Phlogopite

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Phlogopite
Phlogopite 3.JPG
General
Category Mica, phyllosilicates
Formula
(repeating unit)
KMg3(AlSi3O10)(F,OH)2
IMA symbol Phl [1]
Strunz classification 9.EC.20
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group C2/m
Identification
ColorBrown, brownish red, dark brown, yellow, yellowish brown, green, white and gray
Crystal habit Tabular, scaly masses, rarely perfect phenocryst tablets
Twinning Composition twinning
Cleavage Perfect basal (001)
Fracture None
Tenacity Tough, flexible thin laminae
Mohs scale hardness2–2.5
Luster Pearly, sometimes slightly metallic on cleavage surfaces
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.78–2.85
Optical propertiesBiaxial (−), 2V=12
Refractive index nα = 1.530–1.573 nβ = 1.557–1.617 nγ = 1.558–1.618
Birefringence δ =0.0280–0.0450
2V angle 16–20°
Other characteristicsFluorescent
References [2] [3] [4] [5]

Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.

Contents

Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O10(F,OH)2. Iron substitutes for magnesium in variable amounts leading to the more common biotite with higher iron content. For physical and optical identification, it has most of the characteristic properties of biotite.

Paragenesis

Phlogopite is an important and relatively common end-member composition of biotite. Phlogopite micas are found primarily in igneous rocks, although it is also common in contact metamorphic aureoles of intrusive igneous rocks with magnesian country rocks and in marble formed from impure dolomite (dolomite with some siliclastic sediment).

The occurrence of phlogopite mica within igneous rocks is difficult to constrain precisely because the primary control is rock composition as expected, but phlogopite is also controlled by conditions of crystallisation such as temperature, pressure, and vapor content of the igneous rock. Several igneous associations are noted: high-alumina basalts, ultrapotassic igneous rocks, and ultramafic rocks.

Basaltic association

The basaltic occurrence of phlogopite is in association with picrite basalts and high-alumina basalts. Phlogopite is stable in basaltic compositions at high pressures and is often present as partially resorbed phenocrysts or an accessory phase in basalts generated at depth.

Ultrapotassic association

Phlogopite mica is a commonly known phenocryst and groundmass phase within ultrapotassic igneous rocks such as lamprophyre, kimberlite, lamproite, and other deeply sourced ultramafic or high-magnesian melts. In this association phlogopite can form well preserved megacrystic plates to 10 cm, and is present as the primary groundmass mineral, or in association with pargasite amphibole, olivine, and pyroxene. Phlogopite in this association is a primary igneous mineral present because of the depth of melting and high vapor pressures.

Phlogopite bearing peridotite from Finero, Italy. Coin of 1 Swiss franc (diameter 23 mm) for scale. The phlogopites are the glittering minerals surrounded by the green groundmass of olivine. Phlogopite peridotite.jpg
Phlogopite bearing peridotite from Finero, Italy. Coin of 1 Swiss franc (diameter 23 mm) for scale. The phlogopites are the glittering minerals surrounded by the green groundmass of olivine.

Ultramafic rocks

Phlogopite is often found in association with ultramafic intrusions as a secondary alteration phase within metasomatic margins of large layered intrusions. In some cases the phlogopite is considered to be produced by autogenic alteration during cooling. In other instances, metasomatism has resulted in phlogopite formation within large volumes, as in the ultramafic massif at Finero, Italy, within the Ivrea zone. Trace phlogopite, again considered the result of metasomatism, is common within coarse-grained peridotite xenoliths carried up by kimberlite, and so phlogopite appears to be a common trace mineral in the uppermost part of the Earth's mantle. Phlogopite is encountered as a primary igneous phenocryst within lamproites and lamprophyres, [6] the result of highly fluid-rich melt compositions within the deep mantle.

Uses

As the general thermal, electrical and mechanical properties of phlogopite are those of the mica family, the main uses of phlogopite are similar to these of muscovite.

Miscellaneous

The largest documented single crystal of phlogopite was found in Lacey mine, Ontario, Canada; it measured 10 m × 4.3 m × 4.3 m and weighed about 330 tonnes. [7] Similar-sized crystals were also found in Karelia, Russia. [8]

Related Research Articles

<span class="mw-page-title-main">Biotite</span> Group of phyllosilicate minerals within the mica group

Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula K(Mg,Fe)3AlSi3O10(F,OH)2. It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more aluminous end-members include siderophyllite and eastonite. Biotite was regarded as a mineral species by the International Mineralogical Association until 1998, when its status was changed to a mineral group. The term biotite is still used to describe unanalysed dark micas in the field. Biotite was named by J.F.L. Hausmann in 1847 in honor of the French physicist Jean-Baptiste Biot, who performed early research into the many optical properties of mica.

<span class="mw-page-title-main">Kimberlite</span> Igneous rock which sometimes contains diamonds

Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an 83.5-carat (16.70 g) diamond called the Star of South Africa in 1869 spawned a diamond rush and the digging of the open-pit mine called the Big Hole. Previously, the term kimberlite has been applied to olivine lamproites as Kimberlite II, however this has been in error.

<span class="mw-page-title-main">Amphibolite</span> Metamorphic rock type

Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.

<span class="mw-page-title-main">Volcanic rock</span> Rock formed from lava erupted from a volcano

Volcanic rocks are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "pyroclastics," and these are also technically sedimentary rocks.

<span class="mw-page-title-main">Armalcolite</span> Oxide mineral

Armalcolite is a titanium-rich mineral with the chemical formula (Mg,Fe2+)Ti2O5. It was first found at Tranquility Base on the Moon in 1969 during the Apollo 11 mission, and is named for Armstrong, Aldrin and Collins, the three Apollo 11 astronauts. Together with tranquillityite and pyroxferroite, it is one of three new minerals that were discovered on the Moon. Armalcolite was later identified at various locations on Earth and has been synthesized in the laboratory. (Tranquillityite and pyroxferroite were also later found at various locations on Earth). The synthesis requires low pressures, high temperatures and rapid quenching from about 1,000 °C to the ambient temperature. Armalcolite breaks down to a mixture of magnesium-rich ilmenite and rutile at temperatures below 1,000 °C, but the conversion slows down with cooling. Because of this quenching requirement, armalcolite is relatively rare and is usually found in association with ilmenite and rutile, among other minerals.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Diopside</span> Pyroxene mineral

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Hornfels</span>

Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are caused by fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.

<span class="mw-page-title-main">Ultramafic rock</span> Type of igneous and meta-igneous rock

Ultramafic rocks are igneous and meta-igneous rocks with a very low silica content, generally >18% MgO, high FeO, low potassium, and are composed of usually greater than 90% mafic minerals. The Earth's mantle is composed of ultramafic rocks. Ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as carbonatites and ultrapotassic igneous rocks.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Lamproite</span> Mantle rock expulsed to the surface in volcanic pipes

Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements.

<span class="mw-page-title-main">Komatiite</span> Ultramafic mantle-derived volcanic rock

Komatiite is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% magnesium oxide (MgO). It is classified as a 'picritic rock'. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite was named for its type locality along the Komati River in South Africa, and frequently displays spinifex texture composed of large dendritic plates of olivine and pyroxene.

<span class="mw-page-title-main">Picrite basalt</span> Variety of high-magnesium basalt that is very rich in the mineral olivine

Picrite basalt or picrobasalt is a variety of high-magnesium olivine basalt that is very rich in the mineral olivine. It is dark with yellow-green olivine phenocrysts (20-50%) and black to dark brown pyroxene, mostly augite.

<span class="mw-page-title-main">Cumulate rock</span> Igneous rocks formed by the accumulation of crystals from a magma either by settling or floating.

Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group of igneous rocks. Cumulates can be deposited on top of other older cumulates of different composition and colour, typically giving the cumulate rock a layered or banded appearance.

<span class="mw-page-title-main">Ultrapotassic igneous rocks</span> Class of rare ultramafic or mafic igneous rocks rich in potassium

Ultrapotassic igneous rocks are a class of rare, volumetrically minor, generally ultramafic or mafic silica-depleted igneous rocks.

Normative mineralogy is a calculation of the composition of a rock sample that estimates the idealised mineralogy of a rock based on a quantitative chemical analysis according to the principles of geochemistry.

<span class="mw-page-title-main">Igneous rock</span> Rock formed through the cooling and solidification of magma or lava

Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.

<span class="mw-page-title-main">Navajo volcanic field</span> Volcanic field in southwestern United States

The Navajo volcanic field is a monogenetic volcanic field located in the Four Corners region of the United States, in the central part of the Colorado Plateau. The volcanic field consists of over 80 volcanoes and associated intrusions of unusual potassium-rich compositions, with an age range of 26.2 to 24.7 million years (Ma).

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mineralienatlas
  3. Phlogopite WebMineral
  4. http://rruff.geo.arizona.edu/doclib/hom/phlogopite.pdf Handbook of Mineralogy
  5. http://www.mindat.org/min-3193.html Mindat
  6. Kresten, Peter; Troll, Valentin R. (2018). The Alnö Carbonatite Complex, Central Sweden. GeoGuide. Springer International Publishing. ISBN   978-3-319-90223-4.
  7. P. C. Rickwood (1981). "The largest crystals" (PDF). American Mineralogist. 66: 885–907.
  8. "The giant crystal project site". Archived from the original on 2009-06-04. Retrieved 2009-06-06.

Further reading