|Appearance||silvery grey-white metallic|
|Standard atomic weight Ar, std(Ti)||47.867(1)|
|Titanium in the periodic table|
|Atomic number (Z)||22|
|Element category||transition metal|
|Electron configuration||[ Ar ] 3d2 4s2|
Electrons per shell
|2, 8, 10, 2|
|Phase at STP||solid|
|Melting point||1941 K (1668 °C,3034 °F)|
|Boiling point||3560 K(3287 °C,5949 °F)|
|Density (near r.t.)||4.506 g/cm3|
|when liquid (at m.p.)||4.11 g/cm3|
|Heat of fusion||14.15 kJ/mol|
|Heat of vaporization||425 kJ/mol|
|Molar heat capacity||25.060 J/(mol·K)|
| Vapor pressure |
|Oxidation states||−2, −1, +1, +2, +3, +4 (an amphoteric oxide)|
|Electronegativity||Pauling scale: 1.54|
|Atomic radius||empirical:147 pm|
|Covalent radius||160±8 pm|
|Spectral lines of titanium|
|Crystal structure|| hexagonal close-packed (hcp)|
|Speed of sound thin rod||5090 m/s(at r.t.)|
|Thermal expansion||8.6 µm/(m·K)(at 25 °C)|
|Thermal conductivity||21.9 W/(m·K)|
|Electrical resistivity||420 nΩ·m(at 20 °C)|
|Magnetic susceptibility||+153.0·10−6 cm3/mol(293 K)|
|Young's modulus||116 GPa|
|Shear modulus||44 GPa|
|Bulk modulus||110 GPa|
|Vickers hardness||830–3420 MPa|
|Brinell hardness||716–2770 MPa|
|Discovery||William Gregor (1791)|
|First isolation||Jöns Jakob Berzelius (1825)|
|Named by||Martin Heinrich Klaproth (1795)|
|Main isotopes of titanium|
Titanium is a chemical element with the symbol Ti and atomic number 22. It is a lustrous transition metal with a silver color, low density, and high strength. Titanium is resistant to corrosion in sea water, aqua regia, and chlorine.
A chemical element is a species of atom having the same number of protons in their atomic nuclei. For example, the atomic number of oxygen is 8, so the element oxygen consists of all atoms which have exactly 8 protons.
In relation to the chemical elements, a symbol is a code for a chemical element. Symbols for chemical elements normally consist of one or two letters from the Latin alphabet and are written with the first letter capitalised.
The atomic number or proton number of a chemical element is the number of protons found in the nucleus of an atom. It is identical to the charge number of the nucleus. The atomic number uniquely identifies a chemical element. In an uncharged atom, the atomic number is also equal to the number of electrons.
Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791, and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of mineral deposits, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere, and it is found in almost all living things, water bodies, rocks, and soils.The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and titanium trichloride (TiCl3), which is used as a catalyst in the production of polypropylene.
Cornwall is a county in South West England in the United Kingdom. The county is bordered to the north and west by the Celtic Sea, to the south by the English Channel, and to the east by the county of Devon, over the River Tamar which forms most of the border between them. Cornwall forms the westernmost part of the South West Peninsula of the island of Great Britain. The furthest southwestern point of Great Britain is Land's End; the southernmost point is Lizard Point. Cornwall has a population of 563,600 and covers an area of 3,563 km2 (1,376 sq mi). The county has been administered since 2009 by the unitary authority, Cornwall Council. The ceremonial county of Cornwall also includes the Isles of Scilly, which are administered separately. The administrative centre of Cornwall, and its only city, is Truro.
The Kingdom of Great Britain, officially called simply Great Britain, was a sovereign state in western Europe from 1 May 1707 to 31 December 1800. The state came into being following the Treaty of Union in 1706, ratified by the Acts of Union 1707, which united the kingdoms of England and Scotland to form a single kingdom encompassing the whole island of Great Britain and its outlying islands, with the exception of the Isle of Man and the Channel Islands. The unitary state was governed by a single parliament and government that was based in Westminster. The former kingdoms had been in personal union since James VI of Scotland became King of England and King of Ireland in 1603 following the death of Elizabeth I, bringing about the "Union of the Crowns". After the accession of George I to the throne of Great Britain in 1714, the kingdom was in a personal union with the Electorate of Hanover.
William Gregor was the British clergyman and mineralogist who discovered the elemental metal titanium.
Titanium can be alloyed with iron, aluminium, vanadium, and molybdenum, among other elements, to produce strong, lightweight alloys for aerospace (jet engines, missiles, and spacecraft), military, industrial processes (chemicals and petrochemicals, desalination plants, pulp, and paper), automotive, agri-food, medical prostheses, orthopedic implants, dental and endodontic instruments and files, dental implants, sporting goods, jewelry, mobile phones, and other applications.
An alloy is a combination of metals and of a metal or another element. Alloys are defined by a metallic bonding character. An alloy may be a solid solution of metal elements or a mixture of metallic phases. Intermetallic compounds are alloys with a defined stoichiometry and crystal structure. Zintl phases are also sometimes considered alloys depending on bond types.
Iron is a chemical element with symbol Fe and atomic number 26. It is a metal, that belongs to the first transition series and group 8 of the periodic table. It is by mass the most common element on Earth, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust.
Aluminium is a chemical element with the symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic and ductile metal in the boron group. By mass, aluminium makes up about 8% of the Earth's crust; it is the third most abundant element after oxygen and silicon and the most abundant metal in the crust, though it is less common in the mantle below. The chief ore of aluminium is bauxite. Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is found combined in over 270 different minerals.
The two most useful properties of the metal are corrosion resistance and strength-to-density ratio, the highest of any metallic element.In its unalloyed condition, titanium is as strong as some steels, but less dense. There are two allotropic forms and five naturally occurring isotopes of this element, 46Ti through 50Ti, with 48Ti being the most abundant (73.8%). Although they have the same number of valence electrons and are in the same group in the periodic table, titanium and zirconium differ in many chemical and physical properties.
Steel is an alloy of iron and carbon, and sometimes other elements. Because of its high tensile strength and low cost, it is a major component used in buildings, infrastructure, tools, ships, automobiles, machines, appliances, and weapons.
Allotropy or allotropism is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element; the atoms of the element are bonded together in a different manner. For example, the allotropes of carbon include diamond, graphite, graphene, and fullerenes. The term allotropy is used for elements only, not for compounds. The more general term, used for any crystalline material, is polymorphism. Allotropy refers only to different forms of an element within the same phase ; differences in these states alone would not constitute examples of allotropy.
Isotopes are variants of a particular chemical element which differ in neutron number, and consequently in nucleon number. All isotopes of a given element have the same number of protons but different numbers of neutrons in each atom.
As a metal, titanium is recognized for its high strength-to-weight ratio. °C or 3,000 °F) makes it useful as a refractory metal. It is paramagnetic and has fairly low electrical and thermal conductivity.It is a strong metal with low density that is quite ductile (especially in an oxygen-free environment), lustrous, and metallic-white in color. The relatively high melting point (more than 1,650
A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically malleable or ductile. A metal may be a chemical element such as iron, or an alloy such as stainless steel.
The density, or more precisely, the volumetric mass density, of a substance is its mass per unit volume. The symbol most often used for density is ρ, although the Latin letter D can also be used. Mathematically, density is defined as mass divided by volume:
Ductility is a measure of a material's ability to undergo significant plastic deformation before rupture, which may be expressed as percent elongation or percent area reduction from a tensile test. According to Shigley's Mechanical Engineering Design significant denotes about 5.0 percent elongation. See also Eq. 2–12, p. 50 for definitions of percent elongation and percent area reduction. Ductility is often characterized by a material's ability to be stretched into a wire.
Commercially pure (99.2% pure) grades of titanium have ultimate tensile strength of about 434 MPa (63,000 psi), equal to that of common, low-grade steel alloys, but are less dense. Titanium is 60% denser than aluminium, but more than twice as strong 430 °C (806 °F).as the most commonly used 6061-T6 aluminium alloy. Certain titanium alloys (e.g., Beta C) achieve tensile strengths of over 1,400 MPa (200,000 psi). However, titanium loses strength when heated above
Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or Ftu within equations, is the capacity of a material or structure to withstand loads tending to elongate, as opposed to compressive strength, which withstands loads tending to reduce size. In other words, tensile strength resists tension, whereas compressive strength resists compression. Ultimate tensile strength is measured by the maximum stress that a material can withstand while being stretched or pulled before breaking. In the study of strength of materials, tensile strength, compressive strength, and shear strength can be analyzed independently.
The pound per square inch or, more accurately, pound-force per square inch is a unit of pressure or of stress based on avoirdupois units. It is the pressure resulting from a force of one pound-force applied to an area of one square inch. In SI units, 1 psi is approximately equal to 6895 N/m2.
6061 is a precipitation-hardened aluminum alloy, containing magnesium and silicon as its major alloying elements. Originally called "Alloy 61S", it was developed in 1935. It has good mechanical properties, exhibits good weldability, and is very commonly extruded. It is one of the most common alloys of aluminum for general-purpose use.
Titanium is not as hard as some grades of heat-treated steel; it is non-magnetic and a poor conductor of heat and electricity. Machining requires precautions, because the material can gall unless sharp tools and proper cooling methods are used. Like steel structures, those made from titanium have a fatigue limit that guarantees longevity in some applications.
The metal is a dimorphic allotrope of an hexagonal α form that changes into a body-centered cubic (lattice) β form at 882 °C (1,620 °F). The specific heat of the α form increases dramatically as it is heated to this transition temperature but then falls and remains fairly constant for the β form regardless of temperature.
Like aluminium and magnesium, titanium metal and its alloys oxidize immediately upon exposure to air. Titanium readily reacts with oxygen at 1,200 °C (2,190 °F) in air, and at 610 °C (1,130 °F) in pure oxygen, forming titanium dioxide. It is, however, slow to react with water and air at ambient temperatures because it forms a passive oxide coating that protects the bulk metal from further oxidation. When it first forms, this protective layer is only 1–2 nm thick but continues to grow slowly; reaching a thickness of 25 nm in four years.
Atmospheric passivation gives titanium excellent resistance to corrosion, almost equivalent to platinum. Titanium is capable of withstanding attack by dilute sulfuric and hydrochloric acids, chloride solutions, and most organic acids. 550 °C (1,022 °F), it combines with chlorine. It also reacts with the other halogens and absorbs hydrogen.However, titanium is corroded by concentrated acids. As indicated by its negative redox potential, titanium is thermodynamically a very reactive metal that burns in normal atmosphere at lower temperatures than the melting point. Melting is possible only in an inert atmosphere or in a vacuum. At
Titanium is one of the few elements that burns in pure nitrogen gas, reacting at 800 °C (1,470 °F) to form titanium nitride, which causes embrittlement. Because of its high reactivity with oxygen, nitrogen, and some other gases, titanium filaments are applied in titanium sublimation pumps as scavengers for these gases. Such pumps inexpensively and reliably produce extremely low pressures in ultra-high vacuum systems.
|% of total|
Titanium is the ninth-most abundant element in Earth's crust (0.63% by mass)and the seventh-most abundant metal. It is present as oxides in most igneous rocks, in sediments derived from them, in living things, and natural bodies of water. Of the 801 types of igneous rocks analyzed by the United States Geological Survey, 784 contained titanium. Its proportion in soils is approximately 0.5 to 1.5%.
Common titanium-containing minerals are anatase, brookite, ilmenite, perovskite, rutile, and titanite (sphene).Akaogiite is an extremely rare mineral consisting of titanium dioxide. Of these minerals, only rutile and ilmenite have economic importance, yet even they are difficult to find in high concentrations. About 6.0 and 0.7 million tonnes of those minerals were mined in 2011, respectively. Significant titanium-bearing ilmenite deposits exist in western Australia, Canada, China, India, Mozambique, New Zealand, Norway, Sierra Leone, South Africa, and Ukraine. About 186,000 tonnes of titanium metal sponge were produced in 2011, mostly in China (60,000 t), Japan (56,000 t), Russia (40,000 t), United States (32,000 t) and Kazakhstan (20,700 t). Total reserves of titanium are estimated to exceed 600 million tonnes.
The concentration of titanium is about 4 picomolar in the ocean. At 100 °C, the concentration of titanium in water is estimated to be less than 10−7 M at pH 7. The identity of titanium species in aqueous solution remains unknown because of its low solubility and the lack of sensitive spectroscopic methods, although only the 4+ oxidation state is stable in air. No evidence exists for a biological role, although rare organisms are known to accumulate high concentrations of titanium.
Titanium is contained in meteorites, and it has been detected in the Sun and in M-type stars 3,200 °C (5,790 °F). Rocks brought back from the Moon during the Apollo 17 mission are composed of 12.1% TiO2. It is also found in coal ash, plants, and even the human body. Native titanium (pure metallic) is very rare.(the coolest type) with a surface temperature of
Naturally occurring titanium is composed of 5 stable isotopes: 46Ti, 47Ti, 48Ti, 49Ti, and 50Ti, with 48Ti being the most abundant (73.8% natural abundance). At least 21 radioisotopes have been characterized, the most stable of which are 44Ti with a half-life of 63 years; 45Ti, 184.8 minutes; 51Ti, 5.76 minutes; and 52Ti, 1.7 minutes. All other radioactive isotopes have half-lives less than 33 seconds, with the majority less than half a second.
The isotopes of titanium range in atomic weight from 39.99 u (40Ti) to 57.966 u (58Ti). The primary decay mode before the most abundant stable isotope, 48Ti, is electron capture and the primary mode after is beta emission. The primary decay products before 48Ti are element 21 (scandium) isotopes and the primary products after are element 23 (vanadium) isotopes.
Titanium becomes radioactive upon bombardment with deuterons, emitting mainly positrons and hard gamma rays.
The +4 oxidation state dominates titanium chemistry,but compounds in the +3 oxidation state are also common. Commonly, titanium adopts an octahedral coordination geometry in its complexes, but tetrahedral TiCl4 is a notable exception. Because of its high oxidation state, titanium(IV) compounds exhibit a high degree of covalent bonding. Unlike most other transition metals, simple aquo Ti(IV) complexes are unknown.
The most important oxide is TiO2, which exists in three important polymorphs; anatase, brookite, and rutile. All of these are white diamagnetic solids, although mineral samples can appear dark (see rutile). They adopt polymeric structures in which Ti is surrounded by six oxide ligands that link to other Ti centers.
The term titanates usually refers to titanium(IV) compounds, as represented by barium titanate (BaTiO3). With a perovskite structure, this material exhibits piezoelectric properties and is used as a transducer in the interconversion of sound and electricity.Many minerals are titanates, e.g. ilmenite (FeTiO3). Star sapphires and rubies get their asterism (star-forming shine) from the presence of titanium dioxide impurities.
A variety of reduced oxides (suboxides) of titanium are known, mainly reduced stoichiometries of titanium dioxide obtained by atmospheric plasma spraying.Ti3O5, described as a Ti(IV)-Ti(III) species, is a purple semiconductor produced by reduction of TiO2 with hydrogen at high temperatures,and is used industrially when surfaces need to be vapour-coated with titanium dioxide: it evaporates as pure TiO, whereas TiO2 evaporates as a mixture of oxides and deposits coatings with variable refractive index. Also known is Ti2O3, with the corundum structure, and TiO, with the rock salt structure, although often nonstoichiometric.
The alkoxides of titanium(IV), prepared by reacting TiCl4 with alcohols, are colourless compounds that convert to the dioxide on reaction with water. They are industrially useful for depositing solid TiO2 via the sol-gel process. Titanium isopropoxide is used in the synthesis of chiral organic compounds via the Sharpless epoxidation.
Titanium forms a variety of sulfides, but only TiS2 has attracted significant interest. It adopts a layered structure and was used as a cathode in the development of lithium batteries. Because Ti(IV) is a "hard cation", the sulfides of titanium are unstable and tend to hydrolyze to the oxide with release of hydrogen sulfide.
Titanium nitride (TiN) is a member of a family of refractory transition metal nitrides and exhibits properties similar to both covalent compounds including; thermodynamic stability, extreme hardness, thermal/electrical conductivity, and a high melting point.TiN has a hardness equivalent to sapphire and carborundum (9.0 on the Mohs Scale), and is often used to coat cutting tools, such as drill bits. It is also used as a gold-colored decorative finish and as a barrier metal in semiconductor fabrication. Titanium carbide, which is also very hard, is found in cutting tools and coatings.
Titanium tetrachloride (titanium(IV) chloride, TiCl4) is a colorless volatile liquid (commercial samples are yellowish) that, in air, hydrolyzes with spectacular emission of white clouds. Via the Kroll process, TiCl4 is produced in the conversion of titanium ores to titanium dioxide, e.g., for use in white paint. It is widely used in organic chemistry as a Lewis acid, for example in the Mukaiyama aldol condensation. In the van Arkel process, titanium tetraiodide (TiI4) is generated in the production of high purity titanium metal.
Titanium(III) and titanium(II) also form stable chlorides. A notable example is titanium(III) chloride (TiCl3), which is used as a catalyst for production of polyolefins (see Ziegler–Natta catalyst) and a reducing agent in organic chemistry.
Owing to the important role of titanium compounds as polymerization catalyst, compounds with Ti-C bonds have been intensively studied. The most common organotitanium complex is titanocene dichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and Petasis reagent. Titanium forms carbonyl complexes, e.g. (C5H5)2Ti(CO)2.
Following the success of platinum-based chemotherapy, titanium(IV) complexes were among the first non-platinum compounds to be tested for cancer treatment. The advantage of titanium compounds lies in their high efficacy and low toxicity. In biological environments, hydrolysis leads to the safe and inert titanium dioxide. Despite these advantages the first candidate compounds failed clinical trials. Further development resulted in the creation of potentially effective, selective, and stable titanium-based drugs.Their mode of action is not yet well understood.
Titanium was discovered in 1791 by the clergyman and amateur geologist, William Gregor, as an inclusion of a mineral in Cornwall, Great Britain.Gregor recognized the presence of a new element in ilmenite when he found black sand by a stream and noticed the sand was attracted by a magnet. Analyzing the sand, he determined the presence of two metal oxides: iron oxide (explaining the attraction to the magnet) and 45.25% of a white metallic oxide he could not identify. Realizing that the unidentified oxide contained a metal that did not match any known element, Gregor reported his findings to the Royal Geological Society of Cornwall and in the German science journal Crell's Annalen .
Around the same time, Franz-Joseph Müller von Reichenstein produced a similar substance, but could not identify it.The oxide was independently rediscovered in 1795 by Prussian chemist Martin Heinrich Klaproth in rutile from Boinik (German name Bajmócska), a village in Hungary (now Bojničky in Slovakia). Klaproth found that it contained a new element and named it for the Titans of Greek mythology. After hearing about Gregor's earlier discovery, he obtained a sample of manaccanite and confirmed that it contained titanium.
The currently known processes for extracting titanium from its various ores are laborious and costly; it is not possible to reduce the ore by heating with carbon (as in iron smelting) because titanium combines with the carbon to produce titanium carbide. °C under great pressure in a batch process known as the Hunter process. Titanium metal was not used outside the laboratory until 1932 when William Justin Kroll proved that it can be produced by reducing titanium tetrachloride (TiCl4) with calcium. Eight years later he refined this process with magnesium and even sodium in what became known as the Kroll process. Although research continues into more efficient and cheaper processes (e.g., FFC Cambridge, Armstrong), the Kroll process is still used for commercial production.Pure metallic titanium (99.9%) was first prepared in 1910 by Matthew A. Hunter at Rensselaer Polytechnic Institute by heating TiCl4 with sodium at 700–800
Titanium of very high purity was made in small quantities when Anton Eduard van Arkel and Jan Hendrik de Boer discovered the iodide, or crystal bar, process in 1925, by reacting with iodine and decomposing the formed vapours over a hot filament to pure metal.
In the 1950s and 1960s, the Soviet Union pioneered the use of titanium in military and submarine applications(Alfa class and Mike class) as part of programs related to the Cold War. Starting in the early 1950s, titanium came into use extensively in military aviation, particularly in high-performance jets, starting with aircraft such as the F-100 Super Sabre and Lockheed A-12 and SR-71.
Recognizing the strategic importance of titanium,the U.S. Department of Defense supported early efforts of commercialization.
Throughout the period of the Cold War, titanium was considered a strategic material by the U.S. government, and a large stockpile of titanium sponge was maintained by the Defense National Stockpile Center, which was finally depleted in the 2000s.According to 2006 data, the world's largest producer, Russian-based VSMPO-AVISMA, was estimated to account for about 29% of the world market share. As of 2015, titanium sponge metal was produced in seven countries: China, Japan, Russia, Kazakhstan, the US, Ukraine, and India. (in order of output).
In 2006, the U.S. Defense Advanced Research Projects Agency (DARPA) awarded $5.7 million to a two-company consortium to develop a new process for making titanium metal powder. Under heat and pressure, the powder can be used to create strong, lightweight items ranging from armour plating to components for the aerospace, transport, and chemical processing industries.
The processing of titanium metal occurs in four major steps:reduction of titanium ore into "sponge", a porous form; melting of sponge, or sponge plus a master alloy to form an ingot; primary fabrication, where an ingot is converted into general mill products such as billet, bar, plate, sheet, strip, and tube; and secondary fabrication of finished shapes from mill products.
Because it cannot be readily produced by reduction of its dioxide, °C molten magnesium in an argon atmosphere. Titanium metal can be further purified by the van Arkel–de Boer process, which involves thermal decomposition of titanium tetraiodide.titanium metal is obtained by reduction of TiCl4 with magnesium metal in the Kroll process. The complexity of this batch production in the Kroll process explains the relatively high market value of titanium, despite the Kroll process being less expensive than the Hunter process. To produce the TiCl4 required by the Kroll process, the dioxide is subjected to carbothermic reduction in the presence of chlorine. In this process, the chlorine gas is passed over a red-hot mixture of rutile or ilmenite in the presence of carbon. After extensive purification by fractional distillation, the TiCl4 is reduced with 800
A more recently developed batch production method, the FFC Cambridge process,consumes titanium dioxide powder (a refined form of rutile) as feedstock and produces titanium metal, either powder or sponge. The process involves fewer steps than the Kroll process and takes less time. If mixed oxide powders are used, the product is an alloy.
Common titanium alloys are made by reduction. For example, cuprotitanium (rutile with copper added is reduced), ferrocarbon titanium (ilmenite reduced with coke in an electric furnace), and manganotitanium (rutile with manganese or manganese oxides) are reduced.
About fifty grades of titanium and titanium alloys are designed and currently used, although only a couple of dozen are readily available commercially.The ASTM International recognizes 31 grades of titanium metal and alloys, of which grades one through four are commercially pure (unalloyed). Those four vary in tensile strength as a function of oxygen content, with grade 1 being the most ductile (lowest tensile strength with an oxygen content of 0.18%), and grade 4 the least ductile (highest tensile strength with an oxygen content of 0.40%). The remaining grades are alloys, each designed for specific properties of ductility, strength, hardness, electrical resistivity, creep resistance, specific corrosion resistance, and combinations thereof.
In addition to the ASTM specifications, titanium alloys are also produced to meet aerospace and military specifications (SAE-AMS, MIL-T), ISO standards, and country-specific specifications, as well as proprietary end-user specifications for aerospace, military, medical, and industrial applications.
Titanium powder is manufactured using a flow production process known as the Armstrong processthat is similar to the batch production Hunter process. A stream of titanium tetrachloride gas is added to a stream of molten sodium metal; the products (sodium chloride salt and titanium particles) is filtered from the extra sodium. Titanium is then separated from the salt by water washing. Both sodium and chlorine are recycled to produce and process more titanium tetrachloride.
All welding of titanium must be done in an inert atmosphere of argon or helium to shield it from contamination with atmospheric gases (oxygen, nitrogen, and hydrogen).Contamination causes a variety of conditions, such as embrittlement, which reduce the integrity of the assembly welds and lead to joint failure.
Commercially pure flat product (sheet, plate) can be formed readily, but processing must take into account the fact that the metal has a "memory" and tends to spring back. This is especially true of certain high-strength alloys.Titanium cannot be soldered without first pre-plating it in a metal that is solderable. The metal can be machined with the same equipment and the same processes as stainless steel.
Titanium is used in steel as an alloying element (ferro-titanium) to reduce grain size and as a deoxidizer, and in stainless steel to reduce carbon content.Titanium is often alloyed with aluminium (to refine grain size), vanadium, copper (to harden), iron, manganese, molybdenum, and other metals. Titanium mill products (sheet, plate, bar, wire, forgings, castings) find application in industrial, aerospace, recreational, and emerging markets. Powdered titanium is used in pyrotechnics as a source of bright-burning particles.
About 95% of all titanium ore is destined for refinement into titanium dioxide (TiO
2), an intensely white permanent pigment used in paints, paper, toothpaste, and plastics. It is also used in cement, in gemstones, as an optical opacifier in paper, and a strengthening agent in graphite composite fishing rods and golf clubs.
2 pigment is chemically inert, resists fading in sunlight, and is very opaque: it imparts a pure and brilliant white colour to the brown or grey chemicals that form the majority of household plastics. In nature, this compound is found in the minerals anatase, brookite, and rutile. Paint made with titanium dioxide does well in severe temperatures and marine environments. Pure titanium dioxide has a very high index of refraction and an optical dispersion higher than diamond. In addition to being a very important pigment, titanium dioxide is also used in sunscreens.
Because titanium alloys have high tensile strength to density ratio,high corrosion resistance, fatigue resistance, high crack resistance, and ability to withstand moderately high temperatures without creeping, they are used in aircraft, armour plating, naval ships, spacecraft, and missiles. For these applications, titanium is alloyed with aluminium, zirconium, nickel, vanadium, and other elements to manufacture a variety of components including critical structural parts, fire walls, landing gear, exhaust ducts (helicopters), and hydraulic systems. In fact, about two thirds of all titanium metal produced is used in aircraft engines and frames. The titanium 6AL-4V alloy accounts for almost 50% of all alloys used in aircraft applications.
The Lockheed A-12 and its development the SR-71 "Blackbird" were two of the first aircraft frames where titanium was used, paving the way for much wider use in modern military and commercial aircraft. An estimated 59 metric tons (130,000 pounds) are used in the Boeing 777, 45 in the Boeing 747, 18 in the Boeing 737, 32 in the Airbus A340, 18 in the Airbus A330, and 12 in the Airbus A320. The Airbus A380 may use 77 metric tons, including about 11 tons in the engines. 412In aero engine applications, titanium is used for rotors, compressor blades, hydraulic system components, and nacelles. An early use in jet engines was for the Orenda Iroquois in the 1950s. :
Because titanium is resistant to corrosion by sea water, it is used to make propeller shafts, rigging, and heat exchangers in desalination plants;heater-chillers for salt water aquariums, fishing line and leader, and divers' knives. Titanium is used in the housings and components of ocean-deployed surveillance and monitoring devices for science and the military. The former Soviet Union developed techniques for making submarines with hulls of titanium alloys forging titanium in huge vacuum tubes.
Titanium is used in the walls of the Juno spacecraft's vault to shield on-board electronics.
Welded titanium pipe and process equipment (heat exchangers, tanks, process vessels, valves) are used in the chemical and petrochemical industries primarily for corrosion resistance. Specific alloys are used in oil and gas downhole applications and nickel hydrometallurgy for their high strength (e. g.: titanium beta C alloy), corrosion resistance, or both. The pulp and paper industry uses titanium in process equipment exposed to corrosive media, such as sodium hypochlorite or wet chlorine gas (in the bleachery).Other applications include ultrasonic welding, wave soldering, and sputtering targets.
Titanium tetrachloride (TiCl4), a colorless liquid, is important as an intermediate in the process of making TiO2 and is also used to produce the Ziegler–Natta catalyst. Titanium tetrachloride is also used to iridize glass and, because it fumes strongly in moist air, it is used to make smoke screens.
Titanium metal is used in automotive applications, particularly in automobile and motorcycle racing where low weight and high strength and rigidity are critical.The metal is generally too expensive for the general consumer market, though some late model Corvettes have been manufactured with titanium exhausts, and a Corvette Z06's LT4 supercharged engine uses lightweight, solid titanium intake valves for greater strength and resistance to heat.
Titanium is used in many sporting goods: tennis rackets, golf clubs, lacrosse stick shafts; cricket, hockey, lacrosse, and football helmet grills, and bicycle frames and components. Although not a mainstream material for bicycle production, titanium bikes have been used by racing teams and adventure cyclists.
Titanium alloys are used in spectacle frames that are rather expensive but highly durable, long lasting, light weight, and cause no skin allergies. Many backpackers use titanium equipment, including cookware, eating utensils, lanterns, and tent stakes. Though slightly more expensive than traditional steel or aluminium alternatives, titanium products can be significantly lighter without compromising strength. Titanium horseshoes are preferred to steel by farriers because they are lighter and more durable.
Titanium has occasionally been used in architecture. The 42.5 m (139 ft) Monument to Yuri Gagarin, the first man to travel in space ( ), as well as the 110 m (360 ft) Monument to the Conquerors of Space on top of the Cosmonaut Museum in Moscow are made of titanium for the metal's attractive colour and association with rocketry. The Guggenheim Museum Bilbao and the Cerritos Millennium Library were the first buildings in Europe and North America, respectively, to be sheathed in titanium panels. Titanium sheathing was used in the Frederic C. Hamilton Building in Denver, Colorado.
Because of titanium's superior strength and light weight relative to other metals (steel, stainless steel, and aluminium), and because of recent advances in metalworking techniques, its use has become more widespread in the manufacture of firearms. Primary uses include pistol frames and revolver cylinders. For the same reasons, it is used in the body of laptop computers (for example, in Apple's PowerBook line).
Some upmarket lightweight and corrosion-resistant tools, such as shovels and flashlights, are made of titanium or titanium alloys.
Because of its durability, titanium has become more popular for designer jewelry (particularly, titanium rings).Its inertness makes it a good choice for those with allergies or those who will be wearing the jewelry in environments such as swimming pools. Titanium is also alloyed with gold to produce an alloy that can be marketed as 24-karat gold because the 1% of alloyed Ti is insufficient to require a lesser mark. The resulting alloy is roughly the hardness of 14-karat gold and is more durable than pure 24-karat gold.
Titanium's durability, light weight, and dent and corrosion resistance make it useful for watch cases.Some artists work with titanium to produce sculptures, decorative objects and furniture.
Titanium may be anodized to vary the thickness of the surface oxide layer, causing optical interference fringes and a variety of bright colors.With this coloration and chemical inertness, titanium is a popular metal for body piercing.
Titanium has a minor use in dedicated non-circulating coins and medals. In 1999, Gibraltar released the world's first titanium coin for the millennium celebration.The Gold Coast Titans, an Australian rugby league team, award a medal of pure titanium to their player of the year.
Because titanium is biocompatible (non-toxic and not rejected by the body), it has many medical uses, including surgical implements and implants, such as hip balls and sockets (joint replacement) and dental implants that can stay in place for up to 20 years.The titanium is often alloyed with about 4% aluminium or 6% Al and 4% vanadium.
Titanium has the inherent ability to osseointegrate, enabling use in dental implants that can last for over 30 years. This property is also useful for orthopedic implant applications.These benefit from titanium's lower modulus of elasticity (Young's modulus) to more closely match that of the bone that such devices are intended to repair. As a result, skeletal loads are more evenly shared between bone and implant, leading to a lower incidence of bone degradation due to stress shielding and periprosthetic bone fractures, which occur at the boundaries of orthopedic implants. However, titanium alloys' stiffness is still more than twice that of bone, so adjacent bone bears a greatly reduced load and may deteriorate.
Because titanium is non-ferromagnetic, patients with titanium implants can be safely examined with magnetic resonance imaging (convenient for long-term implants). Preparing titanium for implantation in the body involves subjecting it to a high-temperature plasma arc which removes the surface atoms, exposing fresh titanium that is instantly oxidized.
Titanium is used for the surgical instruments used in image-guided surgery, as well as wheelchairs, crutches, and any other products where high strength and low weight are desirable.
Titanium dioxide nanoparticles are widely used in electronics and the delivery of pharmaceuticals and cosmetics.
Because of its corrosion resistance, containers made of titanium have been studied for the long-term storage of nuclear waste. Containers lasting more than 100,000 years are thought possible with manufacturing conditions that minimize material defects.A titanium "drip shield" could also be installed over containers of other types to enhance their longevity.
The fungal species Marasmius oreades and Hypholoma capnoides can bioconvert titanium in titanium polluted soils.
Titanium is non-toxic even in large doses and does not play any natural role inside the human body.An estimated quantity of 0.8 milligrams of titanium is ingested by humans each day, but most passes through without being absorbed in the tissues. It does, however, sometimes bio-accumulate in tissues that contain silica. One study indicates a possible connection between titanium and yellow nail syndrome. An unknown mechanism in plants may use titanium to stimulate the production of carbohydrates and encourage growth. This may explain why most plants contain about 1 part per million (ppm) of titanium, food plants have about 2 ppm, and horsetail and nettle contain up to 80 ppm.
As a powder or in the form of metal shavings, titanium metal poses a significant fire hazard and, when heated in air, an explosion hazard.Water and carbon dioxide are ineffective for extinguishing a titanium fire; Class D dry powder agents must be used instead.
When used in the production or handling of chlorine, titanium should not be exposed to dry chlorine gas because it may result in a titanium–chlorine fire.Even wet chlorine presents a fire hazard when extreme weather conditions cause unexpected drying.
Titanium can catch fire when a fresh, non-oxidized surface comes in contact with liquid oxygen.Fresh metal may be exposed when the oxidized surface is struck or scratched with a hard object, or when mechanical strain causes a crack. This poses a limitation to its use in liquid oxygen systems, such as those in the aerospace industry. Because titanium tubing impurities can cause fires when exposed to oxygen, titanium is prohibited in gaseous oxygen respiration systems. Steel tubing is used for high pressure systems (3,000 p.s.i.) and aluminium tubing for low pressure systems.
Rutile is a mineral composed primarily of titanium dioxide (TiO2).
Ilmenite, also known as manaccanite, is a titanium-iron oxide mineral with the idealized formula FeTiO
3. It is a weakly magnetic black or steel-gray solid. From a commercial perspective, ilmenite is the most important ore of titanium. Ilmenite is the main source of titanium dioxide, which is used in paints, printing inks, fabrics, plastics, paper, sunscreen, food and cosmetics.
Corrosion is a natural process, which converts a refined metal to a more chemically-stable form, such as its oxide, hydroxide, or sulfide. It is the gradual destruction of materials by chemical and/or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and stopping corrosion.
Passivation, in physical chemistry and engineering, refers to a material becoming "passive," that is, less affected or corroded by the environment of future use. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build from spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shell against corrosion. Passivation can occur only in certain conditions, and is used in microelectronics to enhance silicon. The technique of passivation strengthens and preserves the appearance of metallics. In electrochemical treatment of water, passivation reduces the effectiveness of the treatment by increasing the circuit resistance, and active measures are typically used to overcome this effect, the most common being polarity reversal, which results in limited rejection of the fouling layer. Other proprietary systems to avoid electrode passivation, several discussed below, are the subject of ongoing research and development.
Titanium dioxide, also known as titanium(IV) oxide or titania, is the naturally occurring oxide of titanium, chemical formula TiO
2. When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. Generally, it is sourced from ilmenite, rutile and anatase. It has a wide range of applications, including paint, sunscreen and food coloring. When used as a food coloring, it has E number E171. World production in 2014 exceeded 9 million metric tons. It has been estimated that titanium dioxide is used in two-thirds of all pigments, and pigments based on the oxide has been valued at $13.2 billion.
Manganese(IV) oxide is the inorganic compound with the formula MnO
2. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO
2 is for dry-cell batteries, such as the alkaline battery and the zinc-carbon battery. MnO
2 is also used as a pigment and as a precursor to other manganese compounds, such as KMnO
4. It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. MnO
2 in the α polymorph can incorporate a variety of atoms in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in α-MnO
2 as a possible cathode for lithium ion batteries.
Group 4 is a group of elements in the periodic table. It contains the elements titanium (Ti), zirconium (Zr), hafnium (Hf) and rutherfordium (Rf). This group lies in the d-block of the periodic table. The group itself has not acquired a trivial name; it belongs to the broader grouping of the transition metals.
Titanium tetrachloride is the inorganic compound with the formula TiCl4. It is an important intermediate in the production of titanium metal and the pigment titanium dioxide. TiCl4 is a volatile liquid. Upon contact with humid air, it forms spectacular opaque clouds of titanium dioxide (TiO2) and hydrated hydrogen chloride. It is sometimes referred to as "tickle" or "tickle 4" due to the phonetic resemblance of its molecular formula (TiCl4) to the word.
Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).
The Kroll process is a pyrometallurgical industrial process used to produce metallic titanium. It was invented in 1940 by William J. Kroll in Luxembourg. After moving to the United States, Kroll further developed the method for the production of zirconium. The Kroll process replaced the Hunter process for almost all commercial production.
Titanium alloys are metals that contain a mixture of titanium and other chemical elements. Such alloys have very high tensile strength and toughness. They are light in weight, have extraordinary corrosion resistance and the ability to withstand extreme temperatures. However, the high cost of both raw materials and processing limit their use to military applications, aircraft, spacecraft, bicycles, medical devices, jewelry, highly stressed components such as connecting rods on expensive sports cars and some premium sports equipment and consumer electronics.
Lead(IV) oxide, commonly called lead dioxide, plumbic oxide or anhydrous plumbic acid (sometimes wrongly called lead peroxide), is a chemical compound with the formula PbO2. It is an oxide where lead is in an oxidation state of +4; bond type is predominantly covalent. It is an odorless dark-brown crystalline powder which is nearly insoluble in water. It exists in two crystalline forms. The alpha phase has orthorhombic symmetry; it was first synthesized in 1941 and was identified in nature as a rare mineral scrutinyite in 1988. The more common tetragonal beta phase was first identified as the mineral plattnerite around 1845 and later produced synthetically. Lead dioxide is a strong oxidizing agent which is used in the manufacture of matches, pyrotechnics, dyes and other chemicals. It also has several important applications in electrochemistry, in particular in the positive plates of lead acid batteries.
Carbothermic reactions involve the reduction of substances, often metal oxides, using carbon as the reducing agent. These chemical reactions are usually conducted at temperatures of several hundred degrees Celsius. Such processes are applied for production of the elemental forms of many elements. Carbothermic reactions are not useful for some metal oxides, such as those of sodium and potassium. The ability of metals to participate in carbothermic reactions can be predicted from Ellingham diagrams.
Titanium aluminide, TiAl, is an intermetallic chemical compound. It is lightweight and resistant to oxidation and heat, however it suffers from low ductility. The density of γ-TiAl is about 4.0 g/cm³. It finds use in several applications including automobiles and aircraft. The development of TiAl based alloys began about 1970; however the alloys have been used in these applications only since about 2000.
Titanium hydride normally refers to the inorganic compound TiH2 and related nonstoichiometric materials. It is commercially available as a stable grey/black powder, which is used as an additive in the production of Alnico sintered magnets, in the sintering of powdered metals, the production of metal foam, the production of powdered titanium metal and in pyrotechnics.
Kenmare Resources plc is a mining company based in the Republic of Ireland. It is listed on the Irish Stock Exchange and the London Stock Exchange. Kenmare owns and operates the Moma mine. Moma is the world’s largest titanium mineral deposit, located 160km from the city of Nampula in Mozambique, Africa.
The chloride process is used to separate titanium from its ores. In this process, the feedstock is treated at 1000 °C with carbon and chlorine gas, giving titanium tetrachloride. Typical is the conversion starting from the ore ilmenite:
The Becher Process is an industrial process used to upgrade ilmenite to synthetic rutile.
Titanium Beta C refers to Ti Beta-C, a trademark for an alloy of titanium originally filed by RTI International. It is a metastable "beta alloy" which was originally developed in the 1960s; Ti-3Al-8V-6Cr-4Mo-4Zr, nominally 3% aluminum, 8% vanadium, 6% chromium, 4% molybdenum, 4% zirconium and balance: titanium.
Titanium rings are jewelry rings or bands which have been primarily constructed from titanium. The actual compositions of titanium can vary, such as "commercial pure" or "aircraft grade", and titanium rings are often crafted in combination with other materials, such as gemstones and traditional jewelry metals. Even with these variations in composition and materials, titanium rings are commonly referred to as such if they contain any amount of titanium.