Pseudomorph

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Silica pseudomorph after gypsum crystals and silicified serpulid polychaete tubes Silica pseudomorph after gypsum crystals and silicified serpulid polychaete tubes.jpg
Silica pseudomorph after gypsum crystals and silicified serpulid polychaete tubes
Pseudomorph of goethite after pyrite Goethite-Pyrite-44341.jpg
Pseudomorph of goethite after pyrite

In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form (crystal system), resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced by another due to alteration, or chemical substitution, dissolution and refilling, structural changes or incrustation. [1] The name literally means "false form". Terminology for pseudomorphs is "replacer after original", as in brookite after rutile. The term pseudomorphoses was initially used by Haüy. [2]

Contents

Substitution pseudomorph

Native copper pseudomorph after aragonite, with red cuprite and green malachite alteration Native copper pseudomorph after aragonite, western Bolivia.jpg
Native copper pseudomorph after aragonite, with red cuprite and green malachite alteration

An substitution pseudomorph is a pseudomorph in which one mineral or other material is replaced by another. The original shape of the mineral remains unchanged, but chemical composition, color, hardness, and other properties change to those of the replacing mineral.

This happens typically when a mineral of one composition changes by chemical reaction to another of similar composition, retaining the original crystalline shape. It can occur due to the loss of water or through the action of atmospheric agents, such as oxidation, hydration, or carbonation. An example is a change from galena (lead sulfide) to anglesite (lead sulfate) by oxidation. Pyrite crystals transformed into limonite, a compact mixture of iron oxides where goethite generally predominates, are common. In some cases, only partial replacement occurs. The resulting pseudomorph may contain an unaltered core of galena surrounded by anglesite that has the cubic crystal shape of galena.

Infiltration pseudomorph

An example of this process is the replacement of wood by silica (quartz or opal) to form petrified wood in which the substitution may be so perfect as to retain the original cellular structure of the wood. An example of mineral-to-mineral substitution is replacement of aragonite twin crystals by native copper, as occurs at the Corocoro United Copper Mines of Coro Coro, Bolivia.

Paramorph

Cubic crystals of argentite transformed into acanthite (monoclinic), without any external visible change. Specimen from the San Juan de Rayas Mine, Guanajuato, Mexico. 3 cm. Acanthite-Argentite-gld28a.jpg
Cubic crystals of argentite transformed into acanthite (monoclinic), without any external visible change. Specimen from the San Juan de Rayas Mine, Guanajuato, Mexico. 3 cm.

A paramorph (also called allomorph) is a mineral changed on the molecular level only when the structure of a mineral transitions to a more stable polymorph. It has the same chemical composition, but with a different structure. For example, the cubic form of silver sulfide, argentite, does not actually exist below 173°C, and all are pseudomorphized into the monoclinic mineral acanthite. When the structure is very different, as in the aragonite and calcite, the unstable mineral can remains indefinitely in a metastable form, although transformation can occur under some conditions. Usually, the mineral looks identical to the original, unaltered form.

Epimorph and incrustation pseudomorph

An incrustation pseudomorph, also called epimorph, results from a process by which a mineral is coated by another and the encased mineral dissolves. The encasing mineral remains, and retains the shape of the original mineral or material. Alternatively, another mineral may fill the space (the mold) previously occupied by some other mineral or material. Examples of quartz epimorph after calcite are found in the La Viesca Mine, Siero (Asturias), Spain.

In other fields

Pseudomorphs are also common in paleontology . Fossils are often formed by pseudomorphic replacement of the remains by mineral matter. Examples include petrified wood and pyritized gastropod shells.

In biology , a pseudomorph is a cloud of mucus-rich ink released by many species of cephalopod. The name refers to the similarity in appearance between the cephalopod that released it and the cloud itself, in this context meaning literally "false body". This behaviour often allows the cephalopod to escape from predation unharmed, and is often performed as part of what is known as the blanch-ink-jet maneuver.

In philosophy , the concept of pseudomorphosis was used by the German philosopher Oswald Spengler to describe how the forms of an older, more widely dispersed culture affect the expression of forms of a younger, emerging culture. The latter develop into forms that are fundamentally alien to the culture's own world-feeling and thereby prevent it from fully developing its own self-consciousness. [3]

In archaeology , organic pseudomorphs are impressions of organic material that can accumulate on the surface of metal artifacts as they corrode. They may occur when metal artifacts are buried in contact with organics under damp soil. [4]

See also

Related Research Articles

<span class="mw-page-title-main">Limestone</span> Type of sedimentary rock

Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.


A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific minerals, for example, obsidian is an amorphous glass and not a true crystal; lignite (jet) is derived from the decay of wood under extreme pressure underground; and opal is a mineraloid substance because of its non-crystalline nature. Pearl is a mineraloid substance because the calcite crystals and the aragonite crystals are bonded by an organic material, and naturally occurs without definite proportions of the components.

<span class="mw-page-title-main">Calcite</span> Calcium carbonate mineral

Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses.

<span class="mw-page-title-main">Strontianite</span> Rare carbonate mineral and raw material for the extraction of strontium

Strontianite (SrCO3) is an important raw material for the extraction of strontium. It is a rare carbonate mineral and one of only a few strontium minerals. It is a member of the aragonite group.

<span class="mw-page-title-main">Aragonite</span> Calcium carbonate mineral

Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate, the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation from marine and freshwater environments.

<span class="mw-page-title-main">Vanadinite</span> Apatite supergroup, vanadate mineral

Vanadinite is a mineral belonging to the apatite group of phosphates, with the chemical formula Pb5(VO4)3Cl. It is one of the main industrial ores of the metal vanadium and a minor source of lead. A dense, brittle mineral, it is usually found in the form of red hexagonal crystals. It is an uncommon mineral, formed by the oxidation of lead ore deposits such as galena. First discovered in 1801 in Mexico, vanadinite deposits have since been unearthed in South America, Europe, Africa, and North America.

<span class="mw-page-title-main">Speleothem</span> Structure formed in a cave by the deposition of minerals from water

A speleothem is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depending on their depositional history and environment. Their chemical composition, gradual growth, and preservation in caves make them useful paleoclimatic proxies.

<span class="mw-page-title-main">Galena</span> Natural mineral form of lead sulfide

Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.

<span class="mw-page-title-main">Ooid</span> Small sedimentary grain that forms on shallow tropical seabeds

Ooids are small, spheroidal, "coated" (layered) sedimentary grains, usually composed of calcium carbonate, but sometimes made up of iron- or phosphate-based minerals. Ooids usually form on the sea floor, most commonly in shallow tropical seas. After being buried under additional sediment, these ooid grains can be cemented together to form a sedimentary rock called an oolite. Oolites usually consist of calcium carbonate; these belong to the limestone rock family. Pisoids are similar to ooids, but are larger than 2 mm in diameter, often considerably larger, as with the pisoids in the hot springs at Carlsbad in the Czech Republic.

<span class="mw-page-title-main">Petrifaction</span> Process of fossilisation

In geology, petrifaction or petrification is the process by which organic material becomes a fossil through the replacement of the original material and the filling of the original pore spaces with minerals. Petrified wood typifies this process, but all organisms, from bacteria to vertebrates, can become petrified. Petrifaction takes place through a combination of two similar processes: permineralization and replacement. These processes create replicas of the original specimen that are similar down to the microscopic level.

<span class="mw-page-title-main">Anglesite</span> Lead sulfate mineral

Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and therefore has a high specific gravity of 6.3. Anglesite's color is white or gray with pale yellow streaks. It may be dark gray if impure.

<span class="mw-page-title-main">Carbonate rock</span> Class of sedimentary rock

Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolostone), which is composed of mineral dolomite (CaMg(CO3)2). They are usually classified based on texture and grain size. Importantly, carbonate rocks can exist as metamorphic and igneous rocks, too. When recrystallized carbonate rocks are metamorphosed, marble is created. Rare igneous carbonate rocks even exist as intrusive carbonatites and, even rarer, there exists volcanic carbonate lava.

<span class="mw-page-title-main">Leadhillite</span> Lead sulfate carbonate hydroxide mineral

Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55.

In ore deposit geology, supergene processes or enrichment are those that occur relatively near the surface as opposed to deep hypogene processes. Supergene processes include the predominance of meteoric water circulation (i.e. water derived from precipitation) with concomitant oxidation and chemical weathering. The descending meteoric waters oxidize the primary (hypogene) sulfide ore minerals and redistribute the metallic ore elements. Supergene enrichment occurs at the base of the oxidized portion of an ore deposit. Metals that have been leached from the oxidized ore are carried downward by percolating groundwater, and react with hypogene sulfides at the supergene-hypogene boundary. The reaction produces secondary sulfides with metal contents higher than those of the primary ore. This is particularly noted in copper ore deposits where the copper sulfide minerals chalcocite (Cu2S), covellite (CuS), digenite (Cu18S10), and djurleite (Cu31S16) are deposited by the descending surface waters.

Neomorphism refers to the wet metamorphic process in which diagenetic alterations systematically transform minerals into either polymorphs or crystalline structures that are structurally identical to the rock(s) from which they developed.

<span class="mw-page-title-main">Iddingsite</span>

Iddingsite is a microcrystalline rock that is derived from alteration of olivine. It is usually studied as a mineral, and consists of a mixture of remnant olivine, clay minerals, iron oxides, and ferrihydrites. Debates over iddingsite's non-definite crystal structure caused it to be de-listed as an official mineral by the IMA; thus, it is properly referred to as a rock.

<span class="mw-page-title-main">Mollusc shell</span> Exoskeleton of an animal in the phylum Mollusca

The molluscshell is typically a calcareous exoskeleton which encloses, supports and protects the soft parts of an animal in the phylum Mollusca, which includes snails, clams, tusk shells, and several other classes. Not all shelled molluscs live in the sea; many live on the land and in freshwater.

Mineral alteration refers to the various natural processes that alter a mineral's chemical composition or crystallography.

<span class="mw-page-title-main">Rampghill mine</span>

Rampgill mine is a disused lead mine at Nenthead, Alston Moor, Cumbria, England UK Grid Reference: NY78184351

References

  1. Fraile Rodrigo, Jesús; Calvo Rebollar, Miguel (2019). "Pseudomorphs: when the mineral is not what is was". Mineral Up. 5 (3): 8–30. doi:10.5281/zenodo.3674630.
  2. Haüy, René Just (1801). Traité de Mineralogie. Vol. 2. Chez Louis. pp. 140–145.
  3. O. Spengler, The Decline of the West, vol. 2, chapter III 'Problems of the Arabian culture', I 'Historic pseudomorphoses'
  4. de Alarcon, Tessa "Of Daggers and Scabbards: Evidence of Organic Pseudomorphs and X-Radiography." Penn Museum Blog. 16 April 2016.