Chlorite group

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Chlorite group
ChloriteUSGOV.jpg
General
Category Phyllosilicates
Formula
(repeating unit)
(Mg,Fe)3(Si,Al)4O10(OH)2·(Mg,Fe)3(OH)6
IMA symbol Chl [1]
Crystal system Monoclinic 2/m; with some triclinic polymorphs.
Identification
ColorVarious shades of green; rarely yellow, red, or white.
Crystal habit Foliated masses, scaley aggregates, disseminated flakes.
Cleavage Perfect 001
Fracture Lamellar
Mohs scale hardness2–2.5
Luster Vitreous, pearly, dull
Streak Pale green to grey
Specific gravity 2.6–3.3
Refractive index 1.57–1.67
Other characteristicsFolia flexible – not elastic
References [2] [3]

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

Contents

Chlorite minerals show a wide variety of compositions, in which magnesium, iron, aluminium, and silicon substitute for each other in the crystal structure. A complete solid solution series exists between the two most common end members, magnesium-rich clinochlore and iron-rich chamosite. In addition, manganese, zinc, lithium, and calcium species are known. The great range in composition results in considerable variation in physical, optical, and X-ray properties. Similarly, the range of chemical composition allows chlorite group minerals to exist over a wide range of temperature and pressure conditions. For this reason chlorite minerals are ubiquitous minerals within low and medium temperature metamorphic rocks, some igneous rocks, hydrothermal rocks and deeply buried sediments.

The name chlorite is from the Greek chloros (χλωρός), meaning "green", in reference to its color. Chlorite minerals do not contain the element chlorine, also named from the same Greek root.

Properties

Chlorite forms blue-green crystals resembling mica. However, while the plates are flexible, they are not elastic like mica, and are less easily pulled apart. Talc is much softer and feels soapy between the fingers. [4] [5]

The typical general formula for chlorite is (Mg,Fe)3(Si,Al)4O10(OH)2·(Mg,Fe)3(OH)6. This formula emphasizes the structure of the group, which is described as TOT-O and consists of alternating TOT layers and O layers. [3] The TOT layer (Tetrahedral-Octahedral-Tetrahedral = T-O-T) is often referred to as a talc layer, since talc is composed entirely of stacked TOT layers. The TOT layers of talc are electrically neutral and are bound only by relatively weak van der Waals forces. By contrast, the TOT layers of chlorite contain some aluminium in place of silicon, which gives the layers an overall negative charge. These TOT layers are bound together by positively charged O layers, sometimes called brucite layers. Mica is also composed of aluminium-rich, negatively charged TOT layers, but these are bonded together by individual cations (such as potassium, sodium, or calcium ions) rather than a positively charged brucite layer. [6]

Chlorite is considered a clay mineral. It is a nonswelling clay mineral, [7] since water is not adsorbed in the interlayer spaces, and it has a relatively low cation exchange capacity. [8]

Occurrence

Quartz crystal with chlorite inclusions from Minas Gerais, Brazil (size: 4.2 x 3.9 x 3.3 cm) Quartz-Chlorite-Group-139575.jpg
Quartz crystal with chlorite inclusions from Minas Gerais, Brazil (size: 4.2 × 3.9 × 3.3 cm)

Chlorite is a common mineral, found in metamorphic, igneous, and sedimentary rocks. It is an important rock-forming mineral in low- to medium-grade metamorphic rock formed by metamorphism of mafic or pelitic rock. [9] It is also common in igneous rocks, usually as a secondary mineral, formed by alteration of mafic minerals such as biotite, hornblende, pyroxene, or garnet. [10] The glassy rims of pillow basalt on the ocean floor is often altered to pure chlorite, in part by exchange of chemicals with seawater. [11] The green color of many igneous rocks, slates, and schists is due to fine particles of chlorite disseminated throughout the rock. [10] Chlorite is a common weathering product and is widespread in clay and in sedimentary rock containing clay minerals. [9] Chlorite is found in pelites along with quartz, albite, sericite, and garnet, and is also found in associate with actinolite and epidote. [10]

In his pioneering work on metamorphic facies in the Scottish Highlands, G.M. Barrow identified the chlorite zone as the zone of mildest metamorphism. [12] In modern petrology, chlorite is the diagnostic mineral of the greenschist facies. [10] This facies is characterized by temperatures near 450 °C (840 °F) and pressures near 5 kbar. [13] At higher temperatures, much of the chlorite is destroyed by reactions with either potassium feldspar or phengite mica which produce biotite, muscovite, and quartz. At still higher temperatures, other reactions destroy the remaining chlorite, often with release of water vapor. [14]

Chlorite is one of the most common minerals produced by propylitic alteration by hydrothermal systems, where it occurs in the "green rock" environment with epidote, actinolite, albite, hematite, and calcite. [15]

Chlorite pseudomorph after garnet from Michigan (size: 3.5 x 3.1 x 2.7 cm) Chlorite-Group-Garnet-Group-65646.jpg
Chlorite pseudomorph after garnet from Michigan (size: 3.5 × 3.1 × 2.7 cm)

Experiments indicate that chlorite can be stable in peridotite of the Earth's mantle above the ocean lithosphere carried down by subduction, and chlorite may even be present in the mantle volume from which island arc magmas are generated. [16] [17]

Members of the chlorite group

Chlorite schist Chlorite schist.jpg
Chlorite schist
BaileychloreIMA1986-056(Zn,Fe2+,Al,Mg)6(Al,Si)4O10(O,OH)8
BorocookeiteIMA2000-013LiAl4(Si3B)O10(OH)8
Chamosite year: 1820(Fe,Mg)5Al(Si3Al)O10(OH)8
Clinochloreyear: 1851(Mg,Fe2+)5Al(Si3Al)O10(OH)8
Cookeite year: 1866LiAl4(Si3Al)O10(OH)8
Donbassiteyear: 1940Al2[Al2.33][Si3AlO10](OH)8
Gonyeriteyear: 1955(Mn,Mg)5(Fe3+)2Si3O10(OH)8
Nimiteyear: 1968(Ni,Mg,Al)6(Si,Al)4O10(OH)8
Pennantiteyear: 1946(Mn5Al)(Si3Al)O10(OH)8
Ripidolitechlinochlore var.(Mg,Fe,Al)6(Al,Si)4O10(OH)8
SudoiteIMA1966-027Mg2(Al,Fe)3Si3AlO10(OH)8

Clinochlore, pennantite, and chamosite are the most common varieties. Several other sub-varieties have been described. A massive compact variety of clinochlore used as a decorative carving stone is referred to by the trade name seraphinite. It occurs in the Korshunovskoye iron skarn deposit in the Irkutsk Oblast of Eastern Siberia. [18]

Uses

Chlorite does not have any specific industrial uses of any importance. Some rock types containing chlorite, such as chlorite schist, have minor decorative uses or as construction stone. However, chlorite is a common mineral in clay, which has a vast number of uses. [9]

Chlorite schist has been used as roofing granules, the mineral granules adhered to asphalt composition shingles due to the green color. It was quarried near Ely, Minnesota, US, until superseded by synthetic materials.

See also

Related Research Articles

<span class="mw-page-title-main">Gneiss</span> Common high-grade metamorphic rock

Gneiss is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures and pressures than schist. Gneiss nearly always shows a banded texture characterized by alternating darker and lighter colored bands and without a distinct cleavage.

<span class="mw-page-title-main">Schist</span> Easily split medium-grained metamorphic rock

Schist is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes or plates. This texture reflects a high content of platy minerals, such as mica, talc, chlorite, or graphite. These are often interleaved with more granular minerals, such as feldspar or quartz.

<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Metamorphic rock</span> Rock that was subjected to heat and pressure

Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than 150 to 200 °C and, often, elevated pressure of 100 megapascals (1,000 bar) or more, causing profound physical or chemical changes. During this process, the rock remains mostly in the solid state, but gradually recrystallizes to a new texture or mineral composition. The protolith may be an igneous, sedimentary, or existing metamorphic rock.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Metamorphism</span> Change of minerals in pre-existing rocks without melting into liquid magma

Metamorphism is the transformation of existing rock to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.

<span class="mw-page-title-main">Amphibolite</span> Metamorphic rock type

Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.

<span class="mw-page-title-main">Metasomatism</span> Chemical alteration of a rock by hydrothermal and other fluids

Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid.

<span class="mw-page-title-main">Granulite</span> Class of high-grade medium to coarse grained metamorphic rocks

Granulites are a class of high-grade metamorphic rocks of the granulite facies that have experienced high-temperature and moderate-pressure metamorphism. They are medium to coarse–grained and mainly composed of feldspars sometimes associated with quartz and anhydrous ferromagnesian minerals, with granoblastic texture and gneissose to massive structure. They are of particular interest to geologists because many granulites represent samples of the deep continental crust. Some granulites experienced decompression from deep in the Earth to shallower crustal levels at high temperature; others cooled while remaining at depth in the Earth.

<span class="mw-page-title-main">Hornfels</span>

Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are caused by fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.

<span class="mw-page-title-main">Blueschist</span> Type of metavolcanic rock

Blueschist, also called glaucophane schist, is a metavolcanic rock that forms by the metamorphism of basalt and rocks with similar composition at high pressures and low temperatures, approximately corresponding to a depth of 15–30 km (9.3–18.6 mi). The blue color of the rock comes from the presence of the predominant minerals glaucophane and lawsonite.

<span class="mw-page-title-main">Ultramafic rock</span> Type of igneous and meta-igneous rock

Ultramafic rocks are igneous and meta-igneous rocks with a very low silica content, generally >18% MgO, high FeO, low potassium, and are composed of usually greater than 90% mafic minerals. The Earth's mantle is composed of ultramafic rocks. Ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as carbonatites and ultrapotassic igneous rocks.

<span class="mw-page-title-main">Anthophyllite</span> Silicate amphibole mineral

Anthophyllite is an orthorhombic amphibole mineral: ☐Mg2Mg5Si8O22(OH)2 (☐ is for a vacancy, a point defect in the crystal structure), magnesium iron inosilicate hydroxide. Anthophyllite is polymorphic with cummingtonite. Some forms of anthophyllite are lamellar or fibrous and are classed as asbestos. The name is derived from the Latin word anthophyllum, meaning clove, an allusion to the most common color of the mineral. The Anthophyllite crystal is characterized by its perfect cleavage along directions 126 degrees and 54 degrees.

<span class="mw-page-title-main">Komatiite</span> Ultramafic mantle-derived volcanic rock

Komatiite is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% magnesium oxide (MgO). It is classified as a 'picritic rock'. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite was named for its type locality along the Komati River in South Africa, and frequently displays spinifex texture composed of large dendritic plates of olivine and pyroxene.

<span class="mw-page-title-main">Greenschist</span> Metamorphic rock

Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically 300–450 °C (570–840 °F) and 2–10 kilobars (29,000–145,000 psi). Greenschists commonly have an abundance of green minerals such as chlorite, serpentine, and epidote, and platy minerals such as muscovite and platy serpentine. The platiness gives the rock schistosity. Other common minerals include quartz, orthoclase, talc, carbonate minerals and amphibole (actinolite).

The prehnite-pumpellyite facies is a metamorphic facies typical of subseafloor alteration of the oceanic crust around mid-ocean ridge spreading centres. It is a metamorphic grade transitional between zeolite facies and greenschist facies representing a temperature range of 250 to 350 °C and a pressure range of approximately two to seven kilobars. The mineral assemblage is dependent on host composition.

Talc carbonates are a suite of rock and mineral compositions found in metamorphosed ultramafic rocks.

An isograd is a concept used in the study of metamorphic rocks. The metamorphic grade of such a rock is a rough measure of the degree of metamorphism it has undergone, as characterised by the presence of certain index minerals. An isograd is a theoretical surface comprising points all at the same metamorphic grade, and thus separates metamorphic zones whose rocks contain different index minerals.

<span class="mw-page-title-main">Metamorphic facies</span> Set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures

A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.

<span class="mw-page-title-main">Subduction zone metamorphism</span> Changes of rock due to pressure and heat near a subduction zone

A subduction zone is a region of the Earth's crust where one tectonic plate moves under another tectonic plate; oceanic crust gets recycled back into the mantle and continental crust gets created by the formation of arc magmas. Arc magmas account for more than 20% of terrestrially produced magmas and are produced by the dehydration of minerals within the subducting slab as it descends into the mantle and are accreted onto the base of the overriding continental plate. Subduction zones host a unique variety of rock types created by the high-pressure, low-temperature conditions a subducting slab encounters during its descent. The metamorphic conditions the slab passes through in this process creates and destroys water bearing (hydrous) mineral phases, releasing water into the mantle. This water lowers the melting point of mantle rock, initiating melting. Understanding the timing and conditions in which these dehydration reactions occur, is key to interpreting mantle melting, volcanic arc magmatism, and the formation of continental crust.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Chlorite Group: Mineral information, data and localities, Mindat.org
  3. 1 2 Nesse, William D. (2000). Introduction to mineralogy. New York: Oxford University Press. pp. 251–260. ISBN   9780195106916.
  4. Sinkankas, John (1964). Mineralogy for amateurs. Princeton, N.J.: Van Nostrand. p. 486. ISBN   0442276249.
  5. Klein, Cornelis; Hurlbut, Cornelius S. Jr. (1993). Manual of mineralogy : (after James D. Dana) (21st ed.). New York: Wiley. p. 514. ISBN   047157452X.
  6. Klein & Hurlbut 1993, pp. 500–501.
  7. Osacky, Marek; Geramian, Mirjavad; Ivey, Douglas G.; Liu, Qi; Etsell, Thomas H. (16 July 2015). "Influence of Nonswelling Clay Minerals (Illite, Kaolinite, and Chlorite) on Nonaqueous Solvent Extraction of Bitumen". Energy & Fuels. 29 (7): 4150–4159. doi:10.1021/acs.energyfuels.5b00269.
  8. Nadziakiewicza, Małgorzata; Kehoe, Sylvia; Micek, Piotr (23 September 2019). "Physico-Chemical Properties of Clay Minerals and Their Use as a Health Promoting Feed Additive". Animals. 9 (10): 714. doi: 10.3390/ani9100714 . PMC   6827059 . PMID   31548509.
  9. 1 2 3 Nesse 2000, p. 252.
  10. 1 2 3 4 Klein & Hurlbut 1993, p. 522.
  11. Yardley, B. W. D. (1989). An introduction to metamorphic petrology. Harlow, Essex, England: Longman Scientific & Technical. p. 121. ISBN   0582300967.
  12. Yardley 1989, p. 8.
  13. Yardley 1989, p. 50.
  14. Yardley 1989, pp. 64–68.
  15. Wilkinson, Jamie J.; Chang, Zhaoshan; Cooke, David R.; Baker, Michael J.; Wilkinson, Clara C.; Inglis, Shaun; Chen, Huayong; Bruce Gemmell, J. (May 2015). "The chlorite proximitor: A new tool for detecting porphyry ore deposits". Journal of Geochemical Exploration. 152: 10–26. Bibcode:2015JCExp.152...10W. doi: 10.1016/j.gexplo.2015.01.005 . hdl: 10044/1/19967 .
  16. Manthilake, Geeth; Bolfan-Casanova, Nathalie; Novella, Davide; Mookherjee, Mainak; Andrault, Denis (6 May 2016). "Dehydration of chlorite explains anomalously high electrical conductivity in the mantle wedges". Science Advances. 2 (5): e1501631. Bibcode:2016SciA....2E1631M. doi:10.1126/sciadv.1501631. PMC   4928900 . PMID   27386526.
  17. Grove TL, Chatterjee N, Parman SW, et al. (2006). "The influence of H2O on mantle wedge melting". Earth Planet. Sci. Lett. 249 (1–2): 74–89. Bibcode:2006E&PSL.249...74G. doi:10.1016/j.epsl.2006.06.043.
  18. "Seraphinite: Mineral information, data and localities". www.mindat.org. Retrieved 22 Mar 2019.

Further reading