Term symbol

In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom. So while the word symbol suggests otherwise, it represents an actual value of a physical quantity.

For a given electron configuration of an atom, its state depends also on its total angular momentum, including spin and orbital components, which are specified by the term symbol. The usual atomic term symbols assume LS coupling (also known as Russell–Saunders coupling) in which the all-electron total quantum numbers for orbital (L), spin (S) and total (J) angular momenta are good quantum numbers.

In the terminology of atomic spectroscopy, L and S together specify a term; L, S, and J specify a level; and L, S, J and the magnetic quantum number M_J specify a state. The conventional term symbol has the form ^2S+1L_J, where J is written optionally in order to specify a level. L is written using spectroscopic notation: for example, it is written "S", "P", "D", or "F" to represent L = 0, 1, 2, or 3 respectively. For coupling schemes other that LS coupling, such as the jj coupling that applies to some heavy elements, other notations are used to specify the term.

Term symbols apply to both neutral and charged atoms, and to their ground and excited states. Term symbols usually specify the total for all electrons in an atom, but are sometimes used to describe electrons in a given subshell or set of subshells, for example to describe each open subshell in an atom having more than one. The ground state term symbol for neutral atoms is described, in most cases, by Hund's rules. Neutral atoms of the chemical elements have the same term symbol for each column in the s-block and p-block elements, but differ in d-block and f-block elements where the ground-state electron configuration changes within a column, where exceptions to Hund's rules occur. Ground state term symbols for the chemical elements are given below.

Term symbols are also used to describe angular momentum quantum numbers for atomic nuclei and for molecules. For molecular term symbols , Greek letters are used to designate the component of orbital angular momenta along the molecular axis.

The use of the word term for an atom's electronic state is based on the Rydberg–Ritz combination principle, an empirical observation that the wavenumbers of spectral lines can be expressed as the difference of two terms. This was later summarized by the Bohr model, which identified the terms with quantized energy levels, and the spectral wavenumbers of these levels with photon energies.

Tables of atomic energy levels identified by their term symbols are available for atoms and ions in ground and excited states from the National Institute of Standards and Technology (NIST). ^[1]

Term symbols with LS coupling

The usual atomic term symbols assume LS coupling (also known as Russell–Saunders coupling), in which the atom's total spin quantum number S and the total orbital angular momentum quantum number L are "good quantum numbers". (Russell–Saunders coupling is named after Henry Norris Russell and Frederick Albert Saunders, who described it in 1925 ^[2] ). The spin-orbit interaction then couples the total spin and orbital moments to give the total electronic angular momentum quantum number J. Atomic states are then well described by term symbols of the form:

${\displaystyle ^{2S+1}L_{J}}$

where

• S is the total spin quantum number for the atom's electrons. The value 2S + 1 written in the term symbol is the spin multiplicity, which is the number of possible values of the spin magnetic quantum number M_S for a given spin S.
• J is the total angular momentum quantum number for the atom's electrons. J has a value in the range from |L − S| to L + S.
• L is the total orbital quantum number in spectroscopic notation, in which the symbols for L are:

  L =	0	1	2	3	4	5	6	7	8	9	10	11	12	13	14	15	16	...
  	S	P	D	F	G	H	I	K	L	M	N	O	Q	R	T	U	V	(continued alphabetically) [note 1]

The orbital symbols S, P, D and F are derived from the characteristics of the spectroscopic lines corresponding to s, p, d, and f orbitals: sharp, principal, diffuse, and fundamental; the rest are named in alphabetical order from G onwards (omitting J, S and P). When used to describe electronic states of an atom, the term symbol is often written following the electron configuration. For example, 1s²2s²2p^2 3P₀ represents the ground state of a neutral carbon atom. The superscript 3 indicates that the spin multiplicity 2S + 1 is 3 (it is a triplet state), so S = 1; the letter "P" is spectroscopic notation for L = 1; and the subscript 0 is the value of J (in this case J = L − S). ^[1]

Small letters refer to individual orbitals or one-electron quantum numbers, whereas capital letters refer to many-electron states or their quantum numbers.

Terminology: terms, levels, and states

For a given electron configuration,

• The combination of an ${\displaystyle S}$ value and an ${\displaystyle L}$ value is called a term, and has a statistical weight (i.e., number of possible states) equal to ${\displaystyle (2S+1)(2L+1)}$;
• A combination of ${\displaystyle S}$, ${\displaystyle L}$ and ${\displaystyle J}$ is called a level. A given level has a statistical weight of ${\displaystyle 2J+1}$, which is the number of possible states associated with this level in the corresponding term;
• A combination of ${\displaystyle S}$, ${\displaystyle L}$, ${\displaystyle J}$ and ${\displaystyle M_{J}}$ determines a single state.

The product ${\displaystyle (2S+1)(2L+1)}$ as a number of possible states ${\displaystyle |S,M_{S},L,M_{L}\rangle }$ with given S and L is also a number of basis states in the uncoupled representation, where ${\displaystyle S}$, ${\displaystyle M_{S}}$, ${\displaystyle L}$, ${\displaystyle M_{L}}$ (${\displaystyle M_{S}}$ and ${\displaystyle M_{L}}$ are z-axis components of total spin and total orbital angular momentum respectively) are good quantum numbers whose corresponding operators mutually commute. With given ${\displaystyle S}$ and ${\displaystyle L}$, the eigenstates ${\displaystyle |S,M_{S},L,M_{L}\rangle }$ in this representation span function space of dimension ${\displaystyle (2S+1)(2L+1)}$, as ${\displaystyle M_{S}=S,S-1,\dots ,-S+1,-S}$ and ${\displaystyle M_{L}=L,L-1,...,-L+1,-L}$. In the coupled representation where total angular momentum (spin + orbital) is treated, the associated states (or eigenstates) are ${\displaystyle |J,M_{J},S,L\rangle }$ and these states span the function space with dimension of

${\displaystyle \sum _{J=J_{\min }=|L-S|}^{J_{\max }=L+S}(2J+1)}$

as ${\displaystyle M_{J}=J,J-1,\dots ,-J+1,-J}$. Obviously, the dimension of function space in both representations must be the same.

As an example, for ${\displaystyle S=1,L=2}$, there are (2×1+1)(2×2+1) = 15 different states (= eigenstates in the uncoupled representation) corresponding to the ³D term, of which (2×3+1) = 7 belong to the ³D₃ (J = 3) level. The sum of ${\displaystyle (2J+1)}$ for all levels in the same term equals (2S+1)(2L+1) as the dimensions of both representations must be equal as described above. In this case, J can be 1, 2, or 3, so 3 + 5 + 7 = 15.

Term symbol parity

The parity of a term symbol is calculated as

${\displaystyle P=(-1)^{\sum _{i}\ell _{i}},}$

where ${\displaystyle \ell _{i}}$ is the orbital quantum number for each electron. ${\displaystyle P=1}$ means even parity while ${\displaystyle P=-1}$ is for odd parity. In fact, only electrons in odd orbitals (with ${\displaystyle \ell }$ odd) contribute to the total parity: an odd number of electrons in odd orbitals (those with an odd ${\displaystyle \ell }$ such as in p, f,...) correspond to an odd term symbol, while an even number of electrons in odd orbitals correspond to an even term symbol. The number of electrons in even orbitals is irrelevant as any sum of even numbers is even. For any closed subshell, the number of electrons is ${\displaystyle 2(2\ell +1)}$ which is even, so the summation of ${\displaystyle \ell _{i}}$ in closed subshells is always an even number. The summation of quantum numbers ${\textstyle \sum _{i}\ell _{i}}$ over open (unfilled) subshells of odd orbitals (${\displaystyle \ell }$ odd) determines the parity of the term symbol. If the number of electrons in this reduced summation is odd (even) then the parity is also odd (even).

When it is odd, the parity of the term symbol is indicated by a superscript letter "o", otherwise it is omitted:

²P^o
_1⁄2 has odd parity, but ³P₀ has even parity.

Alternatively, parity may be indicated with a subscript letter "g" or "u", standing for gerade (German for "even") or ungerade ("odd"):

²P_1⁄2,u for odd parity, and ³P_0,g for even.

Ground state term symbol

It is relatively easy to calculate the term symbol for the ground state of an atom using Hund's rules. It corresponds with a state with maximum S and L.

1. Start with the most stable electron configuration. Full shells and subshells do not contribute to the overall angular momentum, so they are discarded.
   • If all shells and subshells are full then the term symbol is ¹S₀.
2. Distribute the electrons in the available orbitals, following the Pauli exclusion principle.
   • Conventionally, put 1 electron into orbital with highest m_ℓ and then continue filling other orbitals in descending m_ℓ order with one electron each, until you are out of electrons, or all orbitals in the subshell have one electron. Assign, again conventionally, all these electrons a value +1⁄2 of quantum magnetic spin number m_s.
   • If there are remaining electrons, put them in orbitals in the same order as before, but now assigning m_s = −1⁄2 to them.
3. The overall S is calculated by adding the m_s values for each electron. The overall S is then 1⁄2 times the number of unpaired electrons.
4. The overall L is calculated by adding the ${\displaystyle m_{\ell }}$ values for each electron (so if there are two electrons in the same orbital, add twice that orbital's ${\displaystyle m_{\ell }}$).
5. Calculate J as
   • if less than half of the subshell is occupied, take the minimum value J = |L − S|;
   • if more than half-filled, take the maximum value J = L + S;
   • if the subshell is half-filled, then L will be 0, so J = S.

As an example, in the case of fluorine, the electronic configuration is 1s²2s²2p⁵.

1. Discard the full subshells and keep the 2p⁵ part. So there are five electrons to place in subshell p (${\displaystyle \ell =1}$).
2. There are three orbitals (${\displaystyle m_{\ell }=1,0,-1}$) that can hold up to ${\displaystyle 2(2\ell +1)=6}$ electrons. The first three electrons can take m_s = 1⁄2 (↑) but the Pauli exclusion principle forces the next two to have m_s = −1⁄2 (↓) because they go to already occupied orbitals.

   	${\displaystyle m_{\ell }}$
   	+1	0	−1
   ${\displaystyle m_{s}}$	↑↓	↑↓	↑

3. S = 1⁄2 + 1⁄2 + 1⁄2 − 1⁄2 − 1⁄2 = 1⁄2; and L = 1 + 0 − 1 + 1 + 0 = 1, which is "P" in spectroscopic notation.
4. As fluorine 2p subshell is more than half filled, J = L + S = 3⁄2. Its ground state term symbol is then ^2S+1L_J = ²P_3⁄2.

Atomic term symbols of the chemical elements

In the periodic table, because atoms of elements in a column usually have the same outer electron structure, and always have the same electron structure in the "s-block" and "p-block" elements (see block (periodic table)), all elements may share the same ground state term symbol for the column. Thus, hydrogen and the alkali metals are all ²S_1⁄2, the alkaline earth metals are ¹S₀, the boron column elements are ²P_1⁄2, the carbon column elements are ³P₀, the pnictogens are ⁴S_3⁄2, the chalcogens are ³P₂, the halogens are ²P_3⁄2, and the inert gases are ¹S₀, per the rule for full shells and subshells stated above.

Term symbols for the ground states of most chemical elements ^[3] are given in the collapsed table below. ^[4] In the d-block and f-block, the term symbols are not always the same for elements in the same column of the periodic table, because open shells of several d or f electrons have several closely spaced terms whose energy ordering is often perturbed by the addition of an extra complete shell to form the next element in the column.

For example, the table shows that the first pair of vertically adjacent atoms with different ground-state term symbols are V and Nb. The ⁶D_1⁄2 ground state of Nb corresponds to an excited state of V 2112 cm⁻¹ above the ⁴F_3⁄2 ground state of V, which in turn corresponds to an excited state of Nb 1143 cm⁻¹ above the Nb ground state. ^[1] These energy differences are small compared to the 15158 cm⁻¹ difference between the ground and first excited state of Ca, ^[1] which is the last element before V with no d electrons.

Term symbol of the chemical elements
Group  →	1	2		3	4	5	6	7	8	9	10	11	12	13	14	15	16	17	18
↓  Period
1	H 2S1/2																		He 1S0
2	Li 2S1/2	Be 1S0												B 2P1/2	C 3P0	N 4S3/2	O 3P2	F 2P3/2	Ne 1S0
3	Na 2S1/2	Mg 1S0												Al 2P1/2	Si 3P0	P 4S3/2	S 3P2	Cl 2P3/2	Ar 1S0
4	K 2S1/2	Ca 1S0		Sc 2D3/2	Ti 3F2	V 4F3/2	Cr 7S3	Mn 6S5/2	Fe 5D4	Co 4F9/2	Ni 3F4	Cu 2S1/2	Zn 1S0	Ga 2P1/2	Ge 3P0	As 4S3/2	Se 3P2	Br 2P3/2	Kr 1S0
5	Rb 2S1/2	Sr 1S0		Y 2D3/2	Zr 3F2	Nb 6D1/2	Mo 7S3	Tc 6S5/2	Ru 5F5	Rh 4F9/2	Pd 1S0	Ag 2S1/2	Cd 1S0	In 2P1/2	Sn 3P0	Sb 4S3/2	Te 3P2	I 2P3/2	Xe 1S0
6	Cs 2S1/2	Ba 1S0		Lu 2D3/2	Hf 3F2	Ta 4F3/2	W 5D0	Re 6S5/2	Os 5D4	Ir 4F9/2	Pt 3D3	Au 2S1/2	Hg 1S0	Tl 2P1/2	Pb 3P0	Bi 4S3/2	Po 3P2	At 2P3/2	Rn 1S0
7	Fr 2S1/2	Ra 1S0		Lr 2P1/2?	Rf 3F2	Db 4F3/2?	Sg 5D0?	Bh 6S5/2?	Hs 5D4?	Mt 4F9/2?	Ds 3F4?	Rg 2D5/2?	Cn 1S0?	Nh 2P1/2?	Fl 3P0?	Mc 4S3/2?	Lv 3P2?	Ts 2P3/2?	Og 1S0?
				La 2D3/2	Ce 1G4	Pr 4I9/2	Nd 5I4	Pm 6H5/2	Sm 7F0	Eu 8S7/2	Gd 9D2	Tb 6H15/2	Dy 5I8	Ho 4I15/2	Er 3H6	Tm 2F7/2	Yb 1S0
				Ac 2D3/2	Th 3F2	Pa 4K11/2	U 5L6	Np 6L11/2	Pu 7F0	Am 8S7/2	Cm 9D2	Bk 6H15/2	Cf 5I8	Es 4I15/2	Fm 3H6	Md 2F7/2	No 1S0
s-block f-block d-block p-block

Term symbols for an electron configuration

The process to calculate all possible term symbols for a given electron configuration is somewhat longer.

• First, the total number of possible states N is calculated for a given electron configuration. As before, the filled (sub)shells are discarded, and only the partially filled ones are kept. For a given orbital quantum number ${\displaystyle \ell }$, t is the maximum allowed number of electrons, ${\displaystyle t=2(2\ell +1)}$. If there are e electrons in a given subshell, the number of possible states is
  ${\displaystyle N={t \choose e}={t! \over {e!\,(t-e)!}}.}$

  As an example, consider the carbon electron structure: 1s²2s²2p². After removing full subshells, there are 2 electrons in a p-level (${\displaystyle \ell =1}$), so there are

  ${\displaystyle N={6! \over {2!\,4!}}=15}$

  different states.

• Second, all possible states are drawn. M_L and M_S for each state are calculated, with ${\displaystyle M=\sum _{i=1}^{e}m_{i}}$ where m_i is either ${\displaystyle m_{\ell }}$ or ${\displaystyle m_{s}}$ for the i-th electron, and M represents the resulting M_L or M_S respectively:

  	${\displaystyle m_{\ell }}$
  	+1	0	−1	ML	MS
  all up	↑	↑		1	1
  	↑		↑	0	1
  		↑	↑	−1	1
  all down	↓	↓		1	−1
  	↓		↓	0	−1
  		↓	↓	−1	−1
  one up one down	↑↓			2	0
  	↑	↓		1	0
  	↑		↓	0	0
  	↓	↑		1	0
  		↑↓		0	0
  		↑	↓	−1	0
  	↓		↑	0	0
  		↓	↑	−1	0
  			↑↓	−2	0

• Third, the number of states for each (M_L,M_S) possible combination is counted:

  		MS
  		+1	0	−1
  ML	+2		1
  	+1	1	2	1
  	0	1	3	1
  	−1	1	2	1
  	−2		1

• Fourth, smaller tables can be extracted representing each possible term. Each table will have the size (2L+1) by (2S+1), and will contain only "1"s as entries. The first table extracted corresponds to M_L ranging from −2 to +2 (so L = 2), with a single value for M_S (implying S = 0). This corresponds to a ¹D term. The remaining terms fit inside the middle 3×3 portion of the table above. Then a second table can be extracted, removing the entries for M_L and M_S both ranging from −1 to +1 (and so S = L = 1, a ³P term). The remaining table is a 1×1 table, with L = S = 0, i.e., a ¹S term.

  S = 0, L = 2, J = 2 1D2   MS   0 ML +2 1 +1 1 0 1 −1 1 −2 1

  S=1, L=1, J=2,1,0 3P2, 3P1, 3P0   MS   +1 0 −1 ML +1 1 1 1 0 1 1 1 −1 1 1 1

  S=0, L=0, J=0 1S0   MS   0 ML 0 1

• Fifth, applying Hund's rules, the ground state can be identified (or the lowest state for the configuration of interest). Hund's rules should not be used to predict the order of states other than the lowest for a given configuration. (See examples at Hund's rules § Excited states.)
• If only two equivalent electrons are involved, there is an "Even Rule" which states that, for two equivalent electrons, the only states that are allowed are those for which the sum (L + S) is even.

Case of three equivalent electrons

• For three equivalent electrons (with the same orbital quantum number ${\displaystyle \ell }$), there is also a general formula (denoted by ${\displaystyle X(L,S,\ell )}$ below) to count the number of any allowed terms with total orbital quantum number L and total spin quantum number S.
  ${\displaystyle X(L,S,\ell )={\begin{cases}L-\left\lfloor {\tfrac {L}{3}}\right\rfloor ,&{\text{if }}S=1/2{\text{ and }}0\leq L<\ell \\\ell -\left\lfloor {\tfrac {L}{3}}\right\rfloor ,&{\text{if }}S=1/2{\text{ and }}\ell \leq L\leq 3\ell -1\\\left\lfloor {\tfrac {L}{3}}\right\rfloor -\left\lfloor {\tfrac {L-\ell }{2}}\right\rfloor +\left\lfloor {\tfrac {L-\ell +1}{2}}\right\rfloor ,&{\text{if }}S=3/2{\text{ and }}0\leq L<\ell \\\left\lfloor {\tfrac {L}{3}}\right\rfloor -\left\lfloor {\tfrac {L-\ell }{2}}\right\rfloor ,&{\text{if }}S=3/2{\text{ and }}\ell \leq L\leq 3\ell -3\\0,&{\text{other cases}}\end{cases}}}$

  where the floor function ${\displaystyle \lfloor x\rfloor }$ denotes the greatest integer not exceeding x.

  The detailed proof can be found in Renjun Xu's original paper. ^[5]
• For a general electronic configuration of ${\displaystyle \ell ^{k}}$, namely k equivalent electrons occupying one subshell, the general treatment, and computer code can also be found in this paper. ^[5]

Alternative method using group theory

For configurations with at most two electrons (or holes) per subshell, an alternative and much quicker method of arriving at the same result can be obtained from group theory. The configuration 2p² has the symmetry of the following direct product in the full rotation group:

Γ⁽¹⁾ × Γ⁽¹⁾ = Γ⁽⁰⁾ + [Γ⁽¹⁾] + Γ⁽²⁾,

which, using the familiar labels Γ⁽⁰⁾ = S, Γ⁽¹⁾ = P and Γ⁽²⁾ = D, can be written as

P × P = S + [P] + D.

The square brackets enclose the anti-symmetric square. Hence the 2p² configuration has components with the following symmetries:

S + D (from the symmetric square and hence having symmetric spatial wavefunctions);

P (from the anti-symmetric square and hence having an anti-symmetric spatial wavefunction).

The Pauli principle and the requirement for electrons to be described by anti-symmetric wavefunctions imply that only the following combinations of spatial and spin symmetry are allowed:

¹S + ¹D (spatially symmetric, spin anti-symmetric)

³P (spatially anti-symmetric, spin symmetric).

Then one can move to step five in the procedure above, applying Hund's rules.

The group theory method can be carried out for other such configurations, like 3d², using the general formula

Γ^(j) × Γ^(j) = Γ^(2j) + Γ^(2j−2) + ⋯ + Γ⁽⁰⁾ + [Γ^(2j−1) + ⋯ + Γ⁽¹⁾].

The symmetric square will give rise to singlets (such as ¹S, ¹D, & ¹G), while the anti-symmetric square gives rise to triplets (such as ³P & ³F).

More generally, one can use

Γ^(j) × Γ^(k) = Γ^(j+k) + Γ^(j+k−1) + ⋯ + Γ^(|j−k|)

where, since the product is not a square, it is not split into symmetric and anti-symmetric parts. Where two electrons come from inequivalent orbitals, both a singlet and a triplet are allowed in each case. ^[6]

Summary of various coupling schemes and corresponding term symbols

Basic concepts for all coupling schemes:

• ${\displaystyle {\boldsymbol {\ell }}}$: individual orbital angular momentum vector for an electron, ${\displaystyle \mathbf {s} }$: individual spin vector for an electron, ${\displaystyle \mathbf {j} }$: individual total angular momentum vector for an electron, ${\displaystyle \mathbf {j} ={\boldsymbol {\ell }}+\mathbf {s} }$.
• ${\displaystyle \mathbf {L} }$: Total orbital angular momentum vector for all electrons in an atom (${\displaystyle \mathbf {L} =\sum _{i}{\boldsymbol {\ell }}_{i}}$).
• ${\displaystyle \mathbf {S} }$: total spin vector for all electrons (${\displaystyle \mathbf {S} =\sum _{i}\mathbf {s} _{i}}$).
• ${\displaystyle \mathbf {J} }$: total angular momentum vector for all electrons. The way the angular momenta are combined to form ${\displaystyle \mathbf {J} }$ depends on the coupling scheme: ${\displaystyle \mathbf {J} =\mathbf {L} +\mathbf {S} }$ for LS coupling, ${\displaystyle \mathbf {J} =\sum _{i}\mathbf {j} _{i}}$ for jj coupling, etc.
• A quantum number corresponding to the magnitude of a vector is a letter without an arrow, or without boldface (example: ℓ is the orbital angular momentum quantum number for ${\displaystyle {\boldsymbol {\ell }}}$ and ${\displaystyle {{\hat {\ell }}^{2}}\left|\ell ,m_{\ell },\ldots \right\rangle ={\hbar ^{2}}\ell \left(\ell +1\right)\left|\ell ,m_{\ell },\ldots \right\rangle }$)
• The parameter called multiplicity represents the number of possible values of the total angular momentum quantum number J for certain conditions.
• For a single electron, the term symbol is not written as S is always 1/2, and L is obvious from the orbital type.
• For two electron groups A and B with their own terms, each term may represent S, L and J which are quantum numbers corresponding to the ${\displaystyle \mathbf {S} }$, ${\displaystyle \mathbf {L} }$ and ${\displaystyle \mathbf {J} }$ vectors for each group. "Coupling" of terms A and B to form a new term C means finding quantum numbers for new vectors ${\displaystyle \mathbf {S} =\mathbf {S} _{A}+\mathbf {S} _{B}}$, ${\displaystyle \mathbf {L} =\mathbf {L} _{A}+\mathbf {L} _{B}}$ and ${\displaystyle \mathbf {J} =\mathbf {L} +\mathbf {S} }$. This example is for LS coupling and which vectors are summed in a coupling is depending on which scheme of coupling is taken. Of course, the angular momentum addition rule is that ${\displaystyle X=X_{A}+X_{B},X_{A}+X_{B}-1,\dots ,|X_{A}-X_{B}|}$ where X can be s, ℓ, j, S, L, J or any other angular momentum-magnitude-related quantum number.

LS coupling (Russell–Saunders coupling)

• Coupling scheme: ${\displaystyle \mathbf {L} }$ and ${\displaystyle \mathbf {S} }$ are calculated first then ${\displaystyle \mathbf {J} =\mathbf {L} +\mathbf {S} }$ is obtained. From a practical point of view, it means L, S and J are obtained by using an addition rule of the angular momenta of given electron groups that are to be coupled.
• Electronic configuration + Term symbol: ${\displaystyle n{\ell ^{N}}{{(}^{(2S+1)}}{L_{J}})}$. ${\displaystyle {{(}^{(2S+1)}}{{L}_{J}})}$ is a term which is from coupling of electrons in ${\displaystyle n{\ell ^{N}}}$group. ${\displaystyle n,\ell }$ are principle quantum number, orbital quantum number and ${\displaystyle n{\ell ^{N}}}$means there are N (equivalent) electrons in ${\displaystyle n\ell }$ subshell. For ${\displaystyle L>S}$, ${\displaystyle (2S+1)}$ is equal to multiplicity, a number of possible values in J (final total angular momentum quantum number) from given S and L. For ${\displaystyle S>L}$, multiplicity is ${\displaystyle (2L+1)}$ but ${\displaystyle (2S+1)}$ is still written in the term symbol. Strictly speaking, ${\displaystyle {{(}^{(2S+1)}}{L_{J}})}$ is called level and ${\displaystyle {^{\left(2S+1\right)}{L}}}$ is called term. Sometimes right superscript o is attached to the term symbol, meaning the parity ${\displaystyle P={{\left(-1\right)}^{{\underset {i}{\mathop {\sum } }}\,{\ell _{i}}}}}$ of the group is odd (${\displaystyle P=-1}$).
• Example:
  1. 3d^7 4F_7/2: ⁴F_7/2 is level of 3d⁷ group in which are equivalent 7 electrons are in 3d subshell.
  2. 3d⁷(⁴F)4s4p(³P⁰) ⁶F⁰
     _9/2: ^[7] Terms are assigned for each group (with different principal quantum number n) and rightmost level ⁶F^o
     _9/2 is from coupling of terms of these groups so ⁶F^o
     _9/2 represents final total spin quantum number S, total orbital angular momentum quantum number L and total angular momentum quantum number J in this atomic energy level. The symbols ⁴F and ³P^o refer to seven and two electrons respectively so capital letters are used.
  3. 4f⁷(⁸S⁰)5d (⁷D^o)6p ⁸F_13/2: There is a space between 5d and (⁷D^o). It means (⁸S⁰) and 5d are coupled to get (⁷D^o). Final level ⁸F^o
     _13/2 is from coupling of (⁷D^o) and 6p.
  4. 4f(²F⁰) 5d²(¹G) 6s(²G) ¹P⁰
     ₁: There is only one term ²F^o which is isolated in the left of the leftmost space. It means (²F^o) is coupled lastly; (¹G) and 6s are coupled to get (²G) then (²G) and (²F^o) are coupled to get final term ¹P^o
     ₁.

jj Coupling

• Coupling scheme: ${\displaystyle \mathbf {J} =\sum _{i}\mathbf {j} _{i}}$.
• Electronic configuration + Term symbol: ${\displaystyle {{\left({n_{1}}{\ell _{1}}_{j_{1}}^{N_{1}}{n_{2}}{\ell _{2}}_{j_{2}}^{N_{2}}\ldots \right)}_{J}}}$
• Example:
  1. ${\displaystyle {{\left({\text{6p}}_{\frac {1}{2}}^{2}{\text{6p}}_{\frac {3}{2}}^{}\right)}^{o}}_{3/2}}$: There are two groups. One is ${\displaystyle {\text{6p}}_{1/2}^{2}}$ and the other is ${\displaystyle {\text{6p}}_{\frac {3}{2}}^{}}$. In ${\displaystyle {\text{6p}}_{1/2}^{2}}$, there are 2 electrons having ${\displaystyle j=1/2}$ in 6p subshell while there is an electron having ${\displaystyle j=3/2}$ in the same subshell in ${\displaystyle {\text{6p}}_{\frac {3}{2}}^{}}$. Coupling of these two groups results in ${\displaystyle {1}}$ (coupling of j of three electrons).
  2. ${\displaystyle {\text{4d}}_{5/2}^{3}{\text{4d}}_{3/2}^{2}~\ {{\left({\frac {9}{2}},2\right)}_{11/2}}}$: ${\displaystyle 9/2}$ in () is ${\displaystyle J_{1}}$ for 1st group ${\displaystyle {\text{4d}}_{5/2}^{3}}$ and 2 in () is J₂ for 2nd group ${\displaystyle {\text{4d}}_{3/2}^{2}}$. Subscript 11/2 of term symbol is final J of ${\displaystyle \mathbf {J} =\mathbf {J} _{1}+\mathbf {J} _{2}}$.

J₁L₂ coupling

• Coupling scheme: ${\displaystyle \mathbf {K} =\mathbf {J} _{1}+\mathbf {L} _{2}}$ and ${\displaystyle \mathbf {J} =\mathbf {K} +\mathbf {S} _{2}}$.
• Electronic configuration + Term symbol: ${\displaystyle {n_{1}}{\ell _{1}}^{N_{1}}\left(\mathrm {term} _{1}\right){n_{2}}{\ell _{2}}^{N_{2}}\left(\mathrm {term} _{2}\right)~\ {^{\left(2{S_{2}}+1\right)}{{\left[K\right]}_{J}}}}$. For ${\displaystyle K>S_{2},(2S_{2}+1)}$ is equal to multiplicity, a number of possible values in J (final total angular momentum quantum number) from given S₂ and K. For ${\displaystyle S_{2}>K}$, multiplicity is ${\displaystyle (2K+1)}$ but ${\displaystyle (2S_{2}+1)}$ is still written in the term symbol.
• Example:
  1. 3p⁵(²P^o
     _1/2)5g ²[9/2]^o
     ₅: ${\displaystyle {J_{1}}={\frac {1}{2}},{l_{2}}=4,~{s_{2}}=1/2}$. ${\displaystyle 9/2}$ is K, which comes from coupling of J₁ and ℓ₂. Subscript 5 in term symbol is J which is from coupling of K and s₂.
  2. 4f¹³(²F^o
     _7/2)5d²(¹D) [7/2]^o
     _7/2: ${\displaystyle {J_{1}}={\frac {7}{2}},{L_{2}}=2,~{S_{2}}=0}$. ${\displaystyle 7/2}$ is K, which comes from coupling of J₁ and L₂. Subscript ${\displaystyle 7/2}$ in the term symbol is J which is from coupling of K and S₂.

LS₁ coupling

• Coupling scheme:${\displaystyle \mathbf {K} \ell =\mathbf {L} +\mathbf {S_{1}} }$, ${\displaystyle \mathbf {J} =\mathbf {K} +\mathbf {S_{2}} }$.
• Electronic configuration + Term symbol: ${\displaystyle {n_{1}}{\ell _{1}}^{N_{1}}\left(\mathrm {term} _{1}\right){n_{2}}{\ell _{2}}^{N_{2}}\left(\mathrm {term} _{2}\right)\ ~L~\ {^{\left(2{S_{2}}+1\right)}{{\left[K\right]}_{J}}}}$. For ${\displaystyle K>S_{2},(2S_{2}+1)}$ is equal to multiplicity, a number of possible values in J (final total angular momentum quantum number) from given S₂ and K. For ${\displaystyle S_{2}>K}$, multiplicity is ${\displaystyle (2K+1)}$ but ${\displaystyle (2S_{2}+1)}$ is still written in the term symbol.
• Example:
  1. 3d⁷(⁴P)4s4p(³P^o) D^o 3[5/2]^o
     _7/2: ${\displaystyle {L_{1}}=1,~{L_{2}}=1,~{S_{1}}={\frac {3}{2}},~{S_{2}}=1}$. ${\displaystyle L=2,K=5/2,J=7/2}$.

Most famous coupling schemes are introduced here but these schemes can be mixed to express the energy state of an atom. This summary is based on .

Racah notation and Paschen notation

These are notations for describing states of singly excited atoms, especially noble gas atoms. Racah notation is basically a combination of LS or Russell–Saunders coupling and J₁L₂ coupling. LS coupling is for a parent ion and J₁L₂ coupling is for a coupling of the parent ion and the excited electron. The parent ion is an unexcited part of the atom. For example, in Ar atom excited from a ground state ...3p⁶ to an excited state ...3p⁵4p in electronic configuration, 3p⁵ is for the parent ion while 4p is for the excited electron. ^[8]

In Racah notation, states of excited atoms are denoted as ${\displaystyle \left(^{\left(2{{S}_{1}}+1\right)}{{L}_{1}}_{{J}_{1}}\right)n\ell \left[K\right]_{J}^{o}}$. Quantities with a subscript 1 are for the parent ion, n and ℓ are principal and orbital quantum numbers for the excited electron, K and J are quantum numbers for ${\displaystyle \mathbf {K} =\mathbf {J} _{1}+{\boldsymbol {\ell }}}$ and ${\displaystyle \mathbf {J} =\mathbf {K} +\mathbf {s} }$ where ${\displaystyle {\boldsymbol {\ell }}}$ and ${\displaystyle \mathbf {s} }$ are orbital angular momentum and spin for the excited electron respectively. “o” represents a parity of excited atom. For an inert (noble) gas atom, usual excited states are Np⁵nℓ where N = 2, 3, 4, 5, 6 for Ne, Ar, Kr, Xe, Rn, respectively in order. Since the parent ion can only be ²P_1/2 or ²P_3/2, the notation can be shortened to ${\displaystyle n\ell \left[K\right]_{J}^{o}}$ or ${\displaystyle n\ell '\left[K\right]_{J}^{o}}$, where nℓ means the parent ion is in ²P_3/2 while nℓ′ is for the parent ion in ²P_1/2 state.

Paschen notation is a somewhat odd notation; it is an old notation made to attempt to fit an emission spectrum of neon to a hydrogen-like theory. It has a rather simple structure to indicate energy levels of an excited atom. The energy levels are denoted as n′ℓ#. ℓ is just an orbital quantum number of the excited electron. n′ℓ is written in a way that 1s for (n = N + 1, ℓ = 0), 2p for (n = N + 1, ℓ = 1), 2s for (n = N + 2, ℓ = 0), 3p for (n = N + 2, ℓ = 1), 3s for (n = N + 3, ℓ = 0), etc. Rules of writing n′ℓ from the lowest electronic configuration of the excited electron are: (1) ℓ is written first, (2) n′ is consecutively written from 1 and the relation of ℓ = n′ − 1, n′ − 2, ... , 0 (like a relation between n and ℓ) is kept. n′ℓ is an attempt to describe electronic configuration of the excited electron in a way of describing electronic configuration of hydrogen atom. # is an additional number denoted to each energy level of given n′ℓ (there can be multiple energy levels of given electronic configuration, denoted by the term symbol). # denotes each level in order, for example, # = 10 is for a lower energy level than # = 9 level and # = 1 is for the highest level in a given n′ℓ. An example of Paschen notation is below.

Electronic configuration of Neon	n′ℓ	Electronic configuration of Argon	n′ℓ
1s22s22p6	Ground state	[Ne]3s23p6	Ground state
1s22s22p53s1	1s	[Ne]3s23p54s1	1s
1s22s22p53p1	2p	[Ne]3s23p54p1	2p
1s22s22p54s1	2s	[Ne]3s23p55s1	2s
1s22s22p54p1	3p	[Ne]3s23p55p1	3p
1s22s22p55s1	3s	[Ne]3s23p56s1	3s

See also

• Quantum number
  • Principal quantum number
  • Azimuthal quantum number
  • Spin quantum number
  • Magnetic quantum number
• Angular quantum numbers
• Angular momentum coupling
• Molecular term symbol

Notes

1. There is no official convention for naming orbital angular momentum values greater than 20 (symbol Z) but they are rarely needed. Some authors use Greek letters (α, β, γ, ...) after Z.

References

1. NIST Atomic Spectrum Database For example, to display the levels for a neutral carbon atom, enter "C I" or "C 0" in the "Spectrum" box and click "Retrieve data".
2. Russel, H. N.; Saunders, F. A. (1925) [January 1925]. "New Regularities in the Spectra of the Alkaline Earths". SAO/NASA Astrophysics Data System (ADS). Astrophysical Journal. adsabs.harvard.edu/. 61: 38. Bibcode:1925ApJ....61...38R. doi:10.1086/142872 . Retrieved December 13, 2020– via harvard.edu.
3. "NIST Atomic Spectra Database Ionization Energies Form". NIST Physical Measurement Laboratory. National Institute of Standards and Technology (NIST). October 2018. Retrieved 28 January 2019. This form provides access to NIST critically evaluated data on ground states and ionization energies of atoms and atomic ions.
4. For the sources for these term symbols in the case of the heaviest elements, see Template:Infobox element/symbol-to-electron-configuration/term-symbol.
5. Xu, Renjun; Zhenwen, Dai (2006). "Alternative mathematical technique to determine LS spectral terms". Journal of Physics B: Atomic, Molecular and Optical Physics. 39 (16): 3221–3239. arXiv: physics/0510267 . Bibcode:2006JPhB...39.3221X. doi:10.1088/0953-4075/39/16/007. S2CID   2422425.
6. McDaniel, Darl H. (1977). "Spin factoring as an aid in the determination of spectroscopic terms". Journal of Chemical Education. 54 (3): 147. Bibcode:1977JChEd..54..147M. doi:10.1021/ed054p147.
7. "Atomic Spectroscopy - Different Coupling Scheme 9. Notations for Different Coupling Schemes". Nist. National Institute of Standards and Technology (NIST). 1 November 2017. Retrieved 31 January 2019.
8. "APPENDIX 1 - Coupling Schemes and Notation" (PDF). University of Toronto: Advanced Physics Laboratory - Course Homepage. Retrieved 5 Nov 2017.