Greenalite

Last updated
Greenalite
Galena siderite Cartagena.jpg
Greenalite (green) with galena and siderite, from Spain
General
Category Phyllosilicates
Kaolinite-serpentine group
Formula
(repeating unit)
(Fe2+,Fe3+)2-3Si2O5(OH)4
IMA symbol Gre [1]
Strunz classification 9.ED.15
Crystal system Monoclinic
Crystal class Domatic (m)
(same H-M symbol)
Space group Cm
Unit cell a = 5.54, b = 9.55
c = 7.44 [Å]; β = 104.2°; Z = 2
Identification
ColorGreen, light yellow-green
Crystal habit Rare minute crystals, rounded grains common; as porphyroblasts, oolites
Cleavage None
Mohs scale hardness2.5
Luster Dull, earthy
Streak Greenish-gray
Diaphaneity Translucent to subopaque
Specific gravity 2.85 - 3.15
Optical propertiesBiaxial (+)
Refractive index nα = 1.650 - 1.675 nβ = 1.674 nγ = 1.674
Birefringence δ = 0.024
Pleochroism X = pale yellow, Y and Z = green
Other characteristicsMagnetic
References [2] [3] [4]

Greenalite is a mineral in the kaolinite-serpentine group with the chemical composition (Fe2+,Fe3+)2-3Si2O5(OH)4. [2] [5] It is a member of the serpentine group. [3]

Contents

Occurrence

Greenalite was first described in 1903 for an occurrence in the Mesabi Range near Biwabik, St. Louis County, Minnesota and named for its green color. [3]

Greenalite occurs as a primary mineral in banded iron formations. Rocks which contain greenalite are usually bright green, pale green or pale brown. Greenalite occurs with quartz, stilpnomelane, siderite, chamosite, pyrite and minnesotaite. It is commonly oolitic. [2]

Effect on early life

Greenalite, which is common in Archean rocks, formed rapidly in Archean seawater removing zinc, copper and vanadium in the process. This left the seawater rich in manganese, molybdenum, and cadmium, which are metals favoured by lifeforms at that time. Experiments have shown that the removed metals would have been removed permanently, having a significant effect on early seawater. [6]

Related Research Articles

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Augite</span> Common rock-forming pyroxene mineral

Augite is a common rock-forming pyroxene mineral with formula (Ca,Na)(Mg,Fe,Al,Ti)(Si,Al)2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.

<span class="mw-page-title-main">Pyrophyllite</span> Aluminium silicate hydroxide phyllosilicate mineral

Pyrophyllite is a phyllosilicate mineral composed of aluminium silicate hydroxide: Al2Si4O10(OH)2. It occurs in two forms (habits): crystalline folia and compact masses; distinct crystals are not known.

<span class="mw-page-title-main">Epidote</span> Sorosilicate mineral

Epidote is a calcium aluminium iron sorosilicate mineral.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Jadeite</span> Pyroxene mineral

Jadeite is a pyroxene mineral with composition NaAlSi2O6. It is hard (Mohs hardness of about 6.5 to 7.0), very tough, and dense, with a specific gravity of about 3.4. It is found in a wide range of colors, but is most often found in shades of green or white. Jadeite is formed only in the subduction zones of continental margins, where rock undergoes metamorphism at high pressure but relatively low temperature.

<span class="mw-page-title-main">Pyrrhotite</span> Magnetic iron sulfide mineral

Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S. It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content decreases, and troilite is non-magnetic. Pyrrhotite is generally tabular and brassy/bronze in color with a metallic luster. The mineral occurs with mafic igneous rocks like norites, and may form from pyrite during metamorphic processes. Pyrrhotite is associated and mined with other sulfide minerals like pentlandite, pyrite, chalcopyrite, and magnetite, and has been found globally.

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Chlorite group</span> Type of mineral

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

<span class="mw-page-title-main">Illite</span> Group of related non-expanding clay minerals

Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. The space between this T-O-T sequence of layers is occupied by poorly hydrated potassium cations which are responsible for the absence of swelling. Structurally, illite is quite similar to muscovite with slightly more silicon, magnesium, iron, and water and slightly less tetrahedral aluminium and interlayer potassium. The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small monoclinic grey to white crystals. Due to the small size, positive identification usually requires x-ray diffraction or SEM-EDS analysis. Illite occurs as an altered product of muscovite and feldspar in weathering and hydrothermal environments; it may be a component of sericite. It is common in sediments, soils, and argillaceous sedimentary rocks as well as in some low grade metamorphic rocks. The iron-rich member of the illite group, glauconite, in sediments can be differentiated by x-ray analysis.

<span class="mw-page-title-main">Hauyne</span> Tectosilicate mineral with sometimes a blue colour due to a cyclic trisulfide anion

Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

<span class="mw-page-title-main">Heazlewoodite</span>

Heazlewoodite, Ni3S2, is a rare sulfur-poor nickel sulfide mineral found in serpentinitized dunite. It occurs as disseminations and masses of opaque, metallic light bronze to brassy yellow grains which crystallize in the trigonal crystal system. It has a hardness of 4, a specific gravity of 5.82. Heazlewoodite was first described in 1896 from Heazlewood, Tasmania, Australia.

<span class="mw-page-title-main">Aliettite</span> Mineral

Aliettite is a complex phyllosilicate mineral of the smectite group with a formula of (Ca0.2Mg6(Si,Al)8O20(OH)4·4H2O) or [Mg3Si4O10(OH)2](Ca0.5,Na)0.33(Al,Mg,Fe2+)23(Si,Al)4O10(OH)2·n(H2O).

<span class="mw-page-title-main">Piemontite</span>

Piemontite is a sorosilicate mineral in the monoclinic crystal system with the chemical formula Ca2(Al,Mn3+,Fe3+)3(SiO4)(Si2O7)O(OH). It is a member of the epidote group.

<span class="mw-page-title-main">Népouite</span> Nickel ore from the serpentine family (phyllosilicate)

Népouite is a rare nickel silicate mineral which has the apple green color typical of such compounds. It was named by the French mining engineer Edouard Glasser in 1907 after the place where it was first described, the Népoui Mine, Népoui, Poya Commune, North Province, New Caledonia. The ideal formula is Ni3(Si2O5)(OH)4, but most specimens contain some magnesium, and (Ni,Mg)3(Si2O5)(OH)4 is more realistic. There is a similar mineral called lizardite in which all of the nickel is replaced by magnesium, formula Mg3(Si2O5)(OH)4. These two minerals form a series; intermediate compositions are possible, with varying proportions of nickel to magnesium.

<span class="mw-page-title-main">Caryopilite</span>

Caryopilite (synonymous with ectropite and ektropite) is a brown-colored mineral with formula (Mn2+,Mg)3Si2O5(OH)4. The mineral was discovered in 1889 from a mine in Sweden. It was named for the Greek words for walnut and felt in reference to its appearance.

<span class="mw-page-title-main">Minnesotaite</span> Iron silicate mineral

Minnesotaite is an iron silicate mineral with formula: (Fe2+,Mg)3Si4O10(OH)2. It crystallizes in the triclinic crystal system and occurs as fine needles and platelets with other silicates. It is isostructural with the pyrophyllite-talc mineral group.

<span class="mw-page-title-main">Pecoraite</span> Nickel phyllosilicate mineral of the serpentine group

Pecoraite is a nickel silicate mineral and a member of the serpentine group. It was named after geologist William Thomas Pecora. It is monoclinic and has a chemical composition of Ni3(Si2O5)(OH)4. It is associated with the weathering-and-or oxidation of meteorites or nickel sulfide minerals such as millerite. It is also found in altered ultramafic rocks. Pecoraite is typically a green, lime green, or bluegreen mineral with a waxy, or earthy luster and a mohs hardness of 2.5. Common textural habits associated with pecoraite are curved plates, spirals and tubes. It can also be granular and massive.

Antigorite Monoclinic mineral

Antigorite is a lamellated, monoclinic mineral in the phyllosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentinites. Antigorite, and its serpentine polymorphs, play an important role in subduction zone dynamics due to their relative weakness and high weight percent of water (up to 13 weight % H2O). It is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland and is commonly used as a gemstone in jewelry and carvings.

<span class="mw-page-title-main">Lizardite</span> Magnesium phyllosilicate mineral of the serpentine group

Lizardite is a mineral from the serpentine subgroup with formula Mg3(Si2O5)(OH)4, and the most common type of mineral in the subgroup. It is also a member of the kaolinite-serpentine group.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Handbook of Mineralogy
  3. 1 2 3 Greenalite on Mindat.org
  4. Greenalite on Webmineral
  5. Sleep N.H., Bird D.K. (2007): Niches of the pre-photosynthetic biosphere and geologic preservation of Earth’s earliest ecology. Geobiology 5, 101-117
  6. "Recreation of ancient seawater reveals which nutrients shaped the evolution of early life". www.ox.ac.uk. University of Oxford. 13 November 2023. Retrieved 2023-11-20.