Americium

Americium, ₉₅Am

Americium
Pronunciation	/ˌæməˈrɪsiəm/ ​(AM-ə-RISS-ee-əm)
Appearance	silvery white
Mass number	[243]
Americium in the periodic table
Hydrogen Helium Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson Eu ↑ Am ↓ — plutonium ← americium → curium
Atomic number (Z)	95
Group	f-block groups (no number)
Period	period 7
Block	f-block
Electron configuration	[ Rn ] 5f7 7s2
Electrons per shell	2, 8, 18, 32, 25, 8, 2
Physical properties
Phase at  STP	solid
Melting point	1449  K ​(1176 °C,​2149 °F)
Boiling point	2880 K​(2607 °C,​4725 °F)(calculated)
Density (near  r.t.)	12 g/cm3
Heat of fusion	14.39  kJ/mol
Molar heat capacity	28 [1]  J/(mol·K)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 1239 1356
Atomic properties
Oxidation states	+2, +3, +4, +5, +6, +7 (an  amphoteric oxide)
Electronegativity	Pauling scale: 1.3
Ionization energies	1st: 578 kJ/mol
Atomic radius	empirical:173  pm
Covalent radius	180±6 pm
Spectral lines of americium
Other properties
Natural occurrence	synthetic
Crystal structure	​ double hexagonal close-packed (dhcp)
Thermal conductivity	10 W/(m⋅K)
Electrical resistivity	0.69 µΩ⋅m [1]
Magnetic ordering	paramagnetic
Molar magnetic susceptibility	+1000.0×10−6 cm3/mol [2]
CAS Number	7440-35-9
History
Naming	after the Americas
Discovery	Glenn T. Seaborg, Ralph A. James, Leon O. Morgan, Albert Ghiorso (1944)
Isotopes of americium v e
Main isotopes [3] Decay abun­dance half-life (t1/2) mode pro­duct 241Am synth 432.2 y α 237Np SF – 242m1Am synth 141 y IT 242Am α 238Np SF – 243Am synth 7350 y α 239Np SF –
Category: Americium view talk edit | references

Americium is a synthetic chemical element; it has symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element europium and was thus named after the Americas by analogy. ^{[4] [5] [6]}

Americium was first produced in 1944 by the group of Glenn T. Seaborg from Berkeley, California, at the Metallurgical Laboratory of the University of Chicago, as part of the Manhattan Project. Although it is the third element in the transuranic series, it was discovered fourth, after the heavier curium. The discovery was kept secret and only released to the public in November 1945. Most americium is produced by uranium or plutonium being bombarded with neutrons in nuclear reactors – one tonne of spent nuclear fuel contains about 100 grams of americium. It is widely used in commercial ionization chamber smoke detectors, as well as in neutron sources and industrial gauges. Several unusual applications, such as nuclear batteries or fuel for space ships with nuclear propulsion, have been proposed for the isotope ^242mAm, but they are as yet hindered by the scarcity and high price of this nuclear isomer.

Americium is a relatively soft radioactive metal with a silvery appearance. Its most common isotopes are ²⁴¹Am and ²⁴³Am. In chemical compounds, americium usually assumes the oxidation state +3, especially in solutions. Several other oxidation states are known, ranging from +2 to +7, and can be identified by their characteristic optical absorption spectra. The crystal lattices of solid americium and its compounds contain small intrinsic radiogenic defects, due to metamictization induced by self-irradiation with alpha particles, which accumulates with time; this can cause a drift of some material properties over time, more noticeable in older samples.

History

The 60-inch cyclotron at the Lawrence Radiation Laboratory, University of California, Berkeley, in August 1939

Although americium was likely produced in previous nuclear experiments, it was first intentionally synthesized, isolated and identified in late autumn 1944, at the University of California, Berkeley, by Glenn T. Seaborg, Leon O. Morgan, Ralph A. James, and Albert Ghiorso. They used a 60-inch cyclotron at the University of California, Berkeley. ^[7] The element was chemically identified at the Metallurgical Laboratory (now Argonne National Laboratory) of the University of Chicago. Following the lighter neptunium, plutonium, and heavier curium, americium was the fourth transuranium element to be discovered. At the time, the periodic table had been restructured by Seaborg to its present layout, containing the actinide row below the lanthanide one. This led to americium being located right below its twin lanthanide element europium; it was thus by analogy named after the Americas: "The name americium (after the Americas) and the symbol Am are suggested for the element on the basis of its position as the sixth member of the actinide rare-earth series, analogous to europium, Eu, of the lanthanide series." ^{[8] [9] [10]}

The new element was isolated from its oxides in a complex, multi-step process. First plutonium-239 nitrate (²³⁹PuNO₃) solution was coated on a platinum foil of about 0.5 cm² area, the solution was evaporated and the residue was converted into plutonium dioxide (PuO₂) by calcining. After cyclotron irradiation, the coating was dissolved with nitric acid, and then precipitated as the hydroxide using concentrated aqueous ammonia solution. The residue was dissolved in perchloric acid. Further separation was carried out by ion exchange, yielding a certain isotope of curium. The separation of curium and americium was so painstaking that those elements were initially called by the Berkeley group as pandemonium ^[11] (from Greek for all demons or hell) and delirium (from Latin for madness). ^{[12] [13]}

Initial experiments yielded four americium isotopes: ²⁴¹Am, ²⁴²Am, ²³⁹Am and ²³⁸Am. Americium-241 was directly obtained from plutonium upon absorption of two neutrons. It decays by emission of a α-particle to ²³⁷Np; the half-life of this decay was first determined as 510±20 years but then corrected to 432.2 years. ^[14]

${\displaystyle {\ce {^{239}_{94}Pu ->[{\ce {(n,\gamma)}}] ^{240}_{94}Pu ->[{\ce {(n,\gamma)}}] ^{241}_{94}Pu ->[\beta^-][14.35\ {\ce {yr}}] ^{241}_{95}Am}}\ \left({\ce {->[\alpha][432.2\ {\ce {yr}}] ^{237}_{93}Np}}\right)}$

The times are half-lives

The second isotope ²⁴²Am was produced upon neutron bombardment of the already-created ²⁴¹Am. Upon rapid β-decay, ²⁴²Am converts into the isotope of curium ²⁴²Cm (which had been discovered previously). The half-life of this decay was initially determined at 17 hours, which was close to the presently accepted value of 16.02 h. ^[14]

${\displaystyle {\ce {^{241}_{95}Am ->[{\ce {(n,\gamma)}}] ^{242}_{95}Am}}\ \left({\ce {->[\beta^-][16.02\ {\ce {h}}] ^{242}_{96}Cm}}\right)}$

The discovery of americium and curium in 1944 was closely related to the Manhattan Project; the results were confidential and declassified only in 1945. Seaborg leaked the synthesis of the elements 95 and 96 on the U.S. radio show for children Quiz Kids five days before the official presentation at an American Chemical Society meeting on 11 November 1945, when one of the listeners asked whether any new transuranium element besides plutonium and neptunium had been discovered during the war. ^[12] After the discovery of americium isotopes ²⁴¹Am and ²⁴²Am, their production and compounds were patented listing only Seaborg as the inventor. ^[15] The initial americium samples weighed a few micrograms; they were barely visible and were identified by their radioactivity. The first substantial amounts of metallic americium weighing 40–200 micrograms were not prepared until 1951 by reduction of americium(III) fluoride with barium metal in high vacuum at 1100 °C. ^[16]

Occurrence

See also: Nuclear reprocessing

Americium was detected in the fallout from the Ivy Mike nuclear test.

The longest-lived and most common isotopes of americium, ²⁴¹Am and ²⁴³Am, have half-lives of 432.2 and 7,370 years, respectively. Therefore, any primordial americium (americium that was present on Earth during its formation) should have decayed by now. Trace amounts of americium probably occur naturally in uranium minerals as a result of neutron capture and beta decay (²³⁸U → ²³⁹Pu → ²⁴⁰Pu → ²⁴¹Am), though the quantities would be tiny and this has not been confirmed. ^{[17] [18] [19]} Extraterrestrial long-lived ²⁴⁷Cm is probably also deposited on Earth and has ²⁴³Am as one of its intermediate decay products, but again this has not been confirmed. ^[19]

Existing americium is concentrated in the areas used for the atmospheric nuclear weapons tests conducted between 1945 and 1980, as well as at the sites of nuclear incidents, such as the Chernobyl disaster. For example, the analysis of the debris at the testing site of the first U.S. hydrogen bomb, Ivy Mike, (1 November 1952, Enewetak Atoll), revealed high concentrations of various actinides including americium; but due to military secrecy, this result was not published until later, in 1956. ^[20] Trinitite, the glassy residue left on the desert floor near Alamogordo, New Mexico, after the plutonium-based Trinity nuclear bomb test on 16 July 1945, contains traces of americium-241. Elevated levels of americium were also detected at the crash site of a US Boeing B-52 bomber aircraft, which carried four hydrogen bombs, in 1968 in Greenland. ^[21]

In other regions, the average radioactivity of surface soil due to residual americium is only about 0.01  picocuries per gram (0.37  mBq/g). Atmospheric americium compounds are poorly soluble in common solvents and mostly adhere to soil particles. Soil analysis revealed about 1,900 times higher concentration of americium inside sandy soil particles than in the water present in the soil pores; an even higher ratio was measured in loam soils. ^[22]

Americium is produced mostly artificially in small quantities, for research purposes. A tonne of spent nuclear fuel contains about 100 grams of various americium isotopes, mostly ²⁴¹Am and ²⁴³Am. ^[23] Their prolonged radioactivity is undesirable for the disposal, and therefore americium, together with other long-lived actinides, must be neutralized. The associated procedure may involve several steps, where americium is first separated and then converted by neutron bombardment in special reactors to short-lived nuclides. This procedure is well known as nuclear transmutation, but it is still being developed for americium. ^{[24] [25]} The transuranic elements from americium to fermium occurred naturally in the natural nuclear fission reactor at Oklo, but no longer do so. ^[26]

Americium is also one of the elements that have theoretically been detected in Przybylski's Star. ^[27]

Synthesis and extraction

Isotope nucleosynthesis

Chromatographic elution curves revealing the similarity between the lanthanides Tb, Gd, and Eu and the corresponding actinides Bk, Cm, and Am

Americium has been produced in small quantities in nuclear reactors for decades, and kilograms of its ²⁴¹Am and ²⁴³Am isotopes have been accumulated by now. ^[28] Nevertheless, since it was first offered for sale in 1962, its price, about US$1,500 per gram (US$43,000/oz) of ²⁴¹Am, remains almost unchanged owing to the very complex separation procedure. ^[29] The heavier isotope ²⁴³Am is produced in much smaller amounts; it is thus more difficult to separate, resulting in a higher cost of the order US$100,000–US$160,000 per gram (US$2,800,000–US$4,500,000/oz). ^{[30] [31]}

Americium is not synthesized directly from uranium – the most common reactor material – but from the plutonium isotope ²³⁹Pu. The latter needs to be produced first, according to the following nuclear process:

${\displaystyle {\ce {^{238}_{92}U ->[{\ce {(n,\gamma)}}] ^{239}_{92}U ->[\beta^-][23.5 \ {\ce {min}}] ^{239}_{93}Np ->[\beta^-][2.3565 \ {\ce {d}}] ^{239}_{94}Pu}}}$

The capture of two neutrons by ²³⁹Pu (a so-called (n,γ) reaction), followed by a β-decay, results in ²⁴¹Am:

${\displaystyle {\ce {^{239}_{94}Pu ->[{\ce {2(n,\gamma)}}] ^{241}_{94}Pu ->[\beta^-][14.35 \ {\ce {yr}}] ^{241}_{95}Am}}}$

The plutonium present in spent nuclear fuel contains about 12% of ²⁴¹Pu. Because it beta-decays to ²⁴¹Am, ²⁴¹Pu can be extracted and may be used to generate further ²⁴¹Am. ^[29] However, this process is rather slow: half of the original amount of ²⁴¹Pu decays to ²⁴¹Am after about 15 years, and the ²⁴¹Am amount reaches a maximum after 70 years. ^[32]

The obtained ²⁴¹Am can be used for generating heavier americium isotopes by further neutron capture inside a nuclear reactor. In a light water reactor (LWR), 79% of ²⁴¹Am converts to ²⁴²Am and 10% to its nuclear isomer ^242mAm: ^{[note 1] [33]}

${\displaystyle {\begin{cases}79\%:&{\ce {^{241}_{95}Am ->[{\ce {(n,\gamma)}}] ^{242}_{95}Am}}\\10\%:&{\ce {^{241}_{95}Am ->[{\ce {(n,\gamma)}}] ^{242 m}_{95}Am}}\end{cases}}}$

Americium-242 has a half-life of only 16 hours, which makes its further conversion to ²⁴³Am extremely inefficient. The latter isotope is produced instead in a process where ²³⁹Pu captures four neutrons under high neutron flux:

${\displaystyle {\ce {^{239}_{94}Pu ->[{\ce {4(n,\gamma)}}] \ ^{243}_{94}Pu ->[\beta^-][4.956 \ {\ce {h}}] ^{243}_{95}Am}}}$

Metal generation

Most synthesis routines yield a mixture of different actinide isotopes in oxide forms, from which isotopes of americium can be separated. In a typical procedure, the spent reactor fuel (e.g. MOX fuel) is dissolved in nitric acid, and the bulk of uranium and plutonium is removed using a PUREX-type extraction (Plutonium–URanium EXtraction) with tributyl phosphate in a hydrocarbon. The lanthanides and remaining actinides are then separated from the aqueous residue (raffinate) by a diamide-based extraction, to give, after stripping, a mixture of trivalent actinides and lanthanides. Americium compounds are then selectively extracted using multi-step chromatographic and centrifugation techniques ^[34] with an appropriate reagent. A large amount of work has been done on the solvent extraction of americium. For example, a 2003 EU-funded project codenamed "EUROPART" studied triazines and other compounds as potential extraction agents. ^{[35] [36] [37] [38] [39]} A bis-triazinyl bipyridine complex was proposed in 2009 as such a reagent is highly selective to americium (and curium). ^[40] Separation of americium from the highly similar curium can be achieved by treating a slurry of their hydroxides in aqueous sodium bicarbonate with ozone, at elevated temperatures. Both Am and Cm are mostly present in solutions in the +3 valence state; whereas curium remains unchanged, americium oxidizes to soluble Am(IV) complexes which can be washed away. ^[41]

Metallic americium is obtained by reduction from its compounds. Americium(III) fluoride was first used for this purpose. The reaction was conducted using elemental barium as reducing agent in a water- and oxygen-free environment inside an apparatus made of tantalum and tungsten. ^{[16] [42] [43]}

${\displaystyle \mathrm {2\ AmF_{3}\ +\ 3\ Ba\ \longrightarrow \ 2\ Am\ +\ 3\ BaF_{2}} }$

An alternative is the reduction of americium dioxide by metallic lanthanum or thorium: ^{[43] [44]}

${\displaystyle \mathrm {3\ AmO_{2}\ +\ 4\ La\ \longrightarrow \ 3\ Am\ +\ 2\ La_{2}O_{3}} }$

Physical properties

Double-hexagonal close packing with the layer sequence ABAC in the crystal structure of α-americium (A: green, B: blue, C: red)

In the periodic table, americium is located to the right of plutonium, to the left of curium, and below the lanthanide europium, with which it shares many physical and chemical properties. Americium is a highly radioactive element. When freshly prepared, it has a silvery-white metallic lustre, but then slowly tarnishes in air. With a density of 12 g/cm³, americium is less dense than both curium (13.52 g/cm³) and plutonium (19.8 g/cm³); but has a higher density than europium (5.264 g/cm³)—mostly because of its higher atomic mass. Americium is relatively soft and easily deformable and has a significantly lower bulk modulus than the actinides before it: Th, Pa, U, Np and Pu. ^[45] Its melting point of 1173 °C is significantly higher than that of plutonium (639 °C) and europium (826 °C), but lower than for curium (1340 °C). ^{[44] [46]}

At ambient conditions, americium is present in its most stable α form which has a hexagonal crystal symmetry, and a space group P6₃/mmc with cell parameters a = 346.8  pm and c = 1124 pm, and four atoms per unit cell. The crystal consists of a double-hexagonal close packing with the layer sequence ABAC and so is isotypic with α-lanthanum and several actinides such as α-curium. ^{[42] [46]} The crystal structure of americium changes with pressure and temperature. When compressed at room temperature to 5 GPa, α-Am transforms to the β modification, which has a face-centered cubic (fcc) symmetry, space group Fm3m and lattice constant a = 489 pm. This fcc structure is equivalent to the closest packing with the sequence ABC. ^{[42] [46]} Upon further compression to 23 GPa, americium transforms to an orthorhombic γ-Am structure similar to that of α-uranium. There are no further transitions observed up to 52 GPa, except for an appearance of a monoclinic phase at pressures between 10 and 15 GPa. ^[45] There is no consistency on the status of this phase in the literature, which also sometimes lists the α, β and γ phases as I, II and III. The β-γ transition is accompanied by a 6% decrease in the crystal volume; although theory also predicts a significant volume change for the α-β transition, it is not observed experimentally. The pressure of the α-β transition decreases with increasing temperature, and when α-americium is heated at ambient pressure, at 770 °C it changes into an fcc phase which is different from β-Am, and at 1075 °C it converts to a body-centered cubic structure. The pressure-temperature phase diagram of americium is thus rather similar to those of lanthanum, praseodymium and neodymium. ^[47]

As with many other actinides, self-damage of the crystal structure due to alpha-particle irradiation is intrinsic to americium. It is especially noticeable at low temperatures, where the mobility of the produced structure defects is relatively low, by broadening of X-ray diffraction peaks. This effect makes somewhat uncertain the temperature of americium and some of its properties, such as electrical resistivity. ^[48] So for americium-241, the resistivity at 4.2 K increases with time from about 2 μOhm·cm to 10 μOhm·cm after 40 hours, and saturates at about 16 μOhm·cm after 140 hours. This effect is less pronounced at room temperature, due to annihilation of radiation defects; also heating to room temperature the sample which was kept for hours at low temperatures restores its resistivity. In fresh samples, the resistivity gradually increases with temperature from about 2 μOhm·cm at liquid helium to 69 μOhm·cm at room temperature; this behavior is similar to that of neptunium, uranium, thorium and protactinium, but is different from plutonium and curium which show a rapid rise up to 60 K followed by saturation. The room temperature value for americium is lower than that of neptunium, plutonium and curium, but higher than for uranium, thorium and protactinium. ^[1]

Americium is paramagnetic in a wide temperature range, from that of liquid helium, to room temperature and above. This behavior is markedly different from that of its neighbor curium which exhibits antiferromagnetic transition at 52 K. ^[49] The thermal expansion coefficient of americium is slightly anisotropic and amounts to (7.5±0.2)×10⁻⁶ /°C along the shorter a axis and (6.2±0.4)×10⁻⁶ /°C for the longer c hexagonal axis. ^[46] The enthalpy of dissolution of americium metal in hydrochloric acid at standard conditions is −620.6±1.3 kJ/mol, from which the standard enthalpy change of formation (Δ_fH°) of aqueous Am³⁺ ion is −621.2±2.0 kJ/mol. The standard potential Am³⁺/Am⁰ is −2.08±0.01 V. ^[50]

Chemical properties

Americium metal readily reacts with oxygen and dissolves in aqueous acids. The most stable oxidation state for americium is +3. ^[51] The chemistry of americium(III) has many similarities to the chemistry of lanthanide(III) compounds. For example, trivalent americium forms insoluble fluoride, oxalate, iodate, hydroxide, phosphate and other salts. ^[51] Compounds of americium in oxidation states +2, +4, +5, +6 and +7 have also been studied. This is the widest range that has been observed with actinide elements. The color of americium compounds in aqueous solution is as follows: Am³⁺ (yellow-reddish), Am⁴⁺ (yellow-reddish), Am^VO+2; (yellow), Am^VIO2+2 (brown) and Am^VIIO5−6 (dark green). ^{[52] [53]} The absorption spectra have sharp peaks, due to f-f transitions' in the visible and near-infrared regions. Typically, Am(III) has absorption maxima at ca. 504 and 811 nm, Am(V) at ca. 514 and 715 nm, and Am(VI) at ca. 666 and 992 nm. ^{[54] [55] [56] [57]}

Americium compounds with oxidation state +4 and higher are strong oxidizing agents, comparable in strength to the permanganate ion (MnO−4) in acidic solutions. ^[58] Whereas the Am⁴⁺ ions are unstable in solutions and readily convert to Am³⁺, compounds such as americium dioxide (AmO₂) and americium(IV) fluoride (AmF₄) are stable in the solid state.

The pentavalent oxidation state of americium was first observed in 1951. ^[59] In acidic aqueous solution the AmO+2 ion is unstable with respect to disproportionation. ^{[60] [61] [62]} The reaction

3[AmO₂]⁺ + 4H⁺ → 2[AmO₂]²⁺ + Am³⁺ + 2H₂O

is typical. The chemistry of Am(V) and Am(VI) is comparable to the chemistry of uranium in those oxidation states. In particular, compounds like Li₃AmO₄ and Li₆AmO₆ are comparable to uranates and the ion AmO2+2 is comparable to the uranyl ion, UO2+2. Such compounds can be prepared by oxidation of Am(III) in dilute nitric acid with ammonium persulfate. ^[63] Other oxidising agents that have been used include silver(I) oxide, ^[57] ozone and sodium persulfate. ^[56]

Chemical compounds

Main article: Americium compounds

Oxygen compounds

Three americium oxides are known, with the oxidation states +2 (AmO), +3 (Am₂O₃) and +4 (AmO₂). Americium(II) oxide was prepared in minute amounts and has not been characterized in detail. ^[64] Americium(III) oxide is a red-brown solid with a melting point of 2205 °C. ^[65] Americium(IV) oxide is the main form of solid americium which is used in nearly all its applications. As most other actinide dioxides, it is a black solid with a cubic (fluorite) crystal structure. ^[66]

The oxalate of americium(III), vacuum dried at room temperature, has the chemical formula Am₂(C₂O₄)₃·7H₂O. Upon heating in vacuum, it loses water at 240 °C and starts decomposing into AmO₂ at 300 °C, the decomposition completes at about 470 °C. ^[51] The initial oxalate dissolves in nitric acid with the maximum solubility of 0.25 g/L. ^[67]

Halides

Halides of americium are known for the oxidation states +2, +3 and +4, ^[68] where the +3 is most stable, especially in solutions. ^[69]

Oxidation state	F	Cl	Br	I
+4	Americium(IV) fluoride AmF4 pale pink
+3	Americium(III) fluoride AmF3 pink	Americium(III) chloride AmCl3 pink	Americium(III) bromide AmBr3 light yellow	Americium(III) iodide AmI3 light yellow
+2		Americium(II) chloride AmCl2 black	Americium(II) bromide AmBr2 black	Americium(II) iodide AmI2 black

Reduction of Am(III) compounds with sodium amalgam yields Am(II) salts – the black halides AmCl₂, AmBr₂ and AmI₂. They are very sensitive to oxygen and oxidize in water, releasing hydrogen and converting back to the Am(III) state. Specific lattice constants are:

• Orthorhombic AmCl₂: a = 896.3±0.8 pm, b = 757.3±0.8 pm and c = 453.2±0.6 pm
• Tetragonal AmBr₂: a = 1159.2±0.4 pm and c = 712.1±0.3 pm. ^[70] They can also be prepared by reacting metallic americium with an appropriate mercury halide HgX₂, where X = Cl, Br or I: ^[71]

${\displaystyle {\ce {{Am}+{\underset {mercury\ halide}{HgX2}}->[{} \atop 400-500^{\circ }{\ce {C}}]{AmX2}+{Hg}}}}$

Americium(III) fluoride (AmF₃) is poorly soluble and precipitates upon reaction of Am³⁺ and fluoride ions in weak acidic solutions:

${\displaystyle {\ce {Am^3+ + 3F^- -> AmF3(v)}}}$

The tetravalent americium(IV) fluoride (AmF₄) is obtained by reacting solid americium(III) fluoride with molecular fluorine: ^{[72] [73]}

${\displaystyle {\ce {2AmF3 + F2 -> 2AmF4}}}$

Another known form of solid tetravalent americium fluoride is KAmF₅. ^{[72] [74]} Tetravalent americium has also been observed in the aqueous phase. For this purpose, black Am(OH)₄ was dissolved in 15-M NH₄F with the americium concentration of 0.01 M. The resulting reddish solution had a characteristic optical absorption spectrum which is similar to that of AmF₄ but differed from other oxidation states of americium. Heating the Am(IV) solution to 90 °C did not result in its disproportionation or reduction, however a slow reduction was observed to Am(III) and assigned to self-irradiation of americium by alpha particles. ^[55]

Most americium(III) halides form hexagonal crystals with slight variation of the color and exact structure between the halogens. So, chloride (AmCl₃) is reddish and has a structure isotypic to uranium(III) chloride (space group P6₃/m) and the melting point of 715 °C. ^[68] The fluoride is isotypic to LaF₃ (space group P6₃/mmc) and the iodide to BiI₃ (space group R3). The bromide is an exception with the orthorhombic PuBr₃-type structure and space group Cmcm. ^[69] Crystals of americium(III) chloride hexahydrate (AmCl₃·6H₂O) can be prepared by dissolving americium dioxide in hydrochloric acid and evaporating the liquid. Those crystals are hygroscopic and have yellow-reddish color and a monoclinic crystal structure. ^[75]

Oxyhalides of americium in the form Am^VIO₂X₂, Am^VO₂X, Am^IVOX₂ and Am^IIIOX can be obtained by reacting the corresponding americium halide with oxygen or Sb₂O₃, and AmOCl can also be produced by vapor phase hydrolysis: ^[71]

AmCl₃ + H₂O -> AmOCl + 2HCl

Chalcogenides and pnictides

The known chalcogenides of americium include the sulfide AmS₂, ^[76] selenides AmSe₂ and Am₃Se₄, ^{[76] [77]} and tellurides Am₂Te₃ and AmTe₂. ^[78] The pnictides of americium (²⁴³Am) of the AmX type are known for the elements phosphorus, arsenic, ^[79] antimony and bismuth. They crystallize in the rock-salt lattice. ^[77]

Silicides and borides

Americium monosilicide (AmSi) and "disilicide" (nominally AmSi_x with: 1.87 < x < 2.0) were obtained by reduction of americium(III) fluoride with elementary silicon in vacuum at 1050 °C (AmSi) and 1150−1200 °C (AmSi_x). AmSi is a black solid isomorphic with LaSi, it has an orthorhombic crystal symmetry. AmSi_x has a bright silvery lustre and a tetragonal crystal lattice (space group I4₁/amd), it is isomorphic with PuSi₂ and ThSi₂. ^[80] Borides of americium include AmB₄ and AmB₆. The tetraboride can be obtained by heating an oxide or halide of americium with magnesium diboride in vacuum or inert atmosphere. ^{[81] [82]}

Organoamericium compounds

Predicted structure of amerocene [(η -C₈H₈)₂Am]

Analogous to uranocene, americium forms the organometallic compound amerocene with two cyclooctatetraene ligands, with the chemical formula (η⁸-C₈H₈)₂Am. ^[83] A cyclopentadienyl complex is also known that is likely to be stoichiometrically AmCp₃. ^{[84] [85]}

Formation of the complexes of the type Am(n-C₃H₇-BTP)₃, where BTP stands for 2,6-di(1,2,4-triazin-3-yl)pyridine, in solutions containing n-C₃H₇-BTP and Am³⁺ ions has been confirmed by EXAFS. Some of these BTP-type complexes selectively interact with americium and therefore are useful in its selective separation from lanthanides and another actinides. ^[86]

Biological aspects

Americium is an artificial element of recent origin, and thus does not have a biological requirement. ^{[87] [88]} It is harmful to life. It has been proposed to use bacteria for removal of americium and other heavy metals from rivers and streams. Thus, Enterobacteriaceae of the genus Citrobacter precipitate americium ions from aqueous solutions, binding them into a metal-phosphate complex at their cell walls. ^[89] Several studies have been reported on the biosorption and bioaccumulation of americium by bacteria ^{[90] [91]} and fungi. ^[92]

Fission

The isotope ^242mAm (half-life 141 years) has the largest cross sections for absorption of thermal neutrons (5,700 barns), ^[93] that results in a small critical mass for a sustained nuclear chain reaction. The critical mass for a bare ^242mAm sphere is about 9–14 kg (the uncertainty results from insufficient knowledge of its material properties). It can be lowered to 3–5 kg with a metal reflector and should become even smaller with a water reflector. ^[94] Such small critical mass is favorable for portable nuclear weapons, but those based on ^242mAm are not known yet, probably because of its scarcity and high price. The critical masses of the two readily available isotopes, ²⁴¹Am and ²⁴³Am, are relatively high – 57.6 to 75.6 kg for ²⁴¹Am and 209 kg for ²⁴³Am. ^[95] Scarcity and high price yet hinder application of americium as a nuclear fuel in nuclear reactors. ^[96]

There are proposals of very compact 10-kW high-flux reactors using as little as 20 grams of ^242mAm. Such low-power reactors would be relatively safe to use as neutron sources for radiation therapy in hospitals. ^[97]

Isotopes

See also: Isotopes of americium

About 18 isotopes and 11 nuclear isomers are known for americium, having mass numbers 229, 230, and 232 through 247. ^[3] There are two long-lived alpha-emitters; ²⁴³Am has a half-life of 7,370 years and is the most stable isotope, and ²⁴¹Am has a half-life of 432.2 years. The most stable nuclear isomer is ^242m1Am; it has a long half-life of 141 years. The half-lives of other isotopes and isomers range from 0.64 microseconds for ^245m1Am to 50.8 hours for ²⁴⁰Am. As with most other actinides, the isotopes of americium with odd number of neutrons have relatively high rate of nuclear fission and low critical mass. ^[14]

Americium-241 decays to ²³⁷Np emitting alpha particles of 5 different energies, mostly at 5.486 MeV (85.2%) and 5.443 MeV (12.8%). Because many of the resulting states are metastable, they also emit gamma rays with the discrete energies between 26.3 and 158.5 keV. ^[98]

Americium-242 is a short-lived isotope with a half-life of 16.02 h. ^[14] It mostly (82.7%) converts by β-decay to ²⁴²Cm, but also by electron capture to ²⁴²Pu (17.3%). Both ²⁴²Cm and ²⁴²Pu transform via nearly the same decay chain through ²³⁸Pu down to ²³⁴U.

Nearly all (99.541%) of ^242m1Am decays by internal conversion to ²⁴²Am and the remaining 0.459% by α-decay to ²³⁸Np. The latter subsequently decays to ²³⁸Pu and then to ²³⁴U. ^[14]

Americium-243 transforms by α-emission into ²³⁹Np, which converts by β-decay to ²³⁹Pu, and the ²³⁹Pu changes into ²³⁵U by emitting an α-particle.

Applications

Outside and inside view of an americium-based smoke detector

Ionization-type smoke detector

Main article: Smoke detector § Ionization

Americium is used in the most common type of household smoke detector, which uses ²⁴¹Am in the form of americium dioxide as its source of ionizing radiation. ^[99] This isotope is preferred over ²²⁶ Ra because it emits 5 times more alpha particles and relatively little harmful gamma radiation.

The amount of americium in a typical new smoke detector is 1  microcurie (37  kBq) or 0.29 microgram. This amount declines slowly as the americium decays into neptunium-237, a different transuranic element with a much longer half-life (about 2.14 million years). With its half-life of 432.2 years, the americium in a smoke detector includes about 3% neptunium after 19 years, and about 5% after 32 years. The radiation passes through an ionization chamber, an air-filled space between two electrodes, and permits a small, constant current between the electrodes. Any smoke that enters the chamber absorbs the alpha particles, which reduces the ionization and affects this current, triggering the alarm. Compared to the alternative optical smoke detector, the ionization smoke detector is cheaper and can detect particles which are too small to produce significant light scattering; however, it is more prone to false alarms. ^{[100] [101] [102] [103]}

Radionuclide

As ²⁴¹Am has a roughly similar half-life to ²³⁸Pu (432.2 years vs. 87 years), it has been proposed as an active element of radioisotope thermoelectric generators, for example in spacecraft. ^[104] Although americium produces less heat and electricity – the power yield is 114.7 mW/g for ²⁴¹Am and 6.31 mW/g for ²⁴³Am ^[1] (cf. 390 mW/g for ²³⁸Pu) ^[104] – and its radiation poses more threat to humans owing to neutron emission, the European Space Agency is considering using americium for its space probes. ^[105]

Another proposed space-related application of americium is a fuel for space ships with nuclear propulsion. It relies on the very high rate of nuclear fission of ^242mAm, which can be maintained even in a micrometer-thick foil. Small thickness avoids the problem of self-absorption of emitted radiation. This problem is pertinent to uranium or plutonium rods, in which only surface layers provide alpha-particles. ^{[106] [107]} The fission products of ^242mAm can either directly propel the spaceship or they can heat a thrusting gas. They can also transfer their energy to a fluid and generate electricity through a magnetohydrodynamic generator. ^[108]

One more proposal which utilizes the high nuclear fission rate of ^242mAm is a nuclear battery. Its design relies not on the energy of the emitted by americium alpha particles, but on their charge, that is the americium acts as the self-sustaining "cathode". A single 3.2 kg ^242mAm charge of such battery could provide about 140 kW of power over a period of 80 days. ^[109] Even with all the potential benefits, the current applications of ^242mAm are as yet hindered by the scarcity and high price of this particular nuclear isomer. ^[108]

In 2019, researchers at the UK National Nuclear Laboratory and the University of Leicester demonstrated the use of heat generated by americium to illuminate a small light bulb. This technology could lead to systems to power missions with durations up to 400 years into interstellar space, where solar panels do not function. ^{[110] [111]}

Neutron source

The oxide of ²⁴¹Am pressed with beryllium is an efficient neutron source. Here americium acts as the alpha source, and beryllium produces neutrons owing to its large cross-section for the (α,n) nuclear reaction:

${\displaystyle {\ce {^{241}_{95}Am -> ^{237}_{93}Np + ^{4}_{2}He + \gamma}}}$

${\displaystyle {\ce {^{9}_{4}Be + ^{4}_{2}He -> ^{12}_{6}C + ^{1}_{0}n + \gamma}}}$

The most widespread use of ²⁴¹AmBe neutron sources is a neutron probe – a device used to measure the quantity of water present in soil, as well as moisture/density for quality control in highway construction. ²⁴¹Am neutron sources are also used in well logging applications, as well as in neutron radiography, tomography and other radiochemical investigations. ^[112]

Production of other elements

Americium is a starting material for the production of other transuranic elements and transactinides – for example, 82.7% of ²⁴²Am decays to ²⁴²Cm and 17.3% to ²⁴²Pu. In the nuclear reactor, ²⁴²Am is also up-converted by neutron capture to ²⁴³Am and ²⁴⁴Am, which transforms by β-decay to ²⁴⁴Cm:

${\displaystyle {\ce {^{243}_{95}Am ->[{\ce {(n,\gamma)}}] ^{244}_{95}Am ->[\beta^-][10.1 \ {\ce {h}}] ^{244}_{96}Cm}}}$

Irradiation of ²⁴¹Am by ¹²C or ²²Ne ions yields the isotopes ²⁴⁷Es (einsteinium) or ²⁶⁰Db (dubnium), respectively. ^[112] Furthermore, the element berkelium (²⁴³Bk isotope) had been first intentionally produced and identified by bombarding ²⁴¹Am with alpha particles, in 1949, by the same Berkeley group, using the same 60-inch cyclotron. Similarly, nobelium was produced at the Joint Institute for Nuclear Research, Dubna, Russia, in 1965 in several reactions, one of which included irradiation of ²⁴³Am with ¹⁵N ions. Besides, one of the synthesis reactions for lawrencium, discovered by scientists at Berkeley and Dubna, included bombardment of ²⁴³Am with ¹⁸O. ^[10]

Spectrometer

Americium-241 has been used as a portable source of both gamma rays and alpha particles for a number of medical and industrial uses. The 59.5409 keV gamma ray emissions from ²⁴¹Am in such sources can be used for indirect analysis of materials in radiography and X-ray fluorescence spectroscopy, as well as for quality control in fixed nuclear density gauges and nuclear densometers. For example, the element has been employed to gauge glass thickness to help create flat glass. ^[28] Americium-241 is also suitable for calibration of gamma-ray spectrometers in the low-energy range, since its spectrum consists of nearly a single peak and negligible Compton continuum (at least three orders of magnitude lower intensity). ^[113] Americium-241 gamma rays were also used to provide passive diagnosis of thyroid function. This medical application is however obsolete.

Health concerns

As a highly radioactive element, americium and its compounds must be handled only in an appropriate laboratory under special arrangements. Although most americium isotopes predominantly emit alpha particles which can be blocked by thin layers of common materials, many of the daughter products emit gamma-rays and neutrons which have a long penetration depth. ^[114]

If consumed, most of the americium is excreted within a few days, with only 0.05% absorbed in the blood, of which roughly 45% goes to the liver and 45% to the bones, and the remaining 10% is excreted. The uptake to the liver depends on the individual and increases with age. In the bones, americium is first deposited over cortical and trabecular surfaces and slowly redistributes over the bone with time. The biological half-life of ²⁴¹Am is 50 years in the bones and 20 years in the liver, whereas in the gonads (testicles and ovaries) it remains permanently; in all these organs, americium promotes formation of cancer cells as a result of its radioactivity. ^{[22] [115] [116]}

Americium often enters landfills from discarded smoke detectors. The rules associated with the disposal of smoke detectors are relaxed in most jurisdictions. In 1994, 17-year-old David Hahn extracted the americium from about 100 smoke detectors in an attempt to build a breeder nuclear reactor. ^{[117] [118] [119] [120]} There have been a few cases of exposure to americium, the worst case being that of chemical operations technician Harold McCluskey, who at the age of 64 was exposed to 500 times the occupational standard for americium-241 as a result of an explosion in his lab. McCluskey died at the age of 75 of unrelated pre-existing disease. ^{[121] [122]}

See also

• Actinides in the environment
• Category:Americium compounds

Notes

1. The "metastable" state is marked by the letter m.

References

1. Muller, W.; Schenkel, R.; Schmidt, H. E.; Spirlet, J. C.; McElroy, D. L.; Hall, R. O. A.; Mortimer, M. J. (1978). "The electrical resistivity and specific heat of americium metal". Journal of Low Temperature Physics. 30 (5–6): 561. Bibcode:1978JLTP...30..561M. doi:10.1007/BF00116197.
2. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN   0-8493-0464-4.
3. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
4. Seaborg, Glenn T. (1946). "The Transuranium Elements". Science. 104 (2704): 379–386. Bibcode:1946Sci...104..379S. doi:10.1126/science.104.2704.379. JSTOR   1675046. PMID   17842184.
5. Kostecka, Keith (2008). "Americium – From Discovery to the Smoke Detector and Beyond" (PDF). Bull. Hist. Chem. 33 (2): 89–93. Archived (PDF) from the original on 9 October 2022.
6. "C&En: It's Elemental: The Periodic Table - Americium".
7. Obituary of Dr. Leon Owen (Tom) Morgan (1919–2002), Retrieved 28 November 2010
8. Seaborg, G. T.; James, R.A. and Morgan, L. O.: "The New Element Americium (Atomic Number 95)", THIN PPR (National Nuclear Energy Series, Plutonium Project Record), Vol 14 B The Transuranium Elements: Research Papers, Paper No. 22.1, McGraw-Hill Book Co., Inc., New York, 1949. Abstract; Full text (January 1948), Retrieved 28 November 2010
9. Street, K.; Ghiorso, A.; Seaborg, G. (1950). "The Isotopes of Americium". Physical Review. 79 (3): 530. Bibcode:1950PhRv...79..530S. doi:10.1103/PhysRev.79.530.
10. Greenwood, p. 1252
11. "Americium (Am) | AMERICAN ELEMENTS ®". American Elements: The Materials Science Company. Retrieved 9 May 2024.
12. Pepling, Rachel Sheremeta (2003). "Chemical & Engineering News: It's Elemental: The Periodic Table – Americium" . Retrieved 7 July 2010.
13. Robert E. Krebs (2006). The History and Use of Our Earth's Chemical Elements: A Reference Guide (Second ed.). Greenwood Publishing Group. p. 322. ISBN   978-0-313-33438-2.
14. Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (1997). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 624 (1): 1–124. Bibcode:1997NuPhA.624....1A. doi:10.1016/S0375-9474(97)00482-X. Archived from the original (PDF) on 23 September 2008.
15. Seaborg, Glenn T. U.S. patent 3,156,523 "Element", Filing date: 23 August 1946, Issue date: 10 November 1964
16. Westrum, Edgar F.; Eyring, Leroy (1951). "The Preparation and Some Properties of Americium Metal". Journal of the American Chemical Society. 73 (7): 3396. doi:10.1021/ja01151a116. hdl: 2027/mdp.39015086480962 .
17. Earth, Rachel Ross 2017-05-23T02:31:00Z Planet (23 May 2017). "Facts About Americium". livescience.com. Retrieved 10 August 2019.
18. "Americium - Element information, properties and uses | Periodic Table". www.rsc.org. Retrieved 10 August 2019.
19. Thornton, Brett F.; Burdette, Shawn C. (2019). "Neutron stardust and the elements of Earth". Nature Chemistry. 11 (1): 4–10. Bibcode:2019NatCh..11....4T. doi:10.1038/s41557-018-0190-9. PMID   30552435. S2CID   54632815 . Retrieved 19 February 2022.
20. Fields, P. R.; Studier, M. H.; Diamond, H.; et al. (1956). "Transplutonium Elements in Thermonuclear Test Debris". Physical Review. 102 (1): 180–182. Bibcode:1956PhRv..102..180F. doi:10.1103/PhysRev.102.180.
21. Eriksson, Mats (April 2002). On Weapons Plutonium in the Arctic Environment (PDF). Risø National Laboratory, Roskilde, Denmark: Lund University. p. 28. Archived from the original (PDF) on 18 December 2008. Retrieved 15 November 2008.
22. Human Health Fact Sheet on Americium Archived 16 July 2011 at the Wayback Machine , Los Alamos National Laboratory, Retrieved 28 November 2010
23. Hoffmann, Klaus Kann man Gold machen? Gauner, Gaukler und Gelehrte. Aus der Geschichte der chemischen Elemente (Can you make gold? Crooks, clowns, and scholars. From the history of the chemical elements), Urania-Verlag, Leipzig, Jena, Berlin 1979, no ISBN, p. 233
24. Baetslé, L. Application of Partitioning/Transmutation of Radioactive Materials in Radioactive Waste Management Archived 26 April 2005 at the Wayback Machine , Nuclear Research Centre of Belgium Sck/Cen, Mol, Belgium, September 2001, Retrieved 28 November 2010
25. Fioni, Gabriele; Cribier, Michel and Marie, Frédéric Can the minor actinide, americium-241, be transmuted by thermal neutrons? Archived 11 November 2007 at the Wayback Machine , Department of Astrophysics, CEA/Saclay, Retrieved 28 November 2010
26. Emsley, John (2011). Nature's Building Blocks: An A-Z Guide to the Elements (New ed.). New York, NY: Oxford University Press. ISBN   978-0-19-960563-7.
27. Gopka, V. F.; Yushchenko, A. V.; Yushchenko, V. A.; Panov, I. V.; Kim, Ch. (15 May 2008). "Identification of absorption lines of short half-life actinides in the spectrum of Przybylski's star (HD 101065)". Kinematics and Physics of Celestial Bodies. 24 (2): 89–98. Bibcode:2008KPCB...24...89G. doi:10.3103/S0884591308020049. S2CID   120526363.
28. Greenwood, p. 1262
29. Smoke detectors and americium Archived 12 November 2010 at the Wayback Machine , World Nuclear Association, January 2009, Retrieved 28 November 2010
30. Hammond C. R. "The elements" in Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN   0-8493-0486-5.
31. Emeleus, H. J.; Sharpe, A. G. (1987). Advances in Inorganic Chemistry. Academic Press. p. 2. ISBN   978-0-08-057880-4.
32. BREDL Southern Anti-Plutonium Campaign, Blue Ridge Environmental Defense League, Retrieved 28 November 2010
33. Sasahara, A.; et al. (2004). "Neutron and Gamma Ray Source Evaluation of LWR High Burn-up UO₂ and MOX Spent Fuels". Journal of Nuclear Science and Technology. 41 (4): 448–456. doi: 10.3327/jnst.41.448 . article/200410/000020041004A0333355.php Abstract Archived 24 November 2010 at the Wayback Machine
34. Penneman, pp. 34–48
35. Hudson, M. J.; et al. (2003). "The coordination chemistry of 1,2,4-triazinyl bipyridines with lanthanide(III) elements – implications for the partitioning of americium(III)". Dalton Trans. (9): 1675–1685. doi:10.1039/b301178j.
36. Geist, A.; et al. (11–13 December 2000). "Actinide(III)/Lanthanide(III) Partitioning Using n-Pr-BTP as Extractant: Extraction Kinetics and Extraction Test in a Hollow Fiber Module" (PDF). 6th Information Exchange Meeting on Actinide and Fission Product Partitioning and Transmutation. OECD Nuclear Energy Agency. Archived from the original (PDF) on 24 September 2015. Retrieved 26 May 2014.
37. Hill, C.; Guillaneux, D.; Hérès, X.; Boubals, N. & Ramain, L. (24–26 October 2000). "Sanex-BTP Process Development Studies" (PDF). Atalante 2000: Scientific Research on the Back-end of the Fuel Cycle for the 21st Century. Commissariat à l'énergie atomique. Archived from the original (PDF) on 15 November 2012.
38. Geist, A.; et al. (14–16 October 2002). "Effective Actinide(III)-Lanthanide(III) Separation in Miniature Hollow Fibre Modules" (PDF). 7th Information Exchange Meeting on Actinide and Fission Product Partitioning and Transmutation. OECD Nuclear Energy Agency. Archived from the original (PDF) on 29 September 2009. Retrieved 17 March 2007.
39. Ensor, D.D. "Separation Studies of f-Elements" (PDF). Tennessee Tech University. Archived from the original (PDF) on 22 September 2006.
40. Magnusson D; Christiansen B; Foreman MRS; Geist A; Glatz JP; Malmbeck R; Modolo G; Serrano-Purroy D & Sorel C (2009). "Demonstration of a SANEX Process in Centrifugal Contactors using the CyMe4-BTBP Molecule on a Genuine Fuel Solution". Solvent Extraction and Ion Exchange. 27 (2): 97. doi:10.1080/07366290802672204. S2CID   94720457.
41. Penneman, p. 25
42. Gmelin Handbook of Inorganic Chemistry, System No. 71, transuranics, Part B 1, pp. 57–67.
43. Penneman, p. 3
44. Wade, W.; Wolf, T. (1967). "Preparation and some properties of americium metal". Journal of Inorganic and Nuclear Chemistry. 29 (10): 2577. doi:10.1016/0022-1902(67)80183-0. S2CID   98370243.
45. Benedict, U. (1984). "Study of actinide metals and actinide compounds under high pressures". Journal of the Less Common Metals. 100: 153. doi:10.1016/0022-5088(84)90061-4.
46. McWhan, D. B.; Cunningham, B. B.; Wallmann, J. C. (1962). "Crystal structure, thermal expansion and melting point of americium metal". Journal of Inorganic and Nuclear Chemistry. 24 (9): 1025. doi:10.1016/0022-1902(62)80246-2.
47. Young, D. A. (1991). Phase diagrams of the elements. University of California Press. p. 226. ISBN   978-0-520-91148-2.
48. Benedict, U.; Dufour, C. (1980). "Low temperature lattice expansion of americium dioxide". Physica B+C. 102 (1): 303. Bibcode:1980PhyBC.102..303B. doi:10.1016/0378-4363(80)90178-3.
49. Kanellakopulos, B.; Blaise, A.; Fournier, J. M.; Müller, W. (1975). "The magnetic susceptibility of Americium and curium metal". Solid State Communications. 17 (6): 713. Bibcode:1975SSCom..17..713K. doi:10.1016/0038-1098(75)90392-0.
50. Mondal, J. U.; Raschella, D. L.; Haire, R. G.; Petereson, J. R. (1987). "The enthalpy of solution of 243Am metal and the standard enthalpy of formation of Am3+(aq)". Thermochimica Acta. 116: 235. doi:10.1016/0040-6031(87)88183-2.
51. Penneman, p. 4
52. Americium Archived 9 June 2019 at the Wayback Machine , Das Periodensystem der Elemente für den Schulgebrauch (The periodic table of elements for schools) chemie-master.de (in German), Retrieved 28 November 2010
53. Greenwood, p. 1265
54. Penneman, pp. 10–14
55. Asprey, L. B.; Penneman, R. A. (1961). "First Observation of Aqueous Tetravalent Americium1". Journal of the American Chemical Society. 83 (9): 2200. doi:10.1021/ja01470a040.
56. Coleman, J. S.; Keenan, T. K.; Jones, L. H.; Carnall, W. T.; Penneman, R. A. (1963). "Preparation and Properties of Americium(VI) in Aqueous Carbonate Solutions". Inorganic Chemistry. 2: 58. doi:10.1021/ic50005a017.
57. Asprey, L. B.; Stephanou, S. E.; Penneman, R. A. (1951). "Hexavalent Americium". Journal of the American Chemical Society. 73 (12): 5715. doi:10.1021/ja01156a065.
58. Wiberg, p. 1956
59. Werner, L. B.; Perlman, I. (1951). "The Pentavalent State of Americium". Journal of the American Chemical Society. 73: 495. doi:10.1021/ja01145a540. hdl: 2027/mdp.39015086479774 .
60. Hall, G.; Markin, T. L. (1957). "The self-reduction of americium(V) and (VI) and the disproportionation of americium(V) in aqueous solution". Journal of Inorganic and Nuclear Chemistry. 4 (5–6): 296. doi:10.1016/0022-1902(57)80011-6.
61. Coleman, James S. (1963). "The Kinetics of the Disproportionation of Americium(V)". Inorganic Chemistry. 2: 53. doi:10.1021/ic50005a016.
62. Greenwood, p. 1275
63. Asprey, L. B.; Stephanou, S. E.; Penneman, R. A. (1950). "A New Valence State of Americium, Am(Vi)1". Journal of the American Chemical Society. 72 (3): 1425. doi:10.1021/ja01159a528.
64. Akimoto, Y. (1967). "A note on AmN and AmO". Journal of Inorganic and Nuclear Chemistry. 29 (10): 2650–2652. doi:10.1016/0022-1902(67)80191-X.
65. Wiberg, p. 1972
66. Greenwood, p. 1267
67. Penneman, p. 5
68. Wiberg, p. 1969
69. Asprey, L. B.; Keenan, T. K.; Kruse, F. H. (1965). "Crystal Structures of the Trifluorides, Trichlorides, Tribromides, and Triiodides of Americium and Curium". Inorganic Chemistry. 4 (7): 985. doi:10.1021/ic50029a013. S2CID   96551460.
70. Baybarz, R. D. (1973). "The preparation and crystal structures of americium dichloride and dibromide". Journal of Inorganic and Nuclear Chemistry. 35 (2): 483. doi:10.1016/0022-1902(73)80560-3.
71. Greenwood, p. 1272
72. Asprey, L. B. (1954). "New Compounds of Quadrivalent Americium, AmF₄, KAmF₅". Journal of the American Chemical Society. 76 (7): 2019. doi:10.1021/ja01636a094.
73. Greenwood, p. 1271
74. Penneman, p. 6
75. Burns, John H.; Peterson, Joseph Richard (1971). "Crystal structures of americium trichloride hexahydrate and berkelium trichloride hexahydrate". Inorganic Chemistry. 10: 147. doi:10.1021/ic50095a029.
76. Damien, D.; Jove, J. (1971). "Americium disulfide and diselenide". Inorganic and Nuclear Chemistry Letters. 7 (7): 685. doi:10.1016/0020-1650(71)80055-7.
77. Roddy, J. (1974). "Americium metallides: AmAs, AmSb, AmBi, Am3Se4, and AmSe2". Journal of Inorganic and Nuclear Chemistry. 36 (11): 2531. doi:10.1016/0022-1902(74)80466-5.
78. Damien, D. (1972). "Americium tritelluride and ditelluride". Inorganic and Nuclear Chemistry Letters. 8 (5): 501. doi:10.1016/0020-1650(72)80262-9.
79. Charvillat, J.; Damien, D. (1973). "Americium monoarsenide". Inorganic and Nuclear Chemistry Letters. 9 (5): 559. doi:10.1016/0020-1650(73)80191-6.
80. Weigel, F.; Wittmann, F.; Marquart, R. (1977). "Americium monosilicide and "disilicide"". Journal of the Less Common Metals. 56: 47. doi:10.1016/0022-5088(77)90217-X.
81. Lupinetti, A. J. et al. U.S. patent 6,830,738 "Low-temperature synthesis of actinide tetraborides by solid-state metathesis reactions", Filed 4 Apr 2002, Issued 14 December 2004
82. Eick, Harry A.; Mulford, R. N. R. (1969). "Americium and neptunium borides". Journal of Inorganic and Nuclear Chemistry. 31 (2): 371. doi:10.1016/0022-1902(69)80480-X.
83. Elschenbroich, Christoph (2008). Organometallchemie. Vieweg+teubner Verlag. p. 589. ISBN   978-3-8351-0167-8.
84. Albrecht-Schmitt, Thomas E. (2008). Organometallic and Coordination Chemistry of the Actinides. Springer. p. 8. ISBN   978-3-540-77836-3.
85. Dutkiewicz, Michał S.; Apostolidis, Christos; Walter, Olaf; Arnold, Polly L. (30 January 2017). "Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding". Chemical Science. 2017 (8): 2553–61. doi:10.1039/C7SC00034K. PMC   5431675 . PMID   28553487.
86. Girnt, Denise; Roesky, Peter W.; Geist, Andreas; Ruff, Christian M.; Panak, Petra J.; Denecke, Melissa A. (2010). "6-(3,5-Dimethyl-1H-pyrazol-1-yl)-2,2'-bipyridine as Ligand for Actinide(III)/Lanthanide(III) Separation" (PDF). Inorganic Chemistry. 49 (20): 9627–35. doi:10.1021/ic101309j. PMID   20849125.
87. Toeniskoetter, Steve; Dommer, Jennifer and Dodge, Tony The Biochemical Periodic Tables – Americium, University of Minnesota, Retrieved 28 November 2010
88. Dodge, C.J.; et al. (1998). "Role of Microbes as Biocolloids in the Transport of Actinides from a Deep Underground Radioactive Waste Repository". Radiochim. Acta. 82: 347–354. doi:10.1524/ract.1998.82.special-issue.347. S2CID   99777562.
89. MacAskie, L. E.; Jeong, B. C.; Tolley, M. R. (1994). "Enzymically accelerated biomineralization of heavy metals: application to the removal of americium and plutonium from aqueous flows". FEMS Microbiology Reviews. 14 (4): 351–67. doi: 10.1111/j.1574-6976.1994.tb00109.x . PMID   7917422.
90. Wurtz, E. A.; Sibley, T. H.; Schell, W. R. (1986). "Interactions of Escherichia coli and marine bacteria with 241Am in laboratory cultures". Health Physics. 50 (1): 79–88. doi:10.1097/00004032-198601000-00007. PMID   3511007.
91. Francis, A.J.; et al. (1998). "Role of Bacteria as Biocolloids in the Transport of Actinides from a Deep Underground Radioactive Waste Repository". Radiochimica Acta. 82: 347–354. doi:10.1524/ract.1998.82.special-issue.347. OSTI   2439. S2CID   99777562.
92. Liu, N.; Yang, Y.; Luo, S.; Zhang, T.; Jin, J.; Liao, J.; Hua, X. (2002). "Biosorption of 241Am by Rhizopus arrihizus: preliminary investigation and evaluation". Applied Radiation and Isotopes. 57 (2): 139–43. doi:10.1016/s0969-8043(02)00076-3. PMID   12150270.
93. Pfennig, G.; Klewe-Nebenius, H and Seelmann Eggebert, W. (Eds.): Karlsruhe nuclide, 7 Edition 2006.
94. Dias, H.; Tancock, N. & Clayton, A. (2003). "Critical Mass Calculations for ²⁴¹Am, ^242mAm and ²⁴³Am" (PDF). Nippon Genshiryoku Kenkyujo JAERI: 618–623. Archived from the original (PDF) on 22 July 2011. Abstract Archived 13 March 2012 at the Wayback Machine
95. Institut de Radioprotection et de Sûreté Nucléaire, "Evaluation of nuclear criticality safety data and limits for actinides in transport", p. 16.
96. Ronen, Y.; Aboudy, M. & Regev, D. (2000). "A novel method for energy production using ^242mAm as a nuclear fuel". Nuclear Technology. 129 (3): 407–417. Bibcode:2000NucTe.129..407R. doi:10.13182/nt00-a3071. S2CID   91916073.
97. Ronen, Y.; Aboudy, M. & Regev, D. (2001). "Homogeneous ^242mAm-Fueled Reactor for Neutron Capture Therapy". Nuclear Science and Engineering. 138 (3): 295–304. Bibcode:2001NSE...138..295R. doi:10.13182/nse01-a2215. OSTI   20804726. S2CID   118801999.
98. Klinck, Christian. "α-decay of ²⁴¹Am. Theory – A lecture course on radioactivity". University of Technology Kaiserslautern. Archived from the original on 6 July 2011. Retrieved 28 November 2010.
99. "Smoke Detectors and Americium", Nuclear Issues Briefing Paper, vol. 35, May 2002, archived from the original on 11 September 2002, retrieved 26 August 2015
100. Residential Smoke Alarm Performance, Thomas Cleary. Building and Fire Research Laboratory, National Institute of Standards and Technology; UL Smoke and Fire Dynamics Seminar. November 2007
101. Bukowski, R. W. et al. (2007) Performance of Home Smoke Alarms Analysis of the Response of Several Available Technologies in Residential Fire Settings Archived 22 August 2010 at the Wayback Machine , NIST Technical Note 1455-1
102. "Smoke detectors and americium-241 fact sheet" (PDF). Canadian Nuclear Society. Archived from the original (PDF) on 25 March 2016. Retrieved 31 August 2009.
103. Gerberding, Julie Louise (2004). "Toxicological Profile For Americium" (PDF). United States Department of Health and Human Services/Agency for Toxic Substances and Disease Registry. Archived (PDF) from the original on 6 September 2009. Retrieved 29 August 2009.
104. Basic elements of static RTGs Archived 15 February 2013 at the Wayback Machine , G.L. Kulcinski, NEEP 602 Course Notes (Spring 2000), Nuclear Power in Space, University of Wisconsin Fusion Technology Institute (see last page)
105. Space agencies tackle waning plutonium stockpiles, Spaceflight now, 9 July 2010
106. "Extremely Efficient Nuclear Fuel Could Take Man To Mars in Just Two Weeks". ScienceDaily . 3 January 2001. Archived from the original on 17 October 2007. Retrieved 22 November 2007.
107. Kammash, T.; et al. (10 January 1993). "An americium-fueled gas core nuclear rocket" (PDF). AIP Conf. Proc. Tenth symposium on space nuclear power and propulsion. Vol. 271. pp. 585–589. doi:10.1063/1.43073. hdl: 2027.42/87734 .
108. Ronen, Y.; Shwageraus, E. (2000). "Ultra-thin 242mAm fuel elements in nuclear reactors". Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 455 (2): 442. Bibcode:2000NIMPA.455..442R. doi:10.1016/S0168-9002(00)00506-4.
109. Genuth, Iddo Americium Power Source Archived 7 May 2010 at the Wayback Machine , The Future of Things, 3 October 2006, Retrieved 28 November 2010
110. "UK scientists generate electricity from rare element to power future space missions". National Nuclear Laboratory . 3 May 2019. Retrieved 3 May 2019.
111. "Rare element could power distant space missions". E&T Engineering and Technology. Institution of Engineering and Technology. 3 May 2019. Retrieved 3 May 2019.
112. Binder, Harry H. (1999). Lexikon der chemischen Elemente: das Periodensystem in Fakten, Zahlen und Daten : mit 96 Abbildungen und vielen tabellarischen Zusammenstellungen. Hirzel. ISBN   978-3-7776-0736-8.
113. Nuclear Data Viewer 2.4 Archived 1 June 2017 at the Wayback Machine , NNDC
114. Public Health Statement for Americium Section 1.5., Agency for Toxic Substances and Disease Registry, April 2004, Retrieved 28 November 2010
115. Division of Environmental Health, Office of Radiation Protection (November 2002). "Fact Sheet # 23. Americium-241" (PDF). Archived from the original (PDF) on 11 November 2010. Retrieved 28 November 2010.
116. Frisch, Franz Crystal Clear, 100 x energy, Bibliographisches Institut AG, Mannheim 1977, ISBN   3-411-01704-X, p. 184
117. Ken Silverstein, The Radioactive Boy Scout: When a teenager attempts to build a breeder reactor. Harper's Magazine , November 1998
118. "'Radioactive Boy Scout' Charged in Smoke Detector Theft". Fox News. 4 August 2007. Archived from the original on 8 December 2007. Retrieved 28 November 2007.
119. "Man dubbed 'Radioactive Boy Scout' pleads guilty". Detroit Free Press. Associated Press. 27 August 2007. Archived from the original on 29 September 2007. Retrieved 27 August 2007.
120. "'Radioactive Boy Scout' Sentenced to 90 Days for Stealing Smoke Detectors". Fox News. 4 October 2007. Archived from the original on 13 November 2007. Retrieved 28 November 2007.
121. Cary, Annette (25 April 2008). "Doctor remembers Hanford's 'Atomic Man'". Tri-City Herald. Archived from the original on 10 February 2010. Retrieved 17 June 2008.
122. AP wire (3 June 2005). "Hanford nuclear workers enter site of worst contamination accident". Archived from the original on 13 October 2007. Retrieved 17 June 2007.

Bibliography

• Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8.
• Penneman, R. A. and Keenan T. K. The radiochemistry of americium and curium, University of California, Los Alamos, California, 1960
• Wiberg, Nils (2007). Lehrbuch Der Anorganischen Chemie. De Gruyter. ISBN   978-3-11-017770-1.

Further reading

• Nuclides and Isotopes – 14th Edition, GE Nuclear Energy, 1989.
• Fioni, Gabriele; Cribier, Michel & Marie, Frédéric. "Can the minor actinide, americium-241, be transmuted by thermal neutrons?". Commissariat à l'énergie atomique. Archived from the original on 11 November 2007.
• Stwertka, Albert (1999). A Guide to the Elements . Oxford University Press, USA. ISBN   978-0-19-508083-4.

External links

• Americium at The Periodic Table of Videos (University of Nottingham)
• ATSDR – Public Health Statement: Americium
• World Nuclear Association – Smoke Detectors and Americium