A native metal is any metal that is found pure in its metallic form in nature. [1] [2] Metals that can be found as native deposits singly or in alloys include antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group (gold, copper, lead, aluminium, [3] mercury, silver) and the platinum group (platinum, iridium, osmium, palladium, rhodium, ruthenium). Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.
Only gold, silver, copper and the platinum group occur native in large amounts.[ citation needed ] Over geological time scales, very few metals can resist natural weathering processes like oxidation, so mainly the less reactive metals such as gold and platinum are found as native metals. The others usually occur as isolated pockets where a natural chemical process reduces a common compound or ore of the metal, leaving the pure metal behind as small flakes or inclusions.
Non-metallic elements occurring in the native state include carbon and sulfur. Silicon, a semi-metal, has rarely been found in the native state as small inclusions in gold. [4]
Native metals were prehistoric man's only access to metal, since the process of extracting metals from their ores (smelting) is thought to have been discovered around 6500 BC. However, native metals could be found only in impractically small amounts, so while copper and iron were known well before the Copper Age and Iron Age, they did not have a large impact until smelting appeared.
Most gold is mined as native metal and can be found as nuggets, veins or wires of gold in a rock matrix, or fine grains of gold, mixed in with sediments or bound within rock. The iconic image of gold mining for many is gold panning, which is a method of separating flakes and nuggets of pure gold from river sediments due to their great density. Native gold is the predominant gold mineral on the earth. It is sometimes found alloyed with silver and/or other metals, but true gold compound minerals are uncommon, mainly a handful of selenides and tellurides.
Native silver occurs as elongated dendritic coatings or irregular masses. It may also occur as cubic, octahedral, or dodecahedral crystals. It may occur alloyed with gold as electrum. It often occurs with silver sulfide and sulfosalt minerals. [5] [6] Various amalgams of silver and mercury or other metals and mercury do occur rarely as minerals in nature. An example is the mineral eugenite (Ag11Hg2) and related forms. [7] Silver nuggets, wires, and grains are relatively common, but there are also a large number of silver compound minerals owing to silver being more reactive than gold.
Natural alloys of the platinum group metals include: native osmium (Os,Ir,Ru), rutheniridosmine (Ir,Os,Ru), ruthenium (Ru,Ir), palladium (Pd,Pt), platinum Pt, and rhodium (Rh,Pt). In addition, gold, copper, iron, mercury, tin, and lead may occur in alloys of this group. [8] As with gold, salts and other compounds of the platinum group metals are rare; native platinum and related metals and alloys are the predominant minerals bearing these metals. These metals occur associated with ultramafic intrusions, and placer deposits derived from those intrusions.
Native copper has been historically mined as an early source of the metal. The term Old Copper Complex is used to describe an ancient North American civilization that utilized native copper deposits for weapons, tools, and decorative objects. This society existed around Lake Superior, where they found sources of native copper and mined them between 6000 and 3000 BC. [9] Copper would have been especially useful to ancient humans as it was much stronger than gold, hard enough to be made into useful items such as fishhooks and woodworking tools, but still soft enough to be easily shaped, unlike meteoric iron.
The same deposits of native copper on the Keweenaw Peninsula and Isle Royale were later mined commercially. From 1845 until 1887, the Michigan Copper Country was the leading producer of copper in the United States. Masses of native copper weighing hundreds of tons were sometimes found in the mines.
The spectrum of copper minerals closely resembles that of silver, ranging from oxides of its multiple oxidation states through sulfides and silicates to halides and chlorates, iodates, nitrates and others. Natural alloys of copper (particularly with silver; the two metals can also be found in separate but co-mingled masses) are also found.
Telluric iron (Earth born) is very rare, with only one major deposit known in the world, located on or near Disko Island in Greenland. Most of the native iron on earth is actually not in fact "native", in the traditional sense, to Earth. It mainly comes from iron-nickel meteorites that formed millions of years ago but were preserved from chemical attack by the vacuum of space, and fell to the earth a relatively short time ago. Metallic meteorites are composed primarily of the iron-nickel alloys: taenite (high nickel content) and kamacite (low nickel content). However, there are a few areas on earth where truly native iron can be found. [10] [11]
Native nickel has been described in serpentinite due to hydrothermal alteration of ultramafic rocks in New Caledonia and elsewhere. [12] [13]
Metallic cobalt has been reported in the Canadian Lorraine Mine, Cobalt-Gowganda region, the Timiskaming District, Ontario, Canada, and in the Aidyrlya gold deposit in Orenburgskaya Oblast of the Southern Urals. [14]
All other native metals occur only in small quantities or are found in geologically special regions. For example, metallic cadmium was only found at two locations including the Vilyuy River basin in Siberia. [15] Native molybdenum has been found in lunar regolith and in the Koryakskii volcano in Kamchatka Oblast of Russia. [16] Elsewhere in this region native indium, aluminium, tantalum, tellurium, and other metals have been reported.[ citation needed ] Native lead [17] is quite rare but somewhat more widespread, as are tin, [18] mercury, [19] arsenic, [20] antimony, [21] and bismuth. [22]
Native chromium has been found in small grains in Sichuan, China [23] and other locations. [24]
An alloy is a mixture of chemical elements of which in most cases at least one is a metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Most alloys are metallic and show good electrical conductivity, ductility, opacity, and luster, and may have properties that differ from those of the pure elements such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties such as corrosion resistance or mechanical strength.
A metal is a material that, when polished or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. These properties are all associated with having electrons available at the Fermi level, as against nonmetallic materials which do not. Metals are typically ductile and malleable.
Ore is natural rock or sediment that contains one or more valuable minerals concentrated above background levels, typically containing metals, that can be mined, treated and sold at a profit. The grade of ore refers to the concentration of the desired material it contains. The value of the metals or minerals a rock contains must be weighed against the cost of extraction to determine whether it is of sufficiently high grade to be worth mining and is therefore considered an ore. A complex ore is one containing more than one valuable mineral.
A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the chemical elements, including the lanthanides. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The sixth period contains 32 elements, tied for the most with period 7, beginning with caesium and ending with radon. Lead is currently the last stable element; all subsequent elements are radioactive. For bismuth, however, its only primordial isotope, 209Bi, has a half-life of more than 1019 years, over a billion times longer than the current age of the universe. As a rule, period 6 elements fill their 6s shells first, then their 4f, 5d, and 6p shells, in that order; however, there are exceptions, such as gold.
The platinum-group metals (PGMs), also known as the platinoids, platinides, platidises, platinum group, platinum metals, platinum family or platinum-group elements (PGEs), are six noble, precious metallic elements clustered together in the periodic table. These elements are all transition metals in the d-block.
A base metal is a common and inexpensive metal, as opposed to a precious metal such as gold or silver. In numismatics, coins often derived their value from the precious metal content; however, base metals have also been used in coins in the past and today.
Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.
Ullmannite or Nickel glance is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite.
Tetrahedrite is a copper antimony sulfosalt mineral with formula: (Cu,Fe)
12Sb
4S
13. It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and bismuthian tetrahedrite or annivite is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver.
Sperrylite is a platinum arsenide mineral with the chemical formula PtAs2 and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in addition to massive and reniform habits. It has a Mohs hardness of 6–7 and a very high specific gravity of 10.6.
Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.
An iron–nickel alloy or nickel–iron alloy, abbreviated FeNi or NiFe, is a group of alloys consisting primarily of the elements nickel (Ni) and iron (Fe). It is the main constituent of the "iron" planetary cores and iron meteorites. In chemistry, the acronym NiFe refers to an iron–nickel catalyst or component involved in various chemical reactions, or the reactions themselves; in geology, it refers to the main constituents of telluric planetary cores.
Glass-to-metal seals are a type of mechanical seal which joins glass and metal surfaces. They are very important elements in the construction of vacuum tubes, electric discharge tubes, incandescent light bulbs, glass-encapsulated semiconductor diodes, reed switches, glass windows in metal cases, and metal or ceramic packages of electronic components.
Cobalt is a chemical element; it has symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, somewhat brittle, gray metal.
The coinage metals comprise those metallic chemical elements and alloys which have been used to mint coins. Historically, most coinage metals are from the three nonradioactive members of group 11 of the periodic table: copper, silver and gold. Copper is usually augmented with tin or other metals to form bronze. Gold, silver and bronze or copper were the principal coinage metals of the ancient world, the medieval period and into the late modern period when the diversity of coinage metals increased. Coins are often made from more than one metal, either using alloys, coatings (cladding/plating) or bimetallic configurations. While coins are primarily made from metal, some non-metallic materials have also been used.
Native element minerals are those elements that occur in nature in uncombined form with a distinct mineral structure. The elemental class includes metals, intermetallic compounds, alloys, metalloids, and nonmetals. The Nickel–Strunz classification system also includes the naturally occurring phosphides, silicides, nitrides, carbides, and arsenides.
Rutheniridosmine is a naturally occurring mineral alloy of the elements ruthenium, iridium and osmium with the formula of (Ir,Os,Ru). Rutheniridosmine occurs as hexagonal, opaque, silver-white, metallic grains with a Mohs hardness of six. Platinum, palladium, rhodium, iron, and nickel occur as impurities.
Ferronickel platinum is a very rarely occurring minerals from the mineral class of elements (including natural alloys, intermetallic compounds, carbides, nitrides, phosphides and silicides) with the chemical composition Pt2FeNi and thus is chemically seen as a natural alloy, more precisely an intermetallic compound of platinum, nickel and iron in a ratio of 2:1:1.
Glance or glances, sometimes also galenoids — obsolete or partially obsolete collective name for the morphological group of minerals, compiled according to external characteristics. The group included more than three dozen names, mainly from the group of sulfides and related compounds. As a rule, different examples of glosses have a gray mirror or metallic luster with refractive indices above 3, and sometimes a metallike appearance.