Antigorite

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Antigorite
Antigorite from Poland.jpg
Antigorite crystals in serpentinite from Poland
General
Category Phyllosilicate
Serpentine-Kaolinite group
Formula
(repeating unit)
(Mg, Fe)3Si2O5OH4
IMA symbol Atg [1]
Strunz classification 9.ED.15
Crystal system Monoclinic
Identification
ColorGreen, yellowish-green, blueish-gray
Crystal habit Massive or platy
Cleavage (001) Perfect
Fracture Brittle
Mohs scale hardness3.5–4
Luster Vitreous to greasy
Streak Greenish white
Specific gravity 2.5–2.6
Optical propertiesBiaxial (−)
Refractive index 1.53–1.575
Birefringence δ = 0.005–0.006

Antigorite is a lamellated, monoclinic mineral in the phyllosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. [2] It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentinites. Antigorite, and its serpentine polymorphs, play an important role in subduction zone dynamics due to their relative weakness and high weight percent of water (up to 13 weight % H2O). [3] [4] It is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland [5] and is commonly used as a gemstone in jewelry and carvings.

Contents

Geologic occurrences

Antigorite is found in low-temperature, high-pressure (or high-deformation) environments, including both extensional and compressional tectonic regimes. [6] Serpentines are commonly found in the ultramafic greenschist facies of subduction zones, and are visible on the Earth's surface through secondary exhumation. Serpentinites that contain antigorite are usually highly deformed and show distinct textures, indicative of the dynamic region where they were formed. Antigorite serpentinites commonly have associated minerals of magnetite, chlorite, and carbonates. [7] Olivine under hydrothermal action, low grade metamorphism and weathering will transform into antigorite, which is often associate with talc and carbonate.

Olivine 3Mg2SiO4 + 4H2O + SiO2 Serpentine 2Mg3Si2O5(OH)4
Serpentine 2Mg3Si2O5(OH)4 + 3CO2 Talc Mg3Si4O10(OH)2 + Magnesite 3MgCO3 + 3H2O [8]

Physical properties

Lamellated antigorite occurs in tough, pleated masses. It is usually dark green in color, but may also be yellowish, gray, brown or black. It has a Mohs scale hardness of 3.5–4 and its lustre is vitreous to greasy. [9] Antigorite has a specific gravity of 2.5–2.6. The monoclinic crystals show micaceous cleavage, a distinguished property of phyllosilicates, and fuse with difficulty. [10] Serpentinite rocks that consist of mostly antigorite are commonly mylonites. The antigorite grains that make up these rocks are very fine (on the order of 1 to 10 microns) and are fibrous, which defines a texture in the rock caused by lattice preferred orientation. [11]

Gemstone properties

Polished antigorite 1 kula serpentynit antygorytowy.jpg
Polished antigorite

Antigorite is used as gemstones or for carvings when it appears pure and translucent, although many crystals have black specks of magnetite suspended within. The gem types of antigorite are Bowenite and Williamsite. Bowenite, known for George T. Bowen from Rhode Island (the variety's type locality), who first analyzed the mineral, is translucent and light to dark green, often mottled with cloudy white patches and darker veining. It is the serpentine most frequently encountered in carving and jewelry, and is the state mineral of Rhode Island, United States. A bowenite cabochon featured as part of the "Our Mineral Heritage Brooch", was presented to U.S. First Lady Mrs. Lady Bird Johnson in 1967. Williamsite is very translucent and has a medium to deep apple-green color. Somewhat resembling jade, Williamsite is often cut into cabochons and beads.

Crystal structure

Simplified crystal structure of antigorite looking down the b axis. Blue triangles indicate SiO4 tetrahedra, green layers indicate Mg octahedra. Red line indicates polarity reversal. In this case, m = 17. Simple Antigorite Structure.jpg
Simplified crystal structure of antigorite looking down the b axis. Blue triangles indicate SiO4 tetrahedra, green layers indicate Mg octahedra. Red line indicates polarity reversal. In this case, m = 17.

The magnesian serpentines (antigorite, lizardite, chrysotile) are trioctahedral hydrous phyllosilicates. Their structure is based on 1:1 octahedral-tetrahedral layer structures. Antigorite is monoclinic in the space group Pm. [13] Although the magnesian serpentines have similar compositions, they have significantly different crystallographic structures, which are dependent on how the SiO4 tetrahedra sheets fit in with the octahedral sheets. [14] Antigorite's basic composition has a smaller ratio of octahedral to tetrahedral cations (relative to lizardite and chrysotile), [15] allowing the structure to compensate for the misfit of sheets through periodic flipping of the curved tetrahedra layers, and subsequently their polarity. [16] Polysomes of antigorite are defined by the number of individual tetrahedra (denoted as the value m) which span a wavelength of the direction of curvature. [17] The sheets of tetrahedra allow the platy, fibrous crystals to separate parallel to the 001 (basal) plane, giving antigorite its perfect cleavage.

See also

Related Research Articles

<span class="mw-page-title-main">Biotite</span> Group of phyllosilicate minerals within the mica group

Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula K(Mg,Fe)3AlSi3O10(F,OH)2. It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more aluminous end-members include siderophyllite and eastonite. Biotite was regarded as a mineral species by the International Mineralogical Association until 1998, when its status was changed to a mineral group. The term biotite is still used to describe unanalysed dark micas in the field. Biotite was named by J.F.L. Hausmann in 1847 in honor of the French physicist Jean-Baptiste Biot, who performed early research into the many optical properties of mica.

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Muscovite</span> Hydrated phyllosilicate mineral

Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 meters × 3 meters (16.5 feet × 10 feet) have been found in Nellore, India.

<span class="mw-page-title-main">Serpentine subgroup</span> Group of phyllosilicate minerals

Serpentine subgroup are greenish, brownish, or spotted minerals commonly found in serpentinite. They are used as a source of magnesium and asbestos, and as decorative stone. The name comes from the greenish color and smooth or scaly appearance from the Latin serpentinus, meaning "serpent rock".

<span class="mw-page-title-main">Chrysotile</span> The most commonly encountered form of asbestos

Chrysotile or white asbestos is the most commonly encountered form of asbestos, accounting for approximately 95% of the asbestos in the United States and a similar proportion in other countries. It is a soft, fibrous silicate mineral in the serpentine subgroup of phyllosilicates; as such, it is distinct from other asbestiform minerals in the amphibole group. Its idealized chemical formula is Mg3(Si2O5)(OH)4. The material has physical properties which make it desirable for inclusion in building materials, but poses serious health risks when dispersed into air and inhaled.

<span class="mw-page-title-main">Garnierite</span> Nickel layer silicate

Garnierite is a general name for a green nickel ore which is found in pockets and veins within weathered and serpentinized ultramafic rocks. It forms by lateritic weathering of ultramafic rocks and occurs in many nickel laterite deposits in the world. It is an important nickel ore, having a large weight percent NiO. As garnierite is not a valid mineral name according to the Commission on New Minerals, Nomenclature and Classification (CNMNC), no definite composition or formula has been universally adopted. Some of the proposed compositions are all hydrous Ni-Mg silicates, a general name for the Ni-Mg hydrosilicates which usually occur as an intimate mixture and commonly includes two or more of the following minerals: serpentine, talc, sepiolite, smectite, or chlorite, and Ni-Mg silicates, with or without alumina, that have x-ray diffraction patterns typical of serpentine, talc, sepiolite, chlorite, vermiculite or some mixture of them all.

<span class="mw-page-title-main">Jadeite</span> Pyroxene mineral

Jadeite is a pyroxene mineral with composition NaAlSi2O6. It is hard (Mohs hardness of about 6.5 to 7.0), very tough, and dense, with a specific gravity of about 3.4. It is found in a wide range of colors, but is most often found in shades of green or white. Jadeite is formed only in the subduction zones of continental margins, where rock undergoes metamorphism at high pressure but relatively low temperature.

<span class="mw-page-title-main">Diopside</span> Pyroxene mineral

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

<span class="mw-page-title-main">Brazilianite</span> Yellow-green phosphate mineral

Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.

<span class="mw-page-title-main">Serpentinite</span> Rock formed by hydration and metamorphic transformation of olivine

Serpentinite is a metamorphic rock composed predominantly of one or more serpentine group minerals formed by near to complete serpentinization of mafic to ultramafic rocks. Its name originated from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called serpentine or serpentine rock, particularly in older geological texts and in wider cultural settings.

<span class="mw-page-title-main">Serpentinization</span> Formation of serpentinite by hydration and metamorphic transformation of olivine

Serpentinization is a hydration and metamorphic transformation of ferromagnesian minerals, such as olivine and pyroxene, in mafic and ultramafic rock to produce serpentinite. Minerals formed by serpentinization include the serpentine group minerals, brucite, talc, Ni-Fe alloys, and magnetite. The mineral alteration is particularly important at the sea floor at tectonic plate boundaries.

<span class="mw-page-title-main">Lawsonite</span>

Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to translucent colorless, white, pink, and bluish to pinkish grey glassy to greasy crystals. Refractive indices are nα = 1.665, nβ = 1.672 – 1.676, and nγ = 1.684 – 1.686. It is typically almost colorless in thin section, but some lawsonite is pleochroic from colorless to pale yellow to pale blue, depending on orientation. The mineral has a Mohs hardness of 7.5 and a specific gravity of 3.09. It has perfect cleavage in two directions and a brittle fracture. Not to be confused with Larsonite, a fossiliferous jasper mined in Nevada.

<span class="mw-page-title-main">Wadsleyite</span> Mineral thought to be abundant in the Earths mantle

Wadsleyite is an orthorhombic mineral with the formula β-(Mg,Fe)2SiO4. It was first found in nature in the Peace River meteorite from Alberta, Canada. It is formed by a phase transformation from olivine (α-(Mg,Fe)2SiO4) under increasing pressure and eventually transforms into spinel-structured ringwoodite (γ-(Mg,Fe)2SiO4) as pressure increases further. The structure can take up a limited amount of other bivalent cations instead of magnesium, but contrary to the α and γ structures, a β structure with the sum formula Fe2SiO4 is not thermodynamically stable. Its cell parameters are approximately a = 5.7 Å, b = 11.71 Å and c = 8.24 Å.

<span class="mw-page-title-main">Balangeroite</span>

Balangeroite is found in one of the most important chrysotile mines in Europe, the Balangero Serpentinite. Hence, it is usually mistaken as an asbestiform in an assemblage of other mineral phases like chrysotile, magnetite and Fe-Ni alloys. However, Balangeroite does not lead to serious health problems caused by asbestos fibers.

<span class="mw-page-title-main">Pimelite</span> Nickel-rich smectite deprecated as mineral species in 2006

Pimelite was discredited as a mineral species by the International Mineralogical Association (IMA) in 2006, in an article which suggests that "pimelite" specimens are probably willemseite, or kerolite. This was a mass discreditation, and not based on any re-examination of the type material. Nevertheless, a considerable number of papers have been written, verifying that pimelite is a nickel-dominant smectite. It is always possible to redefine a mineral wrongly discredited.

<span class="mw-page-title-main">Subduction zone metamorphism</span> Changes of rock due to pressure and heat near a subduction zone

A subduction zone is a region of the Earth's crust where one tectonic plate moves under another tectonic plate; oceanic crust gets recycled back into the mantle and continental crust gets produced by the formation of arc magmas. Arc magmas account for more than 20% of terrestrially produced magmas and are produced by the dehydration of minerals within the subducting slab as it descends into the mantle and are accreted onto the base of the overriding continental plate. Subduction zones host a unique variety of rock types formed by the high-pressure, low-temperature conditions a subducting slab encounters during its descent. The metamorphic conditions the slab passes through in this process generates and alters water bearing (hydrous) mineral phases, releasing water into the mantle. This water lowers the melting point of mantle rock, initiating melting. Understanding the timing and conditions in which these dehydration reactions occur, is key to interpreting mantle melting, volcanic arc magmatism, and the formation of continental crust.

<span class="mw-page-title-main">Waterhouseite</span> Hydroxy manganese phosphate mineral

Waterhouseite, Mn7(PO4)2(OH)8, is a hydroxy manganese phosphate mineral. It is a medium-soft, brittle mineral occurring in pseudo-orthorhombic monoclinic bladed crystals and orange-brown to dark brown in color. Waterhouseite is on the softer side with a Mohs hardness of 4, has a specific gravity of 3.5 and a yellowish-brown streak. It is named after Frederick George Waterhouse, first director of the South Australian Museum, as well as recognizes the work Waterhouse Club has done in support of the South Australian Museum.

<span class="mw-page-title-main">Lizardite</span> Magnesium phyllosilicate mineral of the serpentine group

Lizardite is a mineral from the serpentine subgroup with formula Mg3(Si2O5)(OH)4, and the most common type of mineral in the subgroup. It is also a member of the kaolinite-serpentine group.

<span class="mw-page-title-main">Taiwan Black Jade</span> Type of serpentine jade

Taiwan Black Jade is a type of serpentine jade, primarily composed of minerals such as antigorite and magnetite. It exhibits colors ranging from dark green to black. It is found in the Fengtian area of Hualien County, Taiwan. It was discovered during the mining of Taiwan Jade in the 1960s and 1970s but was not at that time recognized as a new variety of mineral. In the 2010s researchers conducted studies and analysis that identified it as a new type of serpentine jade.

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