Tufa is a variety of limestone formed when carbonate minerals precipitate out of water in unheated rivers or lakes. Geothermally heated hot springs sometimes produce similar (but less porous) carbonate deposits, which are known as travertine or thermogene travertine. Tufa is sometimes referred to as meteogene travertine. [1]
Modern and fossil tufa deposits abound with wetland plants; [2] as such, many tufa deposits are characterised by their large macrobiological component, and are highly porous. Tufa forms either in fluvial channels or in lacustrine environments. Ford and Pedley (1996) [3] provide a review of tufa systems worldwide.
Deposits can be classified by their depositional environment (or otherwise by vegetation or petrographically). Pedley (1990) [4] provides an extensive classification system, which includes the following classes of fluvial tufa:
Lacustrine tufas are generally formed at the periphery of lakes and built-up phytoherms (freshwater reefs), and on stromatolites. Oncoids are also common in these environments.
Although sometimes regarded as a distinct carbonate deposit, calcareous sinter formed from ambient temperature water can be considered a sub-type of tufa.
Calcareous speleothems may be regarded as a form of calcareous sinter. They lack any significant macrophyte component due to the absence of light, and for this reason they are often morphologically closer to travertine or calcareous sinter.
Tufa columns are an unusual form of tufa typically associated with saline lakes. They are distinct from most tufa deposits in that they lack any significant macrophyte component, due to the salinity excluding mesophilic organisms. [3] Some tufa columns may actually form from hot-springs, and may therefore constitute a form of travertine. It is generally thought that such features form from CaCO3 precipitated when carbonate rich source waters emerge into alkaline soda lakes. They have also been found in marine settings in the Ikka fjord of Greenland where the Ikaite columns can reach up to 18 m (59 ft) in height. [5]
Tufa deposits form an important habitat for a diverse flora. Bryophytes (mosses, liverworts etc.) and diatoms are well represented. The porosity of the deposits creates a wet habitat ideal for these plants.
Modern tufa is formed from alkaline waters, supersaturated with calcite. On emergence, waters degas CO2 due to the lower atmospheric pCO2 (see partial pressure), resulting in an increase in pH. Since carbonate solubility decreases with increased pH, [6] precipitation is induced. Supersaturation may be enhanced by factors leading to a reduction in pCO2, for example increased air-water interactions at waterfalls may be important, [7] as may photosynthesis. [8]
Recently it has been demonstrated that microbially induced precipitation may be more important than physico-chemical precipitation. Pedley et al. (2009) [9] showed with flume experiments that precipitation does not occur unless a biofilm is present, despite supersaturation.
Calcite is the dominant mineral precipitate, followed by the polymorph aragonite.[ citation needed ]
Tufa is common in many parts of the world including:
Some sources suggest that "tufa" was used as the primary building material for most of the châteaux of the Loire Valley, France. This results from a mis-translation of the terms "tuffeau jaune" and "tuffeau blanc", which are porous varieties of the Late Cretaceous marine limestone known as chalk. [11] [ need quotation to verify ] [12] [ failed verification ]
Tufa is occasionally shaped into a planter. Its porous consistency makes it ideal for alpine gardens. A concrete mixture called hypertufa is used for similar purposes.
In the 4th century BC, tufa was used to build Roman walls up to 10m high and 3.5m thick. [13] The soft stone allows for easy sculpting. Tufa masonry was used in cemeteries, such as the one in Cerveteri. [14]
Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.
Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.
Mono Lake is a saline soda lake in Mono County, California, formed at least 760,000 years ago as a terminal lake in an endorheic basin. The lack of an outlet causes high levels of salts to accumulate in the lake which make its water alkaline.
Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate, the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation from marine and freshwater environments.
Travertine is a form of terrestrial limestone deposited around mineral springs, especially hot springs. It often has a fibrous or concentric appearance and exists in white, tan, cream-colored, and rusty varieties. It is formed by a process of rapid precipitation of calcium carbonate, often at the mouth of a hot spring or in a limestone cave. In the latter, it can form stalactites, stalagmites, and other speleothems. It is frequently used in Italy and elsewhere as a building material. Similar deposits formed from ambient-temperature water are known as tufa.
Plitvice Lakes National Park is one of the oldest and largest national parks in Croatia. In 1979, Plitvice Lakes National Park was inscribed on the UNESCO World Heritage list, for its outstanding and picturesque series of tufa lakes, caves, and connected waterfalls.
A speleothem is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depending on their depositional history and environment. Their chemical composition, gradual growth, and preservation in caves make them useful paleoclimatic proxies.
The Portneuf River is a 124-mile-long (200 km) tributary of the Snake River in southeastern Idaho, United States. It drains a ranching and farming valley in the mountains southeast of the Snake River Plain. The city of Pocatello sits along the river near its emergence from the mountains onto the Snake River Plain.
Dolomite (also known as dolomite rock, dolostone or dolomitic rock) is a sedimentary carbonate rock that contains a high percentage of the mineral dolomite, CaMg(CO3)2. It occurs widely, often in association with limestone and evaporites, though it is less abundant than limestone and rare in Cenozoic rock beds (beds less than about 66 million years in age). One of the first geologists to distinguish dolomite from limestone was Déodat Gratet de Dolomieu; a French mineralogist and geologist whom it is named after. He recognized and described the distinct characteristics of dolomite in the late 18th century, differentiating it from limestone.
Mineral springs are naturally occurring springs that produce hard water, water that contains dissolved minerals. Salts, sulfur compounds, and gases are among the substances that can be dissolved in the spring water during its passage underground. In this they are unlike sweet springs, which produce soft water with no noticeable dissolved gasses. The dissolved minerals may alter the water's taste. Mineral water obtained from mineral springs, and the precipitated salts such as Epsom salt have long been important commercial products.
Flowstones are sheetlike deposits of calcite or other carbonate minerals, formed where water flows down the walls or along the floors of a cave. They are typically found in "solution caves", in limestone, where they are the most common speleothem. However, they may form in any type of cave where water enters that has picked up dissolved minerals. Flowstones are formed via the degassing of vadose percolation waters.
Limescale is a hard, chalky deposit, consisting mainly of calcium carbonate (CaCO3). It often builds up inside kettles, boilers, and pipework, especially that for hot water. It is also often found as a similar deposit on the inner surfaces of old pipes and other surfaces where hard water has flowed. Limescale also forms as travertine or tufa in hard water springs.
Calcareous is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime or being chalky. The term is used in a wide variety of scientific disciplines.
Ikaite is the mineral name for the hexahydrate of calcium carbonate, CaCO3·6H2O. Ikaite tends to form very steep or spiky pyramidal crystals, often radially arranged, of varied sizes from thumbnail size aggregates to gigantic salient spurs. It is only found in a metastable state and decomposes rapidly by losing most of its water content once removed from near-freezing water. This "melting mineral" is more commonly known through its pseudomorphs.
Calcareous sinter is a freshwater calcium carbonate deposit, also known as calc-sinter. Deposits are characterised by low porosity and well-developed lamination, often forming crusts or sedimentary rock layers. Calcareous sinter should not be confused with siliceous sinter, which the term sinter more frequently refers to. It has been suggested that the term "sinter" should be restricted to siliceous spring deposits and be dropped for calcareous deposits entirely.
Calcite crystals form on the surface of quiescent bodies of water, even when the bulk water is not supersaturated with respect to calcium carbonate. The crystals grow, attach to one other and appear to be floating rafts of a white, opaque material. The floating materials have been referred to as calcite rafts or "leopard spots".
Microbiologically induced calcium carbonate precipitation (MICP) is a bio-geochemical process that induces calcium carbonate precipitation within the soil matrix. Biomineralization in the form of calcium carbonate precipitation can be traced back to the Precambrian period. Calcium carbonate can be precipitated in three polymorphic forms, which in the order of their usual stabilities are calcite, aragonite and vaterite. The main groups of microorganisms that can induce the carbonate precipitation are photosynthetic microorganisms such as cyanobacteria and microalgae; sulfate-reducing bacteria; and some species of microorganisms involved in nitrogen cycle. Several mechanisms have been identified by which bacteria can induce the calcium carbonate precipitation, including urea hydrolysis, denitrification, sulfate production, and iron reduction. Two different pathways, or autotrophic and heterotrophic pathways, through which calcium carbonate is produced have been identified. There are three autotrophic pathways, which all result in depletion of carbon dioxide and favouring calcium carbonate precipitation. In heterotrophic pathway, two metabolic cycles can be involved: the nitrogen cycle and the sulfur cycle. Several applications of this process have been proposed, such as remediation of cracks and corrosion prevention in concrete, biogrout, sequestration of radionuclides and heavy metals.
Jvari Pass Travertine Natural Monument is calcareous sinter or tufa in Baidara River valley on the left bank of the road tunnel of the Kobi-Gudauri motorway at 2197 meters above the sea level in Kazbegi Municipality, Georgia.
Truso Travertines Natural Monument is calcareous sinter or tufa in Truso valley on the right bank of Terek river at 2093 meters above the sea level in Kazbegi Municipality, Georgia. It is located about 2 km from village Keterisi where local population lives only seasonally.
Laguna Negra is a lake in the Catamarca Province of Argentina. It lies on the Puna high plateau next to two other lakes and salt flats. The lake is less than 2 metres deep and forms a rough rectangle with a surface of 8.6 square kilometres (3.3 sq mi). Laguna Negra loses its water through evaporation, and is replenished through surface runoff and groundwater which ultimately originate to a large part from snowmelt. The waters of the lake are salty.
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