Freibergite

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Freibergite
Freibergite-258726.jpg
General
Category Sulfosalt minerals
Formula
(repeating unit)
Cu12Sb4S13
IMA symbol Fb [1]
Strunz classification 2.GB.05
Crystal system Cubic
Crystal class Hextetrahedral (43m)
H-M symbol: (4 3m)
Space group I43m
Identification
Formula mass 1,929.46 g/mol
ColorSteel gray to black
Crystal habit massive to well formed crystals
Cleavage None
Fracture Uneven
Mohs scale hardness3.5–4
Luster Metallic
Streak reddish black
Diaphaneity Opaque

Freibergite is a complex sulfosalt mineral of silver, copper, iron, antimony and arsenic with formula (Ag,Cu,Fe)12(Sb,As)4S13. It has cubic crystals and is formed in hydrothermal deposits. It forms one solid solution series with tetrahedrite and another with argentotennantite. Freibergite is an opaque, metallic steel grey to black and leaves a reddish-black streak. It has a Mohs hardness of 3.5 to 4.0 and a specific gravity of 4.85 to 5. It is typically massive to granular in habit with no cleavage and an irregular fracture.

The mineral was first described in 1853 from an occurrence in the silver mines of the type locality at Freiberg, Saxony.

Related Research Articles

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<span class="mw-page-title-main">Erythrite</span> Hydrated cobalt arsenate mineral

Erythrite, also known as red cobalt, is a secondary hydrated cobalt arsenate mineral with the formula Co
3
(AsO
4
)
2
•8H
2
O
. Erythrite and annabergite, chemical formula Ni
3
(AsO
4
)
2
•8H
2
O
, or nickel arsenate form a complete series with the general formula (Co,Ni)
3
(AsO
4
)
2
•8H
2
O
.

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12
Sb
4
S
13
. It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and bismuthian tetrahedrite or annivite is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver.

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<span class="mw-page-title-main">Freieslebenite</span>

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<span class="mw-page-title-main">Chloritoid</span>

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2
Al
4
Si
2
O
10
(OH)
4
. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.

Zircophyllite is a complex mineral, formula (K,Na)3(Mn,Fe)2+7(Zr,Ti,Nb)2Si8O24(OH,F)7. It crystallizes in the triclinic – pinacoidal crystal class as dark brown to black micaceous plates. It has perfect 001 cleavage, a Mohs hardness of 4 to 4.5 and a specific gravity of 3.34. Its indices of refraction are nα=1.708 nβ=1.738 nγ=1.747 and it has a 2V optical angle of 62°.

Alloclasite, or (Co,Fe)AsS, is a sulfosalt mineral. It is a member of the arsenopyrite group. Alloclasite crystallizes in the monoclinic system and typically forms as columnar to radiating acicular prismatic clusters. It is an opaque steel-gray to silver-white, with a metallic luster and a black streak. It is brittle with perfect cleavage, a Mohs hardness of 5 and a specific gravity of 5.91–5.95.

<span class="mw-page-title-main">Penroseite</span>

Penroseite is a rare selenide mineral with formula (Ni,Co,Cu)Se2. It has a gray-steel color and black streak with a hardness of 3. It is an isometric mineral, 2/m3. Penroseite was first discovered in 1925 in a Bolivian rhyolite. It was named for Richard Penrose (1863–1931), an economic geologist.

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References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.