Lists of metalloids

Last updated

This is a list of 194 sources that list elements classified as metalloids. The sources are listed in chronological order. Lists of metalloids differ since there is no rigorous widely accepted definition of metalloid (or its occasional alias, 'semi-metal'). Individual lists share common ground, with variations occurring at the margins. The elements most often regarded as metalloids are boron, silicon, germanium, arsenic, antimony and tellurium. [n 1] Other sources may subtract from this list, add a varying number of other elements, or both.

Contents

Overview

  13 14 15 16 17
2 B
Boron
C
Carbon
N
Nitrogen
O
Oxygen
F
Fluorine
3 Al
Aluminium
Si
Silicon
P
Phosphorus
S
Sulfur
Cl
Chlorine
4 Ga
Gallium
Ge
Germanium
As
Arsenic
Se
Selenium
Br
Bromine
5 In
Indium
Sn
Tin
Sb
Antimony
Te
Tellurium
I
Iodine
6 Tl
Thallium
Pb
Lead
Bi
Bismuth
Po
Polonium
At
Astatine
 
  Commonly recognized (86–99%): B, Si, Ge, As, Sb, Te
  Irregularly recognized (40–49%): Po, At
  Less commonly recognized (24%): Se
  Rarely recognized (8–10%): C, Al
  (All other elements cited in less than 6% of sources)
  Arbitrary metal-nonmetal dividing line: between Be and B, Al and Si, Ge and As, Sb and Te, Po and At

Recognition status, as metalloids, of some elements in the p-block of the periodic table. Percentages are median appearance frequencies in the lists of metalloids. [n 2] The staircase-shaped line is a typical example of the arbitrary metal–nonmetal dividing line found on some periodic tables.

ElementCitationsFrequency
 in n = 194
publications
194 = 100%
 
ArsenicAs191.599%
TelluriumTe190.598%
GermaniumGe184.595%
SiliconSi183.595%
AntimonySb169.587%
BoronB16686%
PoloniumPo94.549%
AstatineAt7740%
SeleniumSe4624%
AluminiumAl189.3%
CarbonC16.58.5%
BismuthBi11.55.9%
PhosphorusP105.2%
BerylliumBe7.53.9%
TinSn5.52.8%
SulfurS31.5%
LivermoriumLv31.5%
IodineI2.51.3%
FleroviumFl10.5%
GalliumGa10.5%
HydrogenH10.5%
LeadPb10.5%
MoscoviumMc10.5%
TennessineTs10.5%

Chronological list

This table shows which elements are included in each of 194 different lists of metalloids. A parenthesized symbol indicates an element whose inclusion in a particular metalloid list is qualified in some way by the author(s). The 'citations' rows show how many and what percentage of the authorities consider each element to be a metalloid, with qualified citations counted as one-half.

Citations as metalloid by element
Element Arsenic Tellu­rium Germa­nium Silicon Anti­mony Boron Polo­nium Asta­tine Sele­nium Alu­minium Carbon Bis­muth Phos­phorus Beryl­lium Tin Sulfur Liver­morium Iodine OtherCount
AsTeGeSiSbBPoAtSeAlCBiPBeSnSLvIavg
Citations
(with qualification)*
191.5
(1)
190.5
(1)
184.5
(3)
183.5
(1)
169.5
(3)
166
(2)
94.5
(5)
77
(6)
46
(4)
18
(2)
16.5
(3)
11.5
(1)
10
(2)
7.5
(1)
5.5
(1)
3
(0)
3
(0)
2.5
(1)
6
(0)''
7.15
 
(% out of 194)99%98%95%95%87%86%49%40%24%9.3%8.5%5.9%5.2%3.9%2.8%1.5%1.5%1.3%3.1%
SourceYr
Simmons [1] 1947AsTeSbSe 4
Pauling [2] 1949AsTeGeSiSbBPo 7
Szabó & Lakatos [3] 1954AsTeGeSiSbBPoAtAlBe 10
Dull, Metcalfe & Williams [4] 1958AsTeGeSiSbBPoAtAl 9
Frey [5] 1958AsTeGeSiSbBPo 7
Johnstone & Miller [6] 1960AsTeGeSiSbBSeCP 9
Edwards et al. [7] 1961AsTeGeSiSbBSeI 8
Bond [8] 1962AsTeGeSiSbBPo 7
Swift & Schaefer [9] 1962AsGeSiSbBBi 6
Hoffman [10] 1963AsTeGeSiSbBBe 7
Nathans [11] 1963AsTeGeSiSbBAt 7
Bailar, Moeller & Kleinberg [12] 1965AsTeGeSe 4
Selwood [13] 1965AsTeGeSiSbBPoAtAlBiSn Ga 12
Bassett et al. [14] 1966TeGeSiSbBPoAlBe 8
Hultgren [15] 1966AsTeGeSiSbSeC 7
Metcalfe, Williams & Castka [16] 1966AsTeGeSiSbBPo(Al) 7.5
Rochow [17] 1966AsTeGeSiSbB(Po)(At)(Se)(C)(Bi)(P) 9
Mahan [18] 1967AsTeGeSiB 5
Paul, King & Farinholt [19] 1967AsTeGeSiSbSe 6
Siebring [20] 1967AsTeGeSiSbBPoAl 8
Cotton & Lynch [21] 1968AsTeGeSiSbBAtSeC 9
Dunstan [22] 1968AsTe(Ge)SbPoAlBiBeSn Pb 7.5
Tyrell & Warren [23] 1968AsTe(Ge)Si(Sb)B(Po)At(Se)(Al)(C)(P)(I) 9.5
Williams, Embree & DeBey [24] 1968AsTeGeSiSbBPoAl 8
Chedd [25] 1969AsTeGeSiSbBPoAt 8
Hägg [26] 1969AsTeGeSbAtSn 6
Holum [27] 1969AsTeGeSiSbBPoAtAl 9
Hunter [28] 1969AsTeSiSbSe 5
Moody [29] 1969AsTeGeSiSbBPoAtAlBe 10
Dickerson, Gray & Haight [30] 1970AsTeGeSiSbB 6
Hardwick & Knobler [31] 1970AsTeGeSiSbB 6
Williams, Embree & DeBay [32] 1970AsTeGeSiSbBPoAlBe 9
Dickson [33] 1971AsTeGeSiSbPo 6
Emsley [34] 1971AsTeGeSb 4
Nitz & Dhonau [35] 1971AsTeGeSiSbBPo 7
Pimentel & Spratley [36] 1971AsTeGeSiSbB(Po)(At)SeC 9
Barrow [37] 1972AsTeGeSiB 5
Choppin & Johnsen [38] 1972AsTeGeSiSbBSe 7
Horvath [39] 1973AsTeGeSiSbBPo 7
Pascoe [40] 1973TeGeSiBAtSeCP 8
Seager & Stoker [41] 1973AsTeGeSiSbBPoAtAlBe 10
Allen & Keefer [42] 1974AsTeGeSiSbBAtSe 8
Andrews [43] 1974AsTeSiBAt 5
Day & Johnson [44] 1974AsTeGeSiSbPoAt 7
Dickson [45] 1974AsTeGeSiSbPoAt 7
Duffy [46] 1974AsTeGeSbSe 5
Fuller [47] 1974AsTeGeSiBSeC 7
Nordmann [48] 1974AsTeGeSiBPoAtSe 8
O'Connor [49] 1974AsTeGeSiSbBPo 7
Rock & Gerhold [50] 1974AsTeGeSiSbBPoAt 8
Pauling & Pauling [51] 1975AsTeGeSiSbBPo 7
Hearst & Ifft [52] 1976AsTeGeSiSbBSe 7
Tyler Miller [53] 1976AsTeGeSiSbBPoAtAl H 10
Waser, Trueblood & Knobler [54] 1976AsTeGeSiSbBPo 7
Bloomfield [55] 1977AsTeGeSiSbBPoAtAl 9
Ucko [56] 1977AsTeGeSiSbBPoAtAl 9
Hill & Holman [57] 1978AsTeGeSiB(C) 5.5
Coxon, Fergusson & Phillips [58] 1980AsTeGeSi(Sb)BAt(Be) 7
Warrena & Geballe [59] 1981AsTeSiBAtSeCPS 9
Walters [60] 1982AsTeGeSiB 5
Edwards & Sienko [61] 1983AsTeGeSbPo(At) 5.5
Holtzclaw, Robinson & Nebergall [62] 1984AsTeGeSiSbBPoAt 8
Boikess & Edelson [63] 1985AsTeGeSiB 5
Peters [64] 1986AsTeGeSiSbBPoAt 8
Hibbert & James [65] 1987AsTeGeSiSbPoBi 7
Jones et al. [66] 1987AsTeGeSiSbBPoAt 8
McQuarrie & Rock [67] 1987AsTeGeSiSbBPoAt 8
Wulfsberg [68] 1987AsTeGeSiSbBSe 7
Thayer [69] 1988AsTeGeSiBP 6
Whitten, Gailey & Davis [70] 1988AsTeGeSiSbBPoAtAl 9
Bailar et al. [71] 1989AsTeGeSiSbBSe 7
Gill [72] 1989AsTeGeSiSbB 6
Malone [73] 1989AsTeGeSiSbBPoAt 8
Petrucci [74] 1989AsTeGeSiSbPoAt 7
Puddephatt & Monaghan [75] 1989AsTeGeSiSbB 6
Scott [76] 1989AsTeGeSiSbB 6
Segal [77] 1989AsTeGeSiSbBPo 7
Oxtoby, Nachtrieb & Freeman [78] 1990AsTeGeSiSbBPoAt 8
Atkins & Beran [79] 1990AsTeGeSiSbPo 6
Ebbing & Wrighton [80] 1993AsTeGeSiSbBAt 7
Zumdahl [81] 1993AsTeGeSiSbBPoAt 8
Birk [82] 1994AsTeGeSiSbBPo 7
Smith [83] 1994AsTeGeSiSbB 6
AAE [84] 1996AsTeGeSiSbBSe 7
Brady & Holum [85] 1996AsTeGeSiSbBPoAt 8
Harrison & de Mora [86] 1996AsTeGeSiB 5
Hook & Post [87] 1996AsTeGeSiSbBPoAt 8
Atkins & Jones [88] 1997AsTeGeSiSbPo 6
Dayah [89] 1997AsTeGeSiSbBPo 7
Mingos [90] 1998AsTeGeSiSbBPo 7
Joesten & Wood [91] 1999AsTeGeSiSbB 6
Kremer [92] 1999AsTeGeSiSbB 6
Thompson [93] 1999AsTeGeSiSbB 6
Umland & Bellama [94] 1999AsTeGeSiBAtSe 7
Callister [95] 2000AsTeGeSiBSeC 7
Enloe [96] 2000AsTeSiBAt 5
Mann, Meek & Allen [97] 2000AsTeGeSiSbBPoBi 8
Phillips, Stozak & Wistrom [98] 2000AsTeGeSiSbBPoAt 8
Ryan [99] 2000AsTeGeSiB 5
Hawkes [100] 2001AsTeGeSbSeBi 6
Lewis & Evans [101] 2001AsTeGeSiSbBPo 7
Masterton & Hurley [102] 2001AsTeGeSiSbB 6
Barrett [103] 2002(As)(Te)(Ge)(Si)(Sb)(B)(Se) 3.5
Chang [104] 2002AsTeGeSiSbBPoAtLv Ts 10
Harding, Johnson & Janes [105] 2002AsTeGeSiSb 5
Johnson [106] 2002AsTeGeSiSbAt 6
Rodgers [107] 2002AsTeGeSiSbBAt 7
Szefer [108] 2002AsTeGeSiSbSe 6
Woodgate [109] 2002AsTeGeSbAl 5
Wright & Welbourn [110] 2002AsTeGeSiB 5
e-encyclopedia [111] 2003AsTeGeSiSbBSe 7
Gupta [112] 2003AsTeGeSiSbB 6
Hunt [113] 2003AsTeGeSiSbB 6
Myers [114] 2003AsTeGeSiSbBAtSe 8
Williams [115] 2003AsTeGeSiSbBPo 7
Atkins [116] 2004AsTeGeSiSbBPo 7
Cox [117] 2004AsTeGeSiSbSe 6
Gilbert, Kirss & Davies [118] 2004AsTeGeSiSbBAtSe 8
Reilly [119] 2004AsTeGeSiSbBPoAtSe 9
Ebbing & Gammon [120] 2005AsTeGeSiSbBAt 7
Fry & Page [121] 2005AsTeGeSiSbB 6
Halliday, Resnick & Walker [122] 2005AsTeGeSiSbBPoAt 8
Holler & Selegue [123] 2005AsTeGeSiSbBPo(At) 7.5
Kotz, Treichel & Weaver [124] 2005AsTeGeSiSbB 6
Meyer [125] 2005AsTeGeSiSbBAt 7
Orchin [126] 2005AsTeGeSiSbBPoAt 8
Swenson [127] 2005AsTeGeSiSbBPoAtSeCBi 11
Baird [128] 2006AsTeGeSiSbBAt 7
Blei & Odian [129] 2006AsTeGeSiSbPoAtLv 8
Brown & Holme [130] 2006AsTeGeSiSbBAt 7
Dashek & Harrison [131] 2006AsTeGeSiSbBPoAt 8
Finch et al. [132] 2006AsTeGeSiSbBSe 7
Goldfrank & Flomenbaum [133] 2006AsTeGeSiSbBAt 7
Hatt [134] 2006AsTeGeSiSbBSe 7
Hérold [135] 2006AsGeSiBPo(At)SeCBiP 9.5
McMonagle [136] 2006AsTeGeSiBLv Fl
Mc
8
Rayner-Canham & Overton [137] 2006AsTeGeSiB 5
Silberberg [138] 2006AsTeGeSiSbB 6
Slade [139] 2006AsTeGeSiSbBPo 7
Wertheim, Oxlade & Stockley [140] 2006AsTeGeSiSbBAtSe 8
Whitley [141] 2006AsTeGeSiSbBPo 7
American Chemical Society [142] 2007AsTeGeSiSbBPo 7
Astruc [143] 2007AsSiBSePS 6
Casper [144] 2007AsTeGeSiSbBPo 7
Crystal [145] 2007AsTeGeSiSbBPo 7
DeGraff [146] 2007AsTeGeSiSbBPo 7
Joesten, Hogg & Castellion [147] 2007AsTeGeSiSbB 6
Lewis [148] 2007AsTeGeSiSbBPoSeCPS 11
Petty [149] 2007AsTeGeSiSbBPoAtSeCBiPSn 13
Rösler, Harders & Bäker [150] 2007AsTeGeSiSbB(Sn) 6.5
Saunders [151] 2007AsTeGeSiSbBPoAt 8
Saunders [152] 2007AsTeGeSiSbBPoAt 8
Shipman, Wilson & Tood [153] 2007AsTeGeSiSbB 6
Bauer, Birk & Sawyer [154] 2008AsTeGeSiSbBAt 7
Clugston & Flemming [155] 2008AsTeGeSiSbSe 6
Encyclopedia Columbia [156] 2008AsTeSbSe 4
Ham [157] 2008AsTeGeSiSbBPo 7
Kelter, Mosher & Scott [158] 2008AsTeGeSiSbBAt 7
Masterton & Hurley [159] 2008AsTeGeSiSbB 6
Merck [160] 2008AsTeGeSiSbBPo 7
Nicolaou & Montagnon [161] 2008AsTeGeSiSbBPoAtC 9
Řezanka & Sigler [162] 2008AsTeSiBAtSe 6
Tro & Neu [163] 2008AsTeGeSiSbB 6
Vallero [164] 2008AsTeGeSiSbBPo 7
Brown et al. [165] 2009AsTeGeSiSbB 6
Burrows et al. [166] 2009AsTeGeSiSbBSe 7
Castor-Perry [167] 2009AsTeGeSiSbBPoAtI 9
Cracolice & Peters [168] 2009AsTeGeSiSbBAt 7
Economou [169] 2009AsTeGeSiSbBPoAtAl 9
Habashi [170] 2009AsTeGeSiSbBPoSeBi 9
Hein & Arena [171] 2009AsTeGeSiSbBPo 7
Leach [172] 2009AsTeGeSiSbBPo 7
Manning [173] 2009AsTeGeSiSbBPo 7
McMurray & Fay [174] 2009AsTeGeSiSbBAt 7
Reger, Goode & Ball [175] 2009AsTeGeSiSbB 6
Schnepp [176] 2009AsTeGeSiSbBPoAt 8
Shubert & Leyba [177] 2009AsTeGeSiSbB 6
Whitten et al. [178] 2009AsTeGeSiSbBAt 7
Aldinger & Weberruss [179] 2010AsTeGeSiSbB 6
Banks et al. [180] 2010AsTeGeSiSbB 6
Fayer [181] 2010AsTeGeSiSbBPoAt 8
Gray [182] 2010AsTeGeSiSbBPo 7
Groysman [183] 2010AsTeGeSiSbPo 6
Halka & Nordstrom [184] 2010AsTeGeSiSbBPo 7
Lombi E & Holm PE [185] 2010AsTeGeSiSbBPoAt 8
NEST Association [186] 2010AsTeGeSiSbBAt 7
RCCS [187] 2010AsTeGeSiSbBPoAtSeCBiPSn 13
Senese [188] 2010AsTeGeSiSb(B)PoAt(Se)C 9
Weiner [189] 2010AsTeGeSiSbBPo 7
Barbalace [190] 2011AsTeGeSiSbBPo 7
Encyclopædia Britannica Online [191] 2011AsTeGeSiSbB(Po)(At) 7
Helmenstine [192] 2011AsTeGeSiSbB(Po) 6.5
Moore [193] 2011AsTeGeSiSbBAt 7
QA International [194] 2011AsTeGeSiSbBSe 7
ElementArsenicTellu­riumGerma­niumSiliconAnti­monyBoronPolo­niumAsta­tineSele­niumAlu­miniumCarbonBis­muthPhos­phorusBeryl­liumTinSulfurLiver­moriumIodineOther

There is an average of 7.15 elements per metalloid list.

Appearance frequency clusters

Clusters of elements and their appearance in the sources Metalloid cluster frequencies.png
Clusters of elements and their appearance in the sources

Elements cited in the listed sources (as of August 2011; n = 194) have appearance frequencies that occur in clusters of comparable values. The diamonds in the graph mark the mean appearance frequency of each cluster.

The resulting geometric trend line has the formula y = 199.47e−0.7423x and an R2 value of 0.9962. [n 3]

Elements regarded as metalloids

The elements commonly classified as metalloids are boron, silicon, germanium, arsenic, antimony and tellurium. [n 4] The status of polonium and astatine is not settled. Most authors recognise one or the other, or both, as metalloids; Herman, Hoffmann and Ashcroft, on the basis of relativistic modelling, predict astatine will be a monatomic metal. [n 5] One or more of carbon, aluminium, phosphorus, selenium, tin or bismuth, these being periodic table neighbours of the elements commonly classified as metalloids, are sometimes recognised as metalloids. [n 6] Selenium, in particular, is commonly designated as a metalloid in environmental chemistry [n 7] on account of similarities in its aquatic chemistry with that of arsenic and antimony. [n 8] There are fewer references to beryllium, in spite of its periodic table position adjoining the dividing line between metals and nonmetals. Isolated references in the literature can also be found to the categorisation of other elements as metalloids. These elements include: hydrogen, nitrogen, [n 9] sulfur, [n 10] zinc, [n 11] gallium, [n 12] iodine, [n 13] lead, [n 14] and radon [n 15] (citations are for references other than those listed above).

Notes

  1. Lack of a rigorous definition:
    • Goldsmith RH 1982, 'Metalloids', Journal of Chemical Education, vol. 59, no. 6, pp. 526–527, doi:10.1021/ed059p526
    • Hawkes SJ 2001, 'Semimetallicity', Journal of Chemical Education, vol. 78, no. 12, pp. 1686–87, doi:10.1021/ed078p1686
  2. For a related commentary see also: Vernon RE 2013, 'Which Elements Are Metalloids?', Journal of Chemical Education, vol. 90, no. 12, pp. 1703–1707, doi:10.1021/ed3008457
  3. The R2 value is a measure of how close a formula fits a set of data points. Values fall between 0.0 and 1.0, with those near 1.0 indicating a good fit.
  4. Elements commonly classified as metalloids:
    • Goldsmith RH 1982, 'Metalloids', Journal of Chemical Education, vol. 59, no. 6, pp. 526–7 (526), doi:10.1021/ed059p526
    • Mann JB, Meek TL & Allen LC 2000, 'Configuration energies of the main group elements', Journal of the American Chemical Society, vol. 122, no. 12, pp. 2780–3 (2783), doi:10.1021ja992866e: Mann et al. refer to these elements as 'the recognized metalloids'.
    • Kotz JC, Treichel P & Weaver GC 2009, Chemistry and Chemical Reactivity, 7th ed., Brooks/Cole, Belmont, California, ISBN   1439041318
  5. Polonium and astatine:
  6. Carbon, aluminium, phosphorus, selenium, tin, bismuth:
    • Rochow EG 1966, The metalloids, DC Heath and Company, Boston, pp. 7–8
    • Cobb HM 2012, Dictionary of Metals, ASM International, Materials Park, OH, p. 145, ISBN   9781615039784
    • Walker CH 2012, Organic Pollutants: An Ecotoxicological Perspective, 2nd ed., CRC Press, Boca Raton, FL, p. 163, ISBN   9781420062588
    • Whiten K, Davis R, Peck L & Stanley G 2014, Chemistry, 10th ed., Brooks/Cole Cengage Learning, Belmont, CA, p. 134, ISBN   9781133610663
  7. Selenium as a metalloid in environmental chemistry:
    • Meyer JS, Adams WJ, Brix KV, Luoma SM, Mount DR, Stubblefield WA & Wood CM (eds) 2005, Toxicity of dietborne metals to aquatic organisms, Proceedings from the Pellston Workshop on Toxicity of Dietborne Metals to Aquatic Organisms, 27 July – 1 August 2002, Fairmont Hot Springs, British Columbia, Canada, Society of Environmental Toxicology and Chemistry, Pensacola, Florida, p. 284, ISBN   1880611708
    • Weiner ER 2013, Applications of Environmental Aquatic Chemistry: A Practical Guide, 3rd ed., CRC Press, Boca Raton, FL, p. 181, ISBN   9781439853320
  8. Similarities in the aquatic chemistry of selenium, arsenic, and antimony:
    • US Environmental Protection Agency 1988, Ambient aquatic life water quality criteria for antimony (III), draft, Office of Research and Development, Environmental Research Laboratories, Washington, p. 1
    • De Zuane J 1997, Handbook of drinking water quality, 2nd ed., John Wiley & Sons, New York, p. 93, ISBN   047128789X
    • Uden PC 2005, 'Speciation of selenium,' in R Cornelis, J Caruso, H Crews & K Heumann (eds), Handbook of elemental speciation II: Species in the environment, food, medicine and occupational health, John Wiley & Sons, Chichester, pp. 346–65 (347–8), ISBN   0470855983
    • Dev N 2008, 'Modelling selenium fate and transport in Great Salt Lake Wetlands' PhD dissertation, University of Utah, ProQuest, Ann Arbor, Michigan, pp. 2–3, ISBN   054986542X
  9. Nitrogen: Rausch MD 1960, 'Cyclopentadienyl compounds of metals and metalloids', Journal of Chemical Education, vol. 37, no. 11, pp. 568–78, doi:10.1021/ed037p568
  10. Sulfur:
    • Chalmers B 1959, Physical metallurgy, John Wiley & Sons, New York, p. 72
    • US Bureau of Naval Personnel 1965, Shipfitter 3 & 2, US Government Printing Office, Washington, p. 26
  11. Zinc: Siebring BR 1967, Chemistry, MacMillan, New York, p. 613
  12. Gallium: Wiberg N 2001, Inorganic chemistry, Academic Press, San Diego, p. 282, ISBN   0123526515
  13. Iodine:
    • Friend JN 1953, Man and the chemical elements, 1st ed., Charles Scribner's Sons, New York, p. 68
    • Rausch MD 1960, 'Cyclopentadienyl compounds of metals and metalloids', Journal of Chemical Education, vol. 37, no. 11, pp. 568–78, doi:10.1021/ed037p568
  14. Lead: Murray JF 1928, 'Cable-sheath corrosion', Electrical World, vol. 92, Dec 29, pp. 1295–7 (1295)
  15. Radon:
    • Hampel CA & Hawley GG 1966, The encyclopedia of chemistry, 3rd ed., Van Nostrand Reinhold, New York,p. 950
    • Stein L 1985, 'New evidence that radon is a metalloid element: ion-exchange reactions of cationic radon', Journal of the Chemical Society, Chemical Communications, vol. 22, pp. 1631–2, doi:10.1039/C39850001631
    • Stein L 1987, 'Chemical properties of radon' in PK Hopke (ed.) 1987, Radon and its decay products: Occurrence, properties, and health effects, American Chemical Society, Washington DC, pp. 240–51 (240, 247–8), ISBN   0841210152

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A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term seems to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-block, p-block, d-block, f-block and g-block.

The origin and usage of the term metalloid is convoluted. Its origin lies in attempts, dating from antiquity, to describe metals and to distinguish between typical and less typical forms. It was first applied to metals that floated on water, and then more popularly to nonmetals. Only recently, since the mid-20th century, has it been widely used to refer to elements with intermediate or borderline properties between metals and nonmetals.

The chemical elements can be broadly divided into metals, metalloids, and nonmetals according to their shared physical and chemical properties. All metals have a shiny appearance ; are good conductors of heat and electricity; form alloys with other metals; and have at least one basic oxide. Metalloids are metallic-looking brittle solids that are either semiconductors or exist in semiconducting forms, and have amphoteric or weakly acidic oxides. Typical nonmetals have a dull, coloured or colourless appearance; are brittle when solid; are poor conductors of heat and electricity; and have acidic oxides. Most or some elements in each category share a range of other properties; a few elements have properties that are either anomalous given their category, or otherwise extraordinary.

The dividing line between metals and nonmetals can be found, in varying configurations, on some representations of the periodic table of the elements. Elements to the lower left of the line generally display increasing metallic behaviour; elements to the upper right display increasing nonmetallic behaviour. When presented as a regular stair-step, elements with the highest critical temperature for their groups lie just below the line.

Fluorine forms a great variety of chemical compounds, within which it always adopts an oxidation state of −1. With other atoms, fluorine forms either polar covalent bonds or ionic bonds. Most frequently, covalent bonds involving fluorine atoms are single bonds, although at least two examples of a higher order bond exist. Fluoride may act as a bridging ligand between two metals in some complex molecules. Molecules containing fluorine may also exhibit hydrogen bonding. Fluorine's chemistry includes inorganic compounds formed with hydrogen, metals, nonmetals, and even noble gases; as well as a diverse set of organic compounds. For many elements the highest known oxidation state can be achieved in a fluoride. For some elements this is achieved exclusively in a fluoride, for others exclusively in an oxide; and for still others the highest oxidation states of oxides and fluorides are always equal.

<span class="mw-page-title-main">Post-transition metal</span> Category of metallic elements

The metallic elements in the periodic table located between the transition metals to their left and the chemically weak nonmetallic metalloids to their right have received many names in the literature, such as post-transition metals, poor metals, other metals, p-block metals and chemically weak metals. The most common name, post-transition metals, is generally used in this article.

<span class="mw-page-title-main">Heavy metals</span> Loosely defined subset of elements that exhibit metallic properties

Heavy metals are generally defined as metals with relatively high densities, atomic weights, or atomic numbers. The criteria used, and whether metalloids are included, vary depending on the author and context. In metallurgy, for example, a heavy metal may be defined on the basis of density, whereas in physics the distinguishing criterion might be atomic number, while a chemist would likely be more concerned with chemical behaviour. More specific definitions have been published, none of which have been widely accepted. The definitions surveyed in this article encompass up to 96 out of the 118 known chemical elements; only mercury, lead and bismuth meet all of them. Despite this lack of agreement, the term is widely used in science. A density of more than 5 g/cm3 is sometimes quoted as a commonly used criterion and is used in the body of this article.

<span class="mw-page-title-main">Properties of nonmetals (and metalloids) by group</span>

Nonmetals show more variability in their properties than do metals. Metalloids are included here since they behave predominately as chemically weak nonmetals.

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