Vesuvianite | |
---|---|
General | |
Category | Sorosilicate |
Formula (repeating unit) | Ca10(Mg, Fe)2Al4(SiO4)5(Si2O7)2(OH,F)4 |
IMA symbol | Ves [1] |
Strunz classification | 9.BG.35 |
Crystal system | Tetragonal |
Crystal class | Ditetragonal dipyramidal (4/mmm) H-M symbol: (4/m 2/m 2/m) |
Space group | P4/nnc |
Unit cell | a = 15.52 Å, c = 11.82 Å Z = 2 |
Identification | |
Color | Yellow, green, brown; colorless to white, brown-black, light green, emerald green, violet, blue-green to blue, pink, purple, red, black, commonly zoned |
Crystal habit | Short pyramidal to long prismatic crystals common, massive to columnar |
Twinning | Fine twin domains observed |
Cleavage | Poor on {110} and {100} very poor on {001} |
Fracture | Sub conchoidal to irregular |
Tenacity | Brittle |
Mohs scale hardness | 6–7 |
Luster | Vitreous to resinous |
Streak | White |
Diaphaneity | Subtransparent to translucent |
Specific gravity | 3.32–3.43 |
Optical properties | Uniaxial (−) |
Refractive index | nω = 1.703–1.752 nε = 1.700–1.746 |
Birefringence | 0.004–0.006 |
Pleochroism | slight in colored varieties |
Solubility | Vesuvianite is virtually insoluble in acids |
Other characteristics | striated lengthwise |
References | [2] [3] [4] |
Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. [3] It was first discovered within included blocks or adjacent to lavas on Mount Vesuvius, hence its name. Attractive-looking crystals are sometimes cut as gemstones. Localities which have yielded fine crystallized specimens include Mount Vesuvius and the Ala Valley near Turin, Piedmont. [5]
The specific gravity is 3.4 and the Mohs hardness is 6+1⁄2. The name "vesuvianite" was given by Abraham Gottlob Werner in 1795, because fine crystals of the mineral are found at Vesuvius; these are brown in color and occur in the ejected limestone blocks of Monte Somma. Several other names were applied to this species, one of which, "idocrase" by René Just Haüy in 1796, is now in common use. [5]
A sky bluish variety known as cyprine has been reported from Franklin, New Jersey and other locations; the blue is due to impurities of copper in a complex calcium aluminum sorosilicate. Californite is a name sometimes used for jade-like vesuvianite, also known as California jade, American jade or Vesuvianite jade. Xanthite is a manganese rich variety. Wiluite is an optically positive variety from Wilui, Siberia. Idocrase is an older synonym sometimes used for gemstone-quality vesuvianite. Also, Vessonite and Vassolite are variant spellings commonly encountered in the gem trade.
Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2 with limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic, botryoidal, reniform or globular aggregates, with only just the crests of small crystals showing any faces, which are almost always curved or composite. Very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with an uneven fracture and a vitreous to pearly luster. Its hardness is 6.5, its specific gravity is 2.80–2.95 and its color varies from light green to yellow, but also colorless, blue, pink or white. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, South Africa. Prehnite is mostly translucent, and rarely transparent.
Lazurite, old name Azure spar is a tectosilicate mineral with sulfate, sulfur and chloride with formula (Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]. It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli.
Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate (SrSO4). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources of the element strontium, commonly used in fireworks and in various metal alloys.
Tugtupite is a beryllium aluminium tectosilicate. It also contains sodium and chlorine and has the formula Na4AlBeSi4O12Cl. Tugtupite is a member of the silica-deficient feldspathoid mineral group. It occurs in high alkali intrusive igneous rocks.
Chrysocolla ( KRIS-ə-KOL-ə) is a hydrous copper phyllosilicate mineral and mineraloid with the formula Cu
2 – xAl
x(H
2Si
2O
5)(OH)
4⋅nH
2O (x < 1) or (Cu, Al)
2H
2Si
2O
5(OH)
4⋅nH
2O).
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3O
8. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.
The scapolites are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite and marialite. Silvialite (Ca,Na)4Al6Si6O24(SO4,CO3) is also a recognized member of the group.
Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).
Clintonite is a calcium magnesium aluminium phyllosilicate mineral. It is a member of the margarite group of micas and the subgroup often referred to as the "brittle" micas. Clintonite has the chemical formula Ca(Mg,Al)
3(Al
3Si)O
10(OH)
2. Like other micas and chlorites, clintonite is monoclinic in crystal form and has a perfect basal cleavage parallel to the flat surface of the plates or scales. The Mohs hardness of clintonite is 6.5, and the specific gravity is 3.0 to 3.1. It occurs as variably colored, colorless, green, yellow, red, to reddish-brown masses and radial clusters.
Clinohumite is an uncommon member of the humite group, a magnesium silicate according to the chemical formula (Mg, Fe)9(SiO4)4(F,OH)2. The formula can be thought of as four olivine (Mg2SiO4), plus one brucite (Mg(OH)2). Indeed, the mineral is essentially a hydrated olivine and occurs in altered ultramafic rocks and carbonatites. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystals are sought by collectors and occasionally fashioned into bright, yellow-orange gemstones. Only two sources of gem-quality material are known: the Pamir Mountains of Tajikistan, and the Taymyr region of northern Siberia. It is one of two humite group minerals that have been cut into gems, the other being the much more common chondrodite.
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.
Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.
Pectolite is a white to gray mineral, NaCa2Si3O8(OH), sodium calcium hydroxide inosilicate. It crystallizes in the triclinic system typically occurring in radiated or fibrous crystalline masses. It has a Mohs hardness of 4.5 to 5 and a specific gravity of 2.7 to 2.9. The gemstone variety, larimar, is a pale to sky blue. There is also a whitish form of the mineral from Alaska that is sometimes marketed as 'Alaska jade'.
Charoite is a rare silicate mineral with the chemical composition K(Ca,Na)
2Si
4O
10(OH,F)•H
2O, first described in 1978. It is named after the Chara River, despite its being 70 kilometres (43 mi) away from the discovery place. When it was discovered, it was thought to be a fake, dyed purple to give it its striking appearance.
Afghanite, (Na,K)22Ca10[Si24Al24O96](SO4)6Cl6, is a hydrous sodium, calcium, potassium, sulfate, chloride, carbonate alumino-silicate mineral. Afghanite is a feldspathoid of the cancrinite group and typically occurs with sodalite group minerals. It forms blue to colorless, typically massive crystals in the trigonal crystal system. The lowering of the symmetry from typical (for cancrinite group) hexagonal one is due to ordering of Si and Al. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 2.55 to 2.65. It has refractive index values of nω = 1.523 and nε = 1.529. It has one direction of perfect cleavage and exhibits conchoidal fracture. It fluoresces a bright orange.
Connellite is a rare mineral species, a hydrous copper chloro-sulfate, Cu19(OH)32(SO4)Cl4·3H2O, crystallizing in the hexagonal system. It occurs as tufts of very delicate acicular crystals of a fine blue color, and is associated with other copper minerals of secondary origin, such as cuprite and malachite. Its occurrence in Cornwall, England, was noted by Philip Rashleigh in 1802, and it was first examined chemically by Prof Arthur Connell FRSE in 1847, after whom it is named.
Wiluite is a dark green, brownish, or black blocky silicate mineral with the chemical formula Ca19(Al,Mg,Fe,Ti)13(B,Al,[ ])5Si18O68(O,OH)10. It has a Mohs hardness of 6 and a specific gravity of 3.36. It has a vitreous lustre, poor cleavage and an irregular brittle fracture. It crystallizes in the tetragonal system and occurs as well-formed crystals with good external form. It is isostructural with the vesuvianite group and is associated with wollastonite and olive-green grossulars (viluites) in a serpentinized skarn.
Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).
Bustamite is a calcium manganese inosilicate (chain silicate) and a member of the wollastonite group. Magnesium, zinc and iron are common impurities substituting for manganese. Bustamite is the high-temperature polymorph of CaMnSi2O6 and johannsenite is the low temperature polymorph. The inversion takes place at 830 °C (1,530 °F), but may be very slow.
Bustamite could be confused with light-colored rhodonite or pyroxmangite, but both these minerals are biaxial (+) whereas bustamite is biaxial (−).
Fluorellestadite is a rare nesosilicate of calcium, with sulfate and fluorine, with the chemical formula Ca10(SiO4)3(SO4)3F2. It is a member of the apatite group, and forms a series with hydroxylellestadite.