Vesuvianite

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Vesuvianite
Vesuvianite-242685.jpg
Vesuvianite from the Jeffrey Mine in Asbestos, Quebec
General
Category Sorosilicate
Formula
(repeating unit)
Ca10(Mg, Fe)2Al4(SiO4)5(Si2O7)2(OH,F)4
IMA symbol Ves [1]
Strunz classification 9.BG.35
Crystal system Tetragonal
Crystal class Ditetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Space group P4/nnc
Unit cell a = 15.52 Å, c = 11.82 Å
Z = 2
Identification
ColorYellow, green, brown; colorless to white, brown-black, light green, emerald green, violet, blue-green to blue, pink, purple, red, black, commonly zoned
Crystal habit Short pyramidal to long prismatic crystals common, massive to columnar
Twinning Fine twin domains observed
Cleavage Poor on {110} and {100} very poor on {001}
Fracture Sub conchoidal to irregular
Tenacity Brittle
Mohs scale hardness6–7
Luster Vitreous to resinous
Streak White
Diaphaneity Subtransparent to translucent
Specific gravity 3.32–3.43
Optical propertiesUniaxial (−)
Refractive index nω = 1.703–1.752
nε = 1.700–1.746
Birefringence 0.004–0.006
Pleochroism slight in colored varieties
Solubility Vesuvianite is virtually insoluble in acids
Other characteristicsstriated lengthwise
References [2] [3] [4]

Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. [3] It was first discovered within included blocks or adjacent to lavas on Mount Vesuvius, hence its name. Attractive-looking crystals are sometimes cut as gemstones. Localities which have yielded fine crystallized specimens include Mount Vesuvius and the Ala Valley near Turin, Piedmont. [5]

The specific gravity is 3.4 and the Mohs hardness is 6+12. The name "vesuvianite" was given by Abraham Gottlob Werner in 1795, because fine crystals of the mineral are found at Vesuvius; these are brown in color and occur in the ejected limestone blocks of Monte Somma. Several other names were applied to this species, one of which, "idocrase" by René Just Haüy in 1796, is now in common use. [5]

A sky bluish variety known as cyprine has been reported from Franklin, New Jersey and other locations; the blue is due to impurities of copper in a complex calcium aluminum sorosilicate. Californite is a name sometimes used for jade-like vesuvianite, also known as California jade, American jade or Vesuvianite jade. Xanthite is a manganese rich variety. Wiluite is an optically positive variety from Wilui, Siberia. Idocrase is an older synonym sometimes used for gemstone-quality vesuvianite. Also, Vessonite and Vassolite are variant spellings commonly encountered in the gem trade.

Related Research Articles

<span class="mw-page-title-main">Prehnite</span> Inosilicate of calcium and aluminium

Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2 with limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic, botryoidal, reniform or globular aggregates, with only just the crests of small crystals showing any faces, which are almost always curved or composite. Very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with an uneven fracture and a vitreous to pearly luster. Its hardness is 6.5, its specific gravity is 2.80–2.95 and its color varies from light green to yellow, but also colorless, blue, pink or white. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, South Africa. Prehnite is mostly translucent, and rarely transparent.

<span class="mw-page-title-main">Lazurite</span> Alumino-silicate mineral whose blue colour is due to a sulfide species and not copper

Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula (Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]. It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli.

<span class="mw-page-title-main">Celestine (mineral)</span> Sulfate mineral

Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate (SrSO4). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources of the element strontium, commonly used in fireworks and in various metal alloys.

<span class="mw-page-title-main">Tugtupite</span>

Tugtupite is a beryllium aluminium tectosilicate. It also contains sodium and chlorine and has the formula Na4AlBeSi4O12Cl. Tugtupite is a member of the silica-deficient feldspathoid mineral group. It occurs in high alkali intrusive igneous rocks.

<span class="mw-page-title-main">Albite</span> Mineral, Na-feldspar, Na-silicate, tectosilicate

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi
3
O
8
. It is a tectosilicate. Its color is usually pure white, hence its name from Latin, albus. It is a common constituent in felsic rocks.

<span class="mw-page-title-main">Scapolite</span> Group of rock-forming silicate minerals

The scapolites are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite and marialite. Silvialite (Ca,Na)4Al6Si6O24(SO4,CO3) is also a recognized member of the group.

<span class="mw-page-title-main">Rhodonite</span> Single chain manganese inosilicate (MnSiO3)

Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).

<span class="mw-page-title-main">Clintonite</span> Phyllosilicate mineral

Clintonite is a calcium magnesium aluminium phyllosilicate mineral. It is a member of the margarite group of micas and the subgroup often referred to as the "brittle" micas. Clintonite has the chemical formula Ca(Mg,Al)
3
(Al
3
Si)O
10
(OH)
2
. Like other micas and chlorites, clintonite is monoclinic in crystal form and has a perfect basal cleavage parallel to the flat surface of the plates or scales. The Mohs hardness of clintonite is 6.5, and the specific gravity is 3.0 to 3.1. It occurs as variably colored, colorless, green, yellow, red, to reddish-brown masses and radial clusters.

<span class="mw-page-title-main">Clinohumite</span> Nesosilicate mineral

Clinohumite is an uncommon member of the humite group, a magnesium silicate according to the chemical formula (Mg, Fe)9(SiO4)4(F,OH)2. The formula can be thought of as four olivine (Mg2SiO4), plus one brucite (Mg(OH)2). Indeed, the mineral is essentially a hydrated olivine and occurs in altered ultramafic rocks and carbonatites. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystals are sought by collectors and occasionally fashioned into bright, yellow-orange gemstones. Only two sources of gem-quality material are known: the Pamir Mountains of Tajikistan, and the Taymyr region of northern Siberia. It is one of two humite group minerals that have been cut into gems, the other being the much more common chondrodite.

<span class="mw-page-title-main">Grossular</span> Garnet, nesosilicate mineral

Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.

<span class="mw-page-title-main">Andradite</span> Nesosilicate mineral species of garnet

Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.

<span class="mw-page-title-main">Charoite</span> Rare silicate mineral

CharoiteK(Ca,Na)
2
Si
4
O
10
(OH,F)•H
2
O
is a rare silicate mineral, first described in 1978. It is named after the Chara River, despite its being 70 km away from the discovery place; the name of the river translated from Evenki means “to melt, melt.” When it was discovered, it was thought to be a fake, dyed purple to give it its striking appearance.

<span class="mw-page-title-main">Afghanite</span> Tectosilicate mineral

Afghanite, (Na,K)22Ca10[Si24Al24O96](SO4)6Cl6, is a hydrous sodium, calcium, potassium, sulfate, chloride, carbonate alumino-silicate mineral. Afghanite is a feldspathoid of the cancrinite group and typically occurs with sodalite group minerals. It forms blue to colorless, typically massive crystals in the trigonal crystal system. The lowering of the symmetry from typical (for cancrinite group) hexagonal one is due to ordering of Si and Al. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 2.55 to 2.65. It has refractive index values of nω = 1.523 and nε = 1.529. It has one direction of perfect cleavage and exhibits conchoidal fracture. It fluoresces a bright orange.

<span class="mw-page-title-main">Connellite</span>

Connellite is a rare mineral species, a hydrous copper chloro-sulfate, Cu19(OH)32(SO4)Cl4·3H2O, crystallizing in the hexagonal system. It occurs as tufts of very delicate acicular crystals of a fine blue color, and is associated with other copper minerals of secondary origin, such as cuprite and malachite. Its occurrence in Cornwall, England, was noted by Philip Rashleigh in 1802, and it was first examined chemically by Prof Arthur Connell FRSE in 1847, after whom it is named.

<span class="mw-page-title-main">Wiluite</span>

Wiluite is a dark green, brownish, or black blocky silicate mineral with the chemical formula Ca19(Al,Mg,Fe,Ti)13(B,Al,[ ])5Si18O68(O,OH)10. It has a Mohs hardness of 6 and a specific gravity of 3.36. It has a vitreous lustre, poor cleavage and an irregular brittle fracture. It crystallizes in the tetragonal system and occurs as well-formed crystals with good external form. It is isostructural with the vesuvianite group and is associated with wollastonite and olive-green grossulars (viluites) in a serpentinized skarn.

<span class="mw-page-title-main">Hydrogrossular</span> Calcium aluminium garnet

Hydrogrossular is a calcium aluminium garnet series (formula: Ca3Al2(SiO4)3−x(OH)4x, with hydroxide (OH) partially replacing silica (SiO4)). The endmembers of the hydrogarnet family (grossular, hibschite, and katoite) depend on the degree of substitution (x):

<span class="mw-page-title-main">Portlandite</span> Calcium hydroxide mineral

Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).

<span class="mw-page-title-main">Bustamite</span>

Bustamite is a calcium manganese inosilicate (chain silicate) and a member of the wollastonite group. Magnesium, zinc and iron are common impurities substituting for manganese. Bustamite is the high-temperature polymorph of CaMnSi2O6 and johannsenite is the low temperature polymorph. The inversion takes place at 830 °C (1,530 °F), but may be very slow.
Bustamite could be confused with light-colored rhodonite or pyroxmangite, but both these minerals are biaxial (+) whereas bustamite is biaxial (−).

<span class="mw-page-title-main">Fluorellestadite</span> Nesosilicate mineral

Fluorellestadite is a rare nesosilicate of calcium, with sulfate and fluorine, with the chemical formula Ca10(SiO4)3(SO4)3F2. It is a member of the apatite group, and forms a series with hydroxylellestadite.

<span class="mw-page-title-main">Piypite</span>

Piypite is a rare potassium, copper sulfate mineral with formula: K2Cu2O(SO4)2. It crystallizes in the tetragonal system and occurs as needlelike crystals and masses. Individual crystals are square in cross-section and often hollow. It is emerald green to black in color with a vitreous to greasy luster.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mindat with location data
  3. 1 2 Handbook of Mineralogy
  4. https://www.mineralienatlas.de/lexikon/index.php/MineralData?mineral=Vesuvianite Mineralienatlas
  5. 1 2 Wikisource-logo.svg One or more of the preceding sentences incorporates text from a publication now in the public domain :  Spencer, Leonard James (1911). "Vesuvianite". In Chisholm, Hugh (ed.). Encyclopædia Britannica . Vol. 27 (11th ed.). Cambridge University Press. p. 1063.

Additional sources