Group 11 element

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Group 11 in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
group 10    group 12
IUPAC group number 11
Name by elementcopper group
Trivial namecoinage metals
CAS group number
(US, pattern A-B-A)
IB
old IUPAC number
(Europe, pattern A-B)
IB

  Period
4
NatCopper.jpg
Copper (Cu)
29 Transition metal
5
Silver crystal.jpg
Silver (Ag)
47 Transition metal
6
Gold-crystals.jpg
Gold (Au)
79 Transition metal
7 Roentgenium (Rg)
111unknown chemical properties

Legend

primordial element
synthetic element
Atomic number color:
black=solid

Group 11, by modern IUPAC numbering, [1] is a group of chemical elements in the periodic table, consisting of copper (Cu), silver (Ag), gold (Au), and roentgenium (Rg), although no chemical experiments have yet been carried out to confirm that roentgenium behaves like the heavier homologue to gold. Group 11 is also known as the coinage metals , due to their usage in minting coins [2] —while the rise in metal prices mean that silver and gold are no longer used for circulating currency, remaining in use for bullion, copper remains a common metal in coins to date, either in the form of copper clad coinage or as part of the cupronickel alloy.[ citation needed ] They were most likely the first three elements discovered. [3] Copper, silver, and gold all occur naturally in elemental form. [4] [5]

Contents

History

All three stable elements of the group have been known since prehistoric times, [2] as all of them occur in metallic form in nature and no extraction metallurgy is necessary to produce them.

Copper was known and used around 4000 BC and many items, weapons and materials were made and used with copper.

The first evidence of silver mining dates back to 3000 BC, in Turkey and Greece, according to the RSC. Ancient people even figured out how to refine silver.

The earliest recorded metal employed by humans appears to be gold, which can be found free or "native". Small amounts of natural gold have been found in Spanish caves used during the late Paleolithic period, c. 40,000 BC. Gold artifacts made their first appearance at the very beginning of the pre-dynastic period in Egypt, at the end of the fifth millennium BC and the start of the fourth, and smelting was developed during the course of the 4th millennium BC; gold artifacts appear in the archeology of Lower Mesopotamia during the early 4th millennium BC.

Roentgenium was made in 1994 by bombarding nickel-64 atoms into bismuth-209 to make roentgenium-272. [6]

Characteristics

Like other groups, the members of this family show patterns in electron configuration, especially in the outermost shells, resulting in trends in chemical behavior, although roentgenium is probably an exception:

Z Element No. of electrons/shell
29copper2, 8, 18, 1
47silver2, 8, 18, 18, 1
79gold2, 8, 18, 32, 18, 1
111roentgenium2, 8, 18, 32, 32, 17, 2 (predicted)

All group 11 elements are relatively inert, corrosion-resistant metals. Copper and gold are colored, but silver is not. Roentgenium is expected to be silvery, though it has not been produced in large enough amounts to confirm this.

These elements have low electrical resistivity so they are used for wiring. Copper is the cheapest and most widely used. Bond wires for integrated circuits are usually gold. Silver and silver-plated copper wiring are found in some special applications.

Occurrence

Copper occurs in its native form in Chile, China, Mexico, Russia and the USA. Various natural ores of copper are: copper pyrites (CuFeS2), cuprite or ruby copper (Cu2O), copper glance (Cu2S), malachite (Cu(OH)2CuCO3), and azurite (Cu(OH)22CuCO3).

Copper pyrite is the principal ore, and yields nearly 76% of the world production of copper.

Production

Silver is found in native form, as an alloy with gold (electrum), and in ores containing sulfur, arsenic, antimony or chlorine. Ores include argentite (Ag2S), chlorargyrite (AgCl) which includes horn silver, and pyrargyrite (Ag3SbS3). Silver is extracted using the Parkes process.

Applications

These metals, especially silver, have unusual properties that make them essential for industrial applications outside of their monetary or decorative value. They are all excellent conductors of electricity. The most conductive (by volume) of all metals are silver, copper and gold in that order. Silver is also the most thermally conductive element, and the most light reflecting element. Silver also has the unusual property that the tarnish that forms on silver is still highly electrically conductive.

Copper is used extensively in electrical wiring and circuitry. Gold contacts are sometimes found in precision equipment for their ability to remain corrosion-free. Silver is used widely in mission-critical applications as electrical contacts, and is also used in photography (because silver nitrate reverts to metal on exposure to light), agriculture, medicine, audiophile and scientific applications.

Gold, silver, and copper are quite soft metals and so are easily damaged in daily use as coins. Precious metal may also be easily abraded and worn away through use. In their numismatic functions these metals must be alloyed with other metals to afford coins greater durability. The alloying with other metals makes the resulting coins harder, less likely to become deformed and more resistant to wear.

Gold coins: Gold coins are typically produced as either 90% gold (e.g. with pre-1933 US coins), or 22 carat (91.66%) gold (e.g. current collectible coins and Krugerrands), with copper and silver making up the remaining weight in each case. Bullion gold coins are being produced with up to 99.999% gold (in the Canadian Gold Maple Leaf series).

Silver coins: Silver coins are typically produced as either 90% silver – in the case of pre-1965 US minted coins (which were circulated in many countries), or sterling silver (92.5%) coins for pre-1920 British Commonwealth and other silver coinage, with copper making up the remaining weight in each case. Old European coins were commonly produced with 83.5% silver. Modern silver bullion coins are often produced with purity varying from 99.9% to 99.999%.

Copper coins: Copper coins are often of quite high purity, around 97%, and are usually alloyed with small amounts of zinc and tin.

Inflation has caused the face value of coins to fall below the hard currency value of the historically used metals. This had led to most modern coins being made of base metalscopper nickel (around 80:20, silver in color) is popular as are nickel-brass (copper (75), nickel (5) and zinc (20), gold in color), manganese-brass (copper, zinc, manganese, and nickel), bronze, or simple plated steel.

Biological role and toxicity

Copper, although toxic in excessive amounts, is essential for life. It can be found in hemocyanin, cytochrome c oxidase and in superoxide dismutase. Copper is shown to have antimicrobial properties which make it useful for hospital doorknobs to keep diseases from being spread. Eating food in copper containers is known to increase the risk of copper toxicity. Wilson's disease is a genetic condition in which a protein important for excretion of excess copper is mutated such that copper builds up in body tissues, causing symptoms including vomiting, weakness, tremors, anxiety, and muscle stiffness.

Elemental gold and silver have no known toxic effects or biological use, although gold salts can be toxic to liver and kidney tissue. [7] [8] Like copper, silver also has antimicrobial properties. The prolonged use of preparations containing gold or silver can also lead to the accumulation of these metals in body tissue; the results of which are irreversible but apparently harmless pigmentation conditions known as chrysiasis and argyria respectively.

Due to being short lived and radioactive, roentgenium has no biological use but it is likely extremely harmful due to its radioactivity.

Related Research Articles

<span class="mw-page-title-main">Alloy</span> Mixture or metallic solid solution composed of two or more elements

An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength.

<span class="mw-page-title-main">Brass</span> Alloy of copper and zinc

Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic, and chemical properties, but copper typically has the larger proportion. In use since prehistoric times, it is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure.

<span class="mw-page-title-main">Coin</span> Small, flat and usually round piece of material used as money

A coin is a small object, usually round and flat, used primarily as a medium of exchange or legal tender. They are standardized in weight, and produced in large quantities at a mint in order to facilitate trade. They are most often issued by a government. Coins often have images, numerals, or text on them. The faces of coins or medals are sometimes called the obverse and the reverse, referring to the front and back sides, respectively. The obverse of a coin is commonly called heads, because it often depicts the head of a prominent person, and the reverse is known as tails.

<span class="mw-page-title-main">Gold</span> Chemical element, symbol Au and atomic number 79

Gold is a chemical element; it has symbol Au and atomic number 79. In pure form, it is a bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal, a group 11 element, and one of the noble metals. It is one of the least reactive chemical elements and is solid under standard conditions.

<span class="mw-page-title-main">Metal</span> Type of material

A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.

<span class="mw-page-title-main">Silver</span> Chemical element, symbol Ag and atomic number 47

Silver is a chemical element; it has symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earth's crust in the pure, free elemental form, as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining.

<span class="mw-page-title-main">Solder</span> Alloy used to join metal pieces

Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics.

<span class="mw-page-title-main">Electrum</span> Alloy of gold and silver

Electrum is a naturally occurring alloy of gold and silver, with trace amounts of copper and other metals. Its color ranges from pale to bright yellow, depending on the proportions of gold and silver. It has been produced artificially and is also known as "green gold".

<span class="mw-page-title-main">Copper</span> Chemical element, symbol Cu and atomic number 29

Copper is a chemical element; it has symbol Cu and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement.

Cupronickel or copper-nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other elements added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent.

<span class="mw-page-title-main">Nickel silver</span> Shiny alloy of copper, nickel, and zinc

Nickel silver, maillechort, German silver, argentan, new silver, nickel brass, albata, or alpacca is a copper alloy with nickel and often zinc. The usual formulation is 60% copper, 20% nickel and 20% zinc. Nickel silver does not contain the element silver. It is named for its silvery appearance, which can make it attractive as a cheaper and more durable substitute. It is also well suited for being plated with silver.

<span class="mw-page-title-main">Brazing</span> Metal-joining technique

Brazing is a metal-joining process in which two or more metal items are joined by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.

Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.

This glossary of numismatics is a list of definitions of terms and concepts relevant to numismatics and coin collecting, as well as sub-fields and related disciplines, with concise explanations for the beginner or professional.

<span class="mw-page-title-main">Native metal</span> Form of metal

A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include aluminium, antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, selenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.

<span class="mw-page-title-main">Metallurgical assay</span> Compositional analysis of an ore, metal, or alloy

A metallurgical assay is a compositional analysis of an ore, metal, or alloy, usually performed in order to test for purity or quality.

<span class="mw-page-title-main">Billon (alloy)</span> Alloy of a precious metal with majority base metal content

Billon is an alloy of a precious metal with a majority base metal content. It is used chiefly for making coins, medals, and token coins.

The coinage metals comprise those metallic chemical elements and alloys which have been used to mint coins. Historically, most coinage metals are from the three nonradioactive members of group 11 of the periodic table: copper, silver and gold. Copper is usually augmented with tin or other metals to form bronze. Gold, silver and bronze or copper were the principal coinage metals of the ancient world, the medieval period and into the late modern period when the diversity of coinage metals increased. Coins are often made from more than one metal, either using alloys, coatings (cladding/plating) or bimetallic configurations. While coins are primarily made from metal, some non-metallic materials have also been used.

C41100 Lubaloy is a wrought copper alloy that is composed mainly of copper and zinc. Lubaloy possesses many favorable characteristics making it, and other types of brass, a popular choice in manufacturing. It is a source material in many processes including the creation of electrical components and bullet-making. There are both positive and negative health effects that are associated with the use of this material.

References

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  5. "List Native Elements Minerals & Naturally Occurring Metals In Pure Form". Mineral Processing & Metallurgy. 2016-09-27. Retrieved 2022-03-25.
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  7. Wright, I. H.; Vesey, C. J. (1986). "Acute poisoning with gold cyanide". Anaesthesia. 41 (79): 936–939. doi: 10.1111/j.1365-2044.1986.tb12920.x . PMID   3022615.
  8. Wu, Ming-Ling; Tsai, Wei-Jen; Ger, Jiin; Deng, Jou-Fang; Tsay, Shyh-Haw; Yang, Mo-Hsiung. (2001). "Cholestatic Hepatitis Caused by Acute Gold Potassium Cyanide Poisoning". Clinical Toxicology. 39 (7): 739–743. doi:10.1081/CLT-100108516. PMID   11778673.