Mineral group

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In geology and mineralogy, a mineral group is a set of mineral species with essentially the same crystal structure and composed of chemically similar elements. [1]

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Silicon-oxygen double chain in the anions of amphibole minerals. Tremolite-chain.png
Silicon-oxygen double chain in the anions of amphibole minerals.

For example, the amphibole group consists of 15 or more mineral species, most of them with the general unit formula A
x
B
y
C
14-3x-2y
Si
8
O
22
(OH)
2
, where A is a trivalent cation such as Fe3+
or Al3+
, B is a divalent cation such as Fe2+
, Ca2+
, or Mg2+
, and C is an alkali metal cation such as Li+
, Na+
, or K+
. In all these minerals, the anions consist mainly of groups of four SiO
4
tetrahedra connected by shared oxygen corners so as to form a double chain of fused six-member rings. In some of the species, aluminum Al3+
may replace some silicon atoms Si4+
in the backbone, with extra B or C cations to balance the charges.

List of groups

[ citation needed ]

See also

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<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Pyroxene</span> Group of inosilicate minerals with single chains of silica tetrahedra

The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.

<span class="mw-page-title-main">Sekaninaite</span> Mg, Fe, Al cyclosilicate mineral

Sekaninaite ((Fe+2,Mg)2Al4Si5O18) is a silicate mineral, the iron-rich analogue of cordierite.

<span class="mw-page-title-main">Hercynite</span>

Hercynite is a spinel mineral with the formula FeAl2O4.

<span class="mw-page-title-main">Silicate mineral</span> Rock-forming minerals with predominantly silicate anions

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<span class="mw-page-title-main">Smectite</span> Mineral mixture of phyllosilicates

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<span class="mw-page-title-main">Frank Hawthorne</span> Canadian mineralogist and crystallographer (born 1946)

Frank Christopher Hawthorne is an English-born Canadian mineralogist, crystallographer and spectroscopist. He works at the University of Manitoba and is currently distinguished professor emeritus. By combining graph theory, bond-valence theory and the moments approach to the electronic energy density of solids he has developed bond topology as a rigorous approach to understanding the atomic arrangements, chemical compositions and paragenesis of complex oxide and oxysalt minerals.

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<span class="mw-page-title-main">Nontronite</span> Phyllosilicate mineral

Nontronite is the iron(III) rich member of the smectite group of clay minerals. Nontronites typically have a chemical composition consisting of more than ~30% Fe2O3 and less than ~12% Al2O3 (ignited basis). Nontronite has very few economic deposits like montmorillonite. Like montmorillonite, nontronite can have variable amounts of adsorbed water associated with the interlayer surfaces and the exchange cations.

<span class="mw-page-title-main">Layered double hydroxides</span> Class of ionic solids characterized by a layered structure

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<span class="mw-page-title-main">Tschermakite</span> Amphibole, double chain inosilicate mineral

The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.

<span class="mw-page-title-main">Cookeite</span> Mineral species of the silicate group and the phyllosilicate subgroup, part of the chlorite family.

Cookeite is a mineral species of the silicate group and the phyllosilicate subgroup, part of the chlorite family, with the formula LiAl4(Si3Al)O10(OH)8. This soft, low-density mineral of variable color has a crystalline structure made up of alternating layers LiAl2(OH)6 and Al2O4(OH)2Si8O12 having several polytypes. Cookeite is often found as a product of hydrothermal alteration of silicates in pegmatites. It forms at relatively low temperatures (below 200 °C) and variable pressures.

This list gives an overview of the classification of minerals (silicates) and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, non-IMA approved minerals and non-named minerals are mostly excluded.

<span class="mw-page-title-main">Jimthompsonite</span>

Jimthompsonite is a magnesium iron silicate mineral with chemical formula (Mg,Fe2+)5Si6O16(OH)2. It is a triple chain silicate (or inosilicate) along with clinojimthompsonite and chesterite. They were described in 1977 by Burham and Veblen. They attracted great mineralogical attention because they were the first examples of new chain silicate structures among a large group known as biopyriboles whose name is derived from the words biotite, pyroxene, and amphiboles.

<span class="mw-page-title-main">Bicchulite</span> Tectosilicate mineral

Bicchulite has an ideal chemical formula of 2CaO•Al2O2•SiO2•H2O, which was formularized from the hydrothermal synthesis of synthetic gehlenite. Also, bicchulite was sighted in the mines of Japan with related minerals. This sodalite-type structured bicchulite has an uncommon ratio of aluminium to silicon, causing difficulties deciphering the structure. Because of bicchulite's structure it has a powdery texture, which leads to complications in obtaining information on the mineral's physical properties. Despite this problem, the color, specific gravity, and crystal size of bicchulite are known. Although bicchulite was only discovered about 40 years ago, technology has been rapidly advancing, allowing more accurate results to be made from experiments done today.

<span class="mw-page-title-main">Ferrogedrite</span> Amphibole, double chain inosilicate mineral

Ferrogedrite is an amphibole mineral with the complex chemical formula of ☐Fe2+2(Fe2+3Al2)(Si6Al2)O22(OH)2. It is sodium and calcium poor, making it part of the magnesium-iron-manganese-lithium amphibole subgroup. Defined as less than 1.00 apfu (atoms per formula unit) of Na + Ca and consisting of greater than 1.00 apfu of (Mg, Fe2+, Mn2+, Li) separating it from the calcic-sodic amphiboles. It is related to anthophyllite amphibole and gedrite through coupled substitution of (Al, Fe3+) for (Mg, Fe2+, Mn) and Al for Si. and determined by the content of silicon in the standard cell.

<span class="mw-page-title-main">Coupled substitution</span> Geological process by which two elements simultaneously substitute into a crystal

Coupled substitution is the geological process by which two elements simultaneous substitute into a crystal in order to maintain overall electrical neutrality and keep the charge constant. In forming a solid solution series, ionic size is more important than ionic charge, as this can be compensated for elsewhere in the structure.

References

  1. Stuart J. Mills, Frédéric Hatert, Ernest H. Nickel, and Giovanni Ferraris (2009): "The standardisation of mineral group hierarchies: application to recent nomenclature proposals". European Journal of Mineralogy, volume 21, number 5, pages 1073-1080. doi : 10.1127/0935-1221/2009/0021-1994