Cuprite

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Cuprite
CupriteUSGOV.jpg
Cuprite from Morenci, Arizona
General
Category Oxide mineral
Formula
(repeating unit)
Cu2O
IMA symbol Cpr [1]
Strunz classification 4.AA.10
Dana classification4.1.1.1
Crystal system Cubic
Crystal class Hexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space group Pn3m
Unit cell a = 4.2685 Å; V = 77.77 Å3; Z = 2
Identification
ColorDark red to conchineal red, sometimes almost black
Crystal habit Cubic, octahedral, and dodecahedral crystals; as hairlike capillary forms, earthy, compact granular and massive
Twinning Penetration twins
Cleavage Fair in four directions forming octahedrons
Fracture Conchoidal to uneven
Tenacity Brittle
Mohs scale hardness3.5 to 4
Luster Adamantine, sub-metallic, earthy
Streak Shining metallic brownish-red
Diaphaneity Transparent, translucent
Specific gravity 6.14
Optical propertiesIsotropic
Refractive index n = 2.849
Pleochroism Visible
References [2] [3] [4]

Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper. [5]

Contents

Cuprite from Tsumeb Mine (size:2.3 x 2.1 x 1.2 cm Cuprite-66649.jpg
Cuprite from Tsumeb Mine (size:2.3 x 2.1 x 1.2 cm

Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, or in combinations. Penetration twins frequently occur. In spite of its nice color, it is rarely used for jewelry because of its low Mohs hardness of 3.5 to 4. It has a relatively high specific gravity of 6.1, imperfect cleavage and is brittle to conchoidal fracture. The luster is sub-metallic to brilliant adamantine. The "chalcotrichite" (from Ancient Greek : χαλκός θρίξ τριχός, "plush copper ore") [5] variety typically shows greatly elongated (parallel to [001]) capillary or needle like crystals forms.

Chalcotrichite from Ray, Arizona Chalcotrichite.jpg
Chalcotrichite from Ray, Arizona

It is a secondary mineral which forms in the oxidized zone of copper sulfide deposits. It frequently occurs in association with native copper, azurite, chrysocolla, malachite, tenorite and a variety of iron oxide minerals. [6] It is known as ruby copper due to its distinctive red color.

Cuprite was first described by Wilhelm Karl Ritter von Haidinger in 1845 and the name derives from the Latin cuprum for its copper content. [5] [3]

Cuprite is found in the Ural Mountains, Altai Mountains, and Sardinia, and in more isolated locations in Cornwall, France, Arizona, Chile, Bolivia, and Namibia. [7]

As a gemstone

Though almost all crystals of cuprite are far too small to yield faceted gemstones, one unique deposit from Onganja in Seeis, Namibia, which was discovered in the 1970s, has produced crystals which were both large and gem quality. Virtually every faceted stone over one carat (0.2 g) in weight is from this single deposit, which has long since been mined out. The number of faceted gems over two carats (0.4 g) is difficult to estimate, but according to Joel Arem, one-time curator for the Smithsonian National Gem and Mineral Collection in Washington, D.C., faceted cuprite of any size is considered one of the most collectible and spectacular gems in existence, with its deep garnet coloring and higher brilliance than a diamond. Only the gem's soft nature prevents it from being among the most valuable jewelry stones.

See also

Related Research Articles

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<span class="mw-page-title-main">Amblygonite</span>

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<span class="mw-page-title-main">Beryl</span> Gemstone: beryllium aluminium silicate

Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring, hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.

<span class="mw-page-title-main">Gemstone</span> Piece of mineral crystal used to make jewelry

A gemstone is a piece of mineral crystal which, when cut or polished, is used to make jewelry or other adornments. However, certain rocks and occasionally organic materials that are not minerals are also used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some soft minerals are used in jewelry because of their luster or other physical properties that have aesthetic value. Rarity and notoriety are other characteristics that lend value to gemstones.

<span class="mw-page-title-main">Sapphire</span> Gem variety of corundum

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<span class="mw-page-title-main">Topaz</span> Silicate mineral

Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al2SiO4(F,OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.

<span class="mw-page-title-main">Tourmaline</span> Cyclosilicate mineral group

Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.

<span class="mw-page-title-main">Chrysoberyl</span> Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

<span class="mw-page-title-main">Rhodochrosite</span> Mineral of manganese carbonate

Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. It crystallizes in the trigonal system, and cleaves with rhombohedral carbonate cleavage in three directions. The crystal system of rhodochrosite is trigonal, with a lattice structure in the a rhombohedral system. The carbonate ions (CO3) are arranged in a triangular planar configuration, and the manganese ions (Mn) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate, rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is located in South Africa, China, and the Americas. It is officially listed as one of the National symbols of Argentina.

<span class="mw-page-title-main">Azurite</span> Copper carbonate mineral

Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's Natural History under the Greek name kuanos (κυανός: "deep blue," root of English cyan) and the Latin name caeruleum. Copper (Cu2+) gives it its blue color.

<span class="mw-page-title-main">Dioptase</span>

Dioptase is an intense emerald-green to bluish-green copper cyclosilicate mineral. It is transparent to translucent. Its luster is vitreous to sub-adamantine. Its formula is Cu6Si6O18·6H2O (also reported as CuSiO2(OH)2). It has a hardness of 5, the same as tooth enamel. Its specific gravity is 3.28–3.35, and it has two perfect and one very good cleavage directions. Additionally, dioptase is very fragile, and specimens must be handled with great care. It is a trigonal mineral, forming 6-sided crystals that are terminated by rhombohedra.

<span class="mw-page-title-main">Chrysocolla</span> Phyllosilicate mineral

Chrysocolla ( KRIS-ə-KOL) is a hydrous copper phyllosilicate mineral and mineraloid with the formula Cu
2 – x
Al
x
(H
2
Si
2
O
5
)(OH)
4
nH
2
O
(x < 1) or (Cu, Al)
2
H
2
Si
2
O
5
(OH)
4
nH
2
O)
.

<span class="mw-page-title-main">Cordierite</span> Mg, Fe, Al cyclosilicate mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings.

<span class="mw-page-title-main">Tsavorite</span> Variety of grossular

Tsavorite or tsavolite is a variety of the garnet group species grossular, a calcium-aluminium garnet with the formula Ca3Al2Si3O12. Trace amounts of vanadium or chromium provide the green color.

<span class="mw-page-title-main">Demantoid</span> Green gemstone variety of the mineral andradite

Demantoid is the green gemstone variety of the mineral andradite, a member of the garnet group of minerals. Andradite is a calcium- and iron-rich garnet. The chemical formula is Ca3Fe2(SiO4)3 with chromium substitution as the cause of the demantoid green color. Ferric iron is the cause of the yellow in the stone.

<span class="mw-page-title-main">Tenorite</span>

Tenorite is a copper oxide mineral with the chemical formula CuO.

<span class="mw-page-title-main">Clinohumite</span> Nesosilicate mineral

Clinohumite is an uncommon member of the humite group, a magnesium silicate according to the chemical formula (Mg, Fe)9(SiO4)4(F,OH)2. The formula can be thought of as four olivine (Mg2SiO4), plus one brucite (Mg(OH)2). Indeed, the mineral is essentially a hydrated olivine and occurs in altered ultramafic rocks and carbonatites. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystals are sought by collectors and occasionally fashioned into bright, yellow-orange gemstones. Only two sources of gem-quality material are known: the Pamir Mountains of Tajikistan, and the Taymyr region of northern Siberia. It is one of two humite group minerals that have been cut into gems, the other being the much more common chondrodite.

<span class="mw-page-title-main">Jeremejevite</span>

Jeremejevite is an aluminium borate mineral with variable fluoride and hydroxide ions. Its chemical formula is Al6B5O15(F,OH)3. It is considered as one of the rarest, thus one of the most expensive stones. For nearly a century, it was considered as one of the rarest gemstones in the world.

<span class="mw-page-title-main">Pseudomalachite</span>

Pseudomalachite is a phosphate of copper with hydroxyl, named from the Greek for "false" and "malachite", because of its similarity in appearance to the carbonate mineral malachite, Cu2(CO3)(OH)2. Both are green coloured secondary minerals found in oxidised zones of copper deposits, often associated with each other. Pseudomalachite is polymorphous with reichenbachite and ludjibaite. It was discovered in 1813. Prior to 1950 it was thought that dihydrite, lunnite, ehlite, tagilite and prasin were separate mineral species, but Berry analysed specimens labelled with these names from several museums, and found that they were in fact pseudomalachite. The old names are no longer recognised by the IMA.

<span class="mw-page-title-main">Paramelaconite</span> Oxide mineral

Paramelaconite is a rare, black-colored copper(I,II) oxide mineral with formula CuI
2
CuII
2
O3 (or Cu4O3). It was discovered in the Copper Queen Mine in Bisbee, Arizona, about 1890. It was described in 1892 and more fully in 1941. Its name is derived from the Greek word for "near" and the similar mineral melaconite, now known as tenorite.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Cuprite". Mindat. Retrieved 2010-07-10.
  3. 1 2 "Cuprite". Webmineral data. Retrieved 2010-07-10.
  4. Handbook of Mineralogy
  5. 1 2 3 Spencer, Leonard James (1911). "Cuprite"  . In Chisholm, Hugh (ed.). Encyclopædia Britannica . Vol. 12 (11th ed.). Cambridge University Press. p. 635.
  6. Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Wiley, p. 299-300 ISBN   0-471-80580-7
  7. Joel E. Arem, Ph.D., F.G.A., Color Encyclopedia of Gemstones, 1977, Van Nostrand Reinhold Company