Minnesotaite | |
---|---|
General | |
Category | Silicate mineral |
Formula (repeating unit) | (Fe2+,Mg)3Si4O10(OH)2 |
IMA symbol | Mns [1] |
Strunz classification | 9.EC.05 |
Crystal system | Triclinic |
Crystal class | Pinacoidal (1) (same H-M symbol) |
Space group | P1 |
Unit cell | a = 5.623(2) Å, b = 9.419(2) Å, c = 9.624(3) Å; α = 85.21(3)°, β = 95.64(3)°, γ = 90.00°; Z = 2 |
Identification | |
Color | Greenish gray to olive-green |
Crystal habit | Occurs as microscopic needles or platelets, the needles occur in radiating clusters or in sheaves; also fibrous |
Twinning | Inferred based on X-ray patterns |
Cleavage | Perfect on {001}, micaceous |
Fracture | Uneven and irregular |
Tenacity | Brittle |
Mohs scale hardness | 1.5 - 2 |
Luster | Greasy to waxy, dull |
Diaphaneity | Translucent |
Specific gravity | 3.01 |
Optical properties | Biaxial (-) |
Refractive index | nα = 1.578 - 1.583 nβ = 1.578 - 1.622 nγ = 1.615 - 1.623 |
Birefringence | δ = 0.037 - 0.040 |
Pleochroism | X= pale green, Z= colorless to pale greenish yellow |
2V angle | Measured: 4° |
Dispersion | r < v moderate |
References | [2] [3] [4] |
Minnesotaite is an iron silicate mineral with formula: (Fe2+,Mg)3Si4O10(OH)2. It crystallizes in the triclinic crystal system and occurs as fine needles and platelets with other silicates. [2] It is isostructural with the pyrophyllite-talc mineral group. [3]
Minnesotaite was first described in 1944 for occurrences in the banded iron formations of northern Minnesota for which it was named. Co-type localities are in the Cuyuna North Range, Crow Wing County and the Mesabi Range in St. Louis County. [3] [5]
It occurs associated with quartz, siderite, stilpnomelane, greenalite and magnetite. [2] [6] In addition to the low grade metamorphic banded iron formations it has also been reported as an alteration mineral associated with sulfide bearing veins. [3]
The Mesabi Iron Range is a mining district in northeastern Minnesota following an elongate trend containing large deposits of iron ore. It is the largest of four major iron ranges in the region collectively known as the Iron Range of Minnesota. First described in 1866, it is the chief iron ore mining district in the United States. The district is located largely in Itasca and Saint Louis counties. It has been extensively worked since 1892, and has seen a transition from high-grade direct shipping ores through gravity concentrates to the current industry exclusively producing iron ore (taconite) pellets. Production has been dominantly controlled by vertically integrated steelmakers since 1901, and therefore is dictated largely by US ironmaking capacity and demand.
Taconite is a variety of iron formation, an iron-bearing sedimentary rock, in which the iron minerals are interlayered with quartz, chert, or carbonate. The name "taconyte" was coined by Horace Vaughn Winchell (1865–1923) – son of Newton Horace Winchell, the Minnesota State Geologist – during their pioneering investigations of the Precambrian Biwabik Iron Formation of northeastern Minnesota. He believed the sedimentary rock sequence hosting the iron-formation was correlative with the Taconic orogeny of New England, and referred to the unfamiliar and as-yet-unnamed iron-bearing rock as the 'taconic rock' or taconyte.
The term Iron Range refers collectively or individually to a number of elongated iron-ore mining districts around Lake Superior in the United States and Canada. Much of the ore-bearing region lies alongside the range of granite hills formed by the Giants Range batholith. These cherty iron ore deposits are Precambrian in the Vermilion Range and middle Precambrian in the Mesabi and Cuyuna ranges, all in Minnesota. The Gogebic Range in Wisconsin and the Marquette Iron Range and Menominee Range in Michigan have similar characteristics and are of similar age. Natural ores and concentrates were produced from 1848 until the mid-1950s, when taconites and jaspers were concentrated and pelletized, and started to become the major source of iron production.
Zinnwaldite, KLiFeAl(AlSi3)O10(OH,F)2, potassium lithium iron aluminium silicate hydroxide fluoride is a silicate mineral in the mica group. The IMA status is as a series between siderophyllite (KFe2Al(Al2Si2)O10(F,OH)2) and polylithionite (KLi2AlSi4O10(F,OH)2) and not considered a valid mineral species.
Ankerite is a calcium, iron, magnesium, manganese carbonate mineral of the group of rhombohedral carbonates with the chemical formula Ca(Fe,Mg,Mn)(CO3)2. In composition it is closely related to dolomite, but differs from this in having magnesium replaced by varying amounts of iron(II) and manganese. It forms a series with dolomite and kutnohorite.
Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2(Mg,Fe2+
)
5Si
8O
22(OH)
2, magnesium iron silicate hydroxide.
Pyroxferroite (Fe2+,Ca)SiO3 is a single chain inosilicate. It is mostly composed of iron, silicon and oxygen, with smaller fractions of calcium and several other metals. Together with armalcolite and tranquillityite, it is one of the three minerals which were discovered on the Moon. It was then found in Lunar and Martian meteorites as well as a mineral in the Earth's crust. Pyroxferroite can also be produced by annealing synthetic clinopyroxene at high pressures and temperatures. The mineral is metastable and gradually decomposes at ambient conditions, but this process can take billions of years.
Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2Al
4Si
2O
10(OH)
4. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.
Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).
Siderophyllite is a rare member of the mica group of silicate minerals with formula KFe2+2Al(Al2Si2)O10(F,OH)2.
Stilpnomelane is a phyllosilicate mineral. It has the chemical formula K(Fe2+,Mg,Fe3+)8(Si,Al)12(O,OH)27·n(H2O).
Greenalite is a mineral in the kaolinite-serpentine group with the chemical composition (Fe2+,Fe3+)2-3Si2O5(OH)4. It is a member of the serpentine group.
Ashburtonite is a rare lead copper silicate-bicarbonate mineral with formula: HPb4Cu2+4Si4O12(HCO3)4(OH)4Cl.
Hsianghualite is a tectosilicate of lithium, calcium and beryllium, with fluorine, a member of the zeolite group. It was discovered in 1958 and named for the type locality, Hsiang Hua, 香花, meaning fragrant flower.
Gilalite is a copper silicate mineral with chemical composition of Cu5Si6O17·7(H2O).
Annite is a phyllosilicate mineral in the mica family. It has a chemical formula of KFe32+AlSi3O10(OH)2. Annite is the iron end member of the biotite mica group, the iron rich analogue of magnesium rich phlogopite. Annite is monoclinic and contains tabular crystals and cleavage fragments with pseudohexagonal outlines. There are contact twins with composition surface {001} and twin axis {310}.
Amesite is a mineral with general formula of Mg2Al2SiO5(OH)4.
Lipscombite (Fe2+,Mn2+)(Fe3+)2(PO4)2(OH)2 is a green gray, olive green, or black. phosphate-based mineral containing iron, manganese, and iron phosphate.
Weeksite is a naturally occurring uranium silicate mineral with the chemical formula: K2(UO2)2Si6O15•4(H2O), potassium uranyl silicate. Weeksite has a Mohs hardness of 1-2. It was named for USGS mineralogist Alice Mary Dowse Weeks (1909–1988).
Groutite is a manganese oxide mineral with formula Mn3+O(OH). It is a member of the diaspore group and is trimorphous with manganite and feitknechtite. It forms lustrous black crystals in the orthorhombic system.