Sudoite | |
---|---|
General | |
Category | Chlorite_group |
Formula (repeating unit) | Mg2Al3(Si3Al)O10(OH)8 |
Crystal system | Monoclinic |
Identification | |
Color | White to light green |
Mohs scale hardness | 2.5–3.5 |
Luster | pearly, dull |
Refractive index | nα = 1.581 à 1.583 nβ = 1.584 à 1.589 nγ = 1.591 à 1.601 |
Birefringence | biaxial (-) ; δ = 0.010 to 0.018 2V = 64 to 70° (measured) 2V = 68 to 72° (calculated) |
References | [1] [2] |
Sudoite is a mineral from the chlorite group. It was named after Toshio Sudo (1911-2000), professor of mineralogy at the University of Tokyo, in Japan, and a pioneer of clay science. [3] The mineral tosudite also bears his name. It was approved as a valid species by the International Mineralogical Association in 1966.
Sudoite is a clay mineral with chemical formula defined as Mg2Al3(Si3Al)O10(OH)8. It has a monoclinic crystal system. Its hardness on the Mohs scale is between 2.5 and 3.5.
Following the Nickel–Strunz classification, it is contained in the "09.EC.55" group:
Mineral | Formula | Symmetry group | Space group |
---|---|---|---|
Baileychlore | (Zn,Al) 3[Fe 2Al][Si 3AlO 10](OH) 8 | 1 or 1 | C1 or C1 |
Borocookeite | Li 1+3xAl 4-x(BSi 3)O 10(OH,F) 8 (x ≤ 0,33) | 2/m | C2/m |
Chamosite | (Fe,Mg,Fe) 5Al(Si 3Al)O 10(OH,O) 8 | 2/m | C2/m |
Clinochlore | (Mg,Fe) 5Al(Si 3Al)O 10(OH) 8 | 2/m | C2/m |
Cookeite | LiAl 4(Si 3Al)O 10(OH) 8 | 1, 2 or 2/m | C1, C2 or Cc |
Donbassite | Al 2[Al 2,33][Si 3AlO 10](OH) 8 | 2/m | C2/m |
Franklinfurnaceite | Ca(Fe,Al)Mn 4Zn 2Si 2O 10(OH) 8 | 2 | C2 |
Glagolevite | NaMg 6[Si 3AlO 10](OH,O) 8·H 2O | 1 | C1 |
Gonyerite | Mn 3[Mn 3Fe][(Si,Fe) 4O 10](OH,O) 8 | unknown | |
Nimite | (Ni,Mg,Fe) 5Al(Si 3Al)O 10(OH) 8 | 2/m | C2/m |
Odinite | (Fe,Mg,Al,Fe,Ti,Mn) 2,5(Si,Al) 2O 5(OH) 4 | m | Cm |
Orthochamosite | (Fe,Mg,Fe) 5Al(Si 3Al)O 10(OH,O) 8 | unknown | |
Pennantite | Mn 5Al(Si 3Al)O 10(OH) 8 | 2/m | C2/m |
Sudoite | Mg 2(Al,Fe) 3Si 3AlO 10(OH) 8 | 2/m | C2/m |
It has been first discovered in the Knollenberg Keuper formation, in the village of Plochingen, Stuttgart Region (Baden-Württemberg, Germany). [4] Despite being an unlikely mineral, it has been described in every continent but Antarctica and Oceania. It is found mainly in hydrothermal or high-pressure/low-temperature (HP/LT) metamorphism contexts [5] [6] [7]
This mineral has been used as gemstone for the production of personal ornaments, beads and pendants, during the Early Ceramic Age (500 BC – 500 AD), in the Lesser Antilles. [8] The precise source of such formation of sudoite allowing to carve artifacts in rather large blocks remain unknown.
Kaolinite ( KAY-ə-lə-nyte, -lih-; also called kaolin) is a clay mineral, with the chemical composition: Al2Si2O5(OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica (SiO4) linked through oxygen atoms to one octahedral sheet of alumina (AlO6).
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.
Schist is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes or plates. This texture reflects a high content of platy minerals, such as mica, talc, chlorite, or graphite. These are often interleaved with more granular minerals, such as feldspar or quartz.
Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétherie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the specimens studied were actually from El Cardoso de la Sierra, in the Spanish province of Guadalajara, not Andalusia.
Metamorphism is the transformation of existing rock to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid.
Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings. Cordierite is also synthesized and used in high temperature applications such as catalytic converters and pizza stones.
Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are caused by fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Blueschist, also called glaucophane schist, is a metavolcanic rock that forms by the metamorphism of basalt and rocks with similar composition at high pressures and low temperatures, approximately corresponding to a depth of 15–30 km (9.3–18.6 mi). The blue color of the rock comes from the presence of the predominant minerals glaucophane and lawsonite.
Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically 300–450 °C (570–840 °F) and 2–10 kilobars (29,000–145,000 psi). Greenschists commonly have an abundance of green minerals such as chlorite, serpentine, and epidote, and platy minerals such as muscovite and platy serpentine. The platiness gives the rock schistosity. Other common minerals include quartz, orthoclase, talc, carbonate minerals and amphibole (actinolite).
A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.
Chamosite is the Fe2+end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low-to-moderate-grade metamorphosed iron deposits, as gray or black crystals in oolitic iron ore. Like other chlorites, it is a product of the hydrothermal alteration of pyroxenes, amphiboles and biotite in igneous rock. The composition of chlorite is often related to that of the original igneous mineral, so that more Fe-rich chlorites are commonly found as replacements of the Fe-rich ferromagnesian minerals (Deer et al., 1992).
A whiteschist is an uncommon metamorphic rock formed at high to ultra-high pressures. It has the characteristic mineral assemblage of kyanite + talc, responsible for its white colour. The name was introduced in 1973 by German mineralogist and petrologist Werner Schreyer. This rock is associated with the metamorphism of some pelites, evaporite sequences or altered basaltic or felsic intrusions. Whiteschists form in the MgO–Fe
2O
3–Al
2O
3–SiO
2–H
2O (MFASH) system. Rocks of this primary chemistry are extremely uncommon and they are in most cases thought to be the result of metasomatic alteration, with the removal of various mobile elements.
Geikielite is a magnesium titanium oxide mineral with formula: MgTiO3. It is a member of the ilmenite group. It crystallizes in the trigonal system forming typically opaque, black to reddish black crystals.
A subduction zone is a region of the Earth's crust where one tectonic plate moves under another tectonic plate; oceanic crust gets recycled back into the mantle and continental crust gets produced by the formation of arc magmas. Arc magmas account for more than 20% of terrestrially produced magmas and are produced by the dehydration of minerals within the subducting slab as it descends into the mantle and are accreted onto the base of the overriding continental plate. Subduction zones host a unique variety of rock types formed by the high-pressure, low-temperature conditions a subducting slab encounters during its descent. The metamorphic conditions the slab passes through in this process generates and alters water bearing (hydrous) mineral phases, releasing water into the mantle. This water lowers the melting point of mantle rock, initiating melting. Understanding the timing and conditions in which these dehydration reactions occur, is key to interpreting mantle melting, volcanic arc magmatism, and the formation of continental crust.
Titanium in zircon geothermometry is a form of a geothermometry technique by which the crystallization temperature of a zircon crystal can be estimated by the amount of titanium atoms which can only be found in the crystal lattice. In zircon crystals, titanium is commonly incorporated, replacing similarly charged zirconium and silicon atoms. This process is relatively unaffected by pressure and highly temperature dependent, with the amount of titanium incorporated rising exponentially with temperature, making this an accurate geothermometry method. This measurement of titanium in zircons can be used to estimate the cooling temperatures of the crystal and infer conditions during which it crystallized. Compositional changes in the crystals growth rings can be used to estimate the thermodynamic history of the entire crystal. This method is useful as it can be combined with radiometric dating techniques that are commonly used with zircon crystals, to correlate quantitative temperature measurements with specific absolute ages. This technique can be used to estimate early Earth conditions, determine metamorphic facies, or to determine the source of detrital zircons, among other uses.
A petrogenetic grid is a geological phase diagram that connects the stability ranges or metastability ranges of metamorphic minerals or mineral assemblages to the conditions of metamorphism. Experimentally determined mineral or mineral-assemblage stability ranges are plotted as metamorphic reaction boundaries in a pressure–temperature cartesian coordinate system to produce a petrogenetic grid for a particular rock composition. The regions of overlap of the stability fields of minerals form equilibrium mineral assemblages used to determine the pressure–temperature conditions of metamorphism. This is particularly useful in geothermobarometry.
The soil matrix is the solid phase of soils, and comprise the solid particles that make up soils. Soil particles can be classified by their chemical composition (mineralogy) as well as their size. The particle size distribution of a soil, its texture, determines many of the properties of that soil, in particular hydraulic conductivity and water potential, but the mineralogy of those particles can strongly modify those properties. The mineralogy of the finest soil particles, clay, is especially important.
Antigorite is a lamellated, monoclinic mineral in the phyllosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentinites. Antigorite, and its serpentine polymorphs, play an important role in subduction zone dynamics due to their relative weakness and high weight percent of water (up to 13 weight % H2O). It is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland and is commonly used as a gemstone in jewelry and carvings.
attribution translated from fr:Sudoïte