Sphalerite is a sulfide mineral with the chemical formula (Zn,Fe)S. It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in sedimentary exhalative, Mississippi-Valley type, and volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite, calcite, dolomite, quartz, rhodochrosite, and fluorite.
Salammoniac, also sal ammoniac or salmiac, is a rare naturally occurring mineral composed of ammonium chloride, NH4Cl. It forms colorless, white, or yellow-brown crystals in the isometric-hexoctahedral class. It has very poor cleavage and is brittle to conchoidal fracture. It is quite soft, with a Mohs hardness of 1.5 to 2, and it has a low specific gravity of 1.5. It is water-soluble. Sal ammoniac is also the archaic name for the chemical compound ammonium chloride.
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. It crystallizes in the trigonal system, and cleaves with rhombohedral carbonate cleavage in three directions. The crystal system of rhodochrosite is trigonal, with a lattice structure in the a rhombohedral system. The carbonate ions (CO3) are arranged in a triangular planar configuration, and the manganese ions (Mn) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate, rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is located in South Africa, China, and the Americas. It is officially listed as one of the National symbols of Argentina.
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3AsS3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from which it was distinguished by the chemical analyses of Joseph L. Proust (1754–1826) in 1804, after whom the mineral received its name.
Acanthite is a form of silver sulfide with the chemical formula Ag2S. It crystallizes in the monoclinic system and is the stable form of silver sulfide below 173 °C (343 °F). Argentite is the stable form above that temperature. As argentite cools below that temperature its cubic form is distorted to the monoclinic form of acanthite. Below 173 °C acanthite forms directly. Acanthite is the only stable form in normal air temperature.
Chalcocite, copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system.
Variscite is a hydrated aluminium phosphate mineral. It is a relatively rare phosphate mineral. It is sometimes confused with turquoise; however, variscite is usually greener in color. The green color results from the presence of small amounts of trivalent chromium.
Chrysocolla ( KRIS-ə-KOL-ə) is a hydrous copper phyllosilicate mineral and mineraloid with the formula Cu
2 – xAl
x(H
2Si
2O
5)(OH)
4⋅nH
2O (x < 1) or (Cu, Al)
2H
2Si
2O
5(OH)
4⋅nH
2O).
Tetrahedrite is a copper antimony sulfosalt mineral with formula: (Cu,Fe)
12Sb
4S
13. It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and bismuthian tetrahedrite or annivite is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver.
Pyrargyrite is a sulfosalt mineral consisting of silver sulfantimonite, Ag3SbS3. Known also as dark red silver ore or ruby silver, it is an important source of the metal.
Stephanite is a silver antimony sulfosalt mineral with formula: Ag5SbS4. It is composed of 68.8% silver, and sometimes is of importance as an ore of this metal.
Miargyrite is a mineral, a sulfide of silver and antimony with the formula AgSbS2. It is a dimorph of cuboargyrite. Originally discovered in the Freiberg district of Germany in 1824, it has subsequently been found in many places where silver is mined. It usually occurs in low temperature hydrothermal deposits. and forms black metallic crystals which may show a dark red internal reflection. The streak is also red.
Polybasite is a sulfosalt mineral of silver, copper, antimony and arsenic. Its chemical formula is [(Ag,Cu)6(Sb,As)2S7][Ag9CuS4].
Freieslebenite is a sulfosalt mineral composed of antimony, lead, and silver. Sulfosalt minerals are complex sulfide minerals with the formula: AmBnSp. The formula of freieslebenite is AgPbSbS3.
Canfieldite is a rare silver tin sulfide mineral with formula: Ag8SnS6. The mineral typically contains variable amounts of germanium substitution in the tin site and tellurium in the sulfur site. There is a complete series between canfieldite and its germanium analogue, argyrodite. It forms black orthorhombic crystals which often appear to be cubic in form due to twinning. The most typical form is as botryoidal rounded grape-like masses. Its Mohs hardness is 2.5 and the specific gravity is 6.28. Canfieldite exhibits conchoidal fracturing and no cleavage.
Howlite, a calcium borosilicate hydroxide (Ca2B5SiO9(OH)5), is a borate mineral found in evaporite deposits.
The silver antimonide mineral dyscrasite has the chemical formula Ag3Sb. It is an opaque, silver white, metallic mineral which crystallizes in the orthorhombic crystal system. It forms pyramidal crystals up to 5 cm (2.0 in) and can also form cylindrical and prismatic crystals.
Pearceite is one of the four so-called "ruby silvers", pearceite Cu(Ag,Cu)6Ag9As2S11, pyrargyrite Ag3SbS3, proustite Ag3AsS3 and miargyrite AgSbS2. It was discovered in 1896 and named after Dr Richard Pearce (1837–1927), a Cornish–American chemist and metallurgist from Denver, Colorado.
Millerite is a nickel sulfide mineral, NiS. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general lack of association with pyrite or pyrrhotite.
