In chemistry, a group (also known as a family) [1] is a column of elements in the periodic table of the chemical elements. There are 18 numbered groups in the periodic table; the 14 f-block columns, between groups 2 and 3, are not numbered. The elements in a group have similar physical or chemical characteristics of the outermost electron shells of their atoms (i.e., the same core charge), because most chemical properties are dominated by the orbital location of the outermost electron.
The modern numbering system of "group 1" to "group 18" has been recommended by the International Union of Pure and Applied Chemistry (IUPAC) since 1988. The 1-18 system is based on each atom's s, p and d electrons beyond those in atoms of the preceding noble gas. Two older incompatible naming schemes can assign the same number to different groups depending on the system being used. The older schemes were used by the Chemical Abstract Service (CAS, more popular in the United States), and by IUPAC before 1988 (more popular in Europe). The system of eighteen groups is generally accepted by the chemistry community, but some dissent exists about membership of elements number 1 and 2 (hydrogen and helium). Similar variation on the inner transition metals continues to exist in textbooks, although the correct positioning has been known since 1948 and was twice endorsed by IUPAC in 1988 (together with the 1–18 numbering) and 2021.
Groups may also be identified using their topmost element, or have a specific name. For example, group 16 is also described as the "oxygen group" and as the "chalcogens". An exception is the "iron group", which usually refers to group 8, but in chemistry may also mean iron, cobalt, and nickel, or some other set of elements with similar chemical properties. In astrophysics and nuclear physics, it usually refers to iron, cobalt, nickel, chromium, and manganese.
Modern group names are numbers 1–18, with the 14 f-block columns remaining unnumbered (together making the 32 columns in the periodic table). Also, trivial names (like halogens) are common. In history, several sets of group names have been used, based on Roman numberings I–VIII, and "A" and "B" suffixes. [2] [3]
IUPAC group | 1 a | 2 | — b | 3 c | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Mendeleev (I–VIII) | I | II | III | IV | V | VI | VII | VIII | I | II | III | IV | V | VI | VII | d | |||
CAS (US, A-B-A) | IA | IIA | IIIB | IVB | VB | VIB | VIIB | VIIIB | IB | IIB | IIIA | IVA | VA | VIA | VIIA | VIIIA | |||
Old IUPAC (Europe, A-B) | IA | IIA | IIIA | IVA | VA | VIA | VIIA | VIII | IB | IIB | IIIB | IVB | VB | VIB | VIIB | 0 | |||
Trivial name r | H and alkali metals | alkaline earth metals | triels | tetrels | pnictogens | chalcogens | halogens | noble gases | |||||||||||
Name by element r | lithium group | beryllium group | scandium group | titanium group | vanadium group | chromium group | manganese group | iron group | cobalt group | nickel group | copper group | zinc group | boron group | carbon group | nitrogen group | oxygen group | fluorine group | helium or neon group | |
Period 1 | H | He | |||||||||||||||||
Period 2 | Li | Be | B | C | N | O | F | Ne | |||||||||||
Period 3 | Na | Mg | Al | Si | P | S | Cl | Ar | |||||||||||
Period 4 | K | Ca | Sc | Ti | V | Cr | Mn | Fe | Co | Ni | Cu | Zn | Ga | Ge | As | Se | Br | Kr | |
Period 5 | Rb | Sr | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd | Ag | Cd | In | Sn | Sb | Te | I | Xe | |
Period 6 | Cs | Ba | La–Yb | Lu | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | Tl | Pb | Bi | Po | At | Rn |
Period 7 | Fr | Ra | Ac–No | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og |
IUPAC name | Old IUPAC (Europe) | Old CAS name (U.S.) | Name by element ('group' or 'family') | IUPAC recommended trivial name | Other names |
---|---|---|---|---|---|
Group 1 | IA | IA | lithium group | hydrogen and alkali metals | "lithium group" excludes hydrogen |
Group 2 | IIA | IIA | beryllium group | alkaline earth metals | |
Group 3 | IIIA | IIIB | scandium group | ||
Group 4 | IVA | IVB | titanium group | ||
Group 5 | VA | VB | vanadium group | ||
Group 6 | VIA | VIB | chromium group | ||
Group 7 | VIIA | VIIB | manganese group | ||
Group 8 | VIII | VIIIB | iron group | ||
Group 9 | VIII | VIIIB | cobalt group | ||
Group 10 | VIII | VIIIB | nickel group | ||
Group 11 | IB | IB | copper group | Sometimes called coinage metals, but the set is arbitrary f | |
Group 12 | IIB | IIB | zinc group | volatile metals [11] | |
Group 13 | IIIB | IIIA | boron group | triels b | icosagens [12] earth metals |
Group 14 | IVB | IVA | carbon group | tetrels c | crystallogens [13] adamantogens [14] merylides [15] |
Group 15 | VB | VA | nitrogen group | pnictogens pentels n | |
Group 16 | VIB | VIA | oxygen group | chalcogens | |
Group 17 | VIIB | VIIA | fluorine group | halogens | |
Group 18 | 0 | VIIIA | helium group or neon group | noble gases | aerogens [16] |
Two earlier group number systems exist: CAS (Chemical Abstracts Service) and old IUPAC. Both use numerals (Arabic or Roman) and letters A and B. Both systems agree on the numbers. The numbers indicate approximately the highest oxidation number of the elements in that group, and so indicate similar chemistry with other elements with the same numeral. The number proceeds in a linearly increasing fashion for the most part, once on the left of the table, and once on the right (see List of oxidation states of the elements), with some irregularities in the transition metals. However, the two systems use the letters differently. For example, potassium (K) has one valence electron. Therefore, it is located in group 1. Calcium (Ca) is in group 2, for it contains two valence electrons.
In the old IUPAC system the letters A and B were designated to the left (A) and right (B) part of the table, while in the CAS system the letters A and B are designated to main group elements (A) and transition elements (B). The old IUPAC system was frequently used in Europe, while the CAS is most common in America. The new IUPAC scheme was developed to replace both systems as they confusingly used the same names to mean different things. The new system simply numbers the groups increasingly from left to right on the standard periodic table. The IUPAC proposal was first circulated in 1985 for public comments, [2] and was later included as part of the 1990 edition of the Nomenclature of Inorganic Chemistry. [19]
While groups are defined to be columns in the periodic table, as described above, there are also sets of elements named "group" that are not a column:
Similar sets: noble metals, coinage metals, precious metals, refractory metals.
The actinide or actinoid series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide.
Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, its usual oxidation state is +3, although some compounds are known with an oxidation state of +2. Lanthanum has no biological role in humans but is essential to some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.
Lutetium is a chemical element; it has symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earth elements; it can also be classified as the first element of the 6th-period transition metals.
Lawrencium is a synthetic chemical element; it has symbol Lr and atomic number 103. It is named after Ernest Lawrence, inventor of the cyclotron, a device that was used to discover many artificial radioactive elements. A radioactive metal, lawrencium is the eleventh transuranium element, the third transfermium, and the last member of the actinide series. Like all elements with atomic number over 100, lawrencium can only be produced in particle accelerators by bombarding lighter elements with charged particles. Fourteen isotopes of lawrencium are currently known; the most stable is 266Lr with half-life 11 hours, but the shorter-lived 260Lr is most commonly used in chemistry because it can be produced on a larger scale.
The lanthanide or lanthanoid series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.
The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows ("periods") and columns ("groups"). It is an icon of chemistry and is widely used in physics and other sciences. It is a depiction of the periodic law, which states that when the elements are arranged in order of their atomic numbers an approximate recurrence of their properties is evident. The table is divided into four roughly rectangular areas called blocks. Elements in the same group tend to show similar chemical characteristics.
In chemistry, a transition metal is a chemical element in the d-block of the periodic table, though the elements of group 12 are sometimes excluded. The lanthanide and actinide elements are called inner transition metals and are sometimes considered to be transition metals as well.
In physics and chemistry, ionization energy (IE) is the minimum energy required to remove the most loosely bound electron of an isolated gaseous atom, positive ion, or molecule. The first ionization energy is quantitatively expressed as
In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule in atomic or molecular orbitals. For example, the electron configuration of the neon atom is 1s2 2s2 2p6, meaning that the 1s, 2s, and 2p subshells are occupied by two, two, and six electrons, respectively.
A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the chemical elements, including the lanthanides. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The sixth period contains 32 elements, tied for the most with period 7, beginning with caesium and ending with radon. Lead is currently the last stable element; all subsequent elements are radioactive. For bismuth, however, its only primordial isotope, 209Bi, has a half-life of more than 1019 years, over a billion times longer than the current age of the universe. As a rule, period 6 elements fill their 6s shells first, then their 4f, 5d, and 6p shells, in that order; however, there are exceptions, such as gold.
A period 1 element is one of the chemical elements in the first row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate periodic (recurring) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that analog elements fall into the same vertical columns. The first period contains fewer elements than any other row in the table, with only two: hydrogen and helium. This situation can be explained by modern theories of atomic structure. In a quantum mechanical description of atomic structure, this period corresponds to the filling of the 1s orbital. Period 1 elements obey the duet rule in that they need two electrons to complete their valence shell.
A period 7 element is one of the chemical elements in the seventh row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behavior of the elements as their atomic number increases: a new row is begun when chemical behavior begins to repeat, meaning that elements with similar behavior fall into the same vertical columns. The seventh period contains 32 elements, tied for the most with period 6, beginning with francium and ending with oganesson, the heaviest element currently discovered. As a rule, period 7 elements fill their 7s shells first, then their 5f, 6d, and 7p shells in that order, but there are exceptions, such as uranium.
Chemistry is the physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions.
Group 3 is the first group of transition metals in the periodic table. This group is closely related to the rare-earth elements. It contains the four elements scandium (Sc), yttrium (Y), lutetium (Lu), and lawrencium (Lr). The group is also called the scandium group or scandium family after its lightest member.
The periodic table is an arrangement of the chemical elements, structured by their atomic number, electron configuration and recurring chemical properties. In the basic form, elements are presented in order of increasing atomic number, in the reading sequence. Then, rows and columns are created by starting new rows and inserting blank cells, so that rows (periods) and columns (groups) show elements with recurring properties. For example, all elements in group (column) 18 are noble gases that are largely—though not completely—unreactive.
Evgeny Mikhailovich Lifshitz was a leading Soviet physicist and brother of the physicist Ilya Lifshitz.
In atomic physics and quantum chemistry, the Aufbau principle, also called the Aufbau rule, states that in the ground state of an atom or ion, electrons first fill subshells of the lowest available energy, then fill subshells of higher energy. For example, the 1s subshell is filled before the 2s subshell is occupied. In this way, the electrons of an atom or ion form the most stable electron configuration possible. An example is the configuration 1s2 2s2 2p6 3s2 3p3 for the phosphorus atom, meaning that the 1s subshell has 2 electrons, and so on.
The lanthanide contraction is the greater-than-expected decrease in atomic radii and ionic radii of the elements in the lanthanide series, from left to right. It is caused by the poor shielding effect of nuclear charge by the 4f electrons along with the expected periodic trend of increasing electronegativity and nuclear charge on moving from left to right. About 10% of the lanthanide contraction has been attributed to relativistic effects.
A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term seems to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-block, p-block, d-block, f-block and g-block.
William Barry Jensen is an American chemist and chemical historian.