Serpentine subgroup

Last updated
Serpentine
Talk on Serpentine.jpg
General
Category Phyllosilicates
Formula
(repeating unit)
X3Si2O5(OH)4,
with X = Mg2+, Fe2+, Ni2+, Mn2+, Zn2+
IMA symbol Srp
Crystal system Monoclinic
Identification
ColorGreen, yellowish-green, blueish-gray (antigorite)
Green, brown, light yellow to white (lizardite)
Greyish green to white (chrysotile)
Cleavage Almost perfect
Fracture Brittle
Mohs scale hardness2.5–6 (original) 3.5–4.0 (antigorite)
2.5 (lizardite)
2.5–3.0 (chrysotile)
Luster Vitreous, silky, greasy, waxy
Streak White,greenish-white
Specific gravity 2.2–2.9
Optical propertiesBiaxial (–)
Refractive index 1.538–1.57 (Tolerance:0.004/–0.07)
Birefringence 0.005–0.012
Ultraviolet fluorescence SWUV: inert to weak blue; LWUV: inert to weak green
Diagnostic featuresColor, cleavage
References [1] [2] [3] [4]
Serpentine from Poland Serpentyn, 2Polska.jpg
Serpentine from Poland

Serpentine subgroup (part of the kaolinite-serpentine group in the category of phyllosilicates) [1] are greenish, brownish, or spotted minerals commonly found in serpentinite. They are used as a source of magnesium and asbestos, and as decorative stone. [5] The name comes from the greenish color and smooth or scaly appearance from the Latin serpentinus, meaning "serpent rock". [6]

Contents

Serpentine subgroup is a set of common rock-forming hydrous magnesium iron phyllosilicate ((Mg,Fe)
3
Si
2
O
5
(OH)
4
) minerals, resulting from the metamorphism of the minerals that are contained in mafic to ultramafic rocks. [7] They may contain minor amounts of other elements including chromium, manganese, cobalt or nickel. In mineralogy and gemology, serpentine may refer to any of the 20 varieties belonging to the serpentine subgroup. Owing to admixture, these varieties are not always easy to individualize, and distinctions are not usually made. There are three important mineral polymorphs of serpentine: antigorite, lizardite and chrysotile.

Serpentine minerals are polymorphous, meaning that they have the same chemical formulae, but the atoms are arranged into different structures, or crystal lattices. [8] Chrysotile, which has a fibrous habit, is one polymorph of serpentine and is one of the more important asbestos minerals. Other polymorphs in the serpentine subgroup may have a platy habit. Antigorite and lizardite are the polymorphs with platy habit.

Many types of serpentine have been used for jewelry and hardstone carving, sometimes under the name "false jade" or "Teton jade". [9] [10]

Properties and structure

Serpentine chemical structure, single molecule Serpetine chemical structure.png
Serpentine chemical structure, single molecule

Most serpentines are opaque to translucent, light (specific gravity between 2.2 and 2.9), soft (hardness 2.5–4), infusible and susceptible to acids. [1] All are microcrystalline and massive in habit, never being found as single crystals. Lustre may be vitreous, silky or greasy. Colors range from white to grey, yellow to green, and brown to black, and are often splotchy or veined. Many are intergrown with other minerals, such as calcite and dolomite.

The basic structural unit of serpentine is a polar layer 0.72 nm thick. A Mg-rich trioctahedral sheet is tightly linked on one side to a single tetrahedral silicate sheet, regardless of the 3–5% larger lateral lattice dimensions of the octahedral sheet. [11] The second level of the structure organized into different serpentine species originates partly to compensate the intra-layer stress due to this dimensional misfit. Good compensation results in a nearly constant layer curvature, with the larger octahedral sheet on the convex side. However, such curvature weakens the H-bonding between the layers. H-bonding tries to maintain flat layers, but this competes with the requirements of misfit compensation. As a result, the layers are locally either curved or flat. [12] Antigorite, lizardite and chrysotile have the same chemical composition, but their different layer of curvatures result in lamellar agglomerated antigorite and lizardite and fibrous chrysotile elongated mineral particles. [13] [14]

Occurrence

Serpentine minerals are ubiquitous in many geological systems where hydrothermal alteration of ultramafic rocks is possible, in both terrestrial (oceanic hydrothermalism, subduction zones and transform faulting) and extraterrestrial environments. [15] The process of alteration from mafic minerals to serpentine group minerals is called serpentinization. Serpentine minerals are often formed by the hydration of olivine-rich ultramafic rocks at relatively low temperatures (0 to ~600 °C). [16] The chemical reaction turns olivine into serpentine minerals. They may also have their origins in metamorphic alterations of peridotite and pyroxene. Serpentines may also pseudomorphously replace other magnesium silicates. Incomplete alteration causes the physical properties of serpentines to vary widely.

Antigorite is the polymorph of serpentine that most commonly forms during metamorphism of wet ultramafic rocks and is stable at the highest temperatures—to over 600 °C (1,100 °F) at depths of 60 km (37 mi) or so. In contrast, lizardite and chrysotile typically form near the Earth's surface and break down at relatively low temperatures, probably well below 400 °C (800 °F). It has been suggested that chrysotile is never stable relative to either of the other two serpentine polymorphs.

Samples of the oceanic crust and uppermost mantle from ocean basins document that ultramafic rocks there commonly contain abundant serpentine. Antigorite contains water in its structure, about 13 percent by weight. Hence, antigorite may play an important role in the transport of water into the earth in subduction zones and in the subsequent release of water to create magmas in island arcs, and some of the water may be carried to yet greater depths.

Occurrence is worldwide, notable localities include New Caledonia, Canada (Quebec), US (northern California, Rhode Island, Connecticut, Massachusetts, Maryland and southern Pennsylvania), [17] Afghanistan, Britain (the Lizard peninsula in Cornwall), Ireland, Greece (Thessaly), China, Russia (Ural Mountains), France, Korea, Austria (Styria and Carinthia), India (Assam, and Manipur), Myanmar (Burma), New Zealand, Norway and Italy.

Uses

Dish of serpentine with inlaid gold fish, 1st century BC to 1st century AD, with 9th-century mounts Serpentine paten Louvre MR415.jpg
Dish of serpentine with inlaid gold fish, 1st century BC to 1st century AD, with 9th-century mounts
Budai carved from serpentine, height 8 cm (3.1 in) Budai in serpentine, height 8 cm arp.jpg
Budai carved from serpentine, height 8 cm (3.1 in)

Serpentines find use in industry for several purposes, such as railway ballasts, building materials, and the asbestiform types find use as thermal and electrical insulation (chrysotile asbestos). The asbestos content can be released into the air when serpentine is excavated and if it is used as a road surface, forming a long-term health hazard by breathing. Asbestos from serpentine can also appear at low levels in water supplies through normal weathering processes, but there is as yet no fully proven health hazard associated with use or ingestion, although the EPA states an increased risk of developing benign intestinal polyps can occur. [18] In its natural state, some forms of serpentine react with carbon dioxide and re-release oxygen into the atmosphere.

The more attractive and durable varieties (all of the antigorite) are termed "noble" or "precious" serpentine and are used extensively as gems and in ornamental carvings. The town of Bhera in the historic Punjab province of the Indian subcontinent was known for centuries for finishing a relatively pure form of green serpentine obtained from quarries in Afghanistan into lapidary work, cups, ornamental sword hilts, and dagger handles. [10] This high-grade serpentine ore was known as sang-i-yashm in Persian, or 'false jade' in English, and was used for generations by Indian craftsmen for lapidary work. [10] [19] It is easily carved, taking a good polish, and is said to have a pleasingly greasy feel. [20] Less valuable serpentine ores of varying hardness and clarity are also sometimes dyed to imitate jade. [20] Misleading synonyms for this material include "Suzhou jade", "Styrian jade", and "New jade".

New Caledonian serpentine is particularly rich in nickel. The Māori of New Zealand once carved beautiful objects from local serpentine, which they called tangiwai, meaning "tears".

The lapis atracius of the Romans, now known as verde antique, or verde antic, is a serpentinite breccia popular as a decorative facing stone. In classical times it was mined at Casambala, Thessaly, Greece. Serpentinite marbles are also widely used: Green Connemara marble (or 'Irish green marble') from Connemara, Ireland (and many other sources[ citation needed ]), and red Rosso di Levanto marble from Italy. Use is limited to indoor settings as serpentinites do not weather well.

Potential harm

Soils derived from serpentine are toxic to many plants, because of high levels of nickel, chromium, and cobalt; growth of many plants is also inhibited by low levels of potassium and phosphorus and a low ratio of calcium/magnesium. The flora is generally very distinctive, with specialized, slow-growing species. Areas of serpentine-derived soil will show as strips of shrubland and open, scattered small trees (often conifers) within otherwise forested areas; these areas are called serpentine barrens.

Antigorite variety

Bowenite from Asbestos mine, Thurman Township, Warren County, New York, US Antigorite (Var. Bowenite).jpg
Bowenite from Asbestos mine, Thurman Township, Warren County, New York, US

Lamellated antigorite occurs in tough, pleated masses. It is usually dark green, but may also be yellowish, gray, brown or black. It has a hardness of 3.5–4 and its luster is greasy. The monoclinic crystals show micaceous cleavage and fuse with difficulty. Antigorite is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland.

Bowenite

Bowenite, a variety of antigorite, is an especially hard serpentine (5.5) of light to dark apple green color, often mottled with cloudy white patches and darker veining. It is the serpentine most frequently encountered in carving and jewelry. The name 'retinalite' is sometimes applied to yellow bowenite. The New Zealand material is called tangiwai.

Although not an official species, bowenite is the state mineral of Rhode Island, United States: this is also the variety's type locality. A bowenite cabochon featured as part of the "Our Mineral Heritage Brooch", was presented to U.S. First Lady Mrs. Lady Bird Johnson in 1967.

Williamsite is an American local varietal name for antigorite that is oil-green with black crystals of chromite or magnetite often included. Somewhat resembling fine jade, williamsite is cut into cabochons and beads. It is found mainly in Maryland and Pennsylvania. [21]

Gymnite

Gymnite is an amorphous form of antigorite. [22] It was originally found in the Bare Hills of Maryland, and is named from the Greek, 'gymnos', meaning "bare" or "naked".

State emblem

In 1965, the California Legislature designated the mineral serpentine as "the official State Rock and lithologic emblem". [23]

Related Research Articles

<span class="mw-page-title-main">Talc</span> Hydrated magnesium phyllosilicate mineral

Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant. It is an ingredient in ceramics, paints, and roofing material. It is a main ingredient in many cosmetics. It occurs as foliated to fibrous masses, and in an exceptionally rare crystal form. It has a perfect basal cleavage and an uneven flat fracture, and it is foliated with a two-dimensional platy form.

<span class="mw-page-title-main">Chrysotile</span> The most commonly encountered form of asbestos

Chrysotile or white asbestos is the most commonly encountered form of asbestos, accounting for approximately 95% of the asbestos in the United States and a similar proportion in other countries. It is a soft, fibrous silicate mineral in the serpentine subgroup of phyllosilicates; as such, it is distinct from other asbestiform minerals in the amphibole group. Its idealized chemical formula is Mg3(Si2O5)(OH)4. The material has physical properties which make it desirable for inclusion in building materials, but poses serious health risks when dispersed into air and inhaled.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Garnierite</span> Nickel layer silicate

Garnierite is a general name for a green nickel ore which is found in pockets and veins within weathered and serpentinized ultramafic rocks. It forms by lateritic weathering of ultramafic rocks and occurs in many nickel laterite deposits in the world. It is an important nickel ore, having a large weight percent NiO. As garnierite is not a valid mineral name according to the Commission on New Minerals, Nomenclature and Classification (CNMNC), no definite composition or formula has been universally adopted. Some of the proposed compositions are all hydrous Ni-Mg silicates, a general name for the Ni-Mg hydrosilicates which usually occur as an intimate mixture and commonly includes two or more of the following minerals: serpentine, talc, sepiolite, smectite, or chlorite, and Ni-Mg silicates, with or without alumina, that have x-ray diffraction patterns typical of serpentine, talc, sepiolite, chlorite, vermiculite or some mixture of them all.

<span class="mw-page-title-main">Tremolite</span> Amphibole, double chain inosilicate mineral

Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro-actinolite. Pure magnesium tremolite is creamy white, but the color grades to dark green with increasing iron content. It has a hardness on Mohs scale of 5 to 6. Nephrite, one of the two minerals known as the gemstone jade, is a green variety of tremolite.

<span class="mw-page-title-main">Diopside</span> Pyroxene mineral

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

<span class="mw-page-title-main">Serpentinite</span> Rock formed by hydration and metamorphic transformation of olivine

Serpentinite is a metamorphic rock composed predominantly of one or more serpentine group minerals formed by near to complete serpentinization of mafic to ultramafic rocks. Its name originated from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called serpentine or serpentine rock, particularly in older geological texts and in wider cultural settings.

<span class="mw-page-title-main">Serpentinization</span> Formation of serpentinite by hydration and metamorphic transformation of olivine

Serpentinization is a hydration and metamorphic transformation of ferromagnesian minerals, such as olivine and pyroxene, in mafic and ultramafic rock to produce serpentinite. Minerals formed by serpentinization include the serpentine group minerals, brucite, talc, Ni-Fe alloys, and magnetite. The mineral alteration is particularly important at the sea floor at tectonic plate boundaries.

<span class="mw-page-title-main">Anthophyllite</span> Silicate amphibole mineral

Anthophyllite is an orthorhombic amphibole mineral: ☐Mg2Mg5Si8O22(OH)2 (☐ is for a vacancy, a point defect in the crystal structure), magnesium iron inosilicate hydroxide. Anthophyllite is polymorphic with cummingtonite. Some forms of anthophyllite are lamellar or fibrous and are classed as asbestos. The name is derived from the Latin word anthophyllum, meaning clove, an allusion to the most common color of the mineral. The Anthophyllite crystal is characterized by its perfect cleavage along directions 126 degrees and 54 degrees.

<span class="mw-page-title-main">Serpentine soil</span> Soil type

Serpentine soil is an uncommon soil type produced by weathered ultramafic rock such as peridotite and its metamorphic derivatives such as serpentinite. More precisely, serpentine soil contains minerals of the serpentine subgroup, especially antigorite, lizardite, and chrysotile or white asbestos, all of which are commonly found in ultramafic rocks. The term "serpentine" is commonly used to refer to both the soil type and the mineral group which forms its parent materials.

Talc carbonates are a suite of rock and mineral compositions found in metamorphosed ultramafic rocks.

<span class="mw-page-title-main">Heazlewoodite</span>

Heazlewoodite, Ni3S2, is a rare sulfur-poor nickel sulfide mineral found in serpentinitized dunite. It occurs as disseminations and masses of opaque, metallic light bronze to brassy yellow grains which crystallize in the trigonal crystal system. It has a hardness of 4, a specific gravity of 5.82. Heazlewoodite was first described in 1896 from Heazlewood, Tasmania, Australia.

<span class="mw-page-title-main">Balangeroite</span>

Balangeroite is found in one of the most important chrysotile mines in Europe, the Balangero Serpentinite. Hence, it is usually mistaken as an asbestiform in an assemblage of other mineral phases like chrysotile, magnetite and Fe-Ni alloys. However, Balangeroite does not lead to serious health problems caused by asbestos fibers.

The Merlis Serpentinites are an aligned group of small serpentinite outcrops in the northwestern French Massif Central. Their parent rocks were peridotites from the upper mantle.

The Coal Creek Serpentinite(Coal Creek Serpentine) is a name for a Precambrian rock formation that outcrops on the southeastern side of the Llano Uplift in Gillespie and Blanco counties, Texas. The Coal Creek Serpentinite is tabular south-dipping body of serpentinite. Its outcrop is about 3.7 mi (6.0 km) long along an east–west axis and varies in width from 0.3 to 1.4 mi (0.48 to 2.25 km). Along the central part of the body, the southern contact of the serpentinite slopes about 60° to the south and gradually decreases in dip to about 40° further west. The southern and northern contacts are shear zones. The serpentinite underlies a very sparsely vegetated east–west trending ridge.

The Staten Island Serpentinite locality is a southward extension of the New England Uplands, adjacent to the Manhattan Prong. It includes Todt Hill on Staten Island, which is the highest point along the Atlantic Seaboard south of Maine, at 410 feet (120 m) above sea level. "Todt" is a Dutch word meaning "dead." This hill perhaps received its name from the Dutch settlers because the hilltops overlooking The Narrows consisted of scattered treeless rocky exposures. The chemical character of the bedrock was, in part, the reason for this. Much of Staten Island is covered by the Harbor Hill moraine, the terminal moraine of the last Wisconsin Stage glacier. However, ledges of bedrock consisting of serpentinite are exposed throughout the upland areas on Staten Island. Grymes Hill, the second highest point on Staten Island and just a few miles from Todt Hill has similar bedrock characteristics. Serpentine, the dominant mineral in serpentinite, is rich in magnesium, an element that most plants cannot tolerate in high concentrations. The enrichment of magnesium in the thin serpentine soil covering the glacier-scoured hilltops is probably responsible for the original barren exposures on Todt Hill.

Antigorite Monoclinic mineral

Antigorite is a lamellated, monoclinic mineral in the phyllosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentinites. Antigorite, and its serpentine polymorphs, play an important role in subduction zone dynamics due to their relative weakness and high weight percent of water (up to 13 weight % H2O). It is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland and is commonly used as a gemstone in jewelry and carvings.

<span class="mw-page-title-main">Lizardite</span> Magnesium phyllosilicate mineral of the serpentine group

Lizardite is a mineral from the serpentine subgroup with formula Mg3(Si2O5)(OH)4, and the most common type of mineral in the subgroup. It is also a member of the kaolinite-serpentine group.

<span class="mw-page-title-main">Taiwan Black Jade</span> Type of serpentine jade

Taiwan Black Jade is a type of serpentine jade, primarily composed of minerals such as antigorite and magnetite. It exhibits colors ranging from dark green to black. It is found in the Fengtian area of Hualien County, Taiwan. It was discovered during the mining of Taiwan Jade in the 1960s and 1970s but was not at that time recognized as a new variety of mineral. In the 2010s researchers conducted studies and analysis that identified it as a new type of serpentine jade.

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