Tetrahedrite

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Tetrahedrite
Tetrahedrite - Black Pine mine, Granite Co., Montana, USA.jpg
Tetrahedrite crystal with traces of quartz (in middle) and micro mimetite, specimen size 3.5 × 2.5 × 2.5 cm
General
Category Sulfosalt mineral
Formula
(repeating unit)
(Cu,Fe)
12
Sb
4
S
13
Strunz classification 2.GB.05
Crystal system Cubic
Crystal class Hextetrahedral (43m)
H-M symbol: (4 3m)
Space group I43m
Unit cell a = 10.39(16) Å; Z = 2
Identification
ColorSteel gray to iron-gray
Crystal habit Groups of tetrahedral crystals; massive, coarse to fine compact granular
Twinning Contact and penetration twins on {111}
Cleavage None
Fracture Uneven to subconchoidal
Tenacity Somewhat brittle
Mohs scale hardness3+12 4
Luster Metallic, commonly splendent
Streak Black, brown to dark red
Diaphaneity Opaque, except in very thin fragments
Specific gravity 4.97
Optical propertiesIsotropic
Refractive index n greater than 2.72
References [1] [2]

Tetrahedrite is a copper antimony sulfosalt mineral with formula: (Cu,Fe)
12
Sb
4
S
13
. It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and bismuthian tetrahedrite or annivite is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver.

Contents

Mineralogy

Tetrahedrite gets its name from the distinctive tetrahedron shaped cubic crystals. The mineral usually occurs in massive form, it is a steel gray to black metallic mineral with Mohs hardness of 3.5 to 4 and specific gravity of 4.6 to 5.2.

Tetrahedrite occurs in low to moderate temperature hydrothermal veins and in some contact metamorphic deposits. It is a minor ore of copper and associated metals. It was first described in 1845 for occurrences in Freiberg, Saxony, Germany. Historically, it was an important ore of copper, the formula Cu3SbS3 corresponding with 57.5% of the metal; it was also worked as an ore of silver, of which element it sometimes contains as much as 30%. [3]

Applications

The now-defunct company Alphabet Energy announced plans to offer a thermoelectric device based on tetrahedrite to turn heat into electricity. The company claimed that other thermoelectrics typically produce about 2.5 percent efficiency, while tetrahedrite could achieve 5 to 10 percent. [4]

Other thermoelectrics are either scarce, expensive ($24–146/kg vs $4 for tetrahedrite) and/or toxic. Working with a natural material also reduces manufacturing costs. [4]

Images

See also

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Sphalerite</span> Zinc-iron sulfide mineral

Sphalerite is a sulfide mineral with the chemical formula (Zn,Fe)S. It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in sedimentary exhalative, Mississippi-Valley type, and volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite, calcite, dolomite, quartz, rhodochrosite, and fluorite.

<span class="mw-page-title-main">Rhodochrosite</span> Mineral of manganese carbonate

Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal, with a structure and cleavage in the carbonate rhombohedral system. The carbonate ions (CO2−
3
) are arranged in a triangular planar configuration, and the manganese ions (Mn2+) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is one of the national symbols of Argentina.

<span class="mw-page-title-main">Galena</span> Natural mineral form of lead sulfide

Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.

<span class="mw-page-title-main">Cuprite</span>

Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper.

<span class="mw-page-title-main">Realgar</span> Arsenic sulfide mineral

Realgar, also known as ″arsenic blende″, ″ruby sulphur″ or ″ruby of arsenic″, is an arsenic sulfide mineral with the chemical formula α-As4S4. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment. It is orange-red in color, melts at 320 °C, and burns with a bluish flame releasing fumes of arsenic and sulfur. Realgar is soft with a Mohs hardness of 1.5 to 2 and has a specific gravity of 3.5. Its streak is orange colored. It is trimorphous with pararealgar and bonazziite.

<span class="mw-page-title-main">Tennantite</span> Copper arsenic sulfosalt mineral

Tennantite is a copper arsenic sulfosalt mineral with an ideal formula Cu12As4S13. Due to variable substitution of the copper by iron and zinc the formula is Cu6[Cu4(Fe,Zn)2]As4S13. It is gray-black, steel-gray, iron-gray or black in color. A closely related mineral, tetrahedrite (Cu12Sb4S13) has antimony substituting for arsenic and the two form a solid solution series. The two have very similar properties and is often difficult to distinguish between tennantite and tetrahedrite. Iron, zinc, and silver substitute up to about 15% for the copper site.

<span class="mw-page-title-main">Ullmannite</span> Nickel antimony sulfide mineral

Ullmannite or Nickel glance is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite.

<span class="mw-page-title-main">Skutterudite</span> Cobalt arsenide mineral

Skutterudite is a cobalt arsenide mineral containing variable amounts of nickel and iron substituting for cobalt with the ideal formula CoAs3. Some references give the arsenic a variable formula subscript of 2–3. High nickel varieties are referred to as nickel-skutterudite, previously chloanthite. It is a hydrothermal ore mineral found in moderate to high temperature veins with other Ni-Co minerals. Associated minerals are arsenopyrite, native silver, erythrite, annabergite, nickeline, cobaltite, silver sulfosalts, native bismuth, calcite, siderite, barite and quartz. It is mined as an ore of cobalt and nickel with a by-product of arsenic.

<span class="mw-page-title-main">Valentinite</span>

Valentinite is an antimony oxide mineral with formula Sb2O3. Valentinite crystallizes in the orthorhombic system and typically forms as radiating clusters of euhedral crystals or as fibrous masses. It is colorless to white with occasional shades or tints of yellow and red. It has a Mohs hardness of 2.5 to 3 and a specific gravity of 5.76. Valentinite occurs as a weathering product of stibnite and other antimony minerals. It is dimorphous with the isometric antimony oxide senarmontite.

<span class="mw-page-title-main">Bournonite</span> Sulfosalt mineral species

Bournonite, wheel ore or berthonite (German: antimonbleikupferblende) is a sulfosalt mineral species, trithioantimoniate of lead and copper with the formula PbCuSbS3.

<span class="mw-page-title-main">Freibergite</span>

Freibergite is a complex sulfosalt mineral of silver, copper, iron, antimony and arsenic with formula (Ag,Cu,Fe)12(Sb,As)4S13. It has cubic crystals and is formed in hydrothermal deposits. It forms one solid solution series with tetrahedrite and another with argentotennantite. Freibergite is an opaque, metallic steel grey to black and leaves a reddish-black streak. It has a Mohs hardness of 3.5 to 4.0 and a specific gravity of 4.85 to 5. It is typically massive to granular in habit with no cleavage and an irregular fracture.

<span class="mw-page-title-main">Stephanite</span>

Stephanite is a silver antimony sulfosalt mineral with formula: Ag5SbS4. It is composed of 68.8% silver, and sometimes is of importance as an ore of this metal.

<span class="mw-page-title-main">Enargite</span> Sulfosalt mineral

Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word enarge, "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as well as massive aggregates. It has a hardness of 3 and a specific gravity of 4.45.

<span class="mw-page-title-main">Boulangerite</span> Sulfosalt mineral: lead antimony sulfide

Boulangerite or antimonbleiblende is an uncommon monoclinic orthorhombic sulfosalt mineral, lead antimony sulfide, formula Pb5Sb4S11. It was named in 1837 in honor of French mining engineer Charles Boulanger (1810–1849), and had been a valid species since pre-IMA. It was first described prior to 1959, and is now grandfathered.

<span class="mw-page-title-main">Native metal</span> Form of metal

A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include aluminium, antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, selenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.

<span class="mw-page-title-main">Coloradoite</span> Rare telluride ore

Coloradoite, also known as mercury telluride (HgTe), is a rare telluride ore associated with metallic deposit. Gold usually occurs within tellurides, such as coloradoite, as a high-finess native metal.

<span class="mw-page-title-main">Dyscrasite</span> Silver antimonide mineral

The silver antimonide mineral dyscrasite has the chemical formula Ag3Sb. It is an opaque, silver white, metallic mineral which crystallizes in the orthorhombic crystal system. It forms pyramidal crystals up to 5 cm (2.0 in) and can also form cylindrical and prismatic crystals.

<span class="mw-page-title-main">Semseyite</span>

Semseyite is a rarely occurring sulfosalt mineral and is part of the class of lead antimony sulfides. It crystallizes in the monoclinic system with the chemical composition Pb9Sb8S21. The mineral forms dark gray to black aggregates.

Chatkalite is a copper, iron, tin sulfide mineral with formula Cu6Fe2+Sn2S8. It crystallizes in the tetragonal crystal system and forms as rounded disseminations within tetrahedrite in quartz veins.

References

  1. Handbook of Mineralogy
  2. "Tetrahedrite: Tetrahedrite mineral information and data". Mindat.org. 2014-07-12. Retrieved 2014-07-17.
  3. Wikisource-logo.svg One or more of the preceding sentences incorporates text from a publication now in the public domain :  Spencer, Leonard James (1911). "Tetrahedrite". In Chisholm, Hugh (ed.). Encyclopædia Britannica . Vol. 26 (11th ed.). Cambridge University Press. pp. 670–671.
  4. 1 2 Jacobs, Suzanne (2014-07-12). "Cheaper Thermoelectric Materials | MIT Technology Review". Technologyreview.com. Archived from the original on 2014-07-17. Retrieved 2014-07-17.