Clintonite

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Clintonite
Clintonite-Spinel-235093.jpg
Clintonite with spinel on orthoclase matrix from Amity, New York (size: 9.3 × 5.7 × 3.8 cm)
General
Category Phyllosilicate mica group
Formula
(repeating unit)
Ca(Mg,Al)
3
(Al
3
Si)O
10
(OH)
2
IMA symbol Cln [1]
Crystal system Monoclinic
Crystal class Prismatic (2/m)
or domatic (m)
Space group C2/m or (?)
Unit cell a = 5.204 Å,
b = 9.026 Å,
c = 9.812 Å;
β = 100.35°; Z = 2
Identification
ColorColorless, yellow, orange, red-brown, brown, green
Crystal habit Tabular pseudohexagonal crystals; foliated or lamellar radiated; massive
Twinning Spiral polysynthetic twinning
Cleavage Perfect on {001}
Tenacity Brittle
Mohs scale hardness3.5 on {001}, 6 at angle to {001}
Luster Vitreous, pearly, submetallic
Streak White, slightly yellow-gray
Diaphaneity Transparent to translucent
Specific gravity 3.0–3.1
Optical propertiesBiaxial (−)
Refractive index nα = 1.643 – 1.648 nβ = 1.655 – 1.662 nγ = 1.655 – 1.663
Birefringence δ = 0.012 – 0.015
Pleochroism X = colorless, pale orange, red-brown; Y = Z = pale brownish yellow, pale green
2V angle Measured: 2° to 40°
References [2] [3] [4] [5]

Clintonite is a calcium magnesium aluminium phyllosilicate mineral. It is a member of the margarite group of micas and the subgroup often referred to as the "brittle" micas. Clintonite has the chemical formula Ca(Mg,Al)
3
(Al
3
Si)O
10
(OH)
2
. Like other micas and chlorites, clintonite is monoclinic in crystal form and has a perfect basal cleavage parallel to the flat surface of the plates or scales. The Mohs hardness of clintonite is 6.5, and the specific gravity is 3.0 to 3.1. It occurs as variably colored, colorless, green, yellow, red, to reddish-brown masses and radial clusters.

The brittle micas differ chemically from the micas in containing less silica and no alkalis, and from the chlorites in containing much less water; in many respects, they are intermediate between the micas and chlorites. [6] Clintonite and its iron-rich variety xanthophyllite are sometimes considered the calcium analogues of the phlogopites. [7]

Typical formation environment is in serpentinized dolomitic limestone and contact metamorphosed skarns. It occurs with talc, spinel, grossular, vesuvianite, clinopyroxene, monticellite, chondrodite, phlogopite, chlorite, quartz, calcite and dolomite. [5]

Clintonite was first described in 1843 for an occurrence in Orange County, New York. It was named for De Witt Clinton (1769–1828). [4]

See also

Related Research Articles

<span class="mw-page-title-main">Biotite</span> Group of phyllosilicate minerals within the mica group

Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula K(Mg,Fe)3AlSi3O10(F,OH)2. It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more aluminous end-members include siderophyllite and eastonite. Biotite was regarded as a mineral species by the International Mineralogical Association until 1998, when its status was changed to a mineral group. The term biotite is still used to describe unanalysed dark micas in the field. Biotite was named by J.F.L. Hausmann in 1847 in honor of the French physicist Jean-Baptiste Biot, who performed early research into the many optical properties of mica.

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Mica</span> Group of phyllosilicate minerals

Micas are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is common in igneous and metamorphic rock and is occasionally found as small flakes in sedimentary rock. It is particularly prominent in many granites, pegmatites, and schists, and "books" of mica several feet across have been found in some pegmatites.

<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Epidote</span> Sorosilicate mineral

Epidote is a calcium aluminium iron sorosilicate mineral.

<span class="mw-page-title-main">Phlogopite</span> Member of the mica family of phyllosilicates

Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.

<span class="mw-page-title-main">Metasomatism</span> Chemical alteration of a rock by hydrothermal and other fluids

Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid.

<span class="mw-page-title-main">Hornfels</span>

Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are caused by fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.

<span class="mw-page-title-main">Chlorite group</span> Type of mineral

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

<span class="mw-page-title-main">Xenotime</span> Phosphate mineral

Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate (YPO4). It forms a solid solution series with chernovite-(Y) (YAsO4) and therefore may contain trace impurities of arsenic, as well as silicon dioxide and calcium. The rare-earth elements dysprosium, erbium, terbium and ytterbium, as well as metal elements such as thorium and uranium (all replacing yttrium) are the expressive secondary components of xenotime. Due to uranium and thorium impurities, some xenotime specimens may be weakly to strongly radioactive. Lithiophyllite, monazite and purpurite are sometimes grouped with xenotime in the informal "anhydrous phosphates" group. Xenotime is used chiefly as a source of yttrium and heavy lanthanide metals (dysprosium, ytterbium, erbium and gadolinium). Occasionally, gemstones are also cut from the finest xenotime crystals.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Hauyne</span> Silicate mineral

Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

<span class="mw-page-title-main">Margarite</span>

Margarite is a calcium rich member of the mica group of the phyllosilicates with formula: CaAl2(Al2Si2)O10(OH)2. It forms white to pinkish or yellowish gray masses or thin laminae. It crystallizes in the monoclinic crystal system. It typically has a specific gravity of around 3 and a Mohs hardness of 4. It is translucent with perfect 010 cleavage and exhibits crystal twinning.

<span class="mw-page-title-main">Tschermakite</span> Amphibole, double chain inosilicate mineral

The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.

Bityite is considered a rare mineral, and it is an endmember to the margarite mica sub-group found within the phyllosilicate group. The mineral was first described by Antoine François Alfred Lacroix in 1908, and later its chemical composition was concluded by Professor Hugo Strunz. Bityite has a close association with beryl, and it generally crystallizes in pseudomorphs after it, or in cavities associated with reformed beryl crystals. The mineral is considered a late-stage constituent in lithium bearing pegmatites, and has only been encountered in a few localities throughout the world. The mineral was named by Lacroix after Mt. Bity, Madagascar from where it was first discovered.

<span class="mw-page-title-main">Chamosite</span> Phyllosilicate mineral member of the chlorite group

Chamosite is the Fe2+end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low to moderate grade of metamorphosed iron deposits, as gray or black crystals in oolitic iron ore. Like other chlorites, it is a product of the hydrothermal alteration of pyroxenes, amphiboles and biotite in igneous rock. The composition of chlorite is often related to that of the original igneous mineral so that more Fe-rich chlorites are commonly found as replacements of the Fe-rich ferromagnesian minerals (Deer et al., 1992).

<span class="mw-page-title-main">Annite</span> Phyllosilicate mineral in the mica family

Annite is a phyllosilicate mineral in the mica family. It has a chemical formula of KFe32+AlSi3O10(OH)2. Annite is the iron end member of the biotite mica group, the iron rich analogue of magnesium rich phlogopite. Annite is monoclinic and contains tabular crystals and cleavage fragments with pseudohexagonal outlines. There are contact twins with composition surface {001} and twin axis {310}.

<span class="mw-page-title-main">Siilinjärvi carbonatite</span>

The Siilinjärvi carbonatite complex is located in central Finland close to the city of Kuopio. It is named after the nearby town of Siilinjärvi, located approximately 5 km west of the southern extension of the complex. Siilinjärvi is the second largest carbonatite complex in Finland after the Sokli formation, and one of the oldest carbonatites on Earth at 2610±4 Ma. The carbonatite complex consists of a roughly 16 km long steeply dipping lenticular body surrounded by granite gneiss. The maximum width of the body is 1.5 km and the surface area is 14.7 km2. The complex was discovered in 1950 by the Geological Survey of Finland with help of local mineral collectors. The exploration drilling began in 1958 by Lohjan Kalkkitehdas Oy. Typpi Oy continued drilling between years 1964 and 1967, and Apatiitti Oy drilled from 1967 to 1968. After the drillings, the laboratory and pilot plant work were made. The mine was opened by Kemira Oyj in 1979 as an open pit. The operation was sold to Yara in 2007.

Hendricksite is a member of the trioctahedral micas group. The mineral was named by Clifford Frondel and Jun Ito in honor of Sterling Brown Hendricks, who studied micas. It was approved in 1966 by the IMA.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mineralienatlas
  3. Webmineral
  4. 1 2 Mindat with location data
  5. 1 2 Handbook of Mineralogy
  6. Wikisource-logo.svg One or more of the preceding sentences incorporates text from a publication now in the public domain :  Spencer, Leonard James (1911). "Clintonite". In Chisholm, Hugh (ed.). Encyclopædia Britannica . Vol. 6 (11th ed.). Cambridge University Press. p. 530.
  7. Alietti, Elisa; et al. (1997). "Clintonite-1M: Crystal chemistry and its relationships to closely associated Al-rich phlogopite" (PDF). American Mineralogist. 82: 936–945. doi:10.2138/am-1997-9-1011.