Celadonite | |
---|---|
General | |
Category | Micas Phyllosilicate |
Formula (repeating unit) | K(Mg,Fe2+ )(Fe3+ ,Al)[Si 4O 10](OH) 2 |
IMA symbol | Cel [1] |
Crystal system | Monoclinic |
Crystal class | Spheroidal (2) (same H-M symbol) |
Space group | C2 |
Identification | |
Color | Blue-green to olive to applegreen |
Cleavage | perfect on {001} |
Tenacity | Fragile |
Mohs scale hardness | 2 |
Luster | Waxy, dull, earthy |
Diaphaneity | Translucent |
Specific gravity | 2.95 - 3.05 |
Density | 2.95 - 3.05 |
Optical properties | Biaxial (-) |
Pleochroism | Visible |
2V angle | 5°- 8° |
Common impurities | Mn, Na, Ca |
Other characteristics | Radioactive 9.11% (K) |
References | [2] [3] [4] |
Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula K(Mg,Fe2+
)(Fe3+
,Al)[Si
4O
10](OH)
2.
It crystallizes in the monoclinic system and usually forms massive aggregates of prismatic crystallites or, more commonly, in dull clay masses. It is soft with a Mohs hardness of 2 and a specific gravity of 3. It forms vesicle fillings and linings in altered basaltic lavas. Early research suggests this mineral has ties to weakly metamorphosed plutonic rocks during formation, and is also found with montmorillonite clays or zeolite crystals. [5] Association with zeolites may indicate these minerals favor the same underlying conditions of crystal growth. [5]
It was first described in 1847 on Monte Baldo, near Verona, Italy. The name is from the French celadon, for sea-green. It is one of two minerals, along with glauconite, used in making the pigment known as green earth. [6]
Common impurities are manganese, calcium and sodium (previously known as natrium).
Hematite, also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of Fe
2O
3. It has the same crystal structure as corundum (Al
2O
3) and ilmenite (FeTiO
3). With this it forms a complete solid solution at temperatures above 950 °C (1,740 °F).
Kaolinite ( KAY-ə-lə-nyte, -lih-; also called kaolin) is a clay mineral, with the chemical composition Al2Si2O5(OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica (SiO4) linked through oxygen atoms to one octahedral sheet of alumina (AlO6).
Titanite, or sphene (from Ancient Greek σφηνώ (sphēnṓ) 'wedge'), is a calcium titanium nesosilicate mineral, CaTiSiO5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly replaced by thorium.
Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2 with limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic, botryoidal, reniform or globular aggregates, with only just the crests of small crystals showing any faces, which are almost always curved or composite. Very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with an uneven fracture and a vitreous to pearly luster. Its hardness is 6.5, its specific gravity is 2.80–2.95 and its color varies from light green to yellow, but also colorless, blue, pink or white. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, South Africa. Prehnite is mostly translucent, and rarely transparent.
Goethite is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α-polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a pigment. Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France. It was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe (1749–1832).
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur.
Azurite or Azure spar is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's Natural History under the Greek name kuanos (κυανός: "deep blue," root of English cyan) and the Latin name caeruleum. Copper (Cu2+) gives it its blue color.
Glauconite is an iron potassium phyllosilicate mineral of characteristic green color which is very friable and has very low weathering resistance.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Palygorskite or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula (Mg,Al)2Si4O10(OH)·4(H2O) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of this mineral can be found in Mexico, where its use is tied to the manufacture of Maya blue in pre-Columbian times.
Heulandite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:
Saponite is a trioctahedral mineral of the smectite group. Its chemical formula is Ca0.25(Mg,Fe)3( 4O10)(OH)2·n(H2O). It is soluble in sulfuric acid. It was first described in 1840 by Svanberg. Varieties of saponite are griffithite, bowlingite and sobotkite.
Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. The space between this T-O-T sequence of layers is occupied by poorly hydrated potassium cations which are responsible for the absence of swelling. Structurally, illite is quite similar to muscovite with slightly more silicon, magnesium, iron, and water and slightly less tetrahedral aluminium and interlayer potassium. The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small monoclinic grey to white crystals. Due to the small size, positive identification usually requires x-ray diffraction or SEM-EDS analysis. Illite occurs as an altered product of muscovite and feldspar in weathering and hydrothermal environments; it may be a component of sericite. It is common in sediments, soils, and argillaceous sedimentary rocks as well as in some low grade metamorphic rocks. The iron-rich member of the illite group, glauconite, in sediments can be differentiated by x-ray analysis.
Thomsonite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, thomsonite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named thomsonite-Ca and thomsonite-Sr. Thomsonite-Ca, by far the more common of the two, is a hydrous sodium, calcium and aluminium silicate, NaCa2Al5Si5O20·6H2O. Strontium can substitute for the calcium and the appropriate species name depends on the dominant element. The species are visually indistinguishable and the series name thomsonite is used whenever testing has not been performed. Globally, thomsonite is one of the rarer zeolites.
Roscoelite is a green mineral from the mica group that contains vanadium.
Amicite is a silicate mineral of the zeolite family. It has a general formula of K2Na2Al4Si4O16·5(H2O). Amicite was described in 1979 from specimens obtained at the Höwenegg quarry in Immendingen, Hegau, in the German state of Baden-Württemberg, which is consequently its type locality. The name is in honor of Giovanni Battista Amici (1786–1863) a botanist, physicist, optician, and inventor of microscope optical elements.
Stellerite is a rare mineral discovered by and named after Georg Wilhelm Steller, a German explorer and zoologist. The mineral has a general formula of Ca[Al2Si7O18]·7H2O. Like most rare minerals, there are few commercial uses for stellerite. Mineral collectors are lucky to find it in good enough crystal form. Zeolites, including stellerite, have been studied using a dehydration process to gauge the potential use of their phases as molecular sieves, sorbents, and catalysts. Its occurrences are in cavities of andesite as sheaf-like clusters of small crystals.
Green earth, also known as terre verte and Verona green, is an inorganic pigment derived from the minerals celadonite and glauconite. Its chemical formula is K[(Al,Fe3+),(Fe2+,Mg)](AlSi3,Si4)O10(OH)2.
Aluminoceladonite is a low-temperature potassium dioctahedral mica mineral which is an end-member in the illite-aluminoceladonite solid solution series. The chemical formula for aluminoceladonite is K(Mg,Fe2+)Al(Si4O10)(OH)2.
Tacharanite is a calcium aluminium silicate hydrate (C-A-S-H) mineral of general chemical formula Ca12Al2Si18O33(OH)36 with some resemblance to the calcium silicate hydrate (C-S-H) mineral tobermorite. It is often found in mineral assemblage with zeolites and other hydrated calcium silicates.