Microcline

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Microcline
Microcline-199473.jpg
General
Category Tectosilicate
Formula
(repeating unit)
KAlSi3O8
IMA symbol Mcc [1]
Space group P1 (no. 2)
Identification
ColorWhite, grey, greyish yellow, yellowish, tan, salmon-pink, bluish green, green.
Crystal habit Can be anhedral or euhedral. Grains are commonly elongate with a tabular appearance. May contain lamellae which formed from exsolved albite.
Twinning Typically displays albite twinning and pericline twinning. This combination leads to a grid pattern, hence microcline displays gridiron twinning. Can also display carlsbad twinning, simple twins, or lack twinning altogether. Lamellae in microcline are discontinuous and "pinch and swell".
Photomicrograph of thin section of microcline showing crosshatched crystal twinning (in cross polarized light) Microcline.jpg
Photomicrograph of thin section of microcline showing crosshatched crystal twinning (in cross polarized light)
Cleavage Has perfect cleavage parallel to {001} and good cleavage on {010}. Cleavages intersect at 90°41'. It can be difficult to see cleavage in thin section due to microcline's low relief.
Fracture Uneven
Tenacity Brittle
Mohs scale hardness6–6.5
Luster Vitreous
Streak White
Diaphaneity Transparent, translucent
Specific gravity 2.5–2.6
Optical propertiesBiaxial negative
Refractive index nα = 1.514 – 1.529 nβ = 1.518 – 1.533 nγ = 1.521 – 1.539
Birefringence Up to first order white (roughly 0.007)
Pleochroism N/A
2V angle 65–88°
ExtinctionInclined extinction to cleavage
Diagnostic featuresGridiron twinning distinguishes microcline from other feldspars. Distinguishable from plagioclase because the lamellae in plagioclase are continuous and do not "pinch and swell."
Alters toCommonly alters to sericite or clay.
ReliefLow negative relief
Optical signBiaxial negative
Color in PPL Colorless

Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase; it is more stable at lower temperatures than orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.

Contents

The chemical compound name is potassium aluminium silicate, and it is known as E number reference E555.

Geology

Microcline may be chemically the same as monoclinic orthoclase, but because it belongs to the triclinic crystal system, the prism angle is slightly less than right angles; hence the name "microcline" from the Greek "small slope". It is a fully ordered triclinic modification of potassium feldspar and is dimorphous with orthoclase. Microcline is identical to orthoclase in many physical properties, and can be distinguished by x-ray or optical examination. When viewed under a polarizing microscope, microcline exhibits a minute multiple twinning which forms a grating-like structure that is unmistakable.

Feldspar (amazonite) Amazonita1.jpeg
Feldspar (amazonite)

Perthite is either microcline or orthoclase with thin lamellae of exsolved albite.

Amazon stone, or amazonite, is a green variety of microcline. It is not found anywhere in the Amazon Basin, however. The Spanish explorers who named it apparently confused it with another green mineral from that region.

The largest documented single crystals of microcline were found in Devil's Hole Beryl Mine, Colorado, US and measured ~50 × 36 × 14 m. This could be one of the largest crystals of any material found so far. [2]

Microcline is exceptionally active ice-nucleating agent in the atmosphere. [3] Recently it has been possible to understand how water binds to the microcline surface. [4]

As food additive

The chemical compound name is potassium aluminium silicate, and it is known as E number reference E555. It was the subject in 2018 of a Call for technical and toxicological data from the EFSA. [5]

In 2008, it (along with other Aluminum compounds) was the subject of a Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Food Contact Materials from the EFSA. [6]

See also

Related Research Articles

<span class="mw-page-title-main">Amazonite</span> Green silicate mineral

Amazonite, also known as amazonstone, is a green tectosilicate mineral, a variety of the potassium feldspar called microcline. Its chemical formula is KAlSi3O8, which is polymorphic to orthoclase.

In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz. It is contrasted with mafic rocks, which are relatively richer in magnesium and iron. Felsic refers to silicate minerals, magma, and rocks which are enriched in the lighter elements such as silicon, oxygen, aluminium, sodium, and potassium. Felsic magma or lava is higher in viscosity than mafic magma/lava.

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Feldspar</span> Group of rock-forming minerals

Feldspar is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.

<span class="mw-page-title-main">Potassium ferrocyanide</span> Chemical compound

Potassium ferrocyanide is the inorganic compound with formula K4[Fe(CN)6]·3H2O. It is the potassium salt of the coordination complex [Fe(CN)6]4−. This salt forms lemon-yellow monoclinic crystals.

<span class="mw-page-title-main">Orthoclase</span> Tectosilicate mineral found in igneous rock

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.

<span class="mw-page-title-main">Anorthoclase</span>

The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and between 64 and 90 percent of NaAlSi3O8.

<span class="mw-page-title-main">Plagioclase</span> Type of feldspar

Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Albite</span> Mineral, Na-feldspar, Na-silicate, tectosilicate

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3
O
8
. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Essexite</span> Igneous rock type

Essexite, also called nepheline monzogabbro, is a dark gray or black holocrystalline plutonic igneous rock. Its name is derived from the type locality in Essex County, Massachusetts, in the United States.

An anticaking agent is an additive placed in powdered or granulated materials, such as table salt or confectioneries, to prevent the formation of lumps (caking) and for easing packaging, transport, flowability, and consumption. Caking mechanisms depend on the nature of the material. Crystalline solids often cake by formation of liquid bridge and subsequent fusion of microcrystals. Amorphous materials can cake by glass transitions and changes in viscosity. Polymorphic phase transitions can also induce caking.

<span class="mw-page-title-main">Sanidine</span> Form of potassium feldspar

Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

<span class="mw-page-title-main">Celsian</span>

Celsian is an uncommon feldspar mineral, barium aluminosilicate, BaAl2Si2O8. The mineral occurs in contact metamorphic rocks with significant barium content. Its crystal system is monoclinic, and it is white, yellow, or transparent in appearance. In pure form, it is transparent. Synthetic barium aluminosilicate is used as a ceramic in dental fillings and other applications.

<span class="mw-page-title-main">Moonstone (gemstone)</span> Semi-precious gemstone

Moonstone is a sodium potassium aluminium silicate ((Na,K)AlSi3O8) of the feldspar group that displays a pearly and opalescent schiller. An alternative name for moonstone is hecatolite.

This glossary of geology is a list of definitions of terms and concepts relevant to geology, its sub-disciplines, and related fields. For other terms related to the Earth sciences, see Glossary of geography terms.

<span class="mw-page-title-main">Rubicline</span>

Rubicline, also referred to as Rb-microcline, is the rubidium analogue of microcline, an important tectosilicate mineral. Its chemical formula is (Rb, K)[AlSi3O8] with an ideal composition of RbAlSi3O8. Chemical analysis by electron microprobe indicated the average weight of the crystal is 56.66% SiO2, 16.95% Al2O3, and 23.77% Rb2O, along with trace amounts of caesium oxide (Cs2O) and iron(III) oxide (Fe2O3).

<span class="mw-page-title-main">Vlasovite</span>

Vlasovite is a rare inosilicate (chain silicate) mineral with sodium and zirconium, with the chemical formula Na2ZrSi4O11. It was discovered in 1961 at Vavnbed Mountain in the Lovozero Massif, in the Northern Region of Russia. The researchers who first identified it, R P Tikhonenkova and M E Kazakova, named it for Kuzma Aleksevich Vlasov (1905–1964), a Russian mineralogist and geochemist who studied the Lovozero massif, and who was the founder of the Institute of Mineralogy, Geochemistry, and Crystal Chemistry of Rare Elements, Moscow, Russia.

<span class="mw-page-title-main">Sodium bisulfite</span> Chemical compound

Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO3. Sodium bisulfite in fact is not a real compound, but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions. It appears in form of white or yellowish-white crystals with an odor of sulfur dioxide. Regardless of its ill-defined nature, sodium bisulfite is used in many different industries such as a food additive with E number E222 in the food industry, a reducing agent in the cosmetic industry, and a decomposer of residual hypochlorite used in the bleaching industry.

References

  1. L.N. Warr (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. P.C. Rickwood (1981). "The largest crystals" (PDF). American Mineralogist. 66: 885–907.
  3. J.D. Atkinson, B.J. Murray, M.T. Woodhouse, T.F. Whale, K.J. Baustian, K.S. Carslaw, S. Dobbie, D. O'Sullivan, T.L. Malkin (2013). "The importance of feldspar for ice nucleation by mineral dust in mixed-phase clouds". Nature. 498: 355–358.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  4. G. Franceschi, A. Conti, L. Lezuo, R. Abart, F. Mittendorfer, M. Schmid, U. Diebold (2024). "How Water Binds to Microcline Feldspar (001)". Journal of Physical Chemistry Letters. 15 (1): 15–22.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  5. "Call for technical and toxicological data on sodium aluminium silicate (E 554) and potassium aluminium silicate (E 555) authorised as food additives in the EU". EFSA.
  6. F. Aguilar, H. Autrup, S. Barlow, L. Castle, R. Crebelli, W. Dekant, K.-H. Engel, N. Gontard, D. Gott, S. Grilli, R. Gürtler, J.-C. Larsen, C. Leclercq, J.-C. Leblanc, F.-X. Malcata, W. Mennes, M.-R. Milana, I. Pratt, I. Rietjens, P. Tobback, F. Toldrá. (2008). "Safety of aluminium from dietary intake[1] – Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Food Contact Materials (AFC)". EFSA Journal. 6 (7). doi: 10.2903/j.efsa.2008.754 . PMC   10193631 .{{cite journal}}: CS1 maint: multiple names: authors list (link)