Porphyry copper deposits are copper ore bodies that are formed from hydrothermal fluids that originate from a voluminous magma chamber several kilometers below the deposit itself. Predating or associated with those fluids are vertical dikes of porphyritic intrusive rocks from which this deposit type derives its name. In later stages, circulating meteoric fluids may interact with the magmatic fluids. Successive envelopes of hydrothermal alteration typically enclose a core of disseminated ore minerals in often stockwork-forming hairline fractures and veins. Because of their large volume, porphyry orebodies can be economic from copper concentrations as low as 0.15% copper and can have economic amounts of by-products such as molybdenum, silver, and gold. In some mines, those metals are the main product.
The first mining of low-grade copper porphyry deposits from large open pits coincided roughly with the introduction of steam shovels, the construction of railroads, and a surge in market demand near the start of the 20th century. Some mines exploit porphyry deposits that contain sufficient gold or molybdenum, but little or no copper.
Porphyry copper deposits are currently the largest source of copper ore. [1] Most of the known porphyry deposits are concentrated in: western South and North America and Southeast Asia and Oceania – along the Pacific Ring of Fire; the Caribbean; southern central Europe and the area around eastern Turkey; scattered areas in China, the Mideast, Russia, and the CIS states; and eastern Australia. [2] [3] Only a few are identified in Africa, in Namibia [4] and Zambia; [5] none are known in Antarctica. The greatest concentration of the largest copper porphyry deposits is in northern Chile. Almost all mines exploiting large porphyry deposits produce from open pits.
Porphyry copper deposits represent an important resource and the dominant source of copper that is mined today to satisfy global demand. [6] Via compilation of geological data, it has been found that the majority of porphyry deposits are Phanerozoic in age and were emplaced at depths of approximately 1 to 6 kilometres with vertical thicknesses on average of 2 kilometres. [6] Throughout the Phanerozoic an estimated 125,895 porphyry copper deposits were formed; however, 62% of them (78,106) have been removed by uplift and erosion. [6] Thus, 38% (47,789) remain in the crust, of which there are 574 known deposits that are at the surface. [6] It is estimated that the Earth's porphyry copper deposits contain approximately 1.7×1011 tonnes of copper, equivalent to more than 8,000 years of global mine production. [6]
Porphyry deposits represent an important resource of copper; however, they are also important sources of gold and molybdenum – with porphyry deposits being the dominant source of the latter. [7] In general, porphyry deposits are characterized by low grades of ore mineralization, a porphyritic intrusive complex that is surrounded by a vein stockwork and hydrothermal breccias. [8] Porphyry deposits are formed in arc-related settings and are associated with subduction zone magmas. [7] Porphyry deposits are clustered in discrete mineral provinces, which implies that there is some form of geodynamic control or crustal influence affecting the location of porphyry formation. [8] Porphyry deposits tend to occur in linear, orogen-parallel belts (such as the Andes in South America). [9]
There also appear to be discrete time periods in which porphyry deposit formation was concentrated or preferred. For copper-molybdenum porphyry deposits, formation is broadly concentrated in three time periods: Palaeocene-Eocene, Eocene-Oligocene, and middle Miocene-Pliocene. [8] For both porphyry and epithermal gold deposits, they are generally from the time period ranging from the middle Miocene to the Recent period, [8] however notable exceptions are known. Most large-scale porphyry deposits have an age of less than 20 million years, [8] however there are notable exceptions, such as the 438 million-year-old Cadia-Ridgeway deposit in New South Wales. This relatively young age reflects the preservation potential of this type of deposit; as they are typically located in zones of highly active tectonic and geological processes, such as deformation, uplift, and erosion. [8] It may be however, that the skewed distribution towards most deposits being less than 20 million years is at least partially an artifact of exploration methodology and model assumptions, as large examples are known in areas which were previously left only partially or under-explored partly due to their perceived older host rock ages, but which were then later found to contain large, world-class examples of much older porphyry copper deposits.[ citation needed ]
In general, the majority of large porphyry deposits are associated with calc-alkaline intrusions, although some of the largest gold-rich deposits are associated with high-K calc-alkaline magma compositions. [8] Numerous world-class porphyry copper-gold deposits are hosted by high-K or shoshonitic intrusions, such as Bingham copper-gold mine in USA, Grasberg copper-gold mine in Indonesia, Northparkes copper-gold mine in Australia, Oyu Tolgoi copper-gold mine in Mongolia and Peschanka copper-gold prospect in Russia. [10]
The magmas responsible for porphyry formation are conventionally thought to be generated by the partial melting of the upper part of post-subduction, stalled slabs that are altered by seawater. [11] Shallow subduction of young, buoyant slabs can result in the production of adakitic lavas via partial melting. [7] Alternatively, metasomatised mantle wedges can produce highly oxidized conditions that results in sulfide minerals releasing ore minerals (copper, gold, molybdenum), which are then able to be transported to upper crustal levels. [11] Mantle melting can also be induced by transitions from convergent to transform margins, as well as the steepening and trenchward retreat of the subducted slab. [11] However, the latest belief is that dehydration that occurs at the blueschist-eclogite transition affects most subducted slabs, rather than partial melting. [7]
After dehydration, solute-rich fluids are released from the slab and metasomatise the overlying mantle wedge of MORB-like asthenosphere, enriching it with volatiles and large ion lithophile elements (LILE). [7] The current belief is that the generation of andesitic magmas is multistage, and involves crustal melting and assimilation of primary basaltic magmas, magma storage at the base of the crust (underplating by dense, mafic magma as it ascends), and magma homogenization. [7] The underplated magma will add a lot of heat to the base of the crust, thereby inducing crustal melting and assimilation of lower-crustal rocks, creating an area with intense interaction of the mantle magma and crustal magma. [7] This progressively evolving magma will become enriched in volatiles, sulfur, and incompatible elements – an ideal combination for the generation of a magma capable of generating an ore deposit. [7] From this point forward in the evolution of a porphyry deposit, ideal tectonic and structural conditions are necessary to allow the transport of the magma and ensure its emplacement in upper-crustal levels.
Although porphyry deposits are associated with arc volcanism, they are not the typical products in that environment. It is believed that tectonic change acts as a trigger for porphyry formation. [8] There are five key factors that can give rise to porphyry development: 1) compression impeding magma ascent through crust, 2) a resultant larger shallow magma chamber, 3) enhanced fractionation of the magma along with volatile saturation and generation of magmatic-hydrothermal fluids, 4) compression restricts offshoots from developing into the surrounding rock, thus concentrating the fluid into a single stock, and 5) rapid uplift and erosion promotes decompression and efficient, eventual deposition of ore. [12]
Porphyry deposits are commonly developed in regions that are zones of low-angle (flat-slab) subduction. [8] A subduction zone that transitions from normal to flat and then back to normal subduction produces a series of effects that can lead to the generation of porphyry deposits. Initially, there will be decreased alkalic magmatism, horizontal shortening, hydration of the lithosphere above the flat-slab, and low heat flow. [8] Upon a return to normal subduction, the hot asthenosphere will once again interact with the hydrated mantle, causing wet melting, crustal melting will ensue as mantle melts pass through, and lithospheric thinning and weakening due to the increased heat flow. [8] The subducting slab can be lifted by aseismic ridges, seamount chains, or oceanic plateaus – which can provide a favourable environment for the development of a porphyry deposit. [8] This interaction between subduction zones and the aforementioned oceanic features can explain the development of multiple metallogenic belts in a given region; as each time the subduction zone interacts with one of these features it can lead to ore genesis. [8] Finally, in oceanic island arcs, ridge subduction can lead to slab flattening or arc reversal; whereas, in continental arcs it can lead to periods of flat slab subduction. [8]
Arc reversal has been shown to slightly pre-date the formation of porphyry deposits in the south-west Pacific, after a collisional event. [13] Arc reversal occurs due to collision between an island arc and either another island arc, a continent, or an oceanic plateau. [11] The collision may result in the termination of subduction and thereby induce mantle melting. [11]
Porphyry deposits do not generally have any requisite structural controls for their formation; although major faults and lineaments are associated with some. [11] [14] The presence of intra-arc fault systems are beneficial, as they can localize porphyry development. [9] Furthermore, some authors have indicated that the occurrence of intersections between continent-scale traverse fault zones and arc-parallel structures are associated with porphyry formation. [9] This is actually the case of Chile's Los Bronces and El Teniente porphyry copper deposits each of which lies at the intersection of two fault systems. [14]
It has been proposed that "misoriented" deep-seated faults that were inactive during magmatism are important zones where porphyry copper-forming magmas stagnate allowing them to achieve their typical igneous differentiation. [15] At a given time differentiated magmas would burst violently out of these fault-traps and head to shallower places in the crust where porphyry copper deposits would be formed. [15]
Characteristics of porphyry copper deposits include:
Porphyry copper deposits are typically mined by open-pit methods.
Copper is not the only metal that occurs in porphyry deposits. There are also porphyry ore deposits mined primarily for molybdenum, many of which contain very little copper. Examples of porphyry molybdenum deposits are the Climax, Urad, Mt. Emmons, and Henderson deposits in central Colorado; the White Pine and Pine Grove deposits in Utah; [23] [24] the Questa deposit in northern New Mexico; and Endako in British Columbia.
The US Geological Survey has classed the Chorolque and Catavi tin deposits in Bolivia as porphyry tin deposits. [25]
Some porphyry copper deposits in oceanic crust environments, such as those in the Philippines, Indonesia, and Papua New Guinea, are sufficiently rich in gold that they are called copper-gold porphyry deposits. [26]
Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the heavier plate dives beneath the second plate and sinks into the mantle. A region where this process occurs is known as a subduction zone, and its surface expression is known as an arc-trench complex. The process of subduction has created most of the Earth's continental crust. Rates of subduction are typically measured in centimeters per year, with rates of convergence as high as 11 cm/year.
A convergent boundary is an area on Earth where two or more lithospheric plates collide. One plate eventually slides beneath the other, a process known as subduction. The subduction zone can be defined by a plane where many earthquakes occur, called the Wadati–Benioff zone. These collisions happen on scales of millions to tens of millions of years and can lead to volcanism, earthquakes, orogenesis, destruction of lithosphere, and deformation. Convergent boundaries occur between oceanic-oceanic lithosphere, oceanic-continental lithosphere, and continental-continental lithosphere. The geologic features related to convergent boundaries vary depending on crust types.
Island arcs are long chains of active volcanoes with intense seismic activity found along convergent tectonic plate boundaries. Most island arcs originate on oceanic crust and have resulted from the descent of the lithosphere into the mantle along the subduction zone. They are the principal way by which continental growth is achieved.
Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, bimetasomatic reaction of different lithologies, and infiltration metasomatism by magmatic-hydrothermal fluids. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that commonly intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from a variety of sources; magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid.
Greisen is a highly altered granitic rock or pegmatite, usually composed predominantly of quartz and micas. Greisen is formed by self-generated alteration of a granite and is a class of moderate- to high-temperature magmatic-hydrothermal alteration related to the late-stage release of volatiles dissolved in a magma during the solidification of that magma.
Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.
A polymetallic replacement deposit, also known as carbonate replacement deposit or high-temperature carbonate-hosted Ag-Pb-Zn deposit, is an orebody of metallic minerals formed by the replacement of sedimentary, usually carbonate rock, by metal-bearing solutions in the vicinity of igneous intrusions. When the ore forms a blanketlike body along the bedding plane of the rock, it is commonly called a manto ore deposit. Other ore geometries are chimneys and veins. Polymetallic replacements/mantos are often stratiform wall-rock replacement orebodies distal to porphyry copper deposits, or porphyry molybdenum deposits. The term manto is derived from the Spanish word manto, meaning "mantle" or "cloak".
Adakites are volcanic rocks of intermediate to felsic composition that have geochemical characteristics of magma originally thought to have formed by partial melting of altered basalt that is subducted below volcanic arcs. Most magmas derived in subduction zones come from the mantle above the subducting plate when hydrous fluids are released from minerals that break down in the metamorphosed basalt, rise into the mantle, and initiate partial melting. However, Defant and Drummond recognized that when young oceanic crust is subducted, adakites are typically produced in the arc. They postulated that when young oceanic crust is subducted it is "warmer" than crust that is typically subducted. The warmer crust enables melting of the metamorphosed subducted basalt rather than the mantle above. Experimental work by several researchers has verified the geochemical characteristics of "slab melts" and the contention that melts can form from young and therefore warmer crust in subduction zones.
Partial melting is the phenomenon that occurs when a rock is subjected to temperatures high enough to cause certain minerals to melt, but not all of them. Partial melting is an important part of the formation of all igneous rocks and some metamorphic rocks, as evidenced by a multitude of geochemical, geophysical and petrological studies.
Iron oxide copper gold ore deposits (IOCG) are important and highly valuable concentrations of copper, gold and uranium ores hosted within iron oxide dominant gangue assemblages which share a common genetic origin.
The Atacama Fault Zone (AFZ) is an extensive system of faults cutting across the Chilean Coastal Cordillera in Northern Chile between the Andean Mountain range and the Pacific Ocean. The fault system is North-South striking and runs for more than 1100 km North and up to 50 km in width through the Andean forearc region. The zone is a direct result of the ongoing subduction of the Eastward moving Nazca Plate beneath the South American Plate and is believed to have formed in the Early Jurassic during the beginnings of the Andean orogeny. The zone can be split into 3 regions: the North, Central and South.
A subduction zone is a region of the Earth's crust where one tectonic plate moves under another tectonic plate; oceanic crust gets recycled back into the mantle and continental crust gets produced by the formation of arc magmas. Arc magmas account for more than 20% of terrestrially produced magmas and are produced by the dehydration of minerals within the subducting slab as it descends into the mantle and are accreted onto the base of the overriding continental plate. Subduction zones host a unique variety of rock types formed by the high-pressure, low-temperature conditions a subducting slab encounters during its descent. The metamorphic conditions the slab passes through in this process generates and alters water bearing (hydrous) mineral phases, releasing water into the mantle. This water lowers the melting point of mantle rock, initiating melting. Understanding the timing and conditions in which these dehydration reactions occur, is key to interpreting mantle melting, volcanic arc magmatism, and the formation of continental crust.
Farallon Negro is a volcano in the Catamarca province of Argentina. Active between about 9-8 million years ago, it was formerly a stratovolcano or a multi vent volcano. Eventually, erosion removed most of the volcano and exposed the underlying structure including subvolcanic intrusions.
The geology of Arizona began to form in the Precambrian. Igneous and metamorphic crystalline basement rock may have been much older, but was overwritten during the Yavapai and Mazatzal orogenies in the Proterozoic. The Grenville orogeny to the east caused Arizona to fill with sediments, shedding into a shallow sea. Limestone formed in the sea was metamorphosed by mafic intrusions. The Great Unconformity is a famous gap in the stratigraphic record, as Arizona experienced 900 million years of terrestrial conditions, except in isolated basins. The region oscillated between terrestrial and shallow ocean conditions during the Paleozoic as multi-cellular life became common and three major orogenies to the east shed sediments before North America became part of the supercontinent Pangaea. The breakup of Pangaea was accompanied by the subduction of the Farallon Plate, which drove volcanism during the Nevadan orogeny and the Sevier orogeny in the Mesozoic, which covered much of Arizona in volcanic debris and sediments. The Mid-Tertiary ignimbrite flare-up created smaller mountain ranges with extensive ash and lava in the Cenozoic, followed by the sinking of the Farallon slab in the mantle throughout the past 14 million years, which has created the Basin and Range Province. Arizona has extensive mineralization in veins, due to hydrothermal fluids and is notable for copper-gold porphyry, lead, zinc, rare minerals formed from copper enrichment and evaporites among other resources.
Hydrothermal mineral deposits are accumulations of valuable minerals which formed from hot waters circulating in Earth's crust through fractures. They eventually produce metallic-rich fluids concentrated in a selected volume of rock, which become supersaturated and then precipitate ore minerals. In some occurrences, minerals can be extracted for a profit by mining. Discovery of mineral deposits consumes considerable time and resources and only about one in every one thousand prospects explored by companies are eventually developed into a mine. A mineral deposit is any geologically significant concentration of an economically useful rock or mineral present in a specified area. The presence of a known but unexploited mineral deposit implies a lack of evidence for profitable extraction.
A crystal mush is magma that contains a significant amount of crystals suspended in the liquid phase (melt). As the crystal fraction makes up less than half of the volume, there is no rigid large-scale three-dimensional network as in solids. As such, their rheological behavior mirrors that of absolute liquids.
An orogenic gold deposit is a type of hydrothermal mineral deposit. More than 75% of the gold recovered by humans through history belongs to the class of orogenic gold deposits. Rock structure is the primary control of orogenic gold mineralization at all scales, as it controls both the transport and deposition processes of the mineralized fluids, creating structural pathways of high permeability and focusing deposition to structurally controlled locations.
Keiko Hattori is a geochemist and mineralogist. She is Distinguished University Professor of Geochemistry and Mineral Deposits in the Department of Earth and Environmental Sciences at the University of Ottawa.
Magmatism along strike-slip faults is the process of rock melting, magma ascent and emplacement, associated with the tectonics and geometry of various strike-slip settings, most commonly occurring along transform boundaries at mid-ocean ridge spreading centres and at strike-slip systems parallel to oblique subduction zones. Strike-slip faults have a direct effect on magmatism. They can either induce magmatism, act as a conduit to magmatism and magmatic flow, or block magmatic flow. In contrast, magmatism can also directly impact on strike-slip faults by determining fault formation, propagation and slip. Both magma and strike-slip faults coexist and affect one another.
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