">Dacite</span> Volcanic rock intermediate in composition between andesite and rhyolite

Dacite is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. It is composed predominantly of plagioclase feldspar and quartz.

<span class="mw-page-title-main">Trachyte</span> Extrusive igneous rock

Trachyte is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and alkali metals. It is the volcanic equivalent of syenite.

<span class="mw-page-title-main">Phonolite</span> Uncommon extrusive rock

Phonolite is an uncommon shallow intrusive or extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. It has an unusually high (12% or more) Na2O + K2O content, defining its position in the TAS classification of igneous rocks. Its coarse grained (phaneritic) intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name phonolite comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name clinkstone is given as a synonym.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Aplite</span> Fine-grained intrusive igneous rock type similar to granite

Aplite is an intrusive igneous rock in which the mineral composition is the same as granite, but in which the grains are much finer, under 1 mm across. Quartz and feldspar are the dominant minerals. The term aplite or aplitic is often used as a textural term to describe veins of quartz and feldspar with a fine to medium-grain "sugary" texture. Aplites are usually very fine-grained, white, grey or pinkish, and their constituents are visible only with the help of a magnifying lens. Dykes and veins of aplite are commonly observed traversing granitic bodies; they occur also, though less frequently, in syenites, diorites, quartz diabases, and gabbros.

<span class="mw-page-title-main">Granitoid</span> Category of coarse-grained igneous rocks

A granitoid is a generic term for a diverse category of coarse-grained igneous rocks that consist predominantly of quartz, plagioclase, and alkali feldspar. Granitoids range from plagioclase-rich tonalites to alkali-rich syenites and from quartz-poor monzonites to quartz-rich quartzolites. As only two of the three defining mineral groups need to be present for the rock to be called a granitoid, foid-bearing rocks, which predominantly contain feldspars but no quartz, are also granitoids. The terms granite and granitic rock are often used interchangeably for granitoids; however, granite is just one particular type of granitoid.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Essexite</span> Igneous rock type

Essexite, also called nepheline monzogabbro, is a dark gray or black holocrystalline plutonic igneous rock. Its name is derived from the type locality in Essex County, Massachusetts, in the United States.

<span class="mw-page-title-main">Monzonite</span> Igneous intrusive rock with low quartz and equal plagioclase and alkali feldspar

Monzonite is an igneous intrusive rock, formed by slow cooling of underground magma that has a moderate silica content and is enriched in alkali metal oxides. Monzonite is composed mostly of plagioclase and alkali feldspar.

Borolanite is an historical petrological name for a pyroxene-melanite bearing nepheline syenite variety which contains nepheline-alkali feldspar pseudomorphs interpreted to be after leucite which occur as conspicuous white spots in the dark rock matrix. The rock occurs in the Borralan Igneous Complex or Loch Borralan Complex which is an alkalic igneous complex near Loch Borralan in northwest Scotland.

<span class="mw-page-title-main">Litchfieldite</span>

Litchfieldite is a rare igneous rock. It is a coarse-grained, foliated variety of nepheline syenite, sometimes called nepheline syenite gneiss or gneissic nepeheline syenite. Litchfieldite is composed of two varieties of feldspar, with nepheline, sodalite, cancrinite and calcite. The mafic minerals, when present, are magnetite and an iron-rich variety of biotite (lepidomelane).

Syenogranite is a fine to coarse grained intrusive igneous rock of the same general composition as granite. They are characteristically felsic.

<span class="mw-page-title-main">Leucitite</span>

Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhibit a considerable variety of types and are of great interest petrographically. For the presence of this mineral it is necessary that the silica percentage of the rock should be low, since leucite is incompatible with free quartz and reacts with it to form potassium feldspar. Because it weathers rapidly, leucite is most common in lavas of recent and Tertiary age, which have a fair amount of potassium, or at any rate have potassium equal to or greater than sodium; if sodium is abundant nepheline occurs rather than leucite.

<span class="mw-page-title-main">Igneous rock</span> Rock formed through the cooling and solidification of magma or lava

Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.

I-type granites are a category of granites originating from igneous sources, first proposed by Chappell and White (1974). They are recognized by a specific set of mineralogical, geochemical, textural, and isotopic characteristics that indicate, for example, magma hybridization in the deep crust. I-type granites are saturated in silica but undersaturated in aluminum; petrographic features are representative of the chemical composition of the initial magma. In contrast S-type granites are derived from partial melting of supracrustal or "sedimentary" source rocks.

<span class="mw-page-title-main">Red Hill Syenite</span>

The Red Hill Syenite is a layered igneous rock complex in central New Hampshire, about 20 mi (32 km) east of Plymouth. The Red Hill Syenite is part of the White Mountain magma series, which underlays the White Mountains of New Hampshire. Red Hill is roughly oval-shaped, covers just under 7.7 square miles (20 km2), and has a summit elevation of 2,028 feet (618 m).

References

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  2. "ALEX STREKEISEN-Syenite-".
  3. Downes, Hilary; Balaganskaya, Elena; Beard, Andrew; Liferovich, Ruslan; Demaiffe, Daniel (2005). "Petrogenetic processes in the ultramafic, alkaline and carbonatitic magmatism in the Kola Alkaline Province: a review" (PDF). Lithos. 85 (1–4): 48–75. Bibcode:2005Litho..85...48D. doi:10.1016/j.lithos.2005.03.020. Archived (PDF) from the original on 2017-01-10.
  4. Lieber, Oscar Montgomery (1856). Report on the Survey of South Carolina. South Carolina General Assembly. p. 32. ISBN   9785880484188 . Retrieved 2 December 2014.
  5. "'Yooperlite' a new rock found in the Upper Peninsula". wilx.com. September 7, 2018. Retrieved 8 September 2018.
  6. "Yooperlite". Mindat.org. Retrieved 9 November 2019.
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  8. "Syenitnaes". Mapcarta. Retrieved 6 May 2016.
  9. 1 2 Recio, C.; Fallick, A.E.; Ugidos, J.M.; Stephens, W.E. (December 1997). "Characterization of multiple fluid-granite interaction processes in the episyenites of Avila-Béjar, Central Iberian Massif, Spain". Chemical Geology. 143 (3–4): 127–144. Bibcode:1997ChGeo.143..127R. doi:10.1016/S0009-2541(97)00106-X.
  10. 1 2 3 McLemore, Virginia T. (2016). "Episyenites in the Sevilleta National Wildlife Refuge, Socorro County, New Mexico: preliminary results" (PDF). New Mexico Geological Society Field Conference Series. 67: 255–262. Archived (PDF) from the original on 2020-06-11. Retrieved 11 June 2020.
  11. 1 2 3 4 Suikkanen, E.; Rämö, O. T. (October 2019). "Episyenites—Characteristics, Genetic Constraints, and Mineral Potential". Mining, Metallurgy & Exploration. 36 (5): 861–878. doi:10.1007/s42461-019-00120-9. hdl: 10138/306792 . S2CID   201313988.
  12. Leroy, J. (1 December 1978). "The Margnac and Fanay uranium deposits of the La Crouzille District (western Massif Central, France); geologic and fluid inclusion studies". Economic Geology. 73 (8): 1611–1634. Bibcode:1978EcGeo..73.1611L. doi:10.2113/gsecongeo.73.8.1611.