Part of a series on the |
Periodic table |
---|
A period 4 element is one of the chemical elements in the fourth row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The fourth period contains 18 elements beginning with potassium and ending with krypton – one element for each of the eighteen groups. It sees the first appearance of d-block (which includes transition metals) in the table.
All 4th-period elements are stable, [1] and many are extremely common in the Earth's crust and/or core; it is the last period with no unstable elements. Many transition metals in the period are very strong, and therefore common in industry, especially iron. [2] Some are toxic, with all known vanadium compounds toxic, [3] arsenic one of the most well-known poisons, and bromine a toxic liquid. Conversely, many elements are essential to human survival, such as calcium, the main component in bones. [2]
Progressing towards increase of atomic number, the Aufbau principle causes elements of the period to put electrons onto 4s, 3d, and 4p subshells, in that order. However, there are exceptions, such as chromium. The first twelve elements—K, Ca, and transition metals—have from 1 to 12 valence electrons respectively, which are placed on 4s and 3d.
Twelve electrons over the electron configuration of argon reach the configuration of zinc, namely 3d10 4s2. After this element, the filled 3d subshell effectively withdraws from chemistry and the subsequent trend looks much like trends in the periods 2 and 3. The p-block elements of period 4 have their valence shell composed of 4s and 4p subshells of the fourth (n = 4) shell and obey the octet rule.
For quantum chemistry namely this period sees transition from the simplified electron shell paradigm to research of many differently-shaped subshells. The relative disposition of their energy levels is governed by the interplay of various physical effects. The period's s-block metals put their differentiating electrons onto 4s despite having vacancies among nominally lower n = 3 states – a phenomenon unseen in lighter elements. Contrariwise, the six elements from gallium to krypton are the heaviest where all electron shells below the valence shell are filled completely. This is no longer possible in further periods due to the existence of f-subshells starting from n = 4.
Chemical element | Block | Electron configuration | ||
---|---|---|---|---|
19 | K | Potassium | s-block | [Ar] 4s1 |
20 | Ca | Calcium | s-block | [Ar] 4s2 |
21 | Sc | Scandium | d-block | [Ar] 3d1 4s2 |
22 | Ti | Titanium | d-block | [Ar] 3d2 4s2 |
23 | V | Vanadium | d-block | [Ar] 3d3 4s2 |
24 | Cr | Chromium | d-block | [Ar] 3d5 4s1 (*) |
25 | Mn | Manganese | d-block | [Ar] 3d5 4s2 |
26 | Fe | Iron | d-block | [Ar] 3d6 4s2 |
27 | Co | Cobalt | d-block | [Ar] 3d7 4s2 |
28 | Ni | Nickel | d-block | [Ar] 3d8 4s2 |
29 | Cu | Copper | d-block | [Ar] 3d10 4s1 (*) |
30 | Zn | Zinc | d-block | [Ar] 3d10 4s2 |
31 | Ga | Gallium | p-block | [Ar] 3d10 4s2 4p1 |
32 | Ge | Germanium | p-block | [Ar] 3d10 4s2 4p2 |
33 | As | Arsenic | p-block | [Ar] 3d10 4s2 4p3 |
34 | Se | Selenium | p-block | [Ar] 3d10 4s2 4p4 |
35 | Br | Bromine | p-block | [Ar] 3d10 4s2 4p5 |
36 | Kr | Krypton | p-block | [Ar] 3d10 4s2 4p6 |
(*) Exception to the Madelung rule
Potassium (K) is an alkali metal, underneath sodium and above rubidium, [4] and the first element of period 4. One of the most reactive chemical elements, it is usually found only in compounds. It is a silvery metal [5] that tarnishes rapidly when exposed to the oxygen in air, which oxidizes it. It is soft enough to be cut with a knife [6] and the second least-dense element.[ citation needed ] Potassium has a relatively low melting point; it will melt under a small open flame. [5] It also is less dense than water, and can, in principle, float [7] (although it will react with any water it is exposed to). [5]
Calcium (Ca) is the second element in the period. An alkali earth metal, native calcium is almost never found in nature,[ citation needed ] because it reacts with water. [8] It has one of the most widely-known biological roles in all animals and some plants, making up structural elements such as bones and teeth. [9] It also has applications in cells, such as signals for cellular processeses. It is regarded as the most abundant mineral in the human body.[ citation needed ]
Scandium (Sc) is the third element in the period, and is the first transition metal in the periodic table. Scandium is quite common in nature, but difficult to isolate because its chemistry mirrors that of the other rare earth compounds quite closely. Scandium has very few commercial applications, the major exception being aluminium alloys.
Titanium (Ti) is an element in group 4. Titanium is both one of the least dense metals and one of the strongest and most corrosion-resistant. As such, it has many applications, especially in alloys with other elements, such as iron. It is commonly used in airplanes, golf clubs, and other objects that must be strong, but lightweight.
Vanadium (V) is an element in group 5. Vanadium is never found in pure form in nature, but is commonly found in compounds. Vanadium is similar to titanium in many ways, such as being very corrosion-resistant, however, unlike titanium, it oxidizes in air even at room temperature. All vanadium compounds have at least some level of toxicity, with some of them being extremely toxic.
Chromium (Cr) is an element in group 6. Chromium is, like titanium and vanadium before it, extremely resistant to corrosion, and is indeed one of the main components of stainless steel. Chromium also has many colorful compounds, and as such is very commonly used in pigments, such as chrome green.
Manganese (Mn) is an element in group 7. Manganese is often found in combination with iron. Manganese, like chromium before it, is an important component in stainless steel, preventing the iron from rusting. Manganese is also often used in pigments, again like chromium. Manganese is also poisonous; if enough is inhaled, it can cause irreversible neurological damage.
Iron (Fe) is an element in group 8. Iron is the most common on Earth among elements of the period, and probably the most well-known of them. It is the principal component of steel. Iron-56 has the lowest energy density of any isotope of any element, meaning that it is the most massive element that can be produced in supergiant stars. Iron also has some applications in the human body; hemoglobin is partly iron.
Cobalt (Co) is an element in group 9. Cobalt is commonly used in pigments, as many compounds of cobalt are blue in color. Cobalt is also a core component of many magnetic and high-strength alloys. The only stable isotope, cobalt-59, is an important component of vitamin B-12, while cobalt-60 is a component of nuclear fallout and can be dangerous in large enough quantities due to its radioactivity.
Nickel (Ni) is an element in group 10. Nickel is rare in the Earth's crust, mainly due to the fact that it reacts with oxygen in the air, with most of the nickel on Earth coming from nickel iron meteorites. However, nickel is very abundant in the Earth's core; along with iron it is one of the two main components. Nickel is an important component of stainless steel, and in many superalloys.
Copper (Cu) is an element in group 11. Copper is one of the few metals that is not white or gray in color, the only[ citation needed ] others being gold, osmium and caesium. Copper has been used by humans for thousands of years to provide a reddish tint[ clarification needed ] to many objects, and is even an essential nutrient to humans, although too much is poisonous. Copper is also commonly used as a wood preservative or fungicides.
Zinc (Zn) is an element in group 12. Zinc is one of the main components of brass, being used since the 10th century BCE. Zinc is also incredibly important to humans; almost 2 billion people in the world suffer from zinc deficiency. However, too much zinc can cause copper deficiency. Zinc is often used in batteries, aptly named carbon-zinc batteries, and is important in many platings, as zinc is very corrosion resistant.
Gallium (Ga) is an element in group 13, under aluminium. Gallium is noteworthy because it has a melting point at about 303 kelvins, right around room temperature. For example, it will be solid on a typical spring day, but will be liquid on a hot summer day. Gallium is an important component in the alloy galinstan, along with tin. Gallium can also be found in semiconductors.
Germanium (Ge) is an element in group 14. Germanium, like silicon above it, is an important semiconductor and is commonly used in diodes and transistors, often in combination with arsenic. Germanium is fairly rare on Earth, leading to its comparatively late discovery. Germanium, in compounds, can sometimes irritate the eyes, skin, or lungs.
Arsenic (As) is an element in group 15. Arsenic, as mentioned above, is often used in semiconductors in alloys with germanium. Arsenic, in pure form and some alloys, is incredibly poisonous to all multicellular life, and as such is a common component in pesticides. Arsenic was also used in some pigments before its toxicity was discovered.
Selenium (Se) is an element in group 16, the chalcogens. Selenium is the first nonmetal in period 4, with properties similar to sulfur. Selenium is quite rare in pure form in nature, mostly being found in minerals such as pyrite, and even then it is quite rare. Selenium is necessary for humans in trace amounts, but is toxic in larger quantities. Selenium is red in monomolar structure but metallic gray in its crystalline structure.
Bromine (Br) is an element in group 17 (halogen). It does not exist in elemental form in nature. Bromine is barely liquid at room temperature, boiling at about 330 kelvins. Bromine is also quite toxic and corrosive, but bromide ions, which are relatively inert, can be found in halite, or table salt. Bromine is often used as a fire retardant because many compounds can be made to release free bromine atoms.
Krypton (Kr) is a noble gas, placed under argon and over xenon. Being a noble gas, krypton rarely interacts with itself or other elements; although compounds have been detected, they are all unstable and decay rapidly, and as such, krypton is often used in fluorescent lights. Krypton, like most noble gases, is also used in lighting because of its many spectral lines and the aforementioned reasons.
Many period 4 elements find roles in controlling protein function as secondary messengers, structural components, or enzyme cofactors. A gradient of potassium is used by cells to maintain a membrane potential which enables neurotransmitter firing and facilitated diffusion among other processes. Calcium is a common signaling molecule for proteins such as calmodulin and plays a critical role in triggering skeletal muscle contraction in vertebrates. Selenium is a component of the noncanonical amino acid, selenocysteine; proteins which contain selenocysteine are known as selenoproteins. Manganese enzymes are utilized by both eukaryotes and prokaryotes, and may play a role in the virulence of some pathogenic bacteria. [10] Vanabins, also known as vanadium-associated proteins, are found in the blood cells of some species of sea squirts. The role of these proteins is disputed, although there is some speculation that they function as oxygen carriers. Zinc ions are used to stabilize the zinc finger milieu of many DNA-binding proteins.
Period 4 elements can also be found complexed with organic small molecules to form cofactors. The most famous example of this is heme: an iron-containing porphyrin compound responsible for the oxygen-carrying function of myoglobin and hemoglobin as well as the catalytic activity of cytochrome enzymes. [11] Hemocyanin replaces hemoglobin as the oxygen carrier of choice in the blood of certain invertebrates, including horseshoe crabs, tarantulas, and octopuses. Vitamin B12 represents one of the few biochemical applications for cobalt.
A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.
The periodic table, also known as the periodic table of the elements, arranges the chemical elements into rows ("periods") and columns ("groups"). It is an icon of chemistry and is widely used in physics and other sciences. It is a depiction of the periodic law, which says that when the elements are arranged in order of their atomic numbers an approximate recurrence of their properties is evident. The table is divided into four roughly rectangular areas called blocks. Elements in the same group tend to show similar chemical characteristics.
In chemistry, a transition metal is a chemical element in the d-block of the periodic table, though the elements of group 12 are sometimes excluded. The lanthanide and actinide elements are called inner transition metals and are sometimes considered to be transition metals as well.
Stable nuclides are nuclides that are not radioactive and so do not spontaneously undergo radioactive decay. When such nuclides are referred to in relation to specific elements, they are usually termed stable isotopes.
A period on the periodic table is a row of chemical elements. All elements in a row have the same number of electron shells. Each next element in a period has one more proton and is less metallic than its predecessor. Arranged this way, elements in the same group (column) have similar chemical and physical properties, reflecting the periodic law. For example, the halogens lie in the second-to-last group and share similar properties, such as high reactivity and the tendency to gain one electron to arrive at a noble-gas electronic configuration. As of 2022, a total of 118 elements have been discovered and confirmed.
The boron group are the chemical elements in group 13 of the periodic table, consisting of boron (B), aluminium (Al), gallium (Ga), indium (In), thallium (Tl) and nihonium (Nh). This group lies in the p-block of the periodic table. The elements in the boron group are characterized by having three valence electrons. These elements have also been referred to as the triels.
A period 5 element is one of the chemical elements in the fifth row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The fifth period contains 18 elements, beginning with rubidium and ending with xenon. As a rule, period 5 elements fill their 5s shells first, then their 4d, and 5p shells, in that order; however, there are exceptions, such as rhodium.
Chemistry is the physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions.
The Goldschmidt classification, developed by Victor Goldschmidt (1888–1947), is a geochemical classification which groups the chemical elements within the Earth according to their preferred host phases into lithophile (rock-loving), siderophile (iron-loving), chalcophile, and atmophile (gas-loving) or volatile.
A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include aluminium, antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, selenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.
The d-block contraction is a term used in chemistry to describe the effect of having full d orbitals on the period 4 elements. The elements in question are gallium, germanium, arsenic, selenium, bromine, and krypton. Their electronic configurations include completely filled d orbitals (d10). The d-block contraction is best illustrated by comparing some properties of the group 13 elements to highlight the effect on gallium.
The coinage metals comprise those metallic chemical elements and alloys which have been used to mint coins. Historically, most coinage metals are from the three nonradioactive members of group 11 of the periodic table: copper, silver and gold. Copper is usually augmented with tin or other metals to form bronze. Gold, silver and bronze or copper were the principal coinage metals of the ancient world, the medieval period and into the late modern period when the diversity of coinage metals increased. While coins are primarily made from metal, some non-metallic materials have also been used.
Trifluorides are compounds in which one atom or ion has three fluorine atoms or ions associated. Many metals form trifluorides, such as iron, the rare-earth elements, and the metals in the aluminium and scandium columns of the periodic table. Most metal trifluorides are poorly soluble in water except Ferric fluoride and Indium(III) fluoride, but several are soluble in other solvents.
Native element minerals are those elements that occur in nature in uncombined form with a distinct mineral structure. The elemental class includes metals, intermetallic compounds, alloys, metalloids, and nonmetals. The Nickel–Strunz classification system also includes the naturally occurring phosphides, silicides, nitrides, carbides, and arsenides.
Metals in medicine are used in organic systems for diagnostic and treatment purposes. Inorganic elements are also essential for organic life as cofactors in enzymes called metalloproteins. When metals are scarce or high quantities, equilibrium is set out of balance and must be returned to its natural state via interventional and natural methods.
The metallic elements in the periodic table located between the transition metals to their left and the chemically weak nonmetallic metalloids to their right have received many names in the literature, such as post-transition metals, poor metals, other metals, p-block metals and chemically weak metals. The most common name, post-transition metals, is generally used in this article.
Heavy metals are generally defined as metals with relatively high densities, atomic weights, or atomic numbers. The criteria used, and whether metalloids are included, vary depending on the author and context. In metallurgy, for example, a heavy metal may be defined on the basis of density, whereas in physics the distinguishing criterion might be atomic number, while a chemist would likely be more concerned with chemical behaviour. More specific definitions have been published, none of which have been widely accepted. The definitions surveyed in this article encompass up to 96 out of the 118 known chemical elements; only mercury, lead and bismuth meet all of them. Despite this lack of agreement, the term is widely used in science. A density of more than 5 g/cm3 is sometimes quoted as a commonly used criterion and is used in the body of this article.
Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table. The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds. Arsenic also bonds readily to itself as seen in the square As3−
4 ions in the mineral skutterudite. In the +3 oxidation state, arsenic is typically pyramidal owing to the influence of the lone pair of electrons.