Calcareous sinter is a freshwater calcium carbonate deposit, also known as calc-sinter. Deposits are characterised by low porosity and well-developed lamination, often forming crusts or sedimentary rock layers. Calcareous sinter should not be confused with siliceous sinter, which the term sinter more frequently[ citation needed ] refers to. It has been suggested[ by whom? ] that the term "sinter" should be restricted to siliceous spring deposits and be dropped for calcareous deposits entirely.
Calcareous sinter is characterised by laminations of prismatic crystals growing perpendicular to the substrate; laminations are separated by thin layers of microcrystalline carbonate. [1] Calcareous sinter is porous due to the calcareous crystals enclosing many small cavities. [2] Macrophytes are absent, consequently porosity is very low. Exclusion of species is due either to high temperature (travertine), high pH/ionic strength (tufa) or absence of light (speleothems).
Pedley (1990) [3] suggests the term be abandoned in favour of tufa for ambient temperature deposits. This avoids any potential confusion with siliceous sinter and prevents deposits formed in different environmental conditions (hot spring deposits, cold spring deposits and speleothems are all lumped together under the term sinter) from being amalgamated into one group.
Deposits are formed from either calcite or aragonite. Precipitation is brought about by degassing of CO2, which decreases the solubility of calcite/aragonite. (See tufa/geochemistry)
The build-up of calc-sinter material in the Eifel Aqueduct was commercially exploited in the 11th and 12th centuries. With deposits up to 30 centimetres (12 in) thick, the material was cut into vertical columns of polished brown rock with impressive layered patterns, which made it much in demand by cathedral builders across large parts of central Europe and beyond. [4] In England it was used to provide polychromy, contrasting with the pale limestone favoured by Norman English Cathedrals. The stone was for many years known as 'Onyx Marble' despite being very obviously neither onyx nor marble. Those studying the stonework at Canterbury Cathedral were unaware of its origins in the aqueduct until 2011. [5] Such large-scale use as the cloisters around a cathedral quadrangle needed many hundreds of columns, which must have been supplied by a well-organised extraction and transport operation. The Eifel deposits, have also been identified at Rochester [6] and in the now lost Romanesque cloister at Norwich [7] as well as the Infirmary Cloister, Chapter House windows, Anselm Chapel door and the Treasury gateway at Canterbury. [8]
Alabaster is a mineral and a soft rock used for carvings and as a source of plaster powder. Archaeologists, geologists, and the stone industry have different definitions and usages for the word alabaster. In archaeology, the term alabaster is a category of objects and artefacts made from the varieties of two different minerals: (i) the fine-grained, massive type of gypsum, and (ii) the fine-grained, banded type of calcite.
Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.
Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate, the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation from marine and freshwater environments.
A stalagmite is a type of rock formation that rises from the floor of a cave due to the accumulation of material deposited on the floor from ceiling drippings. Stalagmites are typically composed of calcium carbonate, but may consist of lava, mud, peat, pitch, sand, sinter, and amberat.
Travertine is a form of terrestrial limestone deposited around mineral springs, especially hot springs. It often has a fibrous or concentric appearance and exists in white, tan, cream-colored, and rusty varieties. It is formed by a process of rapid precipitation of calcium carbonate, often at the mouth of a hot spring or in a limestone cave. In the latter, it can form stalactites, stalagmites, and other speleothems. It is frequently used in Italy and elsewhere as a building material. Similar deposits formed from ambient-temperature water are known as tufa.
A speleothem is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depending on their depositional history and environment. Their chemical composition, gradual growth, and preservation in caves make them useful paleoclimatic proxies.
Tufa is a variety of limestone formed when carbonate minerals precipitate out of water in unheated rivers or lakes. Geothermally heated hot springs sometimes produce similar carbonate deposits, which are known as travertine. Tufa is sometimes referred to as (meteogene) travertine. It should not be confused with hot spring (thermogene) travertine. Tufa, which is calcareous, should also not be confused with tuff, a porous volcanic rock with a similar etymology that is sometimes also called "tufa".
The Portneuf River is a 124-mile-long (200 km) tributary of the Snake River in southeastern Idaho, United States. It drains a ranching and farming valley in the mountains southeast of the Snake River Plain. The city of Pocatello sits along the river near its emergence from the mountains onto the Snake River Plain.
Geyserite, or siliceous sinter, is a form of opaline silica that is often found as crusts or layers around hot springs and geysers. Botryoidal geyserite is known as fiorite. Geyserite is porous due to the silica enclosing many small cavities. Siliceous sinter should not be confused with calcareous sinter, which is made of calcium carbonate.
Mineral springs are naturally occurring springs that produce hard water, water that contains dissolved minerals. Salts, sulfur compounds, and gases are among the substances that can be dissolved in the spring water during its passage underground. In this they are unlike sweet springs, which produce soft water with no noticeable dissolved gasses. The dissolved minerals may alter the water's taste. Mineral water obtained from mineral springs, and the precipitated salts such as Epsom salt have long been important commercial products.
The Eifel Aqueduct was one of the longest aqueducts of the Roman Empire.
Flowstones are sheetlike deposits of calcite or other carbonate minerals, formed where water flows down the walls or along the floors of a cave. They are typically found in "solution caves", in limestone, where they are the most common speleothem. However, they may form in any type of cave where water enters that has picked up dissolved minerals. Flowstones are formed via the degassing of vadose percolation waters.
Limescale is a hard, chalky deposit, consisting mainly of calcium carbonate (CaCO3). It often builds up inside kettles, boilers, and pipework, especially that for hot water. It is also often found as a similar deposit on the inner surfaces of old pipes and other surfaces where hard water has flowed. Limescale also forms as travertine or tufa in hard water springs.
Calcareous is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime or being chalky. The term is used in a wide variety of scientific disciplines.
The carbonate compensation depth (CCD) is the depth, in the oceans, at which the rate of supply of calcium carbonates matches the rate of solvation. That is, solvation 'compensates' supply. Below the CCD solvation is faster, so that carbonate particles dissolve and the carbonate shells (tests) of animals are not preserved. Carbonate particles cannot accumulate in the sediments where the sea floor is below this depth.
A tecoatl is a stone canal making up part of an extensive ancient aqueduct network in the Tehuacán Valley in the state of Puebla in Mexico. The word tecoatl translates to "stone snake" in the Aztec language Nahuatl, but the canal system is far older than the Aztecs. The first segments of the system were laid down approximately 2500 years ago.
The Mess Lake Lava Field is a volcanic field associated with the Mount Edziza volcanic complex of the Northern Cordilleran Volcanic Province in northwestern British Columbia, Canada. It lies northwest of the Spectrum Range on the Kitsu Plateau and consists of young basaltic lava flows and tephra. The source for the basaltic lava and tephra was three cinder cones, including Mess Lake Cone and The Ash Pit, which may be the youngest volcanic feature of the Mount Edziza volcanic complex.
Calcite crystals form on the surface of quiescent bodies of water, even when the bulk water is not supersaturated with respect to calcium carbonate. The crystals grow, attach to one other and appear to be floating rafts of a white, opaque material. The floating materials have been referred to as calcite rafts or "leopard spots".
Calthemite is a secondary deposit, derived from concrete, lime, mortar or other calcareous material outside the cave environment. Calthemites grow on or under, man-made structures and mimic the shapes and forms of cave speleothems, such as stalactites, stalagmites, flowstone etc. Calthemite is derived from the Latin calx "lime" + Latin < Greek théma, "deposit" meaning ‘something laid down’, and the Latin –ita < Greek -itēs – used as a suffix indicating a mineral or rock. The term "speleothem", due to its definition can only be used to describe secondary deposits in caves and does not include secondary deposits outside the cave environment.
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