Litchfieldite is a rare igneous rock. It is a coarse-grained, foliated variety of nepheline syenite, [1] sometimes called nepheline syenite gneiss or gneissic nepeheline syenite. [2] Litchfieldite is composed of two varieties of feldspar (mostly albite but also some microcline), with nepheline, sodalite, cancrinite and calcite. The mafic minerals, when present, are magnetite and an iron-rich variety of biotite (lepidomelane).
The rock was named after its occurrence at Litchfield, Maine, USA, by Bayley in 1892. [3] [4]
It is a very rare rock and also occurs in Blue Mountain and French River, Canada; [4] Soroy and Val River, Norway; Cevadais, Portugal; Canaã, [5] Boca Nova, Itajú da Colonia and Peixes, Brazil.
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Besides the mineral composition litchfieldites are characterized by one or more of the following structures:
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There are two hypotheses for the origin of these rocks:
Both schools of thought are in accordance that rocks like litchfieldite owe their mineral and structural characteristics to the metamorphism.
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Due to the content of alkali elements and alumina, they are very important ore for the glass industry. The iron-bearing minerals when present are strongly magnetic and can be removed through a magnetic field.
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(Estrela, Eldorado, Porto Nacional, Peixe)
(Itaju da Colonia, Santa Cruz da Vitória, Potiriguá, Itabuna)
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.
Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations. It is considered a granitoid. Some syenites contain larger proportions of mafic components and smaller amounts of felsic material than most granites; those are classed as being of intermediate composition.
Phonolite is an uncommon shallow intrusive or extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic. Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. It has an unusually high Na2O + K2O content, defining its position in the TAS classification of igneous rocks. Its coarse grained (phaneritic) intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name phonolite comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name clinkstone is given as a synonym.
Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.
Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.
Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.
Granulites are a class of high-grade metamorphic rocks of the granulite facies that have experienced high-temperature and moderate-pressure metamorphism. They are medium to coarse–grained and mainly composed of feldspars sometimes associated with quartz and anhydrous ferromagnesian minerals, with granoblastic texture and gneissose to massive structure. They are of particular interest to geologists because many granulites represent samples of the deep continental crust. Some granulites experienced decompression from deep in the Earth to shallower crustal levels at high temperature; others cooled while remaining at depth in the Earth.
Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are due to fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.
Charnockite is any orthopyroxene-bearing quartz-feldspar rock formed at high temperature and pressure, commonly found in granulite facies’ metamorphic regions, sensu stricto as an endmember of the charnockite series.
Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite (NaAlSi3O8) and anorthite (CaAl2Si2O8). The albite:anorthite molar ratio of oligoclase ranges from 90:10 to 70:30.
Essexite, also called nepheline monzogabbro, is a dark gray or black holocrystalline plutonic igneous rock. Its name is derived from the type locality in Essex County, Massachusetts, in the United States.
Borolanite is an historical petrological name for a pyroxene-melanite bearing nepheline syenite variety which contains nepheline-alkali feldspar pseudomorphs interpreted to be after leucite which occur as conspicuous white spots in the dark rock matrix. The rock occurs in the Borralan Igneous Complex or Loch Borralan Complex which is an alkalic igneous complex near Loch Borralan in northwest Scotland.
The Spruce Pine Mining District is a swath of the valley of the North Toe River in the Blue Ridge Mountains of northwestern North Carolina. The area is mined for its mica, kaolin, quartz and feldspar. Spruce Pine district is one of the largest suppliers of high-purity quartz, which is used in the manufacture of silicon chips. The district is named after the town of Spruce Pine, which is located in the middle of the region and is the hub of major mining activity there. The district is approximately 25 miles long and 5 miles wide.
Myrmekite is a vermicular, or wormy, intergrowth of quartz in plagioclase. The intergrowths are microscopic in scale, typically with maximum dimensions less than 1 millimeter. The plagioclase is sodium-rich, usually albite or oligoclase. These quartz-plagioclase intergrowths are associated with and commonly in contact with potassium feldspar. Myrmekite is formed under metasomatic conditions, usually in conjunction with tectonic deformations. It has to be clearly separated from micrographic and granophyric intergrowths, which are magmatic.
Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhibit a considerable variety of types and are of great interest petrographically. For the presence of this mineral it is necessary that the silica percentage of the rock should be low, since leucite is incompatible with free quartz and reacts with it to form potassium feldspar. Because it weathers rapidly, leucite is most common in lavas of recent and Tertiary age, which have a fair amount of potassium, or at any rate have potassium equal to or greater than sodium; if sodium is abundant nepheline occurs rather than leucite.
A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.
The Thiviers-Payzac Unit is a metasedimentary succession of late Neoproterozoic and Cambrian age outcropping in the southern Limousin in France. The unit geologically forms part of the Variscan basement of the northwestern Massif Central.
The Red Hill Syenite is a layered igneous rock complex in central New Hampshire, about 20 mi (32 km) east of Plymouth. The Red Hill Syenite is part of the White Mountain magma series, which underlays the White Mountains of New Hampshire. Red Hill is roughly oval-shaped, covers just under 7.7 square miles (20 km2), and has a summit elevation of 2,028 feet (618 m).