Freibergite | |
---|---|
General | |
Category | Sulfosalt minerals |
Formula (repeating unit) | Cu12Sb4S13 |
IMA symbol | Fb [1] |
Strunz classification | 2.GB.05 |
Crystal system | Cubic |
Crystal class | Hextetrahedral (43m) H-M symbol: (4 3m) |
Space group | I43m |
Identification | |
Formula mass | 1,929.46 g/mol |
Color | Steel gray to black |
Crystal habit | massive to well formed crystals |
Cleavage | None |
Fracture | Uneven |
Mohs scale hardness | 3.5–4 |
Luster | Metallic |
Streak | reddish black |
Diaphaneity | Opaque |
Freibergite is a complex sulfosalt mineral of silver, copper, iron, antimony and arsenic with formula (Ag,Cu,Fe)12(Sb,As)4S13. It has cubic crystals and is formed in hydrothermal deposits. It forms one solid solution series with tetrahedrite and another with argentotennantite. Freibergite is an opaque, metallic steel grey to black and leaves a reddish-black streak. It has a Mohs hardness of 3.5 to 4.0 and a specific gravity of 4.85 to 5. It is typically massive to granular in habit with no cleavage and an irregular fracture.
The mineral was first described in 1853 from an occurrence in the silver mines of the type locality at Freiberg, Saxony.
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.
The mineral pyrite ( PY-ryte), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula FeS2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.
Arsenopyrite is an iron arsenic sulfide (FeAsS). It is a hard metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1.
Chalcopyrite ( KAL-kə-PY-ryte, -koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.
Hibonite is a mineral with the chemical formula (Ca,Ce)(Al,Ti,Mg)12O19, occurring in various colours, with a hardness of 7.5–8.0 and a hexagonal crystal structure. It is rare, but is found in high-grade metamorphic rocks on Madagascar. Some presolar grains in primitive meteorites consist of hibonite. Hibonite also is a common mineral in the Ca-Al-rich inclusions found in some chondritic meteorites. Hibonite is closely related to hibonite-Fe ) an alteration mineral from the Allende meteorite. Hibonites were among the first minerals to form as the disk of gas and dust swirling around the young sun cooled.
Erythrite, also known as red cobalt, is a secondary hydrated cobalt arsenate mineral with the formula Co
3(AsO
4)
2•8H
2O. Erythrite and annabergite, chemical formula Ni
3(AsO
4)
2•8H
2O, or nickel arsenate form a complete series with the general formula (Co,Ni)
3(AsO
4)
2•8H
2O.
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S. It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic. Pyrrhotite is generally tabular and brassy/bronze in color with a metallic luster. The mineral occurs with mafic igneous rocks like norites, and may form from pyrite during metamorphic processes. Pyrrhotite is associated and mined with other sulfide minerals like pentlandite, pyrite, chalcopyrite, and magnetite, and has been found globally.
Tetrahedrite is a copper antimony sulfosalt mineral with formula: (Cu,Fe)
12Sb
4S
13. It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and bismuthian tetrahedrite or annivite is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver.
Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4. It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.
Bixbyite is a manganese iron oxide mineral with chemical formula: (Mn,Fe)2O3. The iron/manganese ratio is quite variable and many specimens have almost no iron. It is a metallic dark black with a Mohs hardness of 6.0 – 6.5. It is a somewhat rare mineral sought after by collectors as it typically forms euhedral isometric crystals exhibiting various cubes, octahedra, and dodecahedra.
Sperrylite is a platinum arsenide mineral with the chemical formula PtAs2 and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in addition to massive and reniform habits. It has a Mohs hardness of 6–7 and a very high specific gravity of 10.6.
Safflorite is a rare cobalt iron arsenide mineral with the chemical formula (Co,Fe)As2. Pure safflorite is CoAs2, but iron is virtually always present. Safflorite is a member of the three-way substitution series of arsenides known as the loellingite group. More than fifty percent iron makes the mineral loellingite whereas more than fifty percent nickel and the mineral is rammelsbergite. A parallel series of antimonide minerals exist.
Babingtonite is a calcium iron manganese inosilicate mineral with the formula Ca2(Fe,Mn)FeSi5O14(OH). It is unusual in that iron(III) completely replaces the aluminium so typical of silicate minerals. It is a very dark green to black translucent mineral crystallizing in the triclinic system with typically radial short prismatic clusters and druzy coatings. It occurs with zeolite minerals in cavities in volcanic rocks. Babingtonite contains both iron(II) and iron(III) and shows weak magnetism. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 3.3.
Freieslebenite is a sulfosalt mineral composed of antimony, lead, and silver. Sulfosalt minerals are complex sulfide minerals with the formula: AmBnSp. The formula of freieslebenite is AgPbSbS3.
Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2Al
4Si
2O
10(OH)
4. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.
Zircophyllite is a complex mineral, formula (K,Na)3(Mn,Fe)2+7(Zr,Ti,Nb)2Si8O24(OH,F)7. It crystallizes in the triclinic – pinacoidal crystal class as dark brown to black micaceous plates. It has perfect 001 cleavage, a Mohs hardness of 4 to 4.5 and a specific gravity of 3.34. Its indices of refraction are nα=1.708 nβ=1.738 nγ=1.747 and it has a 2V optical angle of 62°.
Alloclasite, or (Co,Fe)AsS, is a sulfosalt mineral. It is a member of the arsenopyrite group. Alloclasite crystallizes in the monoclinic system and typically forms as columnar to radiating acicular prismatic clusters. It is an opaque steel-gray to silver-white, with a metallic luster and a black streak. It is brittle with perfect cleavage, a Mohs hardness of 5 and a specific gravity of 5.91–5.95.
Penroseite is a rare selenide mineral with formula (Ni,Co,Cu)Se2. It has a gray-steel color and black streak with a hardness of 3. It is an isometric mineral, 2/m3. Penroseite was first discovered in 1925 in a Bolivian rhyolite. It was named for Richard Penrose (1863–1931), an economic geologist.
Delafossite is a copper iron oxide mineral with formula CuFeO2 or Cu1+Fe3+O2. It is a member of the delafossite mineral group, which has the general formula ABO2, a group characterized by sheets of linearly coordinated A cations stacked between edge-shared octahedral layers (BO6). Delafossite, along with other minerals of the ABO2 group, is known for its wide range of electrical properties, its conductivity varying from insulating to metallic. Delafossite is usually a secondary mineral that crystallizes in association with oxidized copper and rarely occurs as a primary mineral.