Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin molybdaenum, which is based on Ancient Greek Μόλυβδος molybdos, meaning lead, since its ores were confused with lead ores. Molybdenum minerals have been known throughout history, but the element was discovered in 1778 by Carl Wilhelm Scheele. The metal was first isolated in 1781 by Peter Jacob Hjelm.
Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is one of the rarest elements in the Earth's crust. Rhenium has the third-highest melting point and second-highest boiling point of any element at 5869 K. Rhenium resembles manganese and technetium chemically and is mainly obtained as a by-product of the extraction and refinement of molybdenum and copper ores. Rhenium shows in its compounds a wide variety of oxidation states ranging from −1 to +7.
Group 6, numbered by IUPAC style, is a group of elements in the periodic table. Its members are chromium (Cr), molybdenum (Mo), tungsten (W), and seaborgium (Sg). These are all transition metals and chromium, molybdenum and tungsten are refractory metals.
A period 5 element is one of the chemical elements in the fifth row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The fifth period contains 18 elements, beginning with rubidium and ending with xenon. As a rule, period 5 elements fill their 5s shells first, then their 4d, and 5p shells, in that order; however, there are exceptions, such as rhodium.
Molybdenum disulfide is an inorganic compound composed of molybdenum and sulfur. Its chemical formula is MoS
2.
Group 7, numbered by IUPAC nomenclature, is a group of elements in the periodic table. They are manganese (Mn), technetium (Tc), rhenium (Re), and bohrium (Bh). All known elements of group 7 are transition metals.
Powellite is a calcium molybdate mineral with formula CaMoO4. Powellite crystallizes with tetragonal – dipyramidal crystal structure as transparent adamantine blue, greenish-brown, yellow-to-grey typically anhedral forms. It exhibits distinct cleavage, and has a brittle-to-conchoidal fracture. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 4.25. It forms a solid solution series with scheelite (calcium tungstate, CaWO4). It has refractive index values of nω=1.974 and nε=1.984.
A chalcogenide is a chemical compound consisting of at least one chalcogen anion and at least one more electropositive element. Although all group 16 elements of the periodic table are defined as chalcogens, the term chalcogenide is more commonly reserved for sulfides, selenides, tellurides, and polonides, rather than oxides. Many metal ores exist as chalcogenides. Photoconductive chalcogenide glasses are used in xerography. Some pigments and catalysts are also based on chalcogenides. The metal dichalcogenide MoS2 is a common solid lubricant.
Rheniite is a very rare rhenium sulfide mineral with the chemical formula. It forms metallic, silver grey platey crystals in the triclinic - pinacoidal class. It has a specific gravity of 7.5.
A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include aluminium, antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, selenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.
The Climax mine, located in Climax, Colorado, United States, is a major molybdenum mine in Lake and Summit counties, Colorado. Shipments from the mine began in 1915. At its highest output, the Climax mine was the largest molybdenum mine in the world, and for many years it supplied three quarters of the world's supply of molybdenum.
The Henderson molybdenum mine is a large underground molybdenum mine west of the town of Empire in Clear Creek County, Colorado, USA. The Henderson mine, which has produced molybdenum since 1976, is owned by Freeport-McMoRan.
The Toquepala mine is a large porphyry copper mine in the Tacna Province, Tacna Department, Peru. The mine is an open-pit mine producing copper, molybdenum, rhenium and silver with minor gold and zinc.
Ferrimolybdite is a hydrous iron molybdate mineral with formula: Fe3+2(MoO4)3·8(H2O) or Fe3+2(MoO4)3·n(H2O). It forms coatings and radial aggregates of soft yellow needles which crystallize in the orthorhombic system.
Lindgrenite is an uncommon copper molybdate mineral with formula: Cu3(MoO4)2(OH)2. It occurs as tabular to platey monoclinic green to yellow green crystals.
Transition-metal dichalcogenide (TMD or TMDC) monolayers are atomically thin semiconductors of the type MX2, with M a transition-metal atom (Mo, W, etc.) and X a chalcogen atom (S, Se, or Te). One layer of M atoms is sandwiched between two layers of X atoms. They are part of the large family of so-called 2D materials, named so to emphasize their extraordinary thinness. For example, a MoS2 monolayer is only 6.5 Å thick. The key feature of these materials is the interaction of large atoms in the 2D structure as compared with first-row transition-metal dichalcogenides, e.g., WTe2 exhibits anomalous giant magnetoresistance and superconductivity.
Molybdenum mining in the United States produced 65,500 metric tons of molybdenum in 2014, worth US$1.8 billion. The US was the world's second-largest molybdenum producer, after China, and provided 25% of the world's supply of molybdenum.
Tugarinovite is a rare molybdenum oxide mineral with formula MoO2. It occurs as a primary mineral phase associated with metasomatism in a sulfur deficient reducing environment. In the type locality it occurs with uraninite, molybdenite, galena, zircon and wulfenite.
Szenicsite is a copper hydroxy molybdate mineral, named after husband and wife Terry and Marissa Szenics, American mineral collectors who found the first specimens. When it was first discovered in Atacama, Chile, it was thought to be lindgrenite. The occurrence appeared in an isolated area, which was about one cubic meter in size. The mineral occurred in cavities of copper bearing powellite and matrix rich molybdenite. These cavities were filled with a material resembling clay. Outside of the zone the szenicsite crystals grew, copper levels seemed to decrease, and the mineralization changed to lindgrenite. Moving further from the zone, the minerals growing seemed to be lacking copper, and consisted of powellite blebs in the ore. Szenicsite was approved by the IMA in 1993.
