Clintonite

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Clintonite
Clintonite-Spinel-235093.jpg
Clintonite with spinel on orthoclase matrix from Amity, New York (size: 9.3 × 5.7 × 3.8 cm)
General
Category Phyllosilicate minerals, mica group
Formula Ca(Mg,Al)
3
(Al
3
Si)O
10
(OH)
2
IMA symbol Cln [1]
Crystal system Monoclinic
Crystal class Prismatic (2/m)
or domatic (m)
Space group C2/m or (?)
Unit cell a = 5.204 Å,
b = 9.026 Å,
c = 9.812 Å;
β = 100.35°; Z = 2
Identification
ColorColorless, yellow, orange, red-brown, brown, green
Crystal habit Tabular pseudohexagonal crystals; foliated or lamellar radiated; massive
Twinning Spiral polysynthetic twinning
Cleavage Perfect on {001}
Tenacity Brittle
Mohs scale hardness3.5 on {001}, 6 at angle to {001}
Luster Vitreous, pearly, submetallic
Streak White, slightly yellow-gray
Diaphaneity Transparent to translucent
Specific gravity 3.0–3.1
Optical propertiesBiaxial (−)
Refractive index nα = 1.643 – 1.648 nβ = 1.655 – 1.662 nγ = 1.655 – 1.663
Birefringence δ = 0.012 – 0.015
Pleochroism X = colorless, pale orange, red-brown; Y = Z = pale brownish yellow, pale green
2V angle Measured: 2° to 40°
References [2] [3] [4] [5]

Clintonite is a calcium magnesium aluminium phyllosilicate mineral. It is a member of the margarite group of micas and the subgroup often referred to as the "brittle" micas. Clintonite has the chemical formula Ca(Mg,Al)
3
(Al
3
Si)O
10
(OH)
2
. Like other micas and chlorites, clintonite is monoclinic in crystal form and has a perfect basal cleavage parallel to the flat surface of the plates or scales. The Mohs hardness of clintonite is 6.5, and the specific gravity is 3.0 to 3.1. It occurs as variably colored, colorless, green, yellow, red, to reddish-brown masses and radial clusters.

The brittle micas differ chemically from the micas in containing less silica and no alkalis, and from the chlorites in containing much less water; in many respects, they are intermediate between the micas and chlorites. [6] Clintonite and its iron-rich variety xanthophyllite are sometimes considered the calcium analogues of the phlogopites. [7]

Typical formation environment is in serpentinized dolomitic limestone and contact metamorphosed skarns. It occurs with talc, spinel, grossular, vesuvianite, clinopyroxene, monticellite, chondrodite, phlogopite, chlorite, quartz, calcite and dolomite. [5]

Clintonite was first described in 1843 for an occurrence in Orange County, New York. It was named for De Witt Clinton (1769–1828). [4]

See also

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mineralienatlas
  3. Webmineral
  4. 1 2 Mindat with location data
  5. 1 2 Handbook of Mineralogy
  6. Wikisource-logo.svg One or more of the preceding sentences incorporates text from a publication now in the public domain :  Spencer, Leonard James (1911). "Clintonite". In Chisholm, Hugh (ed.). Encyclopædia Britannica . Vol. 6 (11th ed.). Cambridge University Press. p. 530.
  7. Alietti, Elisa; et al. (1997). "Clintonite-1M: Crystal chemistry and its relationships to closely associated Al-rich phlogopite" (PDF). American Mineralogist. 82 (9–10): 936–945. Bibcode:1997AmMin..82..936A. doi:10.2138/am-1997-9-1011.