Chamosite | |
---|---|
General | |
Category | Phyllosilicate |
Formula (repeating unit) | (Fe2+,Mg)5Al(AlSi3O10)(OH)8 |
IMA symbol | Chm [1] |
Strunz classification | 9.EC.55 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/m |
Unit cell | a = 5.37 Å, b = 9.3 Å, c = 14.22 Å; β = 97.88°; Z = 2 |
Identification | |
Color | Green, grey-green, black |
Mohs scale hardness | 3 |
References | [2] [3] [4] |
Chamosite is the Fe2+end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low to moderate grade of metamorphosed iron deposits, as gray or black crystals in oolitic iron ore. Like other chlorites, it is a product of the hydrothermal alteration of pyroxenes, amphiboles and biotite in igneous rock. The composition of chlorite is often related to that of the original igneous mineral so that more Fe-rich chlorites are commonly found as replacements of the Fe-rich ferromagnesian minerals (Deer et al., 1992).
In 1820, Pierre Bertier; a mineralogist and mining engineer from Nemours, France, discovered chamosite. The new mineral was found in an area of low to moderate grade metamorphosed iron deposit. Early chamosite (which are chlorites) stirred some controversy after they discovered to have possessed the structure of kaolin rather than chlorite. But further research proved that chamosite was largely in existence with another phyllosilicate called berthierine (which has a kaolin type structure) which was rather difficult to distinguish from chamosite. Chamosite is named after the municipality of Chamoson, between Sion and Martigny, the canton of Valais, Switzerland.
X-ray diffraction (XRD) indicates that the proportion of 7 Å B layers in bertherine-chamosite ranges from 5 to 28%, and chemical analysis by scanning electron microscope-energy-dispersive X-ray spectroscopy (SEM-EDS) indicates positive correlation between %B and Fe/(Fe + Mg) (Ryan and Hillier, 2002). The chamosite structure is very similar to typical chlorite in which they are alternated regular layers with tetrahedral and tri-octahedral components (Rivas Sanchez et al., 2006). Its 2:1 layer structure is similar to that of mica, with a basal spacing of 14 Å. (Rivas Sanchez et al., 2006). In most common chlorites, there are 12.0 octahedral cations per O20(OH)16 and approximately equivalent amounts of aluminium in tetrahedral and octahedral sites [e.g. the magnesia chlorite, clinochlore, (Mg10Al2)(Si6Al2O20)(OH)16] (Deer et al., 1992).
Chamosite has a laminar shape, sheets measure from 20 to 200 μm (Rivas Sanchez et al., 2006). Chamosite may be greenish gray or brown in color. The cleavage are length-slow, the orientation may be α ∧ c=small, β=b, γ ∧ α=small, optic plane= [0 10] (Heinrich, 1965) and has good cleavage on the {001} axis. It has a dull luster and grayish-green streak. Birefringence is much lower than that of the micas, illite, montmorillonite and vermiculite, and refractive indices are higher than those of kaolinite (Deer et al. 1992). The chamosite spectra shows the reflection d=7.18 Å (main value of the chlorite) and the reflection d=14.4 Å (that confirms the presence of chlorite) (Rivas Sanchez et al., 2006).
Chamosite is a relatively uncommon mineral in nature. Since its discovery in Chamoson, only about 15 localities around the world are known to be associated with iron deposits. Chamosite may be found in occurrence with other chlorite minerals. In recent years, berthierine; a more abundant chlorite, was discovered in occurrence with chamosite in the iron deposit of Pena Colorada, Mexico. Chamosite is related to the beginning of a hydrothermal phase and occurs mainly in a mineralized breccia type stock-work in which it fills open spaces and replaces the hot rock through fissures (Rivas Sanchez et al., 2006). The Mamu-Nkporo formation in the locality of Okigwe, Nigeria was studied by Akande and Mucke (1993), and they concluded that the carbonate discovered with associated chamosite was formed in a shallow marine subtidal to intertidal environment developed during periods of rise and fall in sea level. Formation of chamosite bearing oolites record periods of increasing wave energy corresponding to storm conditions between quiet shallow marine sedimentation (Akande and Mucke, 1993). Chamosite is a mineral from which elements may be extracted for commercial purpose. Xuanwei City in Yunnan Province has one of the highest lung cancer mortality rates in China (Dai et al., 2008). This epidemic had long been blamed on hydrocarbons released from the burning of coal. Dai et al. (2008) conducted a mineralogical and geochemical study of coal from two coal mines in this region, and identified chamosite as one of the main minerals in the coal. The chamosite was suspected as the main carcinogen for local high lung cancer incidence in Xuanwei.
Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula K(Mg,Fe)3AlSi3O10(F,OH)2. It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more aluminous end-members include siderophyllite and eastonite. Biotite was regarded as a mineral species by the International Mineralogical Association until 1998, when its status was changed to a mineral group. The term biotite is still used to describe unanalysed dark micas in the field. Biotite was named by J.F.L. Hausmann in 1847 in honor of the French physicist Jean-Baptiste Biot, who performed early research into the many optical properties of mica.
Sekaninaite ((Fe+2,Mg)2Al4Si5O18) is a silicate mineral, the iron-rich analogue of cordierite.
Bornite, also known as peacock ore, is a sulfide mineral with chemical composition Cu5FeS4 that crystallizes in the orthorhombic system (pseudo-cubic).
Ullmannite or Nickel glance is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite.
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.
Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic.
Chondrodite is a nesosilicate mineral with formula (Mg,Fe)
5(SiO
4)
2(F,OH,O)
2. Although it is a fairly rare mineral, it is the most frequently encountered member of the humite group of minerals. It is formed in hydrothermal deposits from locally metamorphosed dolomite. It is also found associated with skarn and serpentinite. It was discovered in 1817 at Pargas in Finland, and named from the Greek for "granule", which is a common habit for this mineral.
In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate.
Greigite is an iron sulfide mineral with the chemical formula Fe2+Fe3+2S4. It is the sulfur equivalent of the iron oxide magnetite (Fe3O4). It was first described in 1964 for an occurrence in San Bernardino County, California, and named after the mineralogist and physical chemist Joseph W. Greig (1895–1977).
Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hydrothermal hot springs and scales, soils, and areas affected by mining. It can be precipitated directly from oxygenated iron-rich aqueous solutions, or by bacteria either as a result of a metabolic activity or passive sorption of dissolved iron followed by nucleation reactions. Ferrihydrite also occurs in the core of the ferritin protein from many living organisms, for the purpose of intra-cellular iron storage.
Julgoldite is a member of the pumpellyite mineral series, a series of minerals characterized by the chemical bonding of silica tetrahedra with alkali and transition metal cations. Julgoldites, along with more common minerals like epidote and vesuvianite, belong to the subclass of sorosilicates, the rock-forming minerals that contain SiO4 tetrahedra that share a common oxygen to form Si2O7 ions with a charge of 6− (Deer et al., 1996). Julgoldite has been recognized for its importance in low grade metamorphism, forming under shear stress accompanied by relatively low temperatures (Coombs, 1953). Julgoldite was named in honor of Professor Julian Royce Goldsmith (1918–1999) of the University of Chicago.
Mosesite is a very rare mineral found in few locations. It is a mercury mineral found as an accessory in deposits of mercury, often in conjunction with limestone. It is known to be found in the U.S. states of Texas and Nevada, and the Mexican states of Guerrero and Querétaro. It was named after Professor Alfred J. Moses (1859–1920) for his contributions to the field of mineralogy in discovering several minerals found alongside mosesite. The mineral itself is various shades of yellow and a high occurrence of spinel twinning. It becomes isotropic when heated to 186 °C (367 °F).
Danalite is an iron beryllium silicate sulfide mineral with formula: Fe2+4Be3(SiO4)3S.
Beraunite is an iron phosphate mineral. It was first described by August Breithaupt for an occurrence in Beraun currently in the Czech Republic. Beraunite occurs as a secondary mineral in iron ore deposits, and as an alteration product of primary phosphate minerals in granite pegmatites.
Delafossite is a copper iron oxide mineral with formula CuFeO2 or Cu1+Fe3+O2. It is a member of the delafossite mineral group, which has the general formula ABO2, a group characterized by sheets of linearly coordinated A cations stacked between edge-shared octahedral layers (BO6). Delafossite, along with other minerals of the ABO2 group, is known for its wide range of electrical properties, its conductivity varying from insulating to metallic. Delafossite is usually a secondary mineral that crystallizes in association with oxidized copper and rarely occurs as a primary mineral.
Djerfisherite is an alkali copper–iron sulfide mineral and a member of the djerfisherite group.
Antigorite is a lamellated, monoclinic mineral in the phyllosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentinites. Antigorite, and its serpentine polymorphs, play an important role in subduction zone dynamics due to their relative weakness and high weight percent of water (up to 13 weight % H2O). It is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland and is commonly used as a gemstone in jewelry and carvings.
Fumarole minerals are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes following deposition from volcanic gas during an eruption or discharge from a volcanic vent or fumarole, but have been encountered on burning coal deposits as well. They can be black or multicoloured and are often unstable upon exposure to the atmosphere.